WO1997040711A1 - Oven-baked french fries having deep-fried taste and texture - Google Patents

Oven-baked french fries having deep-fried taste and texture Download PDF

Info

Publication number
WO1997040711A1
WO1997040711A1 PCT/US1997/006395 US9706395W WO9740711A1 WO 1997040711 A1 WO1997040711 A1 WO 1997040711A1 US 9706395 W US9706395 W US 9706395W WO 9740711 A1 WO9740711 A1 WO 9740711A1
Authority
WO
WIPO (PCT)
Prior art keywords
oven
fries
finished
par
french fries
Prior art date
Application number
PCT/US1997/006395
Other languages
French (fr)
Inventor
Jeffrey John Kester
Patrick Joseph Corrigan
Alyce Johnson Papa
David Thomas Biedermann
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP9538955A priority Critical patent/JPH11508148A/en
Priority to EP97921230A priority patent/EP0906034A1/en
Priority to NZ332275A priority patent/NZ332275A/en
Priority to IL12663297A priority patent/IL126632A0/en
Priority to AU27330/97A priority patent/AU724894B2/en
Priority to BR9710164-8A priority patent/BR9710164A/en
Priority to KR1019980708661A priority patent/KR20000065080A/en
Publication of WO1997040711A1 publication Critical patent/WO1997040711A1/en
Priority to NO984915A priority patent/NO984915L/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/10Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
    • A23L19/12Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops of potatoes
    • A23L19/18Roasted or fried products, e.g. snacks or chips

Definitions

  • the present invention relates to French fried potatoes baked in an oven. More particularly, it relates to oven-finished French fried potatoes that approximate the attributes and characteristics of French fries that have been finished by deep fat frying.
  • French fried potatoes are one of the most popular convenience foods whether they are prepared at home or purchased from fast food restaurants. Deep-fried French fries are particularly well liked by virtue of their textural dichotomy. This textural dichotomy manifests itself in a product which has a fairly crisp exterior and a fairly tender and moist interior. The method of deep frying has been found to be a particularly suitable way for imparting this desired textural dichotomy to French fried potatoes.
  • French fries produced are leathery, dry and tough. Examples of some methods for altering the par-fries and/or methods to produce fully cooked fries, which upon oven-finishing or oven reheating generally result in French fries having poor textural qualities (i.e., dry interiors and tough or soggy exterior crusts), can be found in the prior art, see for example, U.S. 5,000,970 (Shanbhag et al.), U.S. 5,302,410 (Calder et al.), U.S.
  • the oven-finished French fries of the present invention provide one or more advantages in relation to the organoleptic properties, specifically the crust crispness and the moistness of the internal core.
  • the oven finished fries have substantially the same textural dichotomy as deep-fried French fries.
  • the external surface i.e., crust
  • the interior portion i.e., core
  • the oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries in that they possess a combination of attributes, in particular, bulk moisture, total fat, internal moisture content, surface water activity (Aw) and Texture Value, that renders them virtually indistinguishable from deep fried French fries.
  • the oven-finished French fries of the present invention can also be differentiated from commercial oven fries based on subjective evaluations (i.e., expert sensory panelists).
  • the present invention relates to oven-finished French fried potatoes comprising: a) from about 32% to about 50% bulk moisture; b) from about 8% to about 25% total fat; c) from about 55% to about 80% internal moisture content; d) a surface water activity (Aw) of less than or equal to about 0.55; and e) a Texture Value of at least about 200; wherein said Texture Value is the maximum force (grams) or the area (gram sec) under the force deformation curve during the first one- third of a compression test.
  • the oven finished French fries have a texture which is virtually indistinguishable from commercial French fries that have been prepared by deep fat frying such as M c Donald's French fries.
  • the present invention is concerned primarily with the attributes of oven finished French fries.
  • the present invention further relates to oven finished French fries which are ready to eat, and are virtually indistinguishable from deep-fried French fries.
  • deep fried French fries refers to potato strips which have been cooked to a ready-to-eat form by immersion in hot oil.
  • par-fry or “par-fried” refer to potato strips that have been subjected to at least one frying process (e.g., deep frying), but which have not been completely cooked.
  • oven finishing refers to converting the product to a ready-to-eat form by cooking in a toaster, toaster oven, forced air convection oven, high air velocity oven, hot air impingement oven, infrared oven, combined convection/infrared oven, microwave oven, combined microwave/convection oven or a conventional home oven. Typically, cooking entails reducing the moisture content of the food.
  • fat refers to edible fatty substances in a general sense, including natural or synthetic fats and oils consisting essentially of triglycerides, such as, for example soybean oil, corn oil, cottonseed oil, canola oil, sunflower oil, palm oil, coconut oil, fish oil, lard and tallow, which may have been partially or completely hydrogenated or modified otherwise, as well as non-toxic fatty materials having properties similar to triglycerides, herein referred to as fat-substitutes, which materials may be partially or fully indigestible.
  • triglycerides such as, for example soybean oil, corn oil, cottonseed oil, canola oil, sunflower oil, palm oil, coconut oil, fish oil, lard and tallow, which may have been partially or completely hydrogenated or modified otherwise, as well as non-toxic fatty materials having properties similar to triglycerides, herein referred to as fat-substitutes, which materials may be partially or fully indigestible.
  • fat-substitutes non-toxic
  • finished refers to a product that has been subjected to a cooking process to convert it to a ready-to-eat form.
  • conditioned oil refers to oil which has been previously used for frying for such a time that it has developed fried flavor.
  • oven finished refers to a product that has been subjected to an oven baking process to convert it to a ready-to-eat form.
