WO1997044506A1 - Generateurs de gaz hydrogene - Google Patents

Generateurs de gaz hydrogene Download PDF

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Publication number
WO1997044506A1
WO1997044506A1 PCT/JP1996/001337 JP9601337W WO9744506A1 WO 1997044506 A1 WO1997044506 A1 WO 1997044506A1 JP 9601337 W JP9601337 W JP 9601337W WO 9744506 A1 WO9744506 A1 WO 9744506A1
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WO
WIPO (PCT)
Prior art keywords
water
hydrogen gas
tank
electrolytic
gas generator
Prior art date
Application number
PCT/JP1996/001337
Other languages
English (en)
Japanese (ja)
Inventor
Satoru Miyata
Original Assignee
World Fusion Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by World Fusion Co., Ltd. filed Critical World Fusion Co., Ltd.
Priority to AU36098/97A priority Critical patent/AU3609897A/en
Priority to PCT/JP1996/001337 priority patent/WO1997044506A1/fr
Publication of WO1997044506A1 publication Critical patent/WO1997044506A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to a hydrogen gas generator, the purpose of which is to efficiently decompose water, to produce high-purity hydrogen gas for fuel in a suitable manner, to be easily miniaturized, and to produce hydrogen gas.
  • the present invention relates to a hydrogen gas generator capable of easily controlling the generation amount of hydrogen. Background art
  • Hydrogen gas is considered as one of the alternative energies, but conventionally used hydrogen gas generators cannot be suitably used.
  • An example of a conventionally used hydrogen gas generator is “Method and Apparatus for Generating Oxygen and Hydrogen Gas” disclosed in Japanese Patent Publication No. 57-8787.
  • This technology (1) has an anode and a cathode connected to each terminal, and has at least one electrolytic cell adapted to contain an aqueous electrolyte solution that generates a mixture of hydrogen and oxygen when operated. And (2) 1) a container into which the electrolyte is to be filled, 2) an electrode mechanism in the container having at least one pair of electrodes spaced apart, 3) a direction in which the electrolytic mechanism has a vertical member And has a portion adjacent to the bottom of the container.
  • This device is capable of generating hydrogen by electrolyzing water ⁇ . Degrees is not efficiently cooled, thus the high voltage electrode or the like is heated when applied to the device, the water to be electrolyzed by this heat may decrease significantly electrolysis efficiency will evaporate as the steam. For this reason, high voltage cannot be applied to this device, and after all, this device is not an efficient hydrogen generator.
  • a hydrogen generator As a technology for generating a large amount of hydrogen, there is a “hydrogen generator” disclosed in Japanese Patent Publication No. 63-3955.
  • This technology includes an electrolytic cell containing water, a pair of electrodes opposed to the electrolytic cell at a predetermined interval, and a power supply connected between the pair of electrodes.
  • the negative electrode connected to the negative electrode of the power supply is made of a porous body for the i-part or all of it, and on the surface of the electrode, it undergoes a chemical reaction with water to generate hydrogen and generates hydrogen.
  • a hydrogen generator is characterized in that it has a chemical reaction layer formed of a substance that produces a hydroxide.
  • this device when this device is used for the first time, it generates a hydrogen by generating a chemical reaction with water, which is provided on the surface of the chemical reaction tank.
  • the amount of hydrogen generated is increased by the amount of ⁇ substances that produce hydroxides when produced '', but from the second use, it is no different from the amount of hydrogen generated by ordinary electrolyzers, and an efficient hydrogen generator is not.
  • the electrolytic reaction occurs on the surface of the electrode, but the reaction speed is initially high because the porous body has a large surface area, but the air generated by the electrolysis accumulates in the micropores in the electrode, so that it is over time.
  • the reaction speed is reduced, and as a result, the electrode is not efficient. Disclosure of the invention
  • the invention described in claim 1 is a hydrogen gas generator that has an electrolysis unit and an ink tank, and obtains hydrogen gas by electrolyzing water, wherein the electrolysis unit is made of a conductive member. It has an electrolytic plate and an interposed body made of an insulating member interposed between the electrolytic plates. An electrolytic chamber formed of the electrolytic plate and the interposed body is formed in the electrolytic section, and water in the tank is supplied with a liquid feed pipe.
