WO1997042411A1 - Reciprocating compressor - Google Patents

Reciprocating compressor

Info

Publication number
WO1997042411A1
WO1997042411A1 PCT/JP1996/001216 JP9601216W WO9742411A1 WO 1997042411 A1 WO1997042411 A1 WO 1997042411A1 JP 9601216 W JP9601216 W JP 9601216W WO 9742411 A1 WO9742411 A1 WO 9742411A1
Authority
WO
WIPO (PCT)
Prior art keywords
piston
reciprocating compressor
cam
tin
swash plate
Prior art date
Application number
PCT/JP1996/001216
Other languages
French (fr)
Japanese (ja)
Inventor
Masafumi Kato
Akichika Ito
Original Assignee
Kabushiki Kaisha Toyoda Jidoshokki Seisakusho
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=14153264&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1997042411(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kabushiki Kaisha Toyoda Jidoshokki Seisakusho filed Critical Kabushiki Kaisha Toyoda Jidoshokki Seisakusho
Priority to US08/981,695 priority Critical patent/US5943941A/en
Priority to PCT/JP1996/001216 priority patent/WO1997042411A1/en
Priority to EP96913701A priority patent/EP0838590B1/en
Priority to KR1019980700072A priority patent/KR100312933B1/en
Priority to DE69630689T priority patent/DE69630689T2/en
Publication of WO1997042411A1 publication Critical patent/WO1997042411A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • F04B27/0873Component parts, e.g. sealings; Manufacturing or assembly thereof
    • F04B27/0878Pistons
    • F04B27/0886Piston shoes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • F04B27/0873Component parts, e.g. sealings; Manufacturing or assembly thereof
    • F04B27/0878Pistons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/02Light metals
    • F05C2201/025Boron
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/04Heavy metals
    • F05C2201/0469Other heavy metals
    • F05C2201/0475Copper or alloys thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/04Heavy metals
    • F05C2201/0469Other heavy metals
    • F05C2201/0493Tin
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/04Phosphor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/08Ceramics; Oxides
    • F05C2203/0804Non-oxide ceramics
    • F05C2203/0856Sulfides
    • F05C2203/086Sulfides of molybdenum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2253/00Other material characteristics; Treatment of material
    • F05C2253/12Coating