  • oven baking refers to baking in an oven such as a forced air convection oven, hot air impingement oven, infrared oven, a combination of infrared radiation and convection oven, a toaster, toaster oven, a microwave oven, a combination microwave and forced air convection oven, or a conventional home oven.
  • Textture Value is the maximum force (grams) or the area (gram sec) under the force deformation curve recorded during the first one-third of a compression test (see section on analytical test methods for more details).
  • the critical features of the present invention are the Texture Value, the bulk moisture, the internal moisture content, the surface Aw, and the amount of fat present in the oven-finished product. Importantly, it is the combination of these attributes and not a single attribute that distinguishes the present invention from commercial and prior art oven-finished fries and renders them virtually indistinguishable from deep fried French fries.
  • the distinguishing features of the present invention reside in part in the recognition of critical physical characteristics of the par-fries and their thermal properties wherein this relationship can be used to insure oven-finished French fries having moist interiors and crisp crusts for a variety of different oven- finishing processes. More particularly, the present invention recognizes that for oven-finished French fries, a certain range of values for surface Aw and Texture Value are required for optimum palatability.
  • One embodiment of the present invention is the par-fried potato strips which may be prepared by processing steps known in the art.
  • the par- fries may be prepared from a variety of raw potatoes known to be suitable for preparing French fries.
  • the par-fried potato strips are prepared from potatoes of the Russet Burbank, Shepody or Katahdin varieties.
  • the par-fried strips may be of varying shapes and sizes. However, it is preferred that the relatively thin and elongated potato strips known in the art as “shoestrings” be used. Shoestring potato strips, as used herein refer to potato strips that are from about 3/16 to about 5/16 inch square in cross-section and from about 2.5 to about 5 inches in length. Thicker-cut potato strips may also be used herein; e.g., “crinkle cut” strips, straight cut thick potato strips (also known as “regular-cut”) and "steak fry” cuts.
  • the potato strips are blanched according to conventional procedures known in the art. Following blanching, the potato strips may be subjected to additional treatments known in the art. For instance, the potato strips may be treated with sodium acid pyrophosphate (SAPP), a chelating agent used to prevent discoloration of the strips. Dextrose (com syrup) may also be applied to the surface of the strips in order to yield a desired level of brown color development during subsequent processing. In addition, the potato strips may be optionally dried partially to reduce their moisture content. The potato strips are then subjected to one or more frying processes at an oil temperature of from about 270°F (132°C) to about 385° F ( 196 ⁇ C).
  • SAP sodium acid pyrophosphate
  • Dextrose com syrup
  • the potato strips may be optionally dried partially to reduce their moisture content.
  • the potato strips are then subjected to one or more frying processes at an oil temperature of from about 270°F (132°C) to about 385° F ( 196 ⁇ C).
  • the frying process may involve immersion of the potato strips in oil, a heated oil spray which surrounds the potato strip with hot oil, or frying using an oil foam.
  • the blanched potato strips are reduced in moisture to a moisture content of not less than about 60%, after which they are fried at an oil temperature of from about 270°F (132°C) to about 335°F (168°C) for a time sufficient to produce par-fries comprising about 30% to about 58% moisture.
  • the par-fries may be immediately cooled or frozen. Chilling or freezing of the par-fries may be accomplished by methods known in the art. Multiple frying, chilling, and/or freezing steps may be employed during processing of the par-fries.
  • the par-fries may also be treated with various surface treatments (e.g., enrobed with oil; application of hydrocolloid coating; application of water, aqueous solution, or dispersion; etc.) either before or after cooling or freezing.
  • the par-fries may be stored frozen at temperatures between about -70°F (-57°C) and about 20°F (-6.7°C).
  • the moisture, and fat content and thermal properties of the par-fries are important to produce the oven baked fries of this invention. Of particular importance is the distribution of water in the par-fry and the control of water migration from the internal core to the crust region of the par-fries during storage and oven finishing.
  • ready-to-eat oven-baked French fries can be prepared that possess a highly palatable moist interior surrounded by a low-moisture, crisp crust region.
  • the textural dichotomy that results in the oven-finished fry is very similar to that which exists in French fries that are finished by deep frying.
  • Moisture migration from the internal core to the crust region during frozen storage can be partially controlled by frying the potato strips to bulk moisture contents that are preferably equal to or greater than about 40%, more preferably equal to or greater than about 42%, and most preferably equal to or greater than about 44%. Moisture migration can also be minimized during frozen storage by hydrating the crust region prior to frozen storage in order to increase the crust Aw and, thereby, reduce or eliminate the Aw differential between the internal core and the crust, which is the driving force for moisture transfer. Hydration of the crust region can be accomplished by application of water, a water mist, an aqueous solution, or an aqueous dispersion to the surface of the par-fry. Preferably a spraying process is used to hydrate the crust region of the par-fries.
  • Moisture migration from the internal core to the crust region during oven finishing can be minimized by employing oven-finishing conditions that rapidly and/or preferentially dry the surface of the French fry. This can be achieved by selecting oven conditions (temperature, air velocity) that yield a relatively high surface heat transfer coefficient at oven temperature. Higher surface heat transfer coefficients are desirable because this will lead to faster cooking time and the formation of a more distinct and crisp low-moisture crust region. Preferable surface heat transfer coefficients at oven temperature are from about 50 to about 400 watts/m2°C. Preferential drying of the surface of the par-fry can also be achieved by enrobing the par-fries with an edible fat or oil, which increases the conduction of heat from the surrounding air to the fry surface during oven baking.
  • Desired thermal conductivities at oven temperatures of the crust region of the par-fry are from about 0.1 to about 0.3 watts/m°C. Desired thermal conductivities of the high-moisture internal core are from about 0.4 to about 0.7 watts/m°C.