  • a hydrogen gas generator that can feed water into the electrolytic section through a liquid inlet provided in the electrolytic plate through the through hole and that electrolyze water in the electrolytic chamber, the shape of the contact surface of the electrolytic plate with water is uneven.
  • the hydrogen gas generator according to claim 2 wherein at least a part of the unevenness is provided with an acute angle portion. Powder is dispersed in the powder. Hydrogen gas generator.
  • the invention according to claim 3 is the hydrogen gas generator according to claim 2, wherein the infrared radiation ceramic is tolumarin.
  • the invention described in claim 4 is the hydrogen gas generator according to any one of claims i to claim 3, wherein a microbial antioxidant is dispersed in water to be electrolyzed. is there.
  • the invention according to claim 5 is characterized in that, in one of the end electrolytic plates, a liquid inlet for introducing water into the electrolytic portion is provided, and in the other end electrolytic plate, water is supplied to the electrolytic portion.
  • a return liquid hole to send out the inlet hole and the tank are connected and connected via a liquid feed pipe, and the return liquid hole and the ink tank are connected and connected via a return liquid pipe.
  • an annular path is formed in which water in the tank enters the electrolytic section through the liquid feed pipe and water in the electrolytic section returns to the tank through the return liquid pipe, and a drive for circulating water in the circulation path is formed.
  • the hydrogen gas generator according to any one of claims 1 to 4, further comprising means.
  • the invention according to claim 6 is characterized in that the electrolysis section is provided with vent holes for sending out hydrogen gas generated in the electrolysis chamber to the outside of the electrolysis section, the kunk is provided with air inlet holes, and the electrolysis section is provided with an air vent.
  • the air hole and the air inlet of the tank are connected to each other via an air supply pipe, and an air outlet pipe for releasing hydrogen gas in the tank is provided above the tank, that is, an air outlet, an air supply pipe, an air inlet, and a tank.
  • the hydrogen gas generator according to any one of claims 1 to 5, wherein the hydrogen gas generator has an air outlet path including an air outlet pipe.
  • FIG. 1 is a sectional view showing a first embodiment of the hydrogen gas generator of the present invention.
  • FIG. 2 is a perspective view showing an example of the electrolytic plate used in the present invention
  • FIG. 3 is a sectional view thereof.
  • FIG. 4 is a perspective view showing another example of the electrolytic plate used in the present invention
  • FIG. 5 is a sectional view thereof.
  • FIG. 6 is a perspective view showing another example of the electrolytic plate used in the present invention
  • FIG. 7 is a sectional view thereof.
  • FIG. 8 is a sectional view showing a second embodiment of the hydrogen gas generator of the present invention.
  • FIG. 1 is a schematic view showing a first embodiment of the present invention.
  • the hydrogen gas generator (1) in the first embodiment is a hydrogen gas generator (1) which comprises an electrolysis section (2) and a tank section (3) and obtains hydrogen gas by electrolyzing water.
  • the electrolytic part (2) has an electrolytic plate (4) made of a conductive member and an interposed body (11) made of an insulating member interposed between the electrolytic plates (4).
  • An electrolytic chamber (12) comprising an electrolytic plate (4) and an interposed body (11) is formed, and the electrolytic plate (4) and the interposed body (11) are fixed by fixing means (26). Is defined.
  • the water sent from the tank (14) passes through the liquid feed pipe (15) and enters the electrolysis chamber (12) from the liquid inlet (5).
  • the shape of the contact surface of the electrolytic plate (4) with water is uneven, and an acute angle portion (24) is provided.
  • a current supply means (13) is provided for each of the two electrolytic plates (4), and water is electrolyzed in the electrolytic chamber (12) by passing a current between the electrolytic plates (4). I have.
  • the shape of the surface of the electrolytic plate (4) is not particularly limited as long as it is an uneven shape having an acute angle portion (24), and examples thereof include a shape provided with grooves, ridges, projections, depressions, and the like on the surface.