Definitions

  • the present invention relates to a reciprocating compressor that converts the rotation of a driving pong into a reciprocating motion of a biston via a cam, and more specifically, reduces a sliding resistance generated at a link between a cam and a piston. It is related to the structure to perform. Background art
  • a reciprocating compressor as shown in FIG. 10 is known as a compressor used for an air conditioner of an automobile or the like.
  • This compressor includes a pair of cylinder blocks 30 and 31 joined to each other.
  • the swash plate chamber 32 is formed between the two cylinder blocks 30 and 31.
  • Housings 35.36 are joined to the outer end surfaces of the cylinder blocks 30 and 31 via valve plates 33 and 34, respectively.
  • the suction chamber 36 and the discharge chamber 37 are formed between the valve plates 33, 34 and the housings 35, 36.
  • the drive shaft 39 is rotatably supported by the cylinder blocks 30 and 31.
  • the swash plate 40 as a force is fixed to the drive shaft 39 in the swash plate chamber 32.
  • a plurality of pairs of cylinder bores 41 and 42 are formed in each of the cylinder blocks 30 and 31 around the drive shaft 39.
  • the double-headed bistone 43 is accommodated in each pair of cylinder bores 41 and 42, respectively.
  • Show 44 as a cam follower is arranged between swash plate 40 and piston 43.
  • the shroud 44 has an engaging surface 45 slidingly contacting the front and rear surfaces of the swash plate 40, and a spherical surface 47 slidably engaged with the holding recess 46 of the piston 43. .
  • the buttons 43 and the swash plate 40 are made of a lightweight aluminum alloy or the like, but the same kind of metal is liable to seize due to sliding.
  • the shower 44 arranged between the piston 43 and the swash plate 40 is formed of an iron-based metal in order to prevent seizure with the piston 43 and the swash plate 40. You. However, since ferrous metals have a large specific gravity, the size S of the compressor increases the weight S of the entire compressor.
  • the shower 44 can move smoothly along the inner surface of the holding recess 46. No longer. Since the shower 4 is moved in the holding recess 46 by the swash plate 40, if the shower 4 does not move smoothly, it acts between the sliding contact surface 45 of the shower 4 and the swash plate 40. The load increases, and the sliding resistance between the sliding contact surface 45 and the swash plate 40 further increases.
  • the refrigerant gas from the external refrigerant circuit is introduced into the suction chamber 37 through the swash plate chamber 32.
  • An object of the present invention is to provide a reciprocating compressor that can reduce sliding resistance generated at a connection between a cam and a piston. Disclosure of the invention
  • a compressor of the present invention includes a cylinder block having a cylinder bore.
  • the drive shaft is rotatably supported by the cylinder block.
  • the cam is mounted on the drive shaft so that it can rotate integrally.
  • the piston is housed in a cylinder bore with a sliding eye.
  • the cam follower is slidably disposed between the piston and the cam. With the rotation of the cam, the piston reciprocates via the force follower.
  • Bistone is formed using aluminum or an aluminum alloy as a base material.
  • the piston includes a holding portion that slidably holds the cam follower.
  • the holding section of the piston is provided with an S layer mainly composed of tin.
  • the sliding resistance between the retaining portion of the piston and the cam follower is reduced by the coating layer provided on the retaining portion of the piston. For this reason, the cam follower moves smoothly in the holding part of the biston even if the lubricating oil runs short in the compressor. Therefore, the cam can move the cam follower with a small force. As a result, the load acting between the cam follower and the cam is reduced, and the sliding resistance between the force follower and the cam is reduced.
  • FIG. 1 is an enlarged sectional view of a main part showing a swash plate type compressor according to a first embodiment of the present invention.
  • FIG. 2 is a perspective view showing a piston according to the first embodiment.
  • FIG. 3 is an enlarged cross-sectional view of a principal part of the piston.
  • FIG. 4 is a graph showing measurement results during burn-in B in the first embodiment.
  • FIG. 5 is an enlarged sectional view of a main part showing a slanting compressor according to a second embodiment of the present invention.
  • FIG. 6 is a graph showing the measurement result of the burn-in time in the second embodiment.
  • FIG. 7 is a cross-sectional view showing a wave-cam type compressor according to another embodiment of the present invention.
  • FIG. 8 is an enlarged sectional view of a main part showing a cam follower according to another embodiment of the present invention.
  • FIG. 9 is an enlarged sectional view of a main part showing a swash plate according to another embodiment of the present invention.
  • FIG. 10 is a sectional view showing a conventional swash plate type compressor. BEST MODE FOR CARRYING OUT THE INVENTION
  • FIGS. 10 a first embodiment of a swash plate type compressor embodying the present invention will be described with reference to FIGS.
  • the mechanical configuration of the compressor of the first embodiment is almost the same as the compressor shown in FIG. 10 described in the background art. Therefore, here, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals and the description thereof will be omitted, and only the portions different from the compressor of FIG. 10 will be described.
  • the compressor of the present embodiment is different from the compressor shown in FIG. 10 in that a piston 1 having a coating S 6 mainly composed of tin is formed on the entire surface.
  • the piston 1 includes a pair of holding concave portions 2 that slidably hold the spherical surface 47 of the shower 44.
  • the piston 1 is composed of a main body 5 made of aluminum or an aluminum alloy as a base material, and an employee 6 formed on the entire surface of the main body 5.
  • the aluminum alloy for example, A 1 —Si based alloy and ⁇ 1 —Si—Cu based alloy can be suitably used.
  • the base material of the main body 5 is preferably an aluminum alloy containing hard particles.
  • a typical example of such an aluminum alloy is an aluminum-high silicon alloy.
  • Aluminum-high silicon alloy contains about 10 to 30% by weight of silicon. Make sure that the aluminum-silicon alloy has a eutectic composition or less. With a high silicon content, silicon exists as eutectic silicon (that is, hard s particles).
  • the body 5 of the piston 1 is formed using an aluminum-high silicon alloy 4 containing 12% by weight of silicon 3 as a base material.
  • Other materials containing hard particles include A 1 -M n intermetallic compound, A] S i -M n intermetallic compound, A 1 -Fe-M n intermetallic compound, A 1 -Cr There are intermetallic compounds, and these may be used as a base material of the main body 5.
  • the case 44 is formed of SUJ2 material (high carbon chromium bearing steel) specified by JIS, and the swash plate 40 is formed of aluminum-high silicon alloy. I have.
  • the biston 1 used in the compressor of the first embodiment for example, it is possible to appropriately select and use one having various cover layers 6 shown in the following Examples 1 to 4.
  • the piston 1 of Example 1 to Example 1 will be sequentially described.
  • the pistons 1 of Examples I to II have the same configuration of the main body 5 and are different only in the configuration of the coating layer 6.
  • Bistone 1 of Example 2 has a coating layer 6 composed of a tin-copper tin-copper plating layer.
  • This coating layer 6 is formed as follows. That is, an aqueous solution containing 6% by weight of potassium stannate and 0.012% by weight of copper gluconate is maintained at 60 to 80 ° C., and the entire body 5 of bistone 1 is contained in the aqueous solution. After being pickled for about 3 minutes, the surface of the main body 5 is subjected to insolubility. Thereafter, the main body 5 is taken out of the aqueous solution and washed with water.
  • the coating layer 6 has a composition containing 97% of tin and 3% by weight of copper, and its thickness is set at 1.2 m.
  • the piston 1 of Example 1 has a coating layer 6 made of a eutectoid layer of tin and nickel. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% S% of nickel chloride, the holding M part 2 is included in the same manner as in Example 1 above. Tin and nickel are applied to the entire surface of the piston 1 to form a coating layer 6.
  • This coating layer 6 has a composition containing 98% by weight of tin and 2% by weight of nickel, and has a thickness of 1 ⁇ m.
  • Piston 1 in Example 3 has a toughness 6 consisting of eutectoid metal ⁇ of tin and zinc. That is, by using an aqueous solution containing 6% by weight of calcium stannate and 0.055% by weight of zinc sulfate, the surface of the bismuth 1 including the holding concave portion 2 was formed in the same manner as in Example 1 above. As a whole, tin and zinc are eutectoidally plated to form a worker 6.
  • the S 6 to be coated has a composition containing 97% by weight of tin and triplet of zinc, and its thickness can be reduced to 1 / m.
  • Example 1 has an a-layer 6 composed of an eutectoid plating layer of tin and lead.
  • the piston 1 including the holding recess 2 was formed in the same manner as in Example 1 above. Tin and lead are eutectoidally deposited on the entire surface to form the coating layer 6.
  • This covering eyebrow 6 has a composition containing 95% of the contact area and quintuple lead, and its thickness is 2.
  • Piston 1 of Example 1 has a coating layer 6 composed of a eutectoid mesolayer of tin and indium. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% by weight of indium sulfate, in the same manner as in Example 1 above, the bismuth 1 containing the holding recess 2 was used. Tin and indium are eutectoidally deposited on the entire surface of the steel sheet to form a coating 6.
  • the coating layer 6 has a composition containing 97% by weight of tin and 3% by weight of indium, and has a thickness of:
  • Example 1 has a boss 6 consisting of tin-only hiring. That is, by using an aqueous solution containing 6% by weight of sulfuric acid potassium, in the same manner as in Example 1 above, the entire surface of the piston 1 including the holding recess 2 was covered with a tin-only metal. A layer 6 consisting of layers is formed. The thickness of the coating layer 6 is 1. (Example 2)
  • Bistone 1 of Example 1 has a coating layer 6 containing a fluorine resin powder as a solid lubricant on a eutectoid layer of tin and copper. That is, by using an aqueous solution containing 6% by weight of potassium carbonate, 0.003% by weight of copper dalconate and 1.0% by weight of a fluororesin powder, the retention was carried out in the same manner as in Example 1 above. On the entire surface of the piston 1 including the concave portion 2, an ai-extension 6 including a fluorine resin powder in a co-folded pattern of tin and copper is formed.
  • This layer 6 has a composition containing 99% by weight of tin, 0.9% by weight of copper and 0.1% by weight of fluorinated resin powder, and has a thickness of 1.4 ⁇ m. ⁇ .
  • Example 1 has a coating layer 6 composed of an eutectoid metal layer of tin and copper as in Example 1 above. after the coating layer 6 is made form by 1 hour heat treatment at a temperature of 1 5 0 D C is subjected to the coating layer 6.
  • Piston 1 in Example I has a coating 6 consisting of a eutectoid metal brow of tin and net and zinc. That is, by using an aqueous solution containing 6% by weight of potassium stannate, 0.003% of copper gluconate and 0.003% by weight of zinc sulfate, the retention was carried out in the same manner as in Example 1 above.
  • a coating layer 6 made of eutectoid metal shield of tin, ⁇ and zinc is formed on the entire surface of the piston 1 including the recess 2, a coating layer 6 made of eutectoid metal shield of tin, ⁇ and zinc is formed.
  • the coating layer 6 has a composition of 97% by weight of tin, 1.5% by weight of copper and 1.5% by weight of zinc, and has a thickness of 1.2 m.
  • the inventors of the present application conducted the following tests in order to confirm the anti-seizure performance of each of the compressors incorporating the above-mentioned examples 1 to 4.
  • the swash plate 40 and the shroud 44 were used when each compressor incorporated in the vehicle air conditioner was operated under severe operating conditions (the state where lubricating oil was not present in the compressor). It measures the time it takes to burn.
  • each compressor was operated continuously at a suction pressure of -0.5 kg / cm z , a discharge pressure of 3 kg / cm 2 , and a rotation speed of the drive shaft 39 of l OOO rpm.
  • a compressor made of SUJ2 material specified in JIS was used as a compressor shroud 44, and aluminum was used as the compressor swash plate 40.
  • An alloy formed of an alloy was used.
  • bistons formed only of aluminum-high-silicon alloy 4 containing silicon 3 at 12% by weight, that is, bistons without the coating layer 6 were prepared as specific examples.
  • a similar test was performed on a compressor incorporating this piston.
  • Fig. 4 is a graph showing the results of this test. The test results shown in Fig. 4 show that the compressor adopting Biston 1 of Examples 1 to 4 above, which has the Hebrew calendar 6, is more severely used than the compressor employing Biston of Comparative Example.
  • the expression 6 mainly composed of ⁇ is formed on the surface of the piston i. ⁇ is a substance having a self-lubricating action.
  • the sliding resistance between the holding recess 2 of the piston 1 and the spherical surface 47 of the shoe 44 is reduced, and even if the lubricating oil runs short in the compressor, the sliding resistance is reduced. 4 moves smoothly along the inner surface of the holding recess 2. Therefore, the swash plate 40 can move the shower 4 in the holding recess 2 with a small force.
  • the load acting between the sliding contact surface 45 of the shoe 44 and the swash plate 40 is reduced, and the sliding resistance between the sliding contact surface 45 and the swash plate 40 is reduced. .
  • the sliding resistance is reduced. No big problem.
  • the covering eyebrow 6 is formed on the entire surface of the piston 1. For this reason, sliding resistance between the outer peripheral surface of the piston 1 and the inner peripheral surface of the cylinder bore 41.42 is reduced, and the piston 1 can move smoothly in the cylinder bores 41,42.
  • the steel S6 can be densified, The hard metal compound is dispersed in the covering eyebrows 6 and the covering layer 6 is strengthened.
  • the withering, the reduction of the coefficient of friction and the improvement of the abrasion resistance can be further improved.
  • the coating layer 6 is densified, and the hard tin compound (CueSn 5) is added to the layer 3! Dispersed in The coating layer 6 is strengthened.
  • the cover 6 is formed by the chemical mechanics method. According to the chemical plating method, tin and other metals such as copper can be easily co-deposited, and a solid lubricant such as a fluororesin powder can be easily coated in the coating S6. Can be captured.
  • FIGS. 10 The mechanical configuration of the compressor according to the second embodiment is substantially the same as that of the compressor illustrated in FIG. 10 described in the background art. Therefore, here, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and the description thereof will be omitted, and only the portions different from the compressor of FIG. 10 will be described.
  • the compressor of the present embodiment is different from the compressor shown in FIG. 10 in that the compressor is provided with a shower 7 on the entire surface of which the SIS 11 mainly composed of tin is formed. .
  • the main body 12 of the shower 7 is formed of SUJ2 material specified by JIS.
  • the shoe 7 has a spherical surface 8 slidably engaged with the holding concave portion 46 of the piston 43 and a sliding contact surface 10 sliding on front and rear surfaces of the swash plate 40.
  • the spherical surface 8 of the show 7 has a spherical portion 9 having a radius larger than that of the other portion at a substantially central portion thereof.
  • An oil reservoir for retaining the lubricating oil is formed between the spherical surface 9 and the holding recess 46 of the piston 43.
  • the sliding contact surface 10 of the case 7 has a slightly bulged shape, so that lubricating oil can easily enter between the sliding contact surface 10 and the swash plate 40.
  • the swash plate 40 and the piston 43 are formed of an aluminum-high silicon alloy.
  • Example 7 has a restoration 11 consisting of an eutectoid plating layer of tin and copper.
  • This layer 31 is formed as follows. That is, 6% S% potassium anchorate Then, the main body 12 of the shroud 17 is immersed in an aqueous solution containing 0.01% double S% of copper gluconate. In this state, while the main body 12 is connected to the negative electrode, the positive electrode is formed by a metal rod having a high ionization tendency. Then, when a predetermined voltage is applied between both electrodes using the aqueous solution as a lysate, tin and copper are bent out by the electrolytic action and adhere to the surface of the main body 12.
  • the layer 11 has a composition containing 97% by weight of copper and 3% by weight of copper, and has a thickness of 1.2 wm.
  • Example 7 has a 5IS 11 which is made of eutectoid metal plating of ⁇ and nickel. That is, by using an aqueous solution containing potassium stannate of 6 S and 0.05 S% of nickel chloride, a pot was formed on the entire surface of the case 7 in the same manner as in Example 1 above. Nickel and eutectoid plating are performed to form the coating layer 11.
  • the coating layer 11 has a composition containing 98% by weight of tin and double ⁇ % of Nigel, and its thickness is formed to 1 by performing surface polishing.
  • Show 7 in Example 3 has a coating layer 11 consisting of a eutectoid Mek calendar of tin and zinc. That is, by using an aqueous solution containing 6% by weight of calcium stannate and 0.005% by weight of zinc sulfate, tin and zinc were applied to the entire surface of the case 7 in the same manner as in Example 1 above. Is subjected to eutectoid plating to form a coating 11.
  • the extension 11 has a composition containing 97% by weight of a bird and 3% by weight of zinc, and its thickness is formed to 1 m by surface polishing.
  • Example show 7 has a sphere 11 of eutectoid plating of tin and lead. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.07% by weight of lead sulfate, tin was applied to the entire surface of the case 7 in the same manner as in Example 1 above. The ship and the ship are subjected to a joint plating to form a coating layer 11. This wave 3 ⁇ 4 eyebrow 1 1 is 9 5 layers S% It has a composition containing tin and 5% by weight of lead, and its thickness is formed to 2 m by surface polishing.
  • Example 7 has a coated eyebrow 11 consisting of a eutectoid mexium layer of tin and zinc. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% by weight of indium sulfate, the entire surface of the case 7 was treated in the same manner as in Example 1 above. Tin and the alloy are eutectoidally plated to form an overlying eyebrow 11.
  • the upper eyebrows i 1 have a composition containing 97% by weight of tin and 3% by weight of zinc, and are formed to a thickness of 1 m by surface polishing.
  • Show 7 of Example 1 has a coating layer 11 consisting of tinned eyebrows. That is, by using an aqueous solution containing 6% by weight of potassium stannate, the entire surface of the shell 7 was formed of a tin-only plating layer in the same manner as in Example 1 above. 1 is formed. The thickness of the S layer 11 is formed to 1.5 wm by surface polishing.
  • Show 7 in Example I has a coating 11 comprising molybdenum disulfide powder as a solid lubricant in the eutectoid calendar of tin and copper. That is, by using an aqueous solution containing 6-fold lithium stannate, 0.003% by weight of copper dalconate, and 1.0% by weight of molybdenum disulfide powder, the same procedure as in Example 1 was performed. Thus, a coating layer 11 containing molybdenum disulfide powder on the eutectoid plating layer of tin and sea bream is formed on the entire surface of the shell 7.
  • the coating layer 11 has a composition containing 99% by weight of tin, 0.9% by weight of copper, and 0.1% by weight of molybdenum disulfide powder, and the thickness of the coating layer should be polished. Is formed to 1.4 m.
  • Example 1 Show 7 of Example I has a coating layer 11 consisting of a eutectoid plating layer of tin and copper, as in Example I above, but is similar to Example II. After the formation of the substrate 11 and the surface polishing of the coating layer 11 are performed, the coating 11 is subjected to a heat treatment at a temperature of 150 ° C. for 1 hour. (Example 2)
  • Example 7 has a covering 11 made of eutectoid metal of tin, copper and zinc. That is, by using an aqueous solution containing 6% by weight of potassium sulfate, 0.003% by weight of copper gluconate and 0.003% by weight of zinc sulfate, the same manner as in Example 1 above was used. On the entire surface of the steel plate 17, a restoration 11 made of eutectoid plating of tin, copper and zinc is formed. This layer 11 has a composition containing 97% by weight of tin, 1.5% by weight of copper and 1.5% by weight of fl.sub.%, And its thickness is obtained by polishing the surface. It is formed to 1.2 m.
  • the inventors of the present application conducted the following tests in order to confirm the anti-seizure performance of each of the compressors incorporating the above-described examples 7 to 7.
  • the swash plate 40 and the swash plate 7 were tested when each compressor incorporated in the vehicle air-conditioning unit fi was operated under severe operating conditions (prone with no lubricating oil in the compressor). The time it takes for the to burn is measured.
  • each compressor had a suction pressure of -0.5 kg
  • the continuous operation was performed under the condition that the rotation speed of the IS moving sleeve 39 was 100 rpm.
  • the compressor swash plate 40 and the piston 43 were formed of aluminum-high-silicon alloy.
  • a show made of only SUJ2 material that is, a show with no 3D expansion 11 was prepared as an example of specific drawing, and a similar test was performed on a compressor incorporating this shroud. Was done.
  • Figure 6 is a graph showing the results of this test.
  • the test results shown in Fig. 6 show that the compressor adopting the above-described examples 7 to 7 having the restored 11 is more severe than the compressor employing the comparative example. This shows that seizure between the case 7 and the swash plate 40 is unlikely to occur even under various use conditions.
  • the compressor employing the shroud 17 of Example 2 provided with the S layer 11 made of tin and copper co-folded metal shoes has the best anti-seizure performance.
  • the coating layer 1 mainly composed of ⁇ is formed on the surface of the shower 7. Therefore, the sliding resistance between the holding portion 46 of the piston 43 and the spherical surface 8 of the shower 7 is reduced, and the sliding resistance between the swash plate 40 and the sliding contact surface 10 of the shower 7 is reduced. Sliding resistance is reduced. Therefore, there is a shortage of lubricating oil in the compressor. Even in the case where the swash plate 40 and the piston 43 are displaced, the slidability between the swash plate 40 and the piston 43 in the communication is maintained well, and the sliding resistance generated at the connection portion is suppressed.
  • the shower 7 smoothly moves along the inner surface of the holding recess 46 of the piston 43 by the action of the calendar 11 provided on the spherical surface 8.
  • the load acting between the sliding contact surface 10 of the shoe 7 and the swash plate 40 is reduced, and the sliding resistance between the sliding contact surface 10 and the swash plate 40 is also reduced. Is low. Since the layer 11 is also provided on the sliding surface 10 which has been closed, the sliding resistance between the sliding surface 10 and the swash plate 40 is further reduced. For this reason, as in the first embodiment, when increasing the discharge capacity of the compressor, it is assumed that only the piston 43 and the swash plate 40 are enlarged without changing the size of the housing 7. However, there is no problem due to the large sliding resistance.
  • Tin not only has excellent lubrication performance but also has the effect of preventing ⁇ , so if a coating ⁇ ⁇ ⁇ 11 mainly composed of tin is formed on the surface of However, it is also possible to protect the case 7 from ⁇ .
  • the present invention is not limited to the above embodiments, and may be embodied by changing the configuration of each unit as follows, for example.
  • the present invention is embodied by the double-headed piston type swash plate type compressor.
  • the single-headed piston type swash plate type compressor, the inclination angle of the swash plate The compressor may be embodied by a variable displacement compressor capable of adjusting the discharge volume S in accordance with the change in the pressure, or by a tube-cam type compressor as shown in FIG.
  • the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and description thereof will be omitted.
  • the wave cam compressor includes a wave force 48 having a wave-like force surface instead of the swash plate 40 of the compressor shown in FIG.
  • the sliding surface 45 of the shoe 44 is in sliding contact with the front and rear cam surfaces of the single cam 48.
  • the piston 43 reciprocates a plurality of times (twice in FIG. 7) while the driving lux 39 rotates once, and It is necessary to move on the complicated cam surface of the wave cam 48 following the displacement of the cam surface. / JP 121 Therefore, in the wave cam compressor, the sliding between the shaft 44 and the piston 43 and the sliding between the shower 44 and the wave cam 48 are caused by the swash plate compression. It becomes intense compared to the type of machine. Therefore, it is important to reduce the sliding resistance generated at the connection between the wave cam 48 and the piston 43 in order to perform a stable compression operation of the pen-cam type compressor.
  • a substantially hemispherical shrinking member 7.44 is employed as the cam follower.
  • the cam follower may be constituted by a slipper 13 that slides on the swash plate 40 and a ball 14 that engages with the recess 13 a of the slipper 13. .
  • the ball 14 is slidably engaged with the holding recess 46 of the piston 43.
  • the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and description thereof will be omitted.
  • the piston 43 is changed to the piston 1 described in the first embodiment, or at least one of the slipper 13 and the ball 14 is used in the second embodiment. What is necessary is just to apply the cover 11 of step 7.
  • the configuration of the cam follower shown in FIG. 8 may be applied to the above-described ⁇ ⁇ -cam type compressor shown in FIG.
  • the swash plate 40 is also provided with a surface 15 mainly made of tin on the sliding contact surface with the shower 44.
  • the composition of the coating 15 may be the same as that of the coating 6 of the piston 1. In this way, the sliding resistance between the swash plate 40 and the shower 44 is further reduced.
  • a coating layer mainly composed of tin may be provided on the rubbing surface 45 of the shower 44.
  • the show 7 in the second embodiment one in which the object 31 ⁇ 11 is provided only on the sliding surface 10 is prepared, and this show 7 is used as the show in the first embodiment. May be used.
  • the calendar 3 is provided only on the holding section 2 of the piston 1.
  • the coating layer 11 is formed by the spherical surface 8 of the shower 7 and the sliding surface.
  • the employment 15 may be provided on the swash plate 40 as described in (3) above.
  • the piston 1 in the first embodiment that is, the piston 1 provided with the armor 8-6 may be used.
  • the surface of the main body 5 is subjected to alumite treatment, manganese phosphate treatment, zinc phosphate treatment, or Apply a groundwork such as zinc plating. By doing so, the sliding resistance against the sh-44 is further reduced.
  • the sliding surface 4 5 sliding contact surface 1 0 and Gerhard one 4 4 of the body 1 2 Shiyu -7, forming a layer of aluminum Nasera Mix (A l 2 0 3) To do. In this way, the sliding resistance to the swash plate 40 is further reduced.
  • the coexistence ratio of tin and other metals in the coating layers 6 and 11 is appropriately changed according to the target performance of the compressor. For example, when scorpion and copper coexist, it is desirable to change the copper content in the range of 0.1% by weight to 50% by weight. If the copper content is less than 0.1% by weight, the S layer 6,
  • a carbon powder, a boron nitride powder, or the like is used as the solid spreading agent contained in the coating layers 6 and 11 instead of the fluororesin powder or the molybdenum disulfide powder. thing.
  • the CVD method or the vacuum evaporation method may be used instead of the wet plating method such as the electrolytic plating method or the chemical plating method.
  • a dry plating method such as PVD method of sputtering, ion brazing or the like may be used.
  • a composite plating method may be used.
  • the thickness of the employed employee 6.11 is appropriately changed in the range of 1 to 5 m. If the thickness of the eyebrows 6, 1] is thinner than 1, the coefficient of friction cannot be reduced sufficiently. If the coating layer 6.11 is thicker than 5 ⁇ m, strength problems such as separation of the coating layers 6 and 11 may occur.