  • Enrobing par- fries with fat or oil also serves the purpose of providing an added barrier to moisture loss from the internal core as the enrobing oil is partially absorbed into the outer crust region during baking.
  • the surface of the par-fry may also be modified to improve the absorption of radiant heat from the oven. A typical method of accomplishing this would be to alter the color, porosity, and/or reflectivity of the par- fry surface.
  • Thermal conductivities and surface heat transfer coefficients can be calculated as follows.
  • T 2 Temperature on the hot side of the boundary ( C or equivalent)
  • Thermal conductivity for a food material with a crust can be calculated once U, T 2 and T
  • k UL(T 2 -T,)/(T r Ti)
  • k thermal conductivity (W7m-°C or equivalent)
  • prior art oven fries lack the desirable textural dichotomy associated with high-quality deep-fried French fries because the par-fry attributes (moisture; fat; surface fat; thermal properties) and oven-finishing conditions are not optimized for producing a finished oven fry with a moist interior and a crisp low-moisture crust.
  • par-fry attributes moisture; fat; surface fat; thermal properties
  • oven-finishing conditions are not optimized for producing a finished oven fry with a moist interior and a crisp low-moisture crust.
  • many commercial or prior art par-fries are so high in moisture content that upon the recommended oven baking the oven-finished fry is not sufficiently low in bulk moisture content or the crust region has not been sufficiently dehydrated to yield a crisp surface texture.
  • oven- finished French fries having one or more of the following textural deficiencies: a tough surface texture; an interior that is perceived as excessively dry; and/or an excessively crunchy overall texture (i.e., the oven- finished fries do not possess the desired textural dichotomy associated with deep fried French fries).
  • the preferred method comprises controlling the bulk moisture and thermal properties (i.e., thermal conductivity of the high-moisture internal core, thermal conductivity of the crust region, and the surface heat transfer coefficient) of the par-fries.
  • the bulk moisture of the par- fries may be controlled by the process conditions used in producing the par-fries; e.g., the conditions used for dehydrating the potato strips before frying; the par-frying conditions; and the level, if any, of surface hydration of the par-fries.
  • the thermal properties of the par-fries may be the modified likewise and additionally may be modified by application of various ingredients onto the surface of the par-fries (e.g., enrobing with oil; coating with hydrocolloids; etc.).
  • the par-fries useful in the present invention have a bulk moisture of greater than about 30%. Typically the bulk moisture is from about 38% to about 58%, preferably from about 40% to about 56%, more preferably from about 42% to about 54% and even more preferably from about 44% to about 50% bulk moisture.
  • the bulk moisture and thermal properties of the par-fries provide a method for controlling moisture loss from par-fried potato strips during oven finishing such that the resulting French Fries have substantially the same textural dichotomy as deep fried French fries. Further, the bulk moisture and thermal properties of the par-fries indicate how the par-fry processing conditions and oven-finishing conditions may be altered to insure optimum textural characteristics in the oven-finished French fry.
  • the oven-finished French fries of the present invention may be baked in various types of ovens, including a forced air convection oven, hot air impingement oven, infrared oven, a combination of infrared radiation and convection oven, a toaster, a toaster oven, a microwave oven, a combination microwave and forced air convection oven, or a conventional home oven.
  • the baking time is less than or equal to about 15 minutes, preferably less than or equal to about 10 minutes, more preferably less than or equal to about 5 minutes, and most preferably less than or equal to about 3 minutes.
  • the baked fries may optionally be coated with oil to further enhance flavor and mouthfeel.
  • the oil used for coating the baked fries is a flavored or conditioned oil.
  • the oil may be applied to the surface of the baked fries by methods known in the art; e.g., by spraying warm oil onto the surface or by rapid immersion of the fries into a reservoir of warm oil.
  • the oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries in that they possess a combination of attributes, in particular, a certain Texture Value, bulk moisture, internal moisture, surface Aw, and total fat that renders them virtually indistinguishable from French fries that have been finished by deep-fat frying. Further, the oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries based on subjective evaluation (i.e., expert sensory panelists).
  • a critical attribute of the present invention is the Texture Value of the oven-finished French fries. This value is dependent on a combination of factors such as moisture content, crispness of the crust, degree of dehydration of the crust, and other physical properties of the fries.
  • the Texture Value is determined by the use of a Texture Analyzer equipped with a rectangular, blunt steel plate probe. A compression test is run in which the plate compresses the French fry while the force of resistance is measured (see section on analytical test methods for details). The force (grams) vs. time (sec) data is plotted to produce a force deformation curve. Two textural parameters obtained from the force deformation curves are used to characterize the texture of French fries, average maximum force (grams) and average area (gram sec) within the first 1/3 of the compression test.
  • High quality oven-finished French fries of the present invention exhibit distinctive textural dichotomy and are characterized by a Texture Value (i.e., maximum force or area) of at least about 200.
  • a Texture Value i.e., maximum force or area
  • the Texture Value is from about 210 to about 1000, more preferably from about 220 to about 600, and even more preferably from about 240 to about 500.
  • the oven-finished French fries of the present invention have a ratio of the average area to the average maximum force of at least 1.0, preferably 1.04 or greater, more preferably 1.08 or greater, even more preferably 1.12 or greater, and most preferably 1.16 or greater.
  • Over-cooked commercial oven fries may exhibit an average maximum force or area of at least about 200 or greater.
  • the oven-finished fries of the present invention can be distinguished from the overcooked commercial oven fries based on the bulk and/or internal moisture and based on the fact that the ratio of the average area to the average maximum force of the overcooked commercial oven fries generally remains at about 1.0 or less.