  • Figs. 2 and 3 show an example in which a large number of protrusions (8) were provided on the surface of the electrolytic plate (4). It is the perspective view and sectional drawing of an Example.
  • the projection (8) has a shape combining a cylinder and a cone.
  • the projections (8) provided on the upper portion of the electrolytic plate (4) be slightly smaller than the projections (8) provided on the lower portion. New This is because the risk that hydrogen gas generated from the lower protrusion (8) adheres to the upper protrusion (8) is reduced.
  • FIGS. 4 and 5 are a perspective view and a cross-sectional view of the electrolytic plate (4) provided with the ridge (9) on the surface.
  • the groove (10) ⁇ ridge (9) is provided on the surface of the electrolytic plate (4)
  • the groove (1 ()) ⁇ of the ridge (9) is provided so as to be longer in the vertical direction. Hydrogen gas bubbles generated in the lower part of the electrolytic plate (4) are preferable because the risk of adhering to the upper part of the electrolytic plate (4) is reduced.
  • the present invention also includes an electrolytic plate (4) provided with ridges (9) and grooves (10) so as to be longer in the left-right direction.
  • 6 and 7 are a perspective view and a cross-sectional view of an electrolytic plate (4) provided on the surface with ridges (9) and grooves (10) which are long in the left-right direction.
  • the surface is made uneven by deforming the bridging part of (4).
  • the surface of the electrolytic plate (4) may be provided with a bevel.
  • a window it is preferable that the depth of the depression is smaller than the diameter of the depression, because the risk of hydrogen gas accumulating in the depression is reduced.
  • the irregularities on the surface of the electrolytic plate (4) have the effect of increasing the surface area of the electrolytic plate (4), thereby increasing the electrolysis speed and increasing the amount of hydrogen gas generated.
  • the formation of an acute angle portion (24) in part of the unevenness further increases the amount of hydrogen gas generated. That is, the sharp corner (24) acts to rapidly electrolyze water.
  • FIG. 8 is a sectional view showing a second embodiment of the present invention.
  • water is stored in the tank (14), and this water is passed through the liquid supply pipe (15) and electrolyzed.
  • the liquid is sent to the section (2).
  • a return pipe (16) is connected to the tank section (3) used in the second embodiment, and an electrolytic chamber (1) is connected from the return pipe (16) to the tank (14). 2) The warmed water flows inside.
  • an air supply pipe (17) is provided in the tank (14) used in the second embodiment, and an air supply pipe (18) is provided above the tank (14). I have.
  • the shape and size of the tank (14) are not particularly limited, and can be arbitrarily set according to the required amount of hydrogen gas and the like.
  • the tank (14) is provided with a cooling device or a stirring device.
  • a cooling device or a stirring device is preferable.
  • the tank (14) is degraded with time.
  • a cooling device and a stirrer are preferable because the inside temperature rises.
  • the tank (14) is provided with a level gauge (20).
  • the pressure in the electrolysis chamber (12) is substantially equal to the pressure in the tank (14), and the pressure is provided in the tank (14).
  • the level gauge (20) is more preferable because it indicates the height of the water in the electrolysis chamber (12).
  • a filter (19) is provided in the tank (14), and the air supply pipe (17) power, the tank (14) is provided. It is also preferable that the hydrogen gas flowing into the tank passes through the filter (9) and is discharged from the air supply pipe (18) to the outside of the tank (14).
  • the hydrogen gas generated in the electrolysis chamber (12) may contain water droplets and the like. It is preferable to provide such a device because it is possible to catch such water droplets.
  • the filter (19) is provided in the tank (14)
  • the captured water drops fall into the tank (14) and are together with the water transferred to the electrolysis chamber (12). Therefore, water can be electrolyzed without waste, and it is not necessary to provide a separate water drop receiver.
  • a hydrogen gas generator (1) without a filter (19) is also included in the present invention.
  • far-infrared radiation ceramic powder is dispersed in water to be electrolyzed.
  • the substance dispersed in the water to be electrolyzed is not particularly limited as long as it is a ceramic powder that emits far-infrared rays, and examples thereof include titanium dioxide, silica, and alumina.