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Abstract

A compressor is provided with cylinder blocks (30, 31) having cylinder bores (41, 42). A driving shaft (39) is supported rotatably on the cylinder blocks (30, 31). A swash plate (40) is fixed to the driving shaft (39) so that the swash plate can be rotated unitarily with the shaft. A piston (1) is held slidably in the cylinder bores (41, 42). Shoes (44) are provided slidably between the piston (1) and swash plate (40). The rotation of the swash plate (40) causes the shoes to reciprocate the piston. The piston (1) comprises aluminum or an aluminum alloy as a base material. The piston (1) is provided with recesses (2) for retaining the shoes (44) slidably. The retaining recesses (2) are provided with a covering layer (6) formed out of tin as a main component.

Description

明細害  Harm
往復動型圧縮機 技術分野  Reciprocating compressor technical field
本発明は、 駆動紬の回転をカムを介してビス トンの往復運動に変換する往復動 型圧縮機に係り、 より詳しくは、 カムと ピス トンとの連桔部で発生する摺動抵抗 を低减するための構造に関するものである。 背景技術  The present invention relates to a reciprocating compressor that converts the rotation of a driving pong into a reciprocating motion of a biston via a cam, and more specifically, reduces a sliding resistance generated at a link between a cam and a piston. It is related to the structure to perform. Background art
一般に、 自動車等の空調装置に用いられる圧縮機として、 例えば図 1 0に示す ような往復動型圧縮機が知られている。 この圧縮機は、 互いに接合された一対の シリ ンダブ口ック 3 0 , 3 1を備えている。 斜板室 3 2は両シリンダブ口ック 3 0 , 3 1間に形成されている。 各シリ ンダブロック 3 0 , 3 1の外端面にはそれ ぞれ弁板 3 3 , 3 4を介してハウジング 3 5 . 3 6が接合されている。 吸入室 3 6及び吐出室 3 7は弁板 3 3 , 3 4 とハウジング 3 5 , 3 6 との間に形成されて いる。  Generally, for example, a reciprocating compressor as shown in FIG. 10 is known as a compressor used for an air conditioner of an automobile or the like. This compressor includes a pair of cylinder blocks 30 and 31 joined to each other. The swash plate chamber 32 is formed between the two cylinder blocks 30 and 31. Housings 35.36 are joined to the outer end surfaces of the cylinder blocks 30 and 31 via valve plates 33 and 34, respectively. The suction chamber 36 and the discharge chamber 37 are formed between the valve plates 33, 34 and the housings 35, 36.
駆動軸 3 9は両シリ ンダブロック 3 0 , 3 1に回転可能に支持されている。 力 ムと しての斜板 4 0は、 斜板室 3 2内において駆動軸 3 9に固定されている。 拔 数対のシリ ンダボア 4 1 , 4 2は、 駆動轴 3 9の周囲において各シリ ンダブロッ ク 3 0 , 3 1 に形成されている。 両頭型のビス トン 4 3は各対のシリ ンダボア 4 1 , 4 2内にそれぞれ収容されている。 カムフォロワと してのシユ ー 4 4は、 斜 板 4 0 とピス ト ン 4 3との間に配置されている。 シュ一 4 4は、 斜板 4 0の前後 の面に摺接する抱接面 4 5 と、 ピストン 4 3の保持凹部 4 6に摺動可能に係合す る球面 4 7とを有している。  The drive shaft 39 is rotatably supported by the cylinder blocks 30 and 31. The swash plate 40 as a force is fixed to the drive shaft 39 in the swash plate chamber 32. A plurality of pairs of cylinder bores 41 and 42 are formed in each of the cylinder blocks 30 and 31 around the drive shaft 39. The double-headed bistone 43 is accommodated in each pair of cylinder bores 41 and 42, respectively. Show 44 as a cam follower is arranged between swash plate 40 and piston 43. The shroud 44 has an engaging surface 45 slidingly contacting the front and rear surfaces of the swash plate 40, and a spherical surface 47 slidably engaged with the holding recess 46 of the piston 43. .
上記の圧縮機では、 駆動軸 3 9の回転に伴い斜板 4 0が回転すると、 その斜板 4 0の作用によりシユ ー 4 4を介してピス トン 4 3がシリ ンダボア 4 1 . 4 2内 を往復勳する。 このとき、 ビス トン 4 3の上死点から下死点への移動に伴い、 吸 入室 3 7からシリ ンダボア 4 1 . 4 2内に冷媒ガスが吸入される。 そして、 ビス トン 4 3の下死点から上死点への移動に伴い、 シリ ンダボア 4 1 . 4 2内に吸入 された冷媒ガスが圧縮されて、 吐出室 3 8に吐出される。 In the above-described compressor, when the swash plate 40 rotates with the rotation of the drive shaft 39, the piston 43 is moved into the cylinder bore 41.42 through the shower 44 by the action of the swash plate 40. To reciprocate. At this time, refrigerant gas is sucked from the suction chamber 37 into the cylinder bore 41.42 as the biston 43 moves from the top dead center to the bottom dead center. Then, with the movement of the biston 4 3 from the bottom dead center to the top dead center, it is sucked into the cylinder bore 41.42. The compressed refrigerant gas is compressed and discharged to the discharge chamber 38.
一般に、 圧縮機の吐出容量を増大させるためには、 シリ ンダボア 4 1 , 4 2を 拡大するとともに、 それに伴いピス ト ン 4 3、 斜板 4 0及びシユ ー 4 4を大型化 することが考えられる。 通常、 ビス トン 4 3及び斜板 4 0は軽量なアルミニゥム 合金等で形成されているが、 同じ種類の金属同士は摺動によつて焼き付きを生じ 易い。 このため、 ピス トン 4 3と斜板 4 0との間に配置されるシユ ー 4 4は、 ピ ス トン 4 3及び斜板 4 0との焼き付きを防止するために鉄系金属で形成されてい る。 しかし、 鉄系金属は比重が大きいので、 シユー 4 4を大型化すると、 圧縮機 全体の重 Sが增大する。  In general, in order to increase the discharge capacity of the compressor, it is conceivable to enlarge the cylinder bores 41 and 42 and to enlarge the piston 43, the swash plate 40 and the shower 44 accordingly. Can be Normally, the buttons 43 and the swash plate 40 are made of a lightweight aluminum alloy or the like, but the same kind of metal is liable to seize due to sliding. For this reason, the shower 44 arranged between the piston 43 and the swash plate 40 is formed of an iron-based metal in order to prevent seizure with the piston 43 and the swash plate 40. You. However, since ferrous metals have a large specific gravity, the size S of the compressor increases the weight S of the entire compressor.
仮に、 吐出容量の增大を図るために、 シュ一 4 4の大きさを変えることなく、 ビス トン 4 3及び斜板 4 0のみを大型化したとする。 しかし、 吐出容量が増大す ると、 ピス ト ン 4 3からシユ ー 4 4を介して斜板 4 0 に作用する荷重も增大する 。 このため、 シユ ー 4 4の大きさだけが同じであると、 そのシユ ー 4 4の球面 4 7及び摺接面 4 5に作用する単位面積当たりの荷重が大きくなる。 その桔果、 シ ユ ー 4 4の球面 4 7 と ピス ト ン 4 3の保持凹部 4 6 との間の指動抵抗、 及びシュ 一 4 4の摺接面 4 5と斜板 4 0 との間の搢觔抵抗が增大する。  It is assumed that, in order to increase the discharge capacity, only the bistone 43 and the swash plate 40 are enlarged without changing the size of the sleeve 44. However, when the discharge capacity increases, the load acting on the swash plate 40 from the piston 43 via the shower 44 also increases. For this reason, if only the size of the shower 44 is the same, the load per unit area acting on the spherical surface 47 and the sliding contact surface 45 of the shower 44 increases. As a result, the finger movement resistance between the spherical surface 47 of the shower 44 and the holding concave portion 46 of the piston 43 and the sliding motion between the sliding surface 45 of the shoe 44 and the swash plate 40 are described. The resistance between them increases.
シュ一 4 4の球面 4 7とピス ト ン 4 3の保持凹部 4 6 との間の摺動抵抗が増大 すると、 シユ ー 4 4が保持凹部 4 6の内面に沿ってスムーズに動く ことができな くなる。 シユ ー 4は斜板 4 0によって保持凹部 4 6内で動かされるため、 シユ ー 4 4がスムーズに動かないと、 シユ ー 4 の摺接面 4 5 と斜板 4 0 との間に作用 する負荷が増大し、 摺接面 4 5と斜板 4 0 との間の摺動抵抗が更に增大する。 上記の圧縮機では、 外部冷媒回路からの冷媒ガスが、 斜板室 3 2を介して吸入 室 3 7 に導入される。 冷媒ガスが斜板室 3 2に導入されることにより、 その斜板 室 3 2内の各機構が冷却されるとともに、 シリ ンダボア 4 1 . 4 2内への冷媒ガ スの吸入に伴って生ずる脈動が防止される。 ところが、 現在では、 成騸國におけ るォゾン層の破壊の問 Sから、 分子中に塩素を含まない R 1 3 4 a ( C F 3 C H ^ F ) が冷媒ガスとして採用されている。 塩素は極圧添加剤としての性質を備え ている。 極圧添加剤とは、 金属の表面と反応することにより金属化合物膜を構成 して、 摩擦抵抗を減少させる作用を奏する物質である。 斜板室 3 2内に導入され た冷媒ガスが、 自身の有する洗浄作用によって、 斜板 4 0等の表面に滞留してい る潤滑油を洗い流してしまうと、 シユ ー 4 4とそのシュ一 4 4に接触するビス ト ン 4 3及び斜板 4 0との問の潤滑が良好に行われなくなる。 このような埸合、 冷 媒ガスの分子中に極圧添加剤と して働く塩素が存在しないと、 摺勳抵抗が非常に 大き く なる。 When the sliding resistance between the spherical surface 47 of the sleeve 44 and the holding recess 46 of the piston 43 increases, the shower 44 can move smoothly along the inner surface of the holding recess 46. No longer. Since the shower 4 is moved in the holding recess 46 by the swash plate 40, if the shower 4 does not move smoothly, it acts between the sliding contact surface 45 of the shower 4 and the swash plate 40. The load increases, and the sliding resistance between the sliding contact surface 45 and the swash plate 40 further increases. In the above compressor, the refrigerant gas from the external refrigerant circuit is introduced into the suction chamber 37 through the swash plate chamber 32. When the refrigerant gas is introduced into the swash plate chamber 32, each mechanism in the swash plate chamber 32 is cooled, and the pulsation generated due to the suction of the refrigerant gas into the cylinder bore 41.42. Is prevented. However, at present, the question S of the destruction of put that Ozon layer formed騸國, do not contain chlorine in the molecule R 1 3 4 a (CF 3 CH ^ F) is employed as the refrigerant gas. Chlorine has properties as an extreme pressure additive. Extreme pressure additives are substances that form a metal compound film by reacting with the surface of a metal and have the effect of reducing frictional resistance. Introduced into the swash plate room 32 When the coolant gas that has washed away the lubricating oil remaining on the surface of the swash plate 40 or the like due to its own cleaning action, the screws 43 that come into contact with the shower 44 and the shoe 44 are removed. Lubrication between the swash plate 40 and the swash plate 40 is not performed well. In such a case, if chlorine acting as an extreme pressure additive is not present in the molecules of the refrigerant gas, the sliding resistance becomes very large.
本発明の目的は、 カムとピス トンとの連結部で発生する摺動抵抗を低減するこ とができる往復動型圧縮機を提供することにある。 発明の開示  An object of the present invention is to provide a reciprocating compressor that can reduce sliding resistance generated at a connection between a cam and a piston. Disclosure of the invention
上記の目的を達成するために、 本発明の圧縮機は、 シリ ンダボアを有するシリ ンダブロックを備えている。 駆動軸は、 シリ ンダブロックに回転可能に支持され ている。 カムは、 駆動軸に一体回転可能に装着されている。 ピス ト ンは、 シ リ ン ダボア内に摺動目在に収容されている。 カムフォロワは、 ピス ト ンとカムとの間 に摺動自在に配置されている。 カムの回転に伴い、 力厶フ ォロワを介してピス ト ンが往復動する。 ビス トンは、 アルミニウム又はアルミニウム合金を母材して形 成されている。 ピストンは、 カムフォロワを摺動自在に保持する保持部を備えて いる。 ピス トンの保持部には、 錫を主体とした被 S層が設けられている。  In order to achieve the above object, a compressor of the present invention includes a cylinder block having a cylinder bore. The drive shaft is rotatably supported by the cylinder block. The cam is mounted on the drive shaft so that it can rotate integrally. The piston is housed in a cylinder bore with a sliding eye. The cam follower is slidably disposed between the piston and the cam. With the rotation of the cam, the piston reciprocates via the force follower. Bistone is formed using aluminum or an aluminum alloy as a base material. The piston includes a holding portion that slidably holds the cam follower. The holding section of the piston is provided with an S layer mainly composed of tin.
従って、 本発明によれば、 ピス ト ンの保持部に設けられた被覆層により、 ビス ト ンの保持部とカムフ ォロワとの間の摺動抵抗が低減される。 このため、 圧縮機 内において潤滑油の不足が生じたり した埸合でも、 カムフォロワはビス トンの保 持部内をスムーズに動く。 従って、 カムはカムフォロワを小さい力で動かすこと ができる。 その結果、 カムフ ォロワとカムとの間に作用する負荷が軽減され、 力 ムフォロワとカムとの間の摺動抵抗が低減される。 図面の簡単な説明  Therefore, according to the present invention, the sliding resistance between the retaining portion of the piston and the cam follower is reduced by the coating layer provided on the retaining portion of the piston. For this reason, the cam follower moves smoothly in the holding part of the biston even if the lubricating oil runs short in the compressor. Therefore, the cam can move the cam follower with a small force. As a result, the load acting between the cam follower and the cam is reduced, and the sliding resistance between the force follower and the cam is reduced. BRIEF DESCRIPTION OF THE FIGURES