  • Another critical attribute of the present invention is the bulk moisture content of the oven-finished French fries.
  • Bulk moisture is the total amount of water in the fries of the present invention.
  • the oven- finished French fries of the present invention have a bulk moisture of from about 32% to about 50%.
  • Shoestring cut, oven-finished French fries of the present invention have a bulk moisture of from about 32% to about 46%.
  • the bulk moisture of shoestring-cut, oven-finished French fries should be from about 33% to about 44%, and more preferably the bulk moisture should be from about 34% to about 40%.
  • Thicker-cut oven-finished French fries of the present invention typically have a bulk moisture of from about 35% to about 50%.
  • the thicker-cut oven-finished French fries have a bulk moisture of from about 38% to about 48% and more preferably from about 40% to about 46%.
  • the bulk moisture of the products herein can be measured using well- known techniques and commercially available instruments.
  • An oven-finished French fry with a bulk moisture much greater than about 50% will not have developed a sufficient crust structure to yield the desired textural dichotomy (i.e., the fries will lack crispness).
  • the oven- finished fries can become too dry. Keeping the bulk moisture of the oven-finished fries of the present invention at a level between about 32% and 50% allows production of oven fries that possess both a low-moisture, crisp crust region as well as a high-moisture internal core. Internal Moisture
  • the internal moisture content is also an important characteristic of the present invention.
  • the internal moisture content of oven-finished French fries is the moisture content of the interior starch matrix. As mentioned before the interior portion (i.e., core) is well cooked, tender, mealy and moist, yet free from sogginess.
  • the oven-finished French fries of the present invention have an internal moisture of from about 55% to about 80%, preferably from about 60% to about 77%, more preferably from about 63% to about 75%.
  • a distinguishing characteristic of the oven-finished fries of the present invention is the exterior crust.
  • the exterior crust is comprised of dehydrated gelatinized starch and oil or fat.
  • the exterior crust has substantially the same composition as the crust of deep fried French fries made from raw potatoes.
  • the crust may contain ingredients typically applied to the surface of potato strips such as starches, hydrocolloids, gums, flavorings and the like.
  • the texture of fried and baked food products is known to be related in part to the Aw of the product.
  • Crisp textures are generally associated with Aw values less than or equal to about 0.55.
  • the surface Aw is a measurement of the water activity of the crust region of the oven-finished French fries (see section on analytical test methods for details concerning surface Aw measurement).
  • the surface Aw is equal to the vapor pressure of water in the outer crust region divided by the vapor pressure of pure water at the same temperature.
  • the oven-finished French fries of the present invention preferably have a surface Aw of less than or equal to about 0.55, preferably from about 0.10 to about 0.52, more preferably from about 0.15 to about 0.5, and even more preferably from about 0.2 to about 0.45.
  • Edible oil natural or synthetic, is generally on the surface and within the crust region of the oven- finished French fry of the type disclosed in the present invention.
  • Edible oils contribute to the flavor, lubricity and texture of the oven-finished French fry.
  • the edible oils or fats present on the surface and within the crust region of the oven-finished French fry are well known by one skilled in the art and include but are not limited to beef tallow, lard, cottonseed oil, canola, soybean oil, corn oil, palm oil, fish oil, safflower oil, sunflower oil, coconut oil, peanut oil, medium chain triglycerides, structured triglycerides containing a combination of short or medium chain fatty acids and long chain fatty acids (e.g.
  • oils may be conditioned or flavored, see Flavored Vegetable Oils as a Substitute for Beef Tallow in Deep Frying Applications, Food Technology, pp 90-94 (1989) and U.S. Patent 5,104,678 (Yang et al.)
  • the oils may be partially or completely hydrogenated or modified otherwise.
  • non- toxic, fatty materials having properties similar to triglycerides such as sucrose polyesters and OieanTM, from the Procter and Gamble Company, and reduced calorie fats, polyol fatty acid polyesters, and diversely esterified polyol polyesters or combinations of regular fats and fat substitutes may also be present on the surface and/or within the crust region of the oven-finished French fries.
  • Some preferred oils are soybean oil and corn oil.
  • the total amount of oil or fat present in and on the oven-finished French fries of the present invention is from about 8% to about 25%.
  • Shoestring French fries of the present invention typically have from about 12% to about 25% total fat, preferably from about 13% to about 23% fat, and more preferably from about 14% to about 20% total fat.
  • Thicker-cut oven- finished French fries e.g. regular cut, crinkle-cut and steak fries
  • the thicker-cut oven-finished French fries have a total fat level of from about 10% to about 20%, and more preferably from about 12% to about 18%.
  • the edible fat or oil present on the surface and within the crust region of the oven- finished French fries of the present invention has a free fatty acid level of about 0.8% or less.
  • Flavoring agents such as salt, pepper, butter, onion, or garlic may be added to the par-fries or the oven-finished fries oil to enhance the flavor or modify the flavor to any desired taste.
  • flavoring agents such as salt, pepper, butter, onion, or garlic may be added to the par-fries or the oven-finished fries oil to enhance the flavor or modify the flavor to any desired taste.
  • ingredients known in the art may also be added to the edible fats and oils used to fry and/or enrobe the par-fried potato strips, including antioxidants such as TBHQ, chelating agents such as citric acid, and antifoaming agents such as dimethylpolysiloxane.
  • the oven-finished French fries of the present invention can also be distinguished from commercial and prior-art oven fries based on sensory evaluation and Nuclear Magnetic Resonance (NMR) Imaging.
  • Sensory evaluation reveals that the oven-finished French fries of the present invention possess a desirable " textural dichotomy (i.e., a crisp surface surrounding a moist interior) typically associated with deep-fried French fries.