  • the reason that the far-infrared radiation ceramic powder is dispersed in the water to be electrolyzed is that this increases the electrolysis speed of the water. That is, the present invention is based on the experimental viewpoint that far-infrared radiation ceramic powder increases the electrolysis rate of water.
  • the reason that the far-infrared radiation ceramic powder increases the rate of electrolysis of water is as follows. In other words, far-infrared rays make the clusters of water molecules finer, and the finer clusters move actively in the electrolysis chamber (12), and the water molecules in the clusters appear on the surface of the electrolytic plate (4) at a higher frequency. Therefore, the electrolysis rate is thought to increase.
  • the amount of the far-infrared radiation ceramic powder used in the present invention is not particularly limited, and an amount that can achieve the effects of the present invention can be appropriately determined and used.
  • water is electrolyzed to generate hydrogen gas
  • the water is electrolyzed into hydrogen and oxygen and released from the electrolytic cell, but the far-infrared radiation ceramic powder remains in the electrolysis section (2). However, it is not necessary to re-introduce far-infrared radiation ceramic powder when replenishing water for electrolysis to the evening tank (14).
  • tolmarin powder can be particularly preferably used.
  • Tourmaline also known as tourmaline, is an ore produced in Brazil, China, the Urals, Sri Lanka, California, Madagascar, and so on.
  • tolmarin is 3 (NaX 3 Al fi (Bo 3 ) 3 Si e 0 16 (01iF) 4 ) (where X is Mg, Fe, Li.Al, etc.).
  • X is Mg, Fe, Li.Al, etc.
  • piezoelectric and pyroelectric charging phenomena There are more known piezoelectric and pyroelectric charging phenomena.
  • the inventor of the present invention has found that a slight amount of hydrogen gas is generated from water simply by throwing the tormarin powder into water.
  • the inventors of the present invention discovered that when tolmarin powder was introduced into a water electrolysis apparatus, the electrolysis efficiency was significantly increased, and the present invention was reached.
  • the amount of tolmarin powder used in the present invention is not particularly limited, and an amount that can achieve the effect of the present invention can be appropriately determined and used.
  • a microbial antioxidant is dispersed in water to be electrolyzed.
  • EM bacteria Since the microbial antioxidant used in the present invention is secreted from so-called EM bacteria, as a means for dispersing the microbial antioxidant in water, the EM bacteria itself may be dispersed in water.
  • EM bacteria were recently developed by Professor Teruo Higa of the University of the Ryukyus, and are a complex culture solution in which about 80 types of microorganisms such as lactic acid bacteria, yeast, and photosynthetic bacteria are collected and coexist. To date, EM bacteria have been shown to improve soil in the field of agriculture, remove odor from manure in the livestock industry, and reduce garbage. However, there was no example of use in an apparatus that generates hydrogen gas by electrolyzing water.
  • the circulation path (23) is a path through which water flows in the present invention.
  • the circulation path (23) is a tank (14) from the inside of the tank (14) through the liquid feed pipe (15), enters the electrolysis section (2), and then returns the return liquid pipe (16) from the electrolysis section (' ⁇ ). This is a route that flows back to the tank (14).
  • water is first retained in the tank (14) by II, and then transferred to the electrolytic section (2) through the liquid sending pipe (15). Some of this water is electrolyzed in the electrolysis section (2), and the rest of the water moves through the electrolysis section (2) while absorbing the heat generated in the electrolysis plate (4), and returns water ( b ') exits through the reflux pipe and returns to evening (14).
  • a drive means (25) is provided in a part of the circulation path (23).
  • the drive means (25) is not particularly limited, and a pump used for ordinary liquid transfer is suitably used.
  • a stirring device is provided in the tank (14).
  • the stirring device also serves as the driving means (25). That is, the ⁇ ⁇ device in this embodiment urges water downward. Therefore, the water circulates in the circulation path (23) with the force of the stirring device.