図 1 は、 本発明を具体化した第 1実施形態の斜板式圧縮機を示す要部拡大断面 図である。  FIG. 1 is an enlarged sectional view of a main part showing a swash plate type compressor according to a first embodiment of the present invention.
図 2は、 第 1実施形態におけるビストンを示す斜視図である。  FIG. 2 is a perspective view showing a piston according to the first embodiment.
図 3は、 ビス ト ンの要部拡大断面図である。 図 4は、 第 1実施形態における焼き付き B 間の測定钴果を示すグラフである。 図 5は、 本発明を具体化した第 2実施形態の斜扳式圧縮機を示す要部拡大断面 図である。 FIG. 3 is an enlarged cross-sectional view of a principal part of the piston. FIG. 4 is a graph showing measurement results during burn-in B in the first embodiment. FIG. 5 is an enlarged sectional view of a main part showing a slanting compressor according to a second embodiment of the present invention.
図 6は、 第 2実施形態における焼き付き時間の測定桔果を示すグラフである。 図 7は、 本発明の別の実施形態におけるウエーブカム式圧縮機を示す断面図で ある。  FIG. 6 is a graph showing the measurement result of the burn-in time in the second embodiment. FIG. 7 is a cross-sectional view showing a wave-cam type compressor according to another embodiment of the present invention.
図 8は、 本発明の別の実施形態におけるカムフォロワを示す要部拡大断面図で あ  FIG. 8 is an enlarged sectional view of a main part showing a cam follower according to another embodiment of the present invention.
図 9は、 本発明の別の実施形態における斜板を示す要部拡大断面図である。 図 1 0は、 従来の斜板式圧縮機を示す断面図である。 発明を実施するための最良の形態  FIG. 9 is an enlarged sectional view of a main part showing a swash plate according to another embodiment of the present invention. FIG. 10 is a sectional view showing a conventional swash plate type compressor. BEST MODE FOR CARRYING OUT THE INVENTION
(第 1実施形態)  (First Embodiment)
以下、 本発明を具体化した斜板式圧縮機の第 1実施形態を図 1〜図 4 に基づい て説明する。 尚、 この第 1実施形態の圧縮機の機械的な構成は、 背景技術で説明 した図 1 0に示す圧縮機とほぼ同様である。 そのため、 ここでは、 図 1 0 に示す 圧縮機と同一の部材には同一番号を付してその説明を省略し、 図 1 0の圧縮機と 異なる部分についてのみ説明を行うものとする。  Hereinafter, a first embodiment of a swash plate type compressor embodying the present invention will be described with reference to FIGS. Note that the mechanical configuration of the compressor of the first embodiment is almost the same as the compressor shown in FIG. 10 described in the background art. Therefore, here, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals and the description thereof will be omitted, and only the portions different from the compressor of FIG. 10 will be described.
図 1〜図 3に示すように、 本実施形態の圧縮機は、 図 1 0に示す圧縮機とは異 なり、 表面全体に錫を主体とする被覆 S 6が形成されたピス ト ン 1を備えている 。 このピス ト ン 1 は、 シユ ー 4 4の球面 4 7を摺動可能に保持する一対の保持凹 部 2を備えている。  As shown in FIGS. 1 to 3, the compressor of the present embodiment is different from the compressor shown in FIG. 10 in that a piston 1 having a coating S 6 mainly composed of tin is formed on the entire surface. Have. The piston 1 includes a pair of holding concave portions 2 that slidably hold the spherical surface 47 of the shower 44.
ピス ト ン 1 は、 アルミニウム又はアルミニウム合金を母材とする本体 5 と、 そ の本体 5の表面全体に形成された被 S雇 6とから構成されている。 アルミニウム 合金と しては、 例えば A 1 — S i系合金、 Λ 1 — S i - C u系合金を好適に使用 できる。 特に、 本体 5の母材としては、 硬質粒子を含むアルミニウム合金が好ま しい。 このよう なアルミ ニウム合金として代表的なものにアルミニウム一高シリ コン合金がある。 アルミニウム一高シリ コン合金は 1 0 〜 3 0重量%程度のシリ コンを含有している。 アルミニゥム -髙シリ コン合金が共晶組成以下となるよう なシリ コン含有率ならば、 シリ コンは共晶シリ コン (つまり硬 s粒子) として存 在する。 この第 1実施形態では、 図 3に示すように、 ピス トン 1の本体 5が、 シ リコン 3を 1 2重量%含有したアルミニゥム一高シリコン合金 4を母材として形 成されている。 The piston 1 is composed of a main body 5 made of aluminum or an aluminum alloy as a base material, and an employee 6 formed on the entire surface of the main body 5. As the aluminum alloy, for example, A 1 —Si based alloy and 、 1 —Si—Cu based alloy can be suitably used. In particular, the base material of the main body 5 is preferably an aluminum alloy containing hard particles. A typical example of such an aluminum alloy is an aluminum-high silicon alloy. Aluminum-high silicon alloy contains about 10 to 30% by weight of silicon. Make sure that the aluminum-silicon alloy has a eutectic composition or less. With a high silicon content, silicon exists as eutectic silicon (that is, hard s particles). In the first embodiment, as shown in FIG. 3, the body 5 of the piston 1 is formed using an aluminum-high silicon alloy 4 containing 12% by weight of silicon 3 as a base material.
尚、 硬質粒子を含む他の材料としては、 A 1 一 M n金属間化合物、 A 】 一 S i 一 M n金属間化合物、 A 1 - F e - M n金属間化合物、 A 1 - C r金属間化合物 があり、 これらを本体 5の母材として使用してもよい。  Other materials containing hard particles include A 1 -M n intermetallic compound, A] S i -M n intermetallic compound, A 1 -Fe-M n intermetallic compound, A 1 -Cr There are intermetallic compounds, and these may be used as a base material of the main body 5.
又、 この第 1実施形態では、 シユ ー 4 4が J I Sで規定されている S U J 2材 (高炭素クロム軸受け鋼鋼材) で形成され、 斜板 4 0がアルミニウム一高シリコ ン合金で形成されている。  Further, in the first embodiment, the case 44 is formed of SUJ2 material (high carbon chromium bearing steel) specified by JIS, and the swash plate 40 is formed of aluminum-high silicon alloy. I have.
この第 1実施形態の圧縮機に用いられるビス トン 1 としては、 例えば下記の例 ①〜例⑨に示す各種の彼覆層 6を有するものから適宜選択して使用することが可 能である。 以下、 例①〜例⑨のピス ト ン 1について順次説明する。 尚、 例①〜例 ⑨のピス ト ン 1 は、 本体 5の構成は全て同じであり、 被覆層 6の構成が異なるだ けである。  As the biston 1 used in the compressor of the first embodiment, for example, it is possible to appropriately select and use one having various cover layers 6 shown in the following Examples 1 to 4. Hereinafter, the piston 1 of Example 1 to Example 1 will be sequentially described. The pistons 1 of Examples I to II have the same configuration of the main body 5 and are different only in the configuration of the coating layer 6.
(例①)  (Example ②)
例①のビス トン 1 は、 錫と銅との共忻メ ツキ層からなる被覆層 6を有している 。 この被覆層 6 は次のようにして形成される。 即ち、 6重量%の錫酸カリウム及 び 0 . 0 1 2重量%のグルコン酸銅を含有した水溶液が 6 0 〜 8 0 °Cに保たれ、 その水溶液中にビス トン 1の本体 5全体が約 3分間漫漬されることにより、 本体 5の表面に無 ¾解メ ツキが施される。 その後、 本体 5が水溶液中から取り出され て水洗いされる。 その結果、 シユ ー 4 4 と摺接する保持凹部 2を含むビス ト ン 1 の表面全体に錫と網とが共析メ ツキされて、 被覆層 6が形成される。 この被覆層 6は、 9 7重蚤%の錫と 3重量%の銅とを含んだ組成であり、 その厚さは 1 . 2 mでめる。  Bistone 1 of Example 2 has a coating layer 6 composed of a tin-copper tin-copper plating layer. This coating layer 6 is formed as follows. That is, an aqueous solution containing 6% by weight of potassium stannate and 0.012% by weight of copper gluconate is maintained at 60 to 80 ° C., and the entire body 5 of bistone 1 is contained in the aqueous solution. After being pickled for about 3 minutes, the surface of the main body 5 is subjected to insolubility. Thereafter, the main body 5 is taken out of the aqueous solution and washed with water. As a result, tin and the net are eutectoidally plated on the entire surface of the steel 1 including the holding concave portion 2 which is in sliding contact with the case 44, and the coating layer 6 is formed. The coating layer 6 has a composition containing 97% of tin and 3% by weight of copper, and its thickness is set at 1.2 m.
(例②)  (Example ②)
例②のピス ト ン 1は、 錫とニッケルとの共析メ ッキ層からなる被 層 6を有し ている。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 5重 S%の塩化ニッケルを 含有する水溶液を用いることにより、 上記例①と同様にして、 保持 M部 2を含む ピス ト ン 1 の表面全体に錫と二ッケルとが共枳メ ツキされて、 被覆層 6が形成さ れる。 この被 ¾層 6 は、 9 8重量%の錫と 2重量%のニッケルとを含んだ組成で あり、 その厚さは 1 u mである。 The piston 1 of Example 1 has a coating layer 6 made of a eutectoid layer of tin and nickel. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% S% of nickel chloride, the holding M part 2 is included in the same manner as in Example 1 above. Tin and nickel are applied to the entire surface of the piston 1 to form a coating layer 6. This coating layer 6 has a composition containing 98% by weight of tin and 2% by weight of nickel, and has a thickness of 1 μm.
(例③)  (Example ③)
例③のピス ト ン 1 は、 錫と亜鉛との共析メ ッキ βからなる被 膽 6を有してい る。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 5重量%の硫酸亜鉛を含有する 水溶液を用いることにより、 上記例①と同様にして、 保持凹部 2を含むビス ト ン 1 の表面全体に錫と亜鉛とが共析メ ツキされて、 被理雇 6が形成される。 この被 S S 6 は、 9 7重量%の錫と 3重蛋%の亜鉛とを含んだ組成であり、 その厚さは 1 / mでめる。  Piston 1 in Example ③ has a toughness 6 consisting of eutectoid metal β of tin and zinc. That is, by using an aqueous solution containing 6% by weight of calcium stannate and 0.055% by weight of zinc sulfate, the surface of the bismuth 1 including the holding concave portion 2 was formed in the same manner as in Example 1 above. As a whole, tin and zinc are eutectoidally plated to form a worker 6. The S 6 to be coated has a composition containing 97% by weight of tin and triplet of zinc, and its thickness can be reduced to 1 / m.
(例④)  (Example ②)
例④のビス ト ン 1 は、 錫と鉛との共析メ ツキ層からなる被 a層 6を有している Example 1 has an a-layer 6 composed of an eutectoid plating layer of tin and lead.
。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 7重量%の硫酸鉛を含有する水溶 液を用いることにより、 上記例①と同様にして、 保持凹部 2 を含むピス ト ン 1 の 表面全体に錫と鉛とが共析メ ッキされて、 被覆層 6が形成される。 この被覆眉 6 は、 9 5重景%の接と 5重 の鉛とを含んだ組成であり、 その厚さは 2 で ある。 . That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.007% by weight of lead sulfate, the piston 1 including the holding recess 2 was formed in the same manner as in Example 1 above. Tin and lead are eutectoidally deposited on the entire surface to form the coating layer 6. This covering eyebrow 6 has a composition containing 95% of the contact area and quintuple lead, and its thickness is 2.
(例⑤)  (Example ②)
例⑤のピス ト ン 1 は、 錫とイ ンジウムとの共析メ ッキ層からなる被覆層 6を有 している。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 5重量%の硫酸イ ンジゥ ムを含有する水溶液を用いることにより、 上記例①と同様にして、 保持凹部 2を 含むビス ト ン 1 の表面全体に錫とイ ンジゥムとが共析メ ッキされて、 被覆牖 6が 形成される。 この被覆層 6は、 9 7重量%の錫と 3重量%のイ ンジウムとを含ん だ組成であり、 その厚さは である。  Piston 1 of Example 1 has a coating layer 6 composed of a eutectoid mesolayer of tin and indium. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% by weight of indium sulfate, in the same manner as in Example 1 above, the bismuth 1 containing the holding recess 2 was used. Tin and indium are eutectoidally deposited on the entire surface of the steel sheet to form a coating 6. The coating layer 6 has a composition containing 97% by weight of tin and 3% by weight of indium, and has a thickness of:
(例⑥)  (Example ②)
例⑥のビス ト ン 1 は、 錫単独のメ ッキ雇からなる被湲靥 6 を有している。 即ち 、 6重 S %の餛酸カ リ ウムを含有する水溶液を用いることにより、 上記例①と同 様にして、 保持凹部 2を含むピス ト ン 1 の表面全体に、 錫単独のメ ッキ層からな る被湲層 6が形成される。 この被覆層 6の厚さは 1 . である。 (例⑦) Example 1 has a boss 6 consisting of tin-only hiring. That is, by using an aqueous solution containing 6% by weight of sulfuric acid potassium, in the same manner as in Example 1 above, the entire surface of the piston 1 including the holding recess 2 was covered with a tin-only metal. A layer 6 consisting of layers is formed. The thickness of the coating layer 6 is 1. (Example ②)
例⑦のビス トン 1 は、 錫と銅との共析メ ッキ層に固体溷滑剤と してのフッ素榭 脂粉末を含んでなる被覆層 6を有している。 即ち、 6重量%の錕酸カリウム、 0 . 0 0 3重量%のダルコン酸銅及び 1 . 0重量%のフッ素樹脂粉末を含有する水 溶液を用いることにより、 上記例①と同様にして、 保持凹部 2を含むピス ト ン 1 の表面全体に、 錫と銅との共折メ ツキ屨にフッ素樹脂粉末を含んでなる被 ai展 6 が形成される。 この彼復層 6は、 9 9重量%の錫と 0 . 9重量%の銅と 0 . 1重 量%のフッ索榭脂粉末とを含んだ組成であり、 その厚さは 1 . 4 μ πである。  Bistone 1 of Example 1 has a coating layer 6 containing a fluorine resin powder as a solid lubricant on a eutectoid layer of tin and copper. That is, by using an aqueous solution containing 6% by weight of potassium carbonate, 0.003% by weight of copper dalconate and 1.0% by weight of a fluororesin powder, the retention was carried out in the same manner as in Example 1 above. On the entire surface of the piston 1 including the concave portion 2, an ai-extension 6 including a fluorine resin powder in a co-folded pattern of tin and copper is formed. This layer 6 has a composition containing 99% by weight of tin, 0.9% by weight of copper and 0.1% by weight of fluorinated resin powder, and has a thickness of 1.4 μm. π.