  • Commercial and prior-art oven fries do not typically display this desired textural dichotomy.
  • NMR imaging provides a cross-sectional image depicting the moisture and fat distribution within the fries.
  • the high-quality oven-finished French fries of the present invention are characterized by NMR images that appear qualitatively similar to the images of deep-fried French fries, i.e., both products are characterized by images that reveal a high moisture internal core surrounded by a low moisture crust region that contains the fat.
  • NMR images of commercial oven fries typically appear qualitatively different; i.e., the dichotomous feature of a low-moisture crust surrounding a high-moisture core is not as readily apparent.
  • Moisture content of par-fried potato strips and finished French fries is determined by a forced air oven method as follows
  • the Texture Value of finished French fries which correlates with crispness of the fries, is measured with a TA-XT2 Texture Analyzer (version 05 16 equipped with 25-1 load cell, Texture Technologies Corp , Scarsdale, NY)
  • the Texture Analyzer is linked to a standard personal computer (e g IBM 433DX) that records the data via a software program called XT RA Dimension (version 3 7H, Texture Technologies Corp , Scarsdale, NY)
  • the Texture Analyzer is configured with a rectangular, blunt steel plate probe (2 5-3 0 mm thickness, 70 mm width, 90 mm length) that is fastened vertically to the mam arm A "Compression Test" on a smgle French fry will be run to generate a plot of Force (grams) vs Time (sec), from which the Texture Value is obtamed Procedure for Set-up and Calibration of the Texture Analyzer
  • Steps #l-#3 are repeated for each new batch of French fries. Generally, 5 to 10 batches of each type of French fry are evaluated in this manner.
  • either the overall average Maximum Force or Area may be designated as the French fry Texture Value. Both texture measurements correlate to crispness of finished French fries.
  • Internal moisture content of finished French fries i.e. moisture content of the interior starch matrix, is determined as follows: 1. Immediately following removal of finish-cooked French fries from a fryer (deep-fried) or oven (oven-baked), immerse the fries in liquid N2 for 20 seconds to completely freeze the products and stabilize the internal moisture distribution.
  • step #4 until approximately 0 3-0 7 gram of surface shavmgs is collected, this will requ ⁇ e scraping about 10-20 frozen fries
  • Total fat content of par-fried potato stnps, and finished French fries is determined by a solvent extraction method as follows
  • Soxtec HT6 extraction system unit includes heatmg block and cooling condenser
  • Two oven-finished French fry products and one deep-fried French fry product are prepared as follows:
  • Frozen shoestring-cut par-fried potato strips are an acceptable starting product (e.g., Simplot Par- Fries; J. R. Simplot Co., Caldwell, ID).
  • a typical processing history may include: sorted and graded Russet Burbank potatoes are peeled, washed, trimmed and cut axially into shoestring strips (0.25 inch square cross-section).
  • the potato strips are blanched in hot water or steam and partially dried with hot air such that the potato strips are reduced in weight by about 15%.
  • the partially dried strips are then par-fried in partially-hydrogenated soybean oil (Iodine Value of about 67) for about 50 seconds at an oil temperature of about 375°F (190.5°C).
  • the par-fried potato strips are then cooled and frozen in a blast freezer at -30°F (-34.4°C) and packaged.
  • the par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
  • the frozen par-fried potato strips are further processed by deep frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and corn oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 290°F (143.3°C).
  • Primex 108 vegetable oil blend of partially hydrogenated soybean oil and corn oil available from the Procter & Gamble Co.
  • the resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds.
  • the moisture content of the resulting par-fry is about 47% and the fat content is about 15%.
  • the par-fries are enrobed with oil by immersing in liquid vegetable oil (conditioned Primex 108) having a temperature of about 335°F ( ⁇ 168°C) for about 1-3 seconds.
  • the resulting oil-enrobed par-fries are again frozen by immersion in liquid nitrogen.
  • the frozen par-fries are packed into sealed foil-laminate bags and stored at normal freezer temperatures of approximately 0°F (-18 °C) to about -20°F (-29°C).
  • the oil-enrobed par-fries contain about 9% surface fat by weight of the fries.
  • the total fat level is about 22% and the bulk moisture level is about 43%.
  • Frozen retail Ore-Ida® "Shoestrings” French fried potatoes (Ore-Ida Foods, Inc., Boise, ID) are purchased at a local grocery store.
  • the fries comprise about 63% moisture and about 6% fat.
  • the fries are baked in a conventional home oven (General Electric) as follows: approximately 8 oz. of frozen fries are spread uniformly in a single layer over a 9" x 13" solid cooking sheet and baked for about 10 minutes at a temperature of about 450°F (232°C). Upon removal from the oven, the fries are immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by sensory testing.
  • the frozen shoestring-cut par-fried potato strips used as the starting par-fry for preparation of product "A" of this example are further processed by deep-frying.
  • the par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
  • oven-finished French fries according to the present invention (A) have technical attributes that are very similar to deep-fried French fries (C) that are considered the "gold standard.”
  • the commercial oven-finished French fries (B) fall outside the desired ranges for surface Aw and the textural parameters (maximum force, area, and ratio of area to maximum force).
  • French fry products are also evaluated for flavor and texture by sensory testing.
  • a panel of -40 trained individuals rate the products for various sensory attributes on a scale of 1 to 9. Two sensory tests are run, evaluating each of the oven fry products directly against the deep-fried French fries. Following are the sensory test results; each numerical value is the average rating for that attribute.
  • the sensory test results reveal that the oven-finished French fries according to the present invention (A) have flavor and textural attributes very similar to the deep-fried French fries (C).