  • the circulation path (23) has an action of preventing water vapor from being mixed into the hydrogen gas even when a large amount of the hydrogen gas is generated. That is, when a large amount of hydrogen gas is generated from the hydrogen gas generator (1) of the present invention, it is necessary to apply a high voltage to the electrolysis chamber (12). In this case, the electrolysis plate (4) also generates heat. (12) The water temperature in the inside rises.
  • the circulation path (23) in the present invention is used to discharge hot water from the electrolysis chamber (12) and to flow cold water in the evening tank (14) into the electrolysis chamber (12). This prevents the temperature of water in the electrolysis chamber (12) from rising due to the heat generated by the water, thereby preventing the generation of water. That is, in the hydrogen gas generator (1) having the circulation path (23), since steam is not generated even when a high voltage is applied for a long time, water vapor is not mixed into the generated hydrogen gas.
  • the outflow path (22) in the present invention is a path through which hydrogen gas generated in the electrolysis chamber (12) flows. That is, the outflow path (2 2) is defined as the outflow hole (7) of the electrolysis chamber (12), passes through the air supply pipe (17), passes through the popular hole of the tank (14), and is closed (1 4). This is the route that goes inside and passes through the air supply pipe (18) to the hydrogen gas usage site.
  • the inlet of the tank (14) is above the water surface, but the invention is included in the present invention even if the inlet is provided below the water surface. If the air inlet is provided below the water surface, hydrogen gas will go under the water, so even if this hydrogen gas contains water droplets, these water droplets will be captured by the water in the tank (14). It is preferable.
  • a barometer (21) is provided in the outlet path (22).
  • the outflow path (22) is used for generating a large amount of hydrogen gas. In any case, it has the effect of stabilizing the amount of hydrogen gas generated.
  • the outlet path (22) makes the pressure in the electrolysis chamber (12) almost equal to the pressure in the tank (14), the amount of hydrogen gas generated increases, and the pressure in the electrolysis chamber (12) increases.
  • the water in the electrolysis chamber (12) does not flow back into the tank (14) even when the cell size increases, and the contact area of the electrolysis plate (4) and water in the electrolysis chamber (12) changes greatly. Therefore, the amount of generated hydrogen gas is stabilized.
  • Three types of hydrogen gas generators according to the present invention were created, each of which was designated as Units 1 to 3, and the amount of generated hydrogen gas, power consumption, generated gas pressure, and water consumption were measured.
  • Body weight 2 5 1 2 0 3 4 6
  • the hydrogen gas generator according to the present invention is small and can generate a large amount of hydrogen gas, it is used as an industrial gas fuel generator for welding or boilers. It can also be used as a fuel for burning garbage and the like.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Un générateur de gaz hydrogène tel que défini dans la revendication 1 comporte une plaque électrolytique présentant une surface irrégulière en contact avec de l'eau, et une partie de ces irrégularités présente des arêtes vives, de sorte que l'électrolyse peut être effectuée rapidement et son efficacité s'en trouve améliorée. Un générateur de gaz hydrogène tel que défini dans la reventdication 2 ou 3 contient une dispersion de poudre céramique ou de tourmaline à rayonnement dans l'infrarouge lointain, de sorte qu'une grappe de molécules d'eau est atomisée pour ainsi activer l'électrolyse et améliorer son efficacité. Un générateur de gaz hydrogène tel que défini dans la revendication 4 contient une dispersion d'un antioxydant microbien dans l'eau à électrolyser, de manière à empêcher le dépôt de contaminants sur la plaque électrolytique et l'érosion de la plaque elle-même par oxydation, et l'efficacité de l'électrolyse n'est pas diminuée même après un certain temps. Un générateur de gaz hydrogène tel que défini dans la revendication 5 comporte un circuit de circulation où l'eau contenue dans le réservoir pénètre dans la section électrolytique par une tuyau d'alimentation en liquide tandis que l'eau contenue dans la section électrolytique revient au réservoir par un tuyau de reflux. Ce générateur est également pourvu de moyens d'entraînement pour faire circuler l'eau dans le circuit, de sorte que l'intérieur de la chambre électrolytique peut être avantageusement refroidi, l'eau pouvant être ainsi avantageusement électrolysée. Un générateur de gaz hydrogène tel que défini dans la revendication 6 possède un circuit de dégazage comprenant une admission de gaz, un tuyau d'émission de gaz, une admission de gaz, un réservoir et un tuyau de dégazage, de sorte que l'eau contenue dans la chambre électrolytique ne reflue pas vers le réservoir, même lorsque la pression de gaz dans la chambre est accrue, l'eau pouvant être ainsi avantageusement électrolysée.