(例⑧)  (Example ②)
例⑧のビス 卜ン 1 は、 上記例①と同じく、 錫と銅との共析メ ッキ層からなる被 覆層 6を有しているが、 例①と同様にして化学メ ッキ処理によって被覆層 6が形 成された後に、 その被覆層 6には 1 5 0 DCの温度で 1時間熱処理が施される。 Example 1 has a coating layer 6 composed of an eutectoid metal layer of tin and copper as in Example 1 above. after the coating layer 6 is made form by 1 hour heat treatment at a temperature of 1 5 0 D C is subjected to the coating layer 6.
(例⑨)  (Example ②)
例⑨のピス ト ン 1 は、 錫と網及び亜鉛との共析メ ッキ眉からなる被覆雇 6を有 している。 即ち、 6重量%の錫酸カリウム、 0 . 0 0 3重 のグルコン酸銅及 び 0 . 0 0 3重量%の硫酸亜鉛を含有する水溶液を用いることにより、 上記例① と同様にして、 保持凹部 2を含むピス トン 1の表面全体に、 錫と鋦及び亜鉛との 共析メ ツキ盾からなる被覆層 6が形成される。 この被覆層 6は、 9 7重量%の錫 と 1 . 5重量%の銅と 1 . 5重量%の亜鉛とを舎んだ組成であり、 その厚さは 1 . 2 mである。  Piston 1 in Example I has a coating 6 consisting of a eutectoid metal brow of tin and net and zinc. That is, by using an aqueous solution containing 6% by weight of potassium stannate, 0.003% of copper gluconate and 0.003% by weight of zinc sulfate, the retention was carried out in the same manner as in Example 1 above. On the entire surface of the piston 1 including the recess 2, a coating layer 6 made of eutectoid metal shield of tin, 鋦 and zinc is formed. The coating layer 6 has a composition of 97% by weight of tin, 1.5% by weight of copper and 1.5% by weight of zinc, and has a thickness of 1.2 m.
本願発明者等は、 上記例①〜例⑨のビス ト ン 1をそれぞれ組み込んだ各圧縮機 の耐焼き付き性能を確豚するために、 以下のような試験を行った。 この試験は、 車両用の空調装置に組み込まれた各圧縮機を過酷な使用条件下 (圧縮機内に潤滑 油が存在しない伏態) で運転したときの、 斜板 4 0とシユ ー 4 4 とが焼き付くま での時問を測定したものである。 この試験では、 各圧縮機は、 吸入圧力が— 0 . 5 kg/cmz、 吐出圧力が 3 kg/cm2、 駆動軸 3 9の回転速度が l O O O r p mという 条件で連続運転された。 又、 この試験では、 圧縮機のシュ一 4 4として、 J I S で規定されている S U J 2材で形成されたものが用いられ、 圧縮機の斜板 4 0と して、 アルミニウム一高シ リ コ ン合金で形成されたものが用いられた。 更に、 こ の試験に際しては、 シ リ コ ン 3 を 1 2重靈%含有したアルミニゥム一高シリ コン 合金 4のみで形成されたビス トン、 つまり被覆層 6のないビス卜ンが比絞例とし て用意され、 このピス トンを組み込んだ圧縮機についても同様の試験が行われた 図 4 は、 この試験の結果を示すグラフである。 図 4に示す試験桔果は、 彼覆暦 6を有する上記例①〜例⑨のビストン 1を採用した圧縮機が、 比皎例のビス トン を採用した圧縮機と比較して、 過酷な使用条件下でもシュ一 4 4と斜板 4 0 との 垸き付きが生じにく いことを示している。 特に、 錫と網との共折メ ツキ層よりな る被 3!層 6を備えた例①のビス ト ン 1を採用した圧縮機が、 最も耐焼き付き性能 に便れていることが判る。 The inventors of the present application conducted the following tests in order to confirm the anti-seizure performance of each of the compressors incorporating the above-mentioned examples 1 to 4. In this test, the swash plate 40 and the shroud 44 were used when each compressor incorporated in the vehicle air conditioner was operated under severe operating conditions (the state where lubricating oil was not present in the compressor). It measures the time it takes to burn. In this test, each compressor was operated continuously at a suction pressure of -0.5 kg / cm z , a discharge pressure of 3 kg / cm 2 , and a rotation speed of the drive shaft 39 of l OOO rpm. In this test, a compressor made of SUJ2 material specified in JIS was used as a compressor shroud 44, and aluminum was used as the compressor swash plate 40. An alloy formed of an alloy was used. In addition, At the time of the test, bistons formed only of aluminum-high-silicon alloy 4 containing silicon 3 at 12% by weight, that is, bistons without the coating layer 6 were prepared as specific examples. A similar test was performed on a compressor incorporating this piston. Fig. 4 is a graph showing the results of this test. The test results shown in Fig. 4 show that the compressor adopting Biston 1 of Examples 1 to 4 above, which has the Hebrew calendar 6, is more severely used than the compressor employing Biston of Comparative Example. This shows that the gap between the swash plate and the swash plate is hard to occur even under the conditions. In particular, it can be seen that the compressor employing the example 1 with the 3! Layer 6 composed of the co-folded metal layer of tin and the net is most effective in the anti-seizure performance.
以上のように、 この第 1実施形態では、 ピス ト ン iの表面に鎘を主体とする被 現曆 6が形成されている。 鎢は自己溷滑作用を有する物質である。 このため、 ピ ス ト ン 1の保持凹部 2 とシュ一 4 4の球面 4 7 との間の摺動抵抗が低減され、 圧 縮機内において潤滑油の不足が生じたりした場合でも、 シュ一 4 4が保持凹部 2 の内面に沿ってスムーズに動く。 従って、 斜板 4 0はシユ ー 4 を小さい力で保 持凹部 2内で動かすことができる。 その結果、 シュ— 4 4の摺接面 4 5と斜板 4 0との間に作用する負荷が軽減され、 摺接面 4 5と斜板 4 0との間の摺動抵抗が 低減される。 このため、 圧縮機の吐出容量の増大を図る場合に、 シユ ー 4 4の大 きさを変えることなく、 ピス ト ン 1及び斜板 4 0のみを大型化したとしても、 摺 動抵抗の增大による問題は生じない。  As described above, in the first embodiment, the expression 6 mainly composed of 鎘 is formed on the surface of the piston i.鎢 is a substance having a self-lubricating action. For this reason, the sliding resistance between the holding recess 2 of the piston 1 and the spherical surface 47 of the shoe 44 is reduced, and even if the lubricating oil runs short in the compressor, the sliding resistance is reduced. 4 moves smoothly along the inner surface of the holding recess 2. Therefore, the swash plate 40 can move the shower 4 in the holding recess 2 with a small force. As a result, the load acting between the sliding contact surface 45 of the shoe 44 and the swash plate 40 is reduced, and the sliding resistance between the sliding contact surface 45 and the swash plate 40 is reduced. . For this reason, when increasing the discharge capacity of the compressor, even if only the piston 1 and the swash plate 40 are enlarged without changing the size of the shower 44, the sliding resistance is reduced. No big problem.
被覆眉 6はピス トン 1の表面全体に形成されている。 このため、 ピス トン 1の 外周面とシリ ンダボア 4 1 . 4 2の内周面との間の摺勳抵抗が低減され、 ピスト ン 1はシリ ンダボア 4 1 , 4 2内をスムーズに移動できる。  The covering eyebrow 6 is formed on the entire surface of the piston 1. For this reason, sliding resistance between the outer peripheral surface of the piston 1 and the inner peripheral surface of the cylinder bore 41.42 is reduced, and the piston 1 can move smoothly in the cylinder bores 41,42.
錫を主体とする被覆 IS 6中に、 鲖、 ニッケル、 亜鉛、 船、 イ ンジウムの中から 遴択される少なく とも 1種類の金属を含有させることにより、 被 S牖 6が緻密化 するとともに、 硬質な金属化合物が被覆眉 6中に分散されてその彼覆層 6が強化 される。 その枯果、 摩擦係数の低下及び耐磨耗性能の向上を一層図ることができ る。 例えば、 錫を主体とする被 a雇 6中に銅を含有させた埸合には、 被覆層 6が 緻密化し且つ、 硬質な錫ー鋦化合物 (C u e S n 5 ) が彼 3!層 6中に分散されて その被覆層 6が強化される。 By including at least one metal selected from the group consisting of copper, nickel, zinc, ships, and indium in the tin-based coating IS6, the steel S6 can be densified, The hard metal compound is dispersed in the covering eyebrows 6 and the covering layer 6 is strengthened. The withering, the reduction of the coefficient of friction and the improvement of the abrasion resistance can be further improved. For example, when copper is contained in an employee 6 mainly composed of tin, the coating layer 6 is densified, and the hard tin compound (CueSn 5) is added to the layer 3! Dispersed in The coating layer 6 is strengthened.
被覆雇 6は化学メ ッキ法により形成されている。 化学メ ッキ法によれば、 錫と 銅等の他の金属とを容易に共析させることができるとと もに、 フ ッ素樹脂粉末等 の固体潤滑剤を被覆 S 6中に容易に取り込むことができる。  The cover 6 is formed by the chemical mechanics method. According to the chemical plating method, tin and other metals such as copper can be easily co-deposited, and a solid lubricant such as a fluororesin powder can be easily coated in the coating S6. Can be captured.
(第 2実施形態)  (Second embodiment)
次に、 本発明を具体化した斜板式圧縮機の第 2実施形態を図 5及び図 6に基づ いて説明する。 尚、 この第 2実施形態の圧縮機の機械的な構成は、 背景技術で説 明した図 1 0に示す圧縮機とほぼ同様である。 そのため、 ここでは、 図 1 0に示 す圧縮機と同一の部材には同一番号を付してその説明を省略し、 図 1 0の圧縮機 と異なる部分についてのみ説明を行うものとする。  Next, a second embodiment of a swash plate compressor embodying the present invention will be described with reference to FIGS. The mechanical configuration of the compressor according to the second embodiment is substantially the same as that of the compressor illustrated in FIG. 10 described in the background art. Therefore, here, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and the description thereof will be omitted, and only the portions different from the compressor of FIG. 10 will be described.
図 5 に示すように、 本実施形態の圧縮機は、 図 1 0に示す圧縮機とは異なり、 表面全体に錫を主体とする彼 S IS 1 1が形成されたシユ ー 7を備えている。 この シユ ー 7の本体 1 2は、 J I Sで規定されている S U J 2材で形成されている。 シュ一 7は、 ピス トン 4 3の保持凹部 4 6に摺動可能に係合する球面 8 と、 斜板 4 0の前後の面に摺接する摺接面 1 0とを有している。 シユ ー 7の球面 8は、 そ のほぼ中央部にそれ以外の部分より半径の大きい球面部 9を有している。 この球 面部 9とピス ト ン 4 3の保持凹部 4 6との間には、 潤滑油を滞留させるための油 溜まりが形成される。 シユ ー 7の摺接面 1 0は若干膨らんだ形伏をなしており、 潤滑油が摺接面 1 0と斜板 4 0との間に容易に侵入できるようになっている。 又、 この第 2実施形態では、 斜板 4 0及びピス ト ン 4 3が、 アルミ ニウム一高 シ リ コ ン合金で形成されている。  As shown in FIG. 5, the compressor of the present embodiment is different from the compressor shown in FIG. 10 in that the compressor is provided with a shower 7 on the entire surface of which the SIS 11 mainly composed of tin is formed. . The main body 12 of the shower 7 is formed of SUJ2 material specified by JIS. The shoe 7 has a spherical surface 8 slidably engaged with the holding concave portion 46 of the piston 43 and a sliding contact surface 10 sliding on front and rear surfaces of the swash plate 40. The spherical surface 8 of the show 7 has a spherical portion 9 having a radius larger than that of the other portion at a substantially central portion thereof. An oil reservoir for retaining the lubricating oil is formed between the spherical surface 9 and the holding recess 46 of the piston 43. The sliding contact surface 10 of the case 7 has a slightly bulged shape, so that lubricating oil can easily enter between the sliding contact surface 10 and the swash plate 40. In the second embodiment, the swash plate 40 and the piston 43 are formed of an aluminum-high silicon alloy.
この第 2実施形態の圧縮機に用いられるシユ ー 7 としては、 例えば下記の例① 〜例⑨に示す各種の被覆眉 1 1 を有するものから適宜選択して使用することが可 能である。 以下、 例①〜例⑨のシユ ー 7 について順次説明する。 尚、 例①〜例⑨ のシユ ー 7は、 本体 1 2の構成は全て同じであり、 被覆 IS 1 1の構成が異なるだ けである。  As the shower 7 used in the compressor of the second embodiment, for example, it is possible to appropriately select and use one having various covering eyebrows 11 shown in the following Examples I to II. Hereinafter, the example 7 to example 7 will be sequentially described. It should be noted that in the case of Examples 7 to 7, the configurations of the main bodies 12 are all the same, and only the configuration of the covering IS 11 is different.
(例①)  (Example ②)