  • the oven-finished French fries according to the present invention possess the desired textural dichotomy, i.e., a moist interior and a crisp crust, that is typically associated with deep-fried French fries.
  • the commercial oven fries (B) do not possess the desired textural dichotomy as revealed by a significantly lower surface crispness rating.
  • Two oven-finished French fry products and one deep-fried French fry product are prepared as follows:
  • the frozen shoestring-cut par-fried potato strips used as the starting par-fry in Example 1 A are an acceptable starting product for this example (Simplot Par-Fries; J. R. Simplot Co.; Caldwell, ID).
  • the par- fried potato strips have a moisture content of about 64% and a fat content of about 6%.
  • About 1 lb. of the frozen par-fried potato strips are further processed by deep frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 290°F (143.3°C).
  • the resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds.
  • the moisture content of the resulting par-fry is about 48% and the fat content is about 14%.
  • the frozen par-fries are packaged into foil-laminate bags and stored at about 0°F (-18°C).
  • the frozen par-fries are baked in a double impingement oven (Wolverine Co ⁇ oration, Merrimac, MA; Model 2.0 x 051 pilot plant JetzoneTM oven) equipped with a continuous conveyor.
  • the par-fries are arranged in a single layer on an open wire mesh tray that is placed on the oven conveyor belt. Hot air impinges on the product from both the top and bottom, delivered from two banks of tubes located above and below the conveyor belt.
  • the air velocity measured at the product bed is about 5,500 feet per minute (1,676 meters per minute).
  • the air temperature within the oven chamber is 450°F (232°C) and the conveyor speed is adjusted such that the residence time in the oven is 1.25 minutes.
  • the fries are lightly sprayed with warm ( ⁇ I 50°F) conditioned Primex 108 vegetable oil; about 3% oil by weight of the fries is sprayed onto the surface.
  • the oven-finished fries are then immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by tasting.
  • Frozen samples of the Ore-Ida® Vend Fry® for use in the Ore-Ida French Fry VendorTM are obtained from a local distributor and stored at 0°F (-18 °C) or lower.
  • the frozen Ore-Ida® Vend fries are loaded into the freezer compartment of an Ore-Ida Model 890 French Fry VendorTM vending machine (Crane National Vendors, Division of Unidynamics Co ⁇ ., Bridgeton, MO).
  • the Vend fries are baked in the French Fry VendorTM according to the manufacturer's recommendations: about 3.5 oz.
  • Vend fries are deposited into a rotating basket and then baked for about 40 seconds with forced hot air at 465°F (240°C) blowing through the basket.
  • the oven-finished fries are automatically dispensed and then immediately evaluated for various technical attributes or are salted, and evaluated for flavor and texture by tasting.
  • the frozen shoestring-cut par-fried potato strips used as the starting par-fry for preparation of product "D" of this example are further processed by deep-frying.
  • the par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
  • the above French fry products are also evaluated for flavor and texture by tasting
  • the oven- finished French fries accordmg to the present invention (D) have a flavor and texture similar to the "gold standard" deep-fried French fries (F)
  • the oven-finished French fries of the present invention possess the desired textural dichotomy, i e , a moist interior and a crisp crust, that is typically associated with deep-fried French fries
  • the commercial oven fries (E) lack sufficient crispness and do not possess the desired textural dichotomy.
  • a non-digestible fat composition is used to prepare the par-fried potato strips in the following example
  • the non-digestible fat composition is OleanTM, from the Procter & Gamble Company, which comprises a blend of liquid and solid sucrose polyester Sorted and graded Russet Burbank potatoes are peeled, washed, trimmed and cut axially mto shoestring st ⁇ ps (0 25 mch square cross-section)
  • the potato strips are blanched in hot water or steam and partially dried with hot air such that the potato strips are reduced in weight by about 15%
  • the partially dried strips are then par-fried in OleanTM for about 60 seconds at an oil temperature of about 375°F (190 5°C)
  • the par-fried potato strips are then cooled and frozen m a blast freezer at -30°F (-34 4°C) and packaged
  • the par-fried potato strips have a moisture content of about 64% and a fat content of about 8% About 1 lb.
  • par-fried potato strips are further processed by frying in a 45 lb. oil capacity foodservice frying kettle containing OleanTM for about 3 minutes at a temperature of about 300°F ( I49°C).
  • the resulting par-fried potato strips are immediately frozen by immersion in liquid nitrogen for 20 seconds, packaged in foil laminate bags, and stored at normal freezer temperatures of approximately 0°F (-17.8°C).
  • the par-fried potato strips have about 46% moisture and about 20% fat.
  • the resulting reduced calorie oven finished French fries have a texture and flavor very similar to gold standard deep-fried French fries.
  • the finished fries have a bulk moisture content of about 35%, a total fat content of about 15%, an internal moisture content of about 72%, a surface Aw of about 0.4, and a Texture Value of about 250.
  • the frozen shoestring-cut par-fried potato strips used as the starting par- fry in Example 1 A are an acceptable starting product for this example (Simplot Par-Fries; J. R. Simplot Co.; Caldwell, ID).
  • the par- fried potato strips have a moisture content of about 64% and a fat content of about 6%.
  • the frozen par-fried potato strips are further processed by frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 335°F (168.3°C).
  • Primex 108 vegetable oil blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co.
  • the resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds, and then equilibrated to about 0°F (-17.8°C).
  • the par-fries have about 38% moisture and about 17% fat.
  • the frozen par-fries are then surface hydrated by spraying a fine mist of water at ⁇ 70°F (21.1°C) onto the surface of the par-fries.