PCT/JP1996/001337 1996-05-20 1996-05-20 Generateurs de gaz hydrogene WO1997044506A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU36098/97A AU3609897A (en) 1996-05-20 1996-05-20 Hydrogen gas generators
PCT/JP1996/001337 WO1997044506A1 (fr) 1996-05-20 1996-05-20 Generateurs de gaz hydrogene

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Application Number Priority Date Filing Date Title
PCT/JP1996/001337 WO1997044506A1 (fr) 1996-05-20 1996-05-20 Generateurs de gaz hydrogene

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WO1997044506A1 true WO1997044506A1 (fr) 1997-11-27

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Cited By (6)

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KR100862923B1 (ko) 2008-07-14 2008-10-13 황부성 수소산소 혼합가스 발생시스템
JP2009091650A (ja) * 2007-10-04 2009-04-30 Samsung Electro-Mechanics Co Ltd 水素発生装置及びこれを備えた燃料電池発電システム
WO2010119679A1 (fr) * 2009-04-15 2010-10-21 パナソニック株式会社 Dispositif de génération d'hydrogène
JP4598868B1 (ja) * 2009-08-08 2010-12-15 優章 荒井 電解装置、水素の製造方法、水素、内燃機関システム、燃焼システムおよび燃料電池システム
CN103456975A (zh) * 2012-05-31 2013-12-18 佛山市顺德区雷动能源科技有限公司 水催化产氢发电的方法及设备
CN112960826A (zh) * 2021-02-08 2021-06-15 山东军浩苑环保科技有限公司 一种离子水生成装置及生成方法

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JPS5344485A (en) * 1976-10-05 1978-04-21 Asahi Glass Co Ltd Electrode
JPS63250481A (ja) * 1987-04-08 1988-10-18 Hitachi Ltd 水素酸素発生装置

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Title
FOOD & DEVELOPMENT, Vol. 26, No. 7, July 1991, (Tokyo), TETSUJIRO KUBO, "The Surface Activity of Water Made by Tourmaline and its Application", pages 21-24. *
TAKEO MATSUNO, SHUKUJI ASAKURA Authers, "Electro-Chemistry", DAINIPPON TOSHO K.K., 15 May 1976, pages 155-159. *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009091650A (ja) * 2007-10-04 2009-04-30 Samsung Electro-Mechanics Co Ltd 水素発生装置及びこれを備えた燃料電池発電システム
KR100862923B1 (ko) 2008-07-14 2008-10-13 황부성 수소산소 혼합가스 발생시스템
WO2010119679A1 (fr) * 2009-04-15 2010-10-21 パナソニック株式会社 Dispositif de génération d'hydrogène
CN102369312A (zh) * 2009-04-15 2012-03-07 松下电器产业株式会社 氢气生成装置
CN102369312B (zh) * 2009-04-15 2014-11-05 松下电器产业株式会社 氢气生成装置
JP5651584B2 (ja) * 2009-04-15 2015-01-14 パナソニックＩｐマネジメント株式会社 水素生成デバイス
JP4598868B1 (ja) * 2009-08-08 2010-12-15 優章 荒井 電解装置、水素の製造方法、水素、内燃機関システム、燃焼システムおよび燃料電池システム
JP2011058028A (ja) * 2009-08-08 2011-03-24 Masaaki Arai 電解装置、水素の製造方法、水素、内燃機関システム、燃焼システムおよび燃料電池システム
CN103456975A (zh) * 2012-05-31 2013-12-18 佛山市顺德区雷动能源科技有限公司 水催化产氢发电的方法及设备
CN112960826A (zh) * 2021-02-08 2021-06-15 山东军浩苑环保科技有限公司 一种离子水生成装置及生成方法

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