例①のシユ ー 7は、 錫と銅との共析メ ツキ層からなる被復餍 1 1を有している 。 この被 3!層 1 1は次のようにして形成される。 即ち、 6重 S %の錨酸カリ ウム 及び 0 . 0 1 2重 S %のグルコ ン酸銅を含有した水溶液中にシュ一 7の本体 1 2 が浸清される。 この状態で、 本体 1 2が陰電極に接続される一方、 イオン化傾向 の大きい金属棒で陽電極が形成される。 そして、 水溶液を鴛解液と して両電極間 に所定の電圧が印加されると、 その電解作用によって錫と銅とが折出されて本体 1 2の表面に密着される。 その後、 本体 1 2が水溶液中から取り出されて水洗い される。 その結果、 シユ ー 7の表面全体に錫と銅とが共析メ ツキされて、 被 S眉 1 1 が形成される。 メ ッキ処理後のシュ一 7 は、 そのシュ一 7が配置される斜板 4 0 と ビス ト ン 4 3 との間のク リアランス等が考慮されて表面を研磨され、 均一 な被 S 1 1が形成される。 この彼 ¾層 1 1 は、 9 7重量%の踢と 3重量%の銅 とを含んだ組成であり、 その厚さは 1 . 2 w mである。 Example 7 has a restoration 11 consisting of an eutectoid plating layer of tin and copper. This layer 31 is formed as follows. That is, 6% S% potassium anchorate Then, the main body 12 of the shroud 17 is immersed in an aqueous solution containing 0.01% double S% of copper gluconate. In this state, while the main body 12 is connected to the negative electrode, the positive electrode is formed by a metal rod having a high ionization tendency. Then, when a predetermined voltage is applied between both electrodes using the aqueous solution as a lysate, tin and copper are bent out by the electrolytic action and adhere to the surface of the main body 12. Then, the main body 12 is taken out of the aqueous solution and washed. As a result, eutectoid plating of tin and copper is performed on the entire surface of the shower 7 to form an S-brows 11. The surface of the post-mesh-processed shoe 17 is polished in consideration of the clearance between the swash plate 40 and the steel 43 on which the shoe 17 is to be placed, and a uniform surface S 1 1 is formed. The layer 11 has a composition containing 97% by weight of copper and 3% by weight of copper, and has a thickness of 1.2 wm.
(例②)  (Example ②)
例②のシュ一 7 は、 錕とニッケルとの共析メ ツキ雇からなる被 5I S 1 1 を有し ている。 即ち、 6重 S の錫酸カ リ ウム及び 0 . 0 0 5重 S %の塩化ニッケルを 含有する水溶液を用いることにより、 上記例①と同様にして、 シユ ー 7の表面全 体に鍋とニッケルとが共析メ ッキされて、 被覆層 1 1 が形成される。 この被覆層 1 1 は、 9 8重量%の錫と 2重悬%のニッゲルとを含んだ組成であり、 その厚さ は表面研磨を行う ことにより 1 に形成される。  Example 7 has a 5IS 11 which is made of eutectoid metal plating of 錕 and nickel. That is, by using an aqueous solution containing potassium stannate of 6 S and 0.05 S% of nickel chloride, a pot was formed on the entire surface of the case 7 in the same manner as in Example 1 above. Nickel and eutectoid plating are performed to form the coating layer 11. The coating layer 11 has a composition containing 98% by weight of tin and double 悬% of Nigel, and its thickness is formed to 1 by performing surface polishing.
(例③)  (Example ③)
例③のシユ ー 7 は、 錫と亜鉛との共析メ ッキ暦からなる被覆層 1 1 を有してい る。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 5重量%の硫酸亜鉛を含有する 水溶液を用いることにより、 上記例①と同様にして、 シユ ー 7の表面全体に錫と 亜鉛とが共析メ ツキされて、 被覆醺 1 1が形成される。 この被 ¾展 1 1 は、 9 7 重垦%の蜴と 3重量%の亜鉛とを含んだ組成であり、 その厚さは表面研磨を行う ことにより 1 mに形成される。  Show 7 in Example ③ has a coating layer 11 consisting of a eutectoid Mek calendar of tin and zinc. That is, by using an aqueous solution containing 6% by weight of calcium stannate and 0.005% by weight of zinc sulfate, tin and zinc were applied to the entire surface of the case 7 in the same manner as in Example 1 above. Is subjected to eutectoid plating to form a coating 11. The extension 11 has a composition containing 97% by weight of a bird and 3% by weight of zinc, and its thickness is formed to 1 m by surface polishing.
(例④)  (Example ②)
例④のシユー 7 は、 錫と鉛との共析メ ツキ層からなる被 ϋ圏 1 1 を有している 。 即ち、 6重量%の錫酸カ リ ウム及び 0 . 0 0 7重蚤%の硫酸鉛を含有する水溶 液を用いることにより、 上記例①と同様にして、 シユ ー 7の表面全体に錫と船と が共忻メ ツキされて、 被覆層 1 1が形成される。 この波 ¾眉 1 1 は、 9 5重 S % の錫と 5重量%の鉛とを含んだ組成であり、 その厚さは表面研磨を行う ことによ り 2 mに形成される。 Example show 7 has a sphere 11 of eutectoid plating of tin and lead. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.07% by weight of lead sulfate, tin was applied to the entire surface of the case 7 in the same manner as in Example 1 above. The ship and the ship are subjected to a joint plating to form a coating layer 11. This wave ¾ eyebrow 1 1 is 9 5 layers S% It has a composition containing tin and 5% by weight of lead, and its thickness is formed to 2 m by surface polishing.
(例⑤)  (Example ②)
例⑤のシユ ー 7は、 錫とィ ンジゥムとの共析メ ッキ層からなる被覆眉 1 1 を有 している。 即ち、 6重量%の錫酸力 リ ウム及び 0 . 0 0 5重 S %の硫酸ィ ンジゥ ムを含有する水溶液を用いることにより、 上記例①と同様にして、 シユ ー 7 の表 面全体に錫とィ ンジゥムとが共析メ ツキされて、 彼覆眉 1 1が形成される。 この 披覆眉 i 1 は、 9 7重量%の錫と 3重量%のィ ンジゥムとを含んだ組成であり、 その厚さは表面研磨を行う ことにより 1 mに形成される。  Example 7 has a coated eyebrow 11 consisting of a eutectoid mexium layer of tin and zinc. That is, by using an aqueous solution containing 6% by weight of potassium stannate and 0.055% by weight of indium sulfate, the entire surface of the case 7 was treated in the same manner as in Example 1 above. Tin and the alloy are eutectoidally plated to form an overlying eyebrow 11. The upper eyebrows i 1 have a composition containing 97% by weight of tin and 3% by weight of zinc, and are formed to a thickness of 1 m by surface polishing.
(纏)  (Summary)
例⑥のシユ ー 7 は、 錫単独のメ ツキ眉からなる被覆層 1 1 を有している。 即ち 、 6重量%の錫酸カ リ ウムを含有する水溶液を用いることにより、 上記例①と同 様にして、 シュ一 7の表面全体に、 錫単独のメ ツキ層からなる彼 8!牖 1 1 が形成 される。 この彼 S層 1 1 の厚さは表面研磨を行う こ とにより 1 . 5 w mに形成さ れる。  Show 7 of Example 1 has a coating layer 11 consisting of tinned eyebrows. That is, by using an aqueous solution containing 6% by weight of potassium stannate, the entire surface of the shell 7 was formed of a tin-only plating layer in the same manner as in Example 1 above. 1 is formed. The thickness of the S layer 11 is formed to 1.5 wm by surface polishing.
(例⑦)  (Example ②)
例⑦のシユ ー 7は、 錫と銅との共析メ ツキ暦に固体濶滑剤と しての二硫化モリ ブデン粉末を含んでなる被覆雇 1 1 を有している。 即ち、 6重 の錫酸力 リ ウ ム、 0 . 0 0 3重量%のダルコ ン酸銅及び 1 . 0重量%の二硫化モリブデン粉末 を含有する水溶液を用いることにより、 上記例①と同様にして、 シュ一 7の表面 全体に、 錫と鯛との共析メ ツキ層に二硫化モリブデン粉末を含んでなる被覆牖 1 1 が形成される。 この被覆層 1 1 は、 9 9重量%の錫と 0 . 9重悬%の銅と 0 . 1重量%の二硫化モリブデン粉末とを含んだ組成であり、 その厚さは表面研磨を 行う ことにより 1 . 4 mに形成される。  Show 7 in Example I has a coating 11 comprising molybdenum disulfide powder as a solid lubricant in the eutectoid calendar of tin and copper. That is, by using an aqueous solution containing 6-fold lithium stannate, 0.003% by weight of copper dalconate, and 1.0% by weight of molybdenum disulfide powder, the same procedure as in Example 1 was performed. Thus, a coating layer 11 containing molybdenum disulfide powder on the eutectoid plating layer of tin and sea bream is formed on the entire surface of the shell 7. The coating layer 11 has a composition containing 99% by weight of tin, 0.9% by weight of copper, and 0.1% by weight of molybdenum disulfide powder, and the thickness of the coating layer should be polished. Is formed to 1.4 m.
(例⑧)  (Example ②)
例⑧のシユ ー 7 は、 上記例①と同じく、 錫と銅との共析メ ツキ層からなる被覆 雇 1 1 を有しているが、 例①と同様にして ¾解メ ッキ処理による被 騸 1 1 の形 成及びその被覆層 1 1 の表面研磨が行われた後に、 その彼覆牖 1 1 には 1 5 0 °C の温度で 1 時間熱処理が施される。 (例⑨) Show 7 of Example I has a coating layer 11 consisting of a eutectoid plating layer of tin and copper, as in Example I above, but is similar to Example II. After the formation of the substrate 11 and the surface polishing of the coating layer 11 are performed, the coating 11 is subjected to a heat treatment at a temperature of 150 ° C. for 1 hour. (Example ②)
例⑨のシユ ー 7は、 錫と銅及び亜鉛との共析メ ッキ牖からなる被覆履 1 1を有 している。 即ち、 6重 S %の餛酸カリウム、 0 . 0 0 3重量%のグルコン酸銅及 び 0 . 0 0 3重量%の硫酸亜鉛を含有する水溶液を用いることにより、 上記例① と同様にして、 シュ一 7の表面全体に、 錫と銅及び亜鉛との共析メ ツキ牖からな る被復騸 1 1が形成される。 この彼湲層 1 1は、 9 7重量 の錫と 1 . 5重量% の銅と 1 . 5重 fl %の亜鉑とを含んだ組成であり、 その厚さは表面研磨を行うこ とにより 1 . 2 mに形成される。  Example 7 has a covering 11 made of eutectoid metal of tin, copper and zinc. That is, by using an aqueous solution containing 6% by weight of potassium sulfate, 0.003% by weight of copper gluconate and 0.003% by weight of zinc sulfate, the same manner as in Example 1 above was used. On the entire surface of the steel plate 17, a restoration 11 made of eutectoid plating of tin, copper and zinc is formed. This layer 11 has a composition containing 97% by weight of tin, 1.5% by weight of copper and 1.5% by weight of fl.sub.%, And its thickness is obtained by polishing the surface. It is formed to 1.2 m.
本願発明者等は、 上記例①〜例⑨のシユ ー 7をそれぞれ組み込んだ各圧縮機の 耐焼き付き性能を確認するために、 以下のような試験を行った。 この試験は、 車 両用の空調装 fiに組み込まれた各圧縮機を過酷な使用条件下 (圧縮機内に瀾滑油 が存在しない伏態) で運転したときの、 斜板 4 0とシユー 7とが焼き付くまでの 時間を測定したものである。 この試联では、 各圧縮機は、 吸入圧力が - 0 . 5 kg
Figure imgf000014_0001
IS動袖 3 9の回転速度が 1 0 0 0 r p mという条件 で連続運転された。 又、 この試験では、 圧縮機の斜板 4 0及びピス トン 4 3 とし て、 アルミニウム一高シリ コン合金で形成されたものが用いられた。 更に、 この 試験に際しては、 S U J 2材のみで形成されたシユ ー、 つまり被 3Ϊ展 1 1のない シユーが比絞例として用意され、 このシュ一を組み込んだ圧縮機についても同様 の試験が行われた。
The inventors of the present application conducted the following tests in order to confirm the anti-seizure performance of each of the compressors incorporating the above-described examples 7 to 7. In this test, the swash plate 40 and the swash plate 7 were tested when each compressor incorporated in the vehicle air-conditioning unit fi was operated under severe operating conditions (prone with no lubricating oil in the compressor). The time it takes for the to burn is measured. In this test, each compressor had a suction pressure of -0.5 kg
Figure imgf000014_0001
The continuous operation was performed under the condition that the rotation speed of the IS moving sleeve 39 was 100 rpm. In this test, the compressor swash plate 40 and the piston 43 were formed of aluminum-high-silicon alloy. In addition, in this test, a show made of only SUJ2 material, that is, a show with no 3D expansion 11 was prepared as an example of specific drawing, and a similar test was performed on a compressor incorporating this shroud. Was done.
図 6は、 この試験の結果を示すグラフである。 図 6に示す試験桔果は、 被復展 1 1を有する上記例①〜例⑨のシユ ー 7を採用した圧縮機が、 比較例のシユ ーを 採用した圧縮機と比校して、 過酷な使用条件下でもシユ ー 7 と斜板 4 0との焼き 付きが生じにく いことを示している。 特に、 錫と銅との共折メ ツキ履よりなる披 S層 1 1を備えた例①のシュ一 7を採用した圧縮機が、 最も耐焼き付き性能に優 れていることが判る。  Figure 6 is a graph showing the results of this test. The test results shown in Fig. 6 show that the compressor adopting the above-described examples 7 to 7 having the restored 11 is more severe than the compressor employing the comparative example. This shows that seizure between the case 7 and the swash plate 40 is unlikely to occur even under various use conditions. In particular, it can be seen that the compressor employing the shroud 17 of Example 2 provided with the S layer 11 made of tin and copper co-folded metal shoes has the best anti-seizure performance.
以上のように、 この第 2実施形態では、 シユ ー 7の表面に錤を主体とする被覆 層】 1 が形成されている。 このため、 ピス トン 4 3の保持 部 4 6 とシユ ー 7の 球面 8 との間の摺動抵抗が低減されるとともに、 斜板 4 0とシユ ー 7の摺接面 1 0との間の摺動抵抗が低減される。 従って、 圧縮機内において潤滑油の不足が生 じたり した場合でも、 斜板 4 0 とピス トン 4 3との逋桔都における斶滑性が良好 に保たれ、 その連結部で発生する摺動抵抗が抑制される。 As described above, in the second embodiment, the coating layer 1 mainly composed of 錤 is formed on the surface of the shower 7. Therefore, the sliding resistance between the holding portion 46 of the piston 43 and the spherical surface 8 of the shower 7 is reduced, and the sliding resistance between the swash plate 40 and the sliding contact surface 10 of the shower 7 is reduced. Sliding resistance is reduced. Therefore, there is a shortage of lubricating oil in the compressor. Even in the case where the swash plate 40 and the piston 43 are displaced, the slidability between the swash plate 40 and the piston 43 in the communication is maintained well, and the sliding resistance generated at the connection portion is suppressed.