  • the frozen par-fries are tumbled in order to achieve a uniform application of water onto the surface of the par-fries. Spraying of the water mist is continued until about 7% (by weight of the par-fries) of water is applied to the surface of the par- fries.
  • the frozen hydrated par-fries are then stored at between 0°F (-17.8°C) and 20°F (-6.7°C).
  • the hydrated par-fries comprise about 43% bulk moisture and about 15% total fat. Hydration of the par-fry surface increases the Aw of the crust region, thereby reducing or eliminating the Aw differential between the internal core and the crust region, which is the driving force for moisture migration during frozen storage.
  • the hydrated par- fries are arranged in a single layer on an open wire mesh oven tray and baked for 1.5 minutes at an air temperature of about 425°F (2I8.3°C).
  • a turbulent hot air flow exists within the oven chamber.
  • the air velocity at the center of the oven chamber (immediately above the product bed) is about 900 feet per minute (274 meters per minute).
  • the oven-finished French fries have a desirable textural dichotomy, i.e., a crisp surface texture and moist interior.

Abstract

The present invention relates to French fried potatoes produced from an oven that approximate the attributes and characteristics of French fries that have been finished by deep fat frying. The oven-finished French fries of the present invention can be differentiated from commercial and prior-art oven fries in that they possess a combination of attributes, in particular, bulk moisture, total fat, internal moisture, surface water activity and a Texture Value, that renders them virtually indistinguishable from deep fried French fries. The oven-finished French fries comprise from about 32 % to about 50 % bulk moisture, from about 8 % to about 25 % total fat, from about 55 % to about 80 % internal moisture content, a surface water activity of less than or equal to about 0.55, and a Texture Value (maximum force [grams] or area under the force deformation curve [gram sec] within the first one-third of a specific compression test) of at least about 200.

Description

OVEN-BAKED FRENCH FRIES HAVING DEEP-FRIED TASTE AND TEXTURE
BACKGROUND OF THE INVENTION
The present invention relates to French fried potatoes baked in an oven. More particularly, it relates to oven-finished French fried potatoes that approximate the attributes and characteristics of French fries that have been finished by deep fat frying.
French fried potatoes are one of the most popular convenience foods whether they are prepared at home or purchased from fast food restaurants. Deep-fried French fries are particularly well liked by virtue of their textural dichotomy. This textural dichotomy manifests itself in a product which has a fairly crisp exterior and a fairly tender and moist interior. The method of deep frying has been found to be a particularly suitable way for imparting this desired textural dichotomy to French fried potatoes.
Recent attention has been directed to the use of ovens for preparing French fries from the partially fried (herein after par-fried) frozen state. The prior art oven-finished products are by no means equivalent to deep fried French fries. This is because during oven finishing, moisture migrates from the internal core outward to the crust region. This tends to make the oven-finished French fries limp, i.e., the fries lack surface crispness.
Attempts to improve the texture by longer heating time, higher oven temperature, rapid heating (e.g., microwave), etc. have generally been unable to provide the desired balance of moist interior encased by a low-moisture, crisp crust. Generally, the French fries produced are leathery, dry and tough. Examples of some methods for altering the par-fries and/or methods to produce fully cooked fries, which upon oven-finishing or oven reheating generally result in French fries having poor textural qualities (i.e., dry interiors and tough or soggy exterior crusts), can be found in the prior art, see for example, U.S. 5,000,970 (Shanbhag et al.), U.S. 5,302,410 (Calder et al.), U.S. 3,865,964 (Kellermeier) and U.S. 5,242,699 (Bednar et al.). The poor textural qualities affect the palatability of the oven-finished product. Thus, a great demand exists today for French fried potatoes that are oven-finished and that, in the ready- to-eat state, have the color, texture, mouthfeel and taste of deep fried French fries.
The oven-finished French fries of the present invention provide one or more advantages in relation to the organoleptic properties, specifically the crust crispness and the moistness of the internal core. The oven finished fries have substantially the same textural dichotomy as deep-fried French fries. The external surface (i.e., crust) is moderately crisp and not excessively oily and the interior portion (i.e., core) is well cooked, tender, mealy and moist, yet free from sogginess.
The oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries in that they possess a combination of attributes, in particular, bulk moisture, total fat, internal moisture content, surface water activity (Aw) and Texture Value, that renders them virtually indistinguishable from deep fried French fries. The oven-finished French fries of the present invention can also be differentiated from commercial oven fries based on subjective evaluations (i.e., expert sensory panelists).
It is therefore an objective of the present invention to provide oven-finished French fries that are significantly preferred over commercial and prior art oven finished products on the basis of taste/eating satisfaction and that are parity in taste with deep fried French fries.
It is also an objective of the present invention to provide oven-finished French fries which are virtually indistinguishable from deep-fat fried French fried potatoes which may be purchased in fast food restaurants.
It is further an objective of the present invention to provide oven finished French fries which have a moist interior surrounded by a crisp yet tender outer surface.
These and other objectives of the present invention will be made clear by the disclosure herein.
All percentages are by weight unless otherwise indicated.
SUMMARY OF THE INVENTION
The present invention relates to oven-finished French fried potatoes comprising: a) from about 32% to about 50% bulk moisture; b) from about 8% to about 25% total fat; c) from about 55% to about 80% internal moisture content; d) a surface water activity (Aw) of less than or equal to about 0.55; and e) a Texture Value of at least about 200; wherein said Texture Value is the maximum force (grams) or the area (gram sec) under the force deformation curve during the first one- third of a compression test.
The oven finished French fries have a texture which is virtually indistinguishable from commercial French fries that have been prepared by deep fat frying such as McDonald's French fries.