シユー 7は、 その球面 8に設けられた披 S暦 1 1 の作用によって、 ピストン 4 3の保持凹部 4 6の内面に沿ってスムーズに動く。 その結果、 シユー 7の摺接面 1 0 と斜板 4 0 との間に作用する負荷が軽滅され、 これによつても摺接面 1 0と 斜板 4 0との間の摺動抵抗が低'减される。 被 層 1 1 はシユー了の摺接面 1 0に も設けられているので、 その摺接面 1 0と斜板 4 0 との間の摺動抵抗は一層低减 される。 このため、 前記第 1実施形態と同じく、 圧縮機の吐出容量の増大を図る 埸合に、 シユー 7の大きさを変えることなく、 ピス ト ン 4 3及び斜板 4 0のみを 大型化したとしても、 摺動抵抗の增大による問題は生じない。  The shower 7 smoothly moves along the inner surface of the holding recess 46 of the piston 43 by the action of the calendar 11 provided on the spherical surface 8. As a result, the load acting between the sliding contact surface 10 of the shoe 7 and the swash plate 40 is reduced, and the sliding resistance between the sliding contact surface 10 and the swash plate 40 is also reduced. Is low. Since the layer 11 is also provided on the sliding surface 10 which has been closed, the sliding resistance between the sliding surface 10 and the swash plate 40 is further reduced. For this reason, as in the first embodiment, when increasing the discharge capacity of the compressor, it is assumed that only the piston 43 and the swash plate 40 are enlarged without changing the size of the housing 7. However, there is no problem due to the large sliding resistance.
錫は、 便れた潤滑性能を持っているだけでなく、 銪を防ぐ効果も持っているの で、 鉄系金属よりなるシユー 7 の表面に錫を主体とする被覆牖 1 1を形成すれば 、 シユ ー 7を婧から保護することもできる。  Tin not only has excellent lubrication performance but also has the effect of preventing 銪, so if a coating と す る 11 mainly composed of tin is formed on the surface of However, it is also possible to protect the case 7 from 婧.
錫を主体とする被 S!暦 1 1中に鐧等の他の金属を含有させることによって生じ る作用効果は、 前記第 1実施形態と同様である。  The function and effect produced by including other metals such as 鐧 in the S! Calendar 11 mainly composed of tin are the same as those in the first embodiment.
尚、 本発明は上記各実施形態に限定されるものではなく、 例えば以下のように 各部の構成を変更して具体化することも可能である。  The present invention is not limited to the above embodiments, and may be embodied by changing the configuration of each unit as follows, for example.
( 1 ) 上記第 1及び第 2実施形態では、 両頭ピス ト ン型の斜板式圧縮機で本発 明を具体化したが、 例えば片頭ピス ト ン型の斜板式圧縮機、 斜板の傾斜角の変更 に伴って吐出容 Sを調整することができる可変容量型圧縮機、 或いは図 7 に示す ようなゥヱーブカム式圧縮機等で具体化してもよい。 尚、 この図 7に示すゥヱー ブカム式圧縮櫸において、 図 1 0に示す圧縮機と同一の部材には同一番号を付し てその説明を省略する。 図 7に示すように、 このウェーブカム式圧縮機は、 図 1 0に示す圧縮機の斜板 4 0の代わりに、 ウェーブ状の力厶面を有するウェーブ力 ム 4 8を備えている。 そして、 シユー 4 4の摺接面 4 5がゥヱ一ブカム 4 8の前 後のカム面に摺接するようになつている。  (1) In the first and second embodiments, the present invention is embodied by the double-headed piston type swash plate type compressor. For example, the single-headed piston type swash plate type compressor, the inclination angle of the swash plate The compressor may be embodied by a variable displacement compressor capable of adjusting the discharge volume S in accordance with the change in the pressure, or by a tube-cam type compressor as shown in FIG. In this case, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and description thereof will be omitted. As shown in FIG. 7, the wave cam compressor includes a wave force 48 having a wave-like force surface instead of the swash plate 40 of the compressor shown in FIG. The sliding surface 45 of the shoe 44 is in sliding contact with the front and rear cam surfaces of the single cam 48.
このようなゥ - 一ブカ厶式圧縮機では、 駆動岫 3 9が 1回転する間にピス トン 4 3が複数回 (図 7では 2回) 往復動するようになっており、 シユー 4 4はゥェ ーブカム 4 8の複雑なカム面上をそのカム面の変位に追随して動く必要がある。 /JP 121 このため、 ウェーブカム式圧縮機では、 シュ一 4 4 とピス トン 4 3との間の摺動 、 及びシユ ー 4 4とウエーブカム 4 8との間の摺動が、 斜板式圧縮機の埸合と比 絞して激しくなる。 従って、 ウェーブカム 4 8とピス ト ン 4 3との連結部で発生 する摺動抵抗を低減することは、 ゥニーブカム式圧縮機が安定した圧縮動作を行 う上で重要なものとなる。 In such a ゥ -one boom type compressor, the piston 43 reciprocates a plurality of times (twice in FIG. 7) while the driving lux 39 rotates once, and It is necessary to move on the complicated cam surface of the wave cam 48 following the displacement of the cam surface. / JP 121 Therefore, in the wave cam compressor, the sliding between the shaft 44 and the piston 43 and the sliding between the shower 44 and the wave cam 48 are caused by the swash plate compression. It becomes intense compared to the type of machine. Therefore, it is important to reduce the sliding resistance generated at the connection between the wave cam 48 and the piston 43 in order to perform a stable compression operation of the pen-cam type compressor.
この図 7の圧縮機において、 ウェーブカム 4 8とピス トン 4 3との連結部で発 生する摺動抵抗を低減するためには、 ピス ト ン 4 3を上記第 1実施形態で説明し たビス トン 1 に変更するか、 或いはシユ ー 4 4を上記第 2実施形態で説明したシ ユ ー 7に変更すればよい。  In the compressor of FIG. 7, in order to reduce the sliding resistance generated at the connection between the wave cam 48 and the piston 43, the piston 43 was described in the first embodiment. What is necessary is just to change it to biston 1, or to change show 44 to show 7 explained in the second embodiment.
( 2 ) 上記第 1及び第 2実施形態では、 カムフォロワとしてほぼ半球状をなす シュ一 7 . 4 4を採用したが、 シュ一了 . 4 4に代えて、 ローラを用いた構造と してもよい。 或いは、 図 8に示すように、 カムフォロワを、 斜板 4 0に摺接する スリ ッパ 1 3及びスリ ッパ 1 3の凹部 1 3 aに係合するボール 1 4によつて構成 してもよい。 ボール 1 4は、 ピス トン 4 3の保持凹部 4 6に摺動可能に係合して いる。 尚、 この図 8において、 図 1 0に示す圧縮機と同一の部材には同一番号を 付してその説明を省略する。 この図 8の構成においては、 ピストン 4 3を上記第 1実施形態で説明したピス トン 1 に変更するか、 或いはスリ ッパ 1 3及びボール 1 4の少なく とも一方に、 上記第 2実施形態におけるシユ ー 7の被 牖 1 1を施 せばよい。  (2) In the above-described first and second embodiments, a substantially hemispherical shrinking member 7.44 is employed as the cam follower. However, instead of the shrinking member 44, a structure using rollers may be employed. Good. Alternatively, as shown in FIG. 8, the cam follower may be constituted by a slipper 13 that slides on the swash plate 40 and a ball 14 that engages with the recess 13 a of the slipper 13. . The ball 14 is slidably engaged with the holding recess 46 of the piston 43. In FIG. 8, the same members as those of the compressor shown in FIG. 10 are denoted by the same reference numerals, and description thereof will be omitted. In the configuration of FIG. 8, the piston 43 is changed to the piston 1 described in the first embodiment, or at least one of the slipper 13 and the ball 14 is used in the second embodiment. What is necessary is just to apply the cover 11 of step 7.
この図 8 に示すカムフォロヮの構成を、 前述した図 7のゥエ ーブカム式圧縮機 に適用してもよい。  The configuration of the cam follower shown in FIG. 8 may be applied to the above-described カ ム -cam type compressor shown in FIG.
( 3 ) 上記第 1実施形態において、 図 9に示すように、 斜板 4 0のシユ ー 4 4 との摺接面にも、 錫を主体とする被 s躧 1 5を形成すること。 この被 a展 1 5の 組成は、 ピス ト ン 1の被 ¾層 6 と同じもので良い。 このようにすれば、 斜板 4 0 とシユー 4 4 との問の摺動抵抗が一層低減される。  (3) In the first embodiment, as shown in FIG. 9, the swash plate 40 is also provided with a surface 15 mainly made of tin on the sliding contact surface with the shower 44. The composition of the coating 15 may be the same as that of the coating 6 of the piston 1. In this way, the sliding resistance between the swash plate 40 and the shower 44 is further reduced.
斜板 4 0に彼覆層 1 5を設ける代わりに、 シユ ー 4 4 の擂接面 4 5に錫を主体 とする被覆層を設けてもよい。 言い換えれば、 第 2実施形態におけるシユ ー 7と して、 被 31騸 1 1が摺接面 1 0にのみ設けられたものを用意し、 このシユ ー 7を 第 1実施形態におけるシユーと して用いてもよい。 ( 4 ) 上記第 1実施形態において、 被 3!暦 6をピス トン 1の保持 部 2のみに 設けること。 Instead of providing the cover layer 15 on the swash plate 40, a coating layer mainly composed of tin may be provided on the rubbing surface 45 of the shower 44. In other words, as the show 7 in the second embodiment, one in which the object 31 被 11 is provided only on the sliding surface 10 is prepared, and this show 7 is used as the show in the first embodiment. May be used. (4) In the first embodiment described above, the calendar 3 is provided only on the holding section 2 of the piston 1.
( 5 ) 上記第 2実施形態において、 被覆層 1 1をシユ ー 7の球面 8及び摺接面 (5) In the second embodiment, the coating layer 11 is formed by the spherical surface 8 of the shower 7 and the sliding surface.
1 0の何れか一方のみに設けること。 被 ai牖 1 1をシュ一 7の球面 8のみに設け たときには、 上記 ( 3 ) で説明したように、 斜板 4 0に被現雇 1 5を設けてもよ い。 彼 層 1 1 をシユ ー 7の摺接面 1 0のみに設けたときには、 第 1実施形態に おけるピス ト ン 1、 つまり披 8牖 6を備えたピス ト ン 1 を用いてもよい。 Provided in only one of 10. When the ai 牖 11 is provided only on the spherical surface 8 of the shoe 17, the employment 15 may be provided on the swash plate 40 as described in (3) above. When the layer 11 is provided only on the sliding contact surface 10 of the show 7, the piston 1 in the first embodiment, that is, the piston 1 provided with the armor 8-6 may be used.
( 6 ) 上記第 1実施形態において、 ピス ト ン 1 の本体 5上に披] i¾ 6を形成す るのに先立って、 本体 5の表面にアルマイ ト処理、 燐酸マンガン処理、 燐酸亜鉛 処理、 或いは亜鉛メ ツキ処理等の下地処理を施すこと。 このようにすれば、 シュ - 4 4に対する摺動抵抗が更に低減される。  (6) In the first embodiment, prior to forming the piston 6 on the main body 5 of the piston 1, the surface of the main body 5 is subjected to alumite treatment, manganese phosphate treatment, zinc phosphate treatment, or Apply a groundwork such as zinc plating. By doing so, the sliding resistance against the sh-44 is further reduced.
( 7 ) 上記各実施形態において、 シユ ー 7の本体 1 2 の摺接面 1 0及びシュ一 4 4の摺接面 4 5に、 アルミ ナセラ ミ ックス (A l 2 0 3 ) の層を形成すること 。 このようにすれば、 斜板 4 0に対する摺勅抵抗が更に低減される。 (7) In the above embodiments, the sliding surface 4 5 sliding contact surface 1 0 and Gerhard one 4 4 of the body 1 2 Shiyu -7, forming a layer of aluminum Nasera Mix (A l 2 0 3) To do. In this way, the sliding resistance to the swash plate 40 is further reduced.
( 8 ) 上記各実施形態において、 被覆層 6 , 1 1中における錫とその他の金属 との共存比率を、 目的とする圧縮機の性能に応じて適宜変更すること。 例えば、 蝎と銅とを共存させる埸合には、 銅の含有率を 0 . 1重量%~ 5 0重量%の範囲 で変更するのが望ましい。 銅の含有率が 0 . 1重量%より小さいと、 被 S層 6 , (8) In the above embodiments, the coexistence ratio of tin and other metals in the coating layers 6 and 11 is appropriately changed according to the target performance of the compressor. For example, when scorpion and copper coexist, it is desirable to change the copper content in the range of 0.1% by weight to 50% by weight. If the copper content is less than 0.1% by weight, the S layer 6,
1 1が十分に緻密化及び強化されず、 銅を含有させることによって得られる効果 に乏しく なる。 銅の含有率が 5 0重量%より大きいと、 鍚の自己潤滑作用が十分 に発揮されなくなって、 摺動抵抗が增大する。 11 is not sufficiently densified and strengthened, and the effect obtained by containing copper is poor. If the copper content is more than 50% by weight, the self-lubricating effect of (1) cannot be sufficiently exerted, and the sliding resistance increases.
( 9 ) 上記各実施形態において、 被覆層 6 , 1 1中に含有させる固体濶佾剤と して、 フッ素樹脂粉末や二硫化モリブデン粉末に代えて、 カーボン粉末や窒化ホ ゥ素粉末等を用いること。  (9) In each of the above embodiments, a carbon powder, a boron nitride powder, or the like is used as the solid spreading agent contained in the coating layers 6 and 11 instead of the fluororesin powder or the molybdenum disulfide powder. thing.
( 1 0 ) 上記各実施形態において、 被 雇 6 , 1 1を形成する場合に、 電解メ ッキ法ゃ化学メ ッキ法等の湿式メ ッキ法に代えて、 C V D法、 或いは真空蒸着、 スパッタリ ング、 イオンブレーティ ングの P V D法等の乾式メ ツキ法を利用して もよい。 上記 ( 9 ) で説明した固体濶滑剤を被 6 , 1 1中に含有させる場合 には、 複合メ ツキ法を利用してもよい。 ( 1 1 ) 上記各実施形態において、 被 a雇 6 . 1 1の厚さを、 1〜 5 mの範 囲で適宜変更すること。 被 31眉 6 , 1 】が 1 より薄いと、 摩擦係数を十分に 小さくできない。 被 ¾層 6 . 1 1が 5 〃 mより厚いと、 被覆層 6 , 1 1が剝離す る等の強度上の不具合が生じる可能性がある。 (10) In each of the above embodiments, when forming the employees 6 and 11, the CVD method or the vacuum evaporation method may be used instead of the wet plating method such as the electrolytic plating method or the chemical plating method. Alternatively, a dry plating method such as PVD method of sputtering, ion brazing or the like may be used. When the solid lubricant described in the above (9) is contained in the coatings 6, 11, a composite plating method may be used. (11) In each of the above embodiments, the thickness of the employed employee 6.11 is appropriately changed in the range of 1 to 5 m. If the thickness of the eyebrows 6, 1] is thinner than 1, the coefficient of friction cannot be reduced sufficiently. If the coating layer 6.11 is thicker than 5 μm, strength problems such as separation of the coating layers 6 and 11 may occur.

Claims

請求の範囲 The scope of the claims
1. シ リ ンダボア (4 1 , 4 2 ) を有するシリ ンダブロ ック ( 3 0 , 3 1 ) と、 そのシ リ ンダブロ ッ ク ( 3 0 , 3 1 ) に回転可能に支持された駆動軸 ( 3 9 ) と 、 その駆動蚰 ( 3 9 ) に一体回転可能に装着されたカム ( 4 0 ; 4 8 ) と、 前記 シ リ ンダボア ( 4 1 , 4 2 ) 内に摺動自在に収容されたピス ト ン ( 1 ) と、 その ピス ト ン ( 1 ) とカム ( 4 0 ; 4 8 ) との間に摺動自在に配置されたカムフォ口 ヮ ( 4 4 ; 1 3 , 1 4 ) とを備え、 カム ( 4 0 : 4 8 ) の回転に伴いカムフ ォロ ヮ ( 4 4 ; 1 3 , 1 4 ) を介してピス ト ン ( 1 ) が往復動する往復動型圧縮機に おいて、 1. A cylinder block (30, 31) having a cylinder bore (41, 42) and a drive shaft (30, 31) rotatably supported by the cylinder block (30, 31). 39), a cam (40; 48) rotatably mounted on the drive shaft (39), and a cam slidably accommodated in the cylinder bore (41, 42). A piston (1) and a cam 口 (44; 13; 14) slidably disposed between the piston (1) and the cam (40; 48). In the reciprocating compressor, the piston (1) reciprocates via the cam follower (44; 13; 14) as the cam (40: 48) rotates.
前記ピス ト ン ( 1 ) は、 アルミ ニウム又はアルミニウム合金を母材と して形成 されるとと もに、 前記カムフォ ロワ ( 4 4 ; 1 3. 1 4 ) を摺動自在に保持する 保持部 ( 2 ) を備え、 その保持部 ( 2 ) には錫を主体と した彼 眉 ( 6 ) が設け られている往復動型圧縮機。  The piston (1) is formed using aluminum or an aluminum alloy as a base material, and a holding portion that slidably holds the cam follower (44; 13.14). A reciprocating compressor equipped with (2) and having his eyebrows (6) mainly made of tin in its holding part (2).
2. シ リ ンダボア ( 4 1 , 4 2 ) を有するシリ ンダブ口ッ ク ( 3 0 , 3 1 ) と、 そのシリ ンダブロック ( 3 0 , 3 1 ) に回転可能に支持された駆動軸 ( 3 9 ) と 、 その駆動軸 ( 3 9 ) に一体回転可能に装着されたカム ( 4 0 ; 4 8 ) と、 前記 シ リ ンダボア ( 4 1 , 2 ) 内に招動自在に収容されたピス ト ン ( 4 3 ) と、 そ のビス ト ン ( 4 3 ) とカム ( 4 0 ; 4 8 ) との間に摺動自在に配置されたカムフ ォロワ ( 7 ; 1 3. 1 4 ) とを備え、 カム ( 4 0 ; 4 8 ) の回転に伴いカムフ ォ ロワ ( 7 ; 1 3 , 1 4 ) を介してピス ト ン ( 4 3 ) が注復動する往復動型圧縮機 において、 2. A cylinder lock (30, 31) having a cylinder bore (41, 42) and a drive shaft (3, 3) rotatably supported by the cylinder block (30, 31). 9), a cam (40; 48) rotatably mounted on the drive shaft (39) thereof, and a piston accommodated in the cylinder bore (41, 2) so as to be freely slidable. (43) and a cam follower (7; 13.14) slidably disposed between the piston (43) and the cam (40; 48). In a reciprocating compressor in which the piston (43) reciprocates via the cam follower (7; 13, 14) with the rotation of the cam (40; 48),
前記カムフ ォロワ ( 7 ; 1 3 , 1 4 ) は、 鉄系金属を母材と して形成されると と もに、 前記ビス トン ( 4 3 ) に摺動自在に保持される第 1摺接部 ( 8 ) 及び前 記カム ( 4 0 ; 4 8) と摺接する第 2¾接部 ( 1 0 ) を備え、 第 1摺接部 ( 8 ) 及び第 2摺接部 ( 1 0) の少なく と も一方には、 錫を主体と した被 S盾 ( 1 1 ) が設けられている往復動型圧縮機。 The cam follower (7; 13, 14) is formed of a ferrous metal as a base material and is slidably held by the biston (43). (8) and a second contact portion (10) that is in sliding contact with the cam (40; 48), and at least the first sliding portion (8) and the second sliding portion (10) are provided. On the other hand, a reciprocating compressor equipped with an S shield (11) mainly made of tin.
3. 請求項 1 に記載の往復動型圧縮機において、 前記ピス ト ン ( 1 ) は、 前記シ リ ンダボア ( 4 1 , 4 2 ) の内周面と摺接する外周面を備え、 前記被 31層 ( 6 ) はピス ト ン ( 1 ) の外周面にも設けられている往復動型圧縮機。 3. The reciprocating compressor according to claim 1, wherein the piston (1) includes an outer peripheral surface that is in sliding contact with an inner peripheral surface of the cylinder bore (41, 42); The layer (6) is a reciprocating compressor also provided on the outer peripheral surface of the piston (1).
4. 請求項 1 に記載の注復動型圧縮機において、 前記力ム ( 4 0 ; 4 8 ) は、 前 記カムフォロワ (4 4 ; 1 3. 1 4 ) と摺接する摺接部を備え、 その摺接部には 錫を主体と した彼 S曆 ( 1 5 ) が設けられている往復動型圧縮機。 4. The reciprocating compressor according to claim 1, wherein the force (40; 48) includes a sliding portion that slides on the cam follower (44; 13.14). The sliding part is a reciprocating compressor equipped with S 彼 (15) mainly made of tin.
5. 請求項 2に記載の往復動型圧縮機において、 前記カム ( 4 0 ; 4 8 ) は、 前 記カムフォロワ ( 7 ; 1 3. 1 4 ) の第 2摺接部 ( 1 0 ) と摺接する摺接部を備 え、 その摺接部には錫を主体とした被覆眉 ( 1 5 ) が設けられている往復動型圧 5. The reciprocating compressor according to claim 2, wherein the cam (40; 48) is in sliding contact with a second sliding contact portion (10) of the cam follower (7; 13.14). A sliding contact portion is provided, and the sliding contact portion is provided with a tin-based covering eyebrow (15).
6. 請求項 1に記載の往復動型圧縮機において、 前記被 S眉 ( 6 ) 中には、 銅、 ニッケル、 亜鉛、 鉛、 インジゥムの中から選択される少なく とも 1種類の金属が 含有されている往復動型圧縮機。 6. The reciprocating compressor according to claim 1, wherein the S eyebrow (6) contains at least one metal selected from copper, nickel, zinc, lead, and indium. Reciprocating compressor.
7. I 求項 2に記載の注復動型圧縮機において、 前記被覆雇 ( 1 1 ) 中には、 鐧 、 ニッケル、 亜鉛、 鉛、 ィンジゥムの中から選択される少なく とも 1種類の金属 が含有されている往復動型圧縮機。 7. I In the reciprocating compressor according to claim 2, wherein at least one metal selected from the group consisting of copper, nickel, zinc, lead, and zinc is contained in the coating (11). Reciprocating compressor contained.
8. 請求項 1に記載の往復動型圧縮機において、 前記カムフォ口ヮは球面 ( 4 7 ) を有するシユー (4 4 ) であり、 前記ピス ト ン ( 1 ) の保持部はシユー ( 4 4 ) の球面 ( 4 7 ) を摺動自在に保持する凹部 ( 2 ) である往復動型圧縮機。 8. The reciprocating compressor according to claim 1, wherein the cam fo is a shower (44) having a spherical surface (47), and a holding portion of the piston (1) is a shower (44). A reciprocating compressor which is a concave portion (2) for slidably holding a spherical surface (47) of (4).
9. 請求項 2に記載の往復動型圧縮機において、 前記カムフォロワはほぼ半球伏 をなすシユー ( 7 ) であり、 そのシュ一 ( 7 ) は第 1摺接部を構成する球面 ( 8 ) を儺え、 前記ビス ト ン ( 4 3 ) はシユー ( 7 ) の球面 (8) を摺動自在に保持 する凹部 ( 4 6 ) を備えている往復動型圧縮機。 9. The reciprocating compressor according to claim 2, wherein the cam follower is a show (7) having a substantially hemispherical shape, and the cam (7) has a spherical surface (8) constituting a first sliding contact portion. In addition, the piston (43) is a reciprocating compressor having a recess (46) for slidably holding a spherical surface (8) of a shoe (7).
1 0. 請求項 1に記載の往復動型圧縮機において、 前記被覆眉 (6) 中には、 フ ッ素樹脂粉末、 二硫化モリ ブデン粉末、 カーボン粉末、 窒化ホウ素粉末の中から 選択される 1種類の固体潤滑剤が含有されている往復動型圧縮機。 10. The reciprocating compressor according to claim 1, wherein the coated eyebrows (6) are selected from a fluorine resin powder, a molybdenum disulfide powder, a carbon powder, and a boron nitride powder. A reciprocating compressor containing one type of solid lubricant.
1 1. 請求項 2に記載の往復動型圧縮機において、 前記被 s (i n 中には、 フッ素榭脂粉末、 二硫化モリプデン粉末、 カーボン粉末、 窒化ホウ素粉末の中か ら iS択される 1種類の固体潤滑剤が含有されている往復勦型圧縮機 n 1 1. The reciprocating compressor according to claim 2, wherein s (in is selected from among a fluorine resin powder, a molybdenum disulfide powder, a carbon powder, and a boron nitride powder. reciprocating勦型compressor n the type of the solid lubricant is contained
PCT/JP1996/001216 1995-03-07 1996-05-08 Reciprocating compressor WO1997042411A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US08/981,695 US5943941A (en) 1995-03-07 1996-05-08 Reciprocating compressor
PCT/JP1996/001216 WO1997042411A1 (en) 1996-05-08 1996-05-08 Reciprocating compressor
EP96913701A EP0838590B1 (en) 1996-05-08 1996-05-08 Reciprocating compressor
KR1019980700072A KR100312933B1 (en) 1996-05-08 1996-05-08 Reciprocating Compressor
DE69630689T DE69630689T2 (en) 1996-05-08 1996-05-08 PISTON COMPRESSOR

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1996/001216 WO1997042411A1 (en) 1996-05-08 1996-05-08 Reciprocating compressor

Publications (1)

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WO1997042411A1 true WO1997042411A1 (en) 1997-11-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1996/001216 WO1997042411A1 (en) 1995-03-07 1996-05-08 Reciprocating compressor

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EP (1) EP0838590B1 (en)
KR (1) KR100312933B1 (en)
DE (1) DE69630689T2 (en)
WO (1) WO1997042411A1 (en)

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JP2002317758A (en) * 2001-04-20 2002-10-31 Toyota Industries Corp Swash plate in swash plate-type compressor

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JP2000257555A (en) * 1999-03-08 2000-09-19 Toyota Autom Loom Works Ltd Compressor
JP2001050158A (en) * 1999-08-06 2001-02-23 Toyota Autom Loom Works Ltd Fixed displacement one side swash plate type compressor
US6129996A (en) * 1999-08-16 2000-10-10 Ford Motor Company Conversion coatings of tin with cobalt and bismuth for aluminum sliding surfaces
EP1172556A3 (en) * 2000-07-14 2004-05-12 Kabushiki Kaisha Toyota Jidoshokki Swash plate compressor piston shoes
JP4292700B2 (en) * 2000-09-18 2009-07-08 株式会社豊田自動織機 Swash plate compressor
JP2002257045A (en) * 2001-03-02 2002-09-11 Toyota Industries Corp Piston type compressor
JP2002317759A (en) * 2001-04-25 2002-10-31 Toyota Industries Corp Shoe for swash plate-type compressor and swash plate- type compressor having the same
KR100391307B1 (en) * 2001-06-04 2003-07-16 한라공조주식회사 Method for preparing a solid film lubricant
WO2003072940A2 (en) * 2002-02-25 2003-09-04 Luk Fahrzeug-Hydraulik Gmbh & Co. Kg Reciprocating piston machine
DE102004057367A1 (en) * 2004-11-27 2006-06-01 Zexel Valeo Compressor Europe Gmbh axial piston
KR102257499B1 (en) 2016-05-03 2021-05-31 엘지전자 주식회사 Linear compressor and a method for manufacturing the same

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JP2002317758A (en) * 2001-04-20 2002-10-31 Toyota Industries Corp Swash plate in swash plate-type compressor
JP4496662B2 (en) * 2001-04-20 2010-07-07 株式会社豊田自動織機 Swash plate in swash plate compressor

Also Published As

Publication number Publication date
DE69630689T2 (en) 2004-09-23
EP0838590B1 (en) 2003-11-12
KR100312933B1 (en) 2002-05-13
DE69630689D1 (en) 2003-12-18
EP0838590A4 (en) 2000-02-23
KR19990028773A (en) 1999-04-15
EP0838590A1 (en) 1998-04-29

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