DETAILED DESCRIPTION OF THE INVENTION
The present invention is concerned primarily with the attributes of oven finished French fries. The present invention further relates to oven finished French fries which are ready to eat, and are virtually indistinguishable from deep-fried French fries.
Definitions
As used herein the term "deep fried French fries" refers to potato strips which have been cooked to a ready-to-eat form by immersion in hot oil.
As used herein the terms "par-fry" or "par-fried" refer to potato strips that have been subjected to at least one frying process (e.g., deep frying), but which have not been completely cooked. As used herein the term "oven finishing" refers to converting the product to a ready-to-eat form by cooking in a toaster, toaster oven, forced air convection oven, high air velocity oven, hot air impingement oven, infrared oven, combined convection/infrared oven, microwave oven, combined microwave/convection oven or a conventional home oven. Typically, cooking entails reducing the moisture content of the food.
As used herein the term "fat" or "oil" refers to edible fatty substances in a general sense, including natural or synthetic fats and oils consisting essentially of triglycerides, such as, for example soybean oil, corn oil, cottonseed oil, canola oil, sunflower oil, palm oil, coconut oil, fish oil, lard and tallow, which may have been partially or completely hydrogenated or modified otherwise, as well as non-toxic fatty materials having properties similar to triglycerides, herein referred to as fat-substitutes, which materials may be partially or fully indigestible. The terms "fat" and "oil" are used interchangeably.
As used herein the term "finished" refers to a product that has been subjected to a cooking process to convert it to a ready-to-eat form.
As used herein the term "conditioned oil" refers to oil which has been previously used for frying for such a time that it has developed fried flavor.
As used herein the term "oven finished" refers to a product that has been subjected to an oven baking process to convert it to a ready-to-eat form.
As used herein the term "oven baking" refers to baking in an oven such as a forced air convection oven, hot air impingement oven, infrared oven, a combination of infrared radiation and convection oven, a toaster, toaster oven, a microwave oven, a combination microwave and forced air convection oven, or a conventional home oven.
As used herein the term "Texture Value" is the maximum force (grams) or the area (gram sec) under the force deformation curve recorded during the first one-third of a compression test (see section on analytical test methods for more details).
OVEN-FINISHED FRENCH FRIES
The critical features of the present invention are the Texture Value, the bulk moisture, the internal moisture content, the surface Aw, and the amount of fat present in the oven-finished product. Importantly, it is the combination of these attributes and not a single attribute that distinguishes the present invention from commercial and prior art oven-finished fries and renders them virtually indistinguishable from deep fried French fries.
The distinguishing features of the present invention reside in part in the recognition of critical physical characteristics of the par-fries and their thermal properties wherein this relationship can be used to insure oven-finished French fries having moist interiors and crisp crusts for a variety of different oven- finishing processes. More particularly, the present invention recognizes that for oven-finished French fries, a certain range of values for surface Aw and Texture Value are required for optimum palatability. One embodiment of the present invention is the par-fried potato strips which may be prepared by processing steps known in the art. The par- fries may be prepared from a variety of raw potatoes known to be suitable for preparing French fries. Preferably the par-fried potato strips are prepared from potatoes of the Russet Burbank, Shepody or Katahdin varieties. The par-fried strips may be of varying shapes and sizes. However, it is preferred that the relatively thin and elongated potato strips known in the art as "shoestrings" be used. Shoestring potato strips, as used herein refer to potato strips that are from about 3/16 to about 5/16 inch square in cross-section and from about 2.5 to about 5 inches in length. Thicker-cut potato strips may also be used herein; e.g., "crinkle cut" strips, straight cut thick potato strips (also known as "regular-cut") and "steak fry" cuts.
The potato strips are blanched according to conventional procedures known in the art. Following blanching, the potato strips may be subjected to additional treatments known in the art. For instance, the potato strips may be treated with sodium acid pyrophosphate (SAPP), a chelating agent used to prevent discoloration of the strips. Dextrose (com syrup) may also be applied to the surface of the strips in order to yield a desired level of brown color development during subsequent processing. In addition, the potato strips may be optionally dried partially to reduce their moisture content. The potato strips are then subjected to one or more frying processes at an oil temperature of from about 270°F (132°C) to about 385° F ( 196 βC). The frying process may involve immersion of the potato strips in oil, a heated oil spray which surrounds the potato strip with hot oil, or frying using an oil foam. In a preferred embodiment, the blanched potato strips are reduced in moisture to a moisture content of not less than about 60%, after which they are fried at an oil temperature of from about 270°F (132°C) to about 335°F (168°C) for a time sufficient to produce par-fries comprising about 30% to about 58% moisture. After frying, the par-fries may be immediately cooled or frozen. Chilling or freezing of the par-fries may be accomplished by methods known in the art. Multiple frying, chilling, and/or freezing steps may be employed during processing of the par-fries. The par-fries may also be treated with various surface treatments (e.g., enrobed with oil; application of hydrocolloid coating; application of water, aqueous solution, or dispersion; etc.) either before or after cooling or freezing. The par-fries may be stored frozen at temperatures between about -70°F (-57°C) and about 20°F (-6.7°C).
The moisture, and fat content and thermal properties of the par-fries are important to produce the oven baked fries of this invention. Of particular importance is the distribution of water in the par-fry and the control of water migration from the internal core to the crust region of the par-fries during storage and oven finishing. By controlling moisture transfer from the internal core to the crust region during frozen storage and oven-finishing, ready-to-eat oven-baked French fries can be prepared that possess a highly palatable moist interior surrounded by a low-moisture, crisp crust region. The textural dichotomy that results in the oven-finished fry is very similar to that which exists in French fries that are finished by deep frying. Moisture migration from the internal core to the crust region during frozen storage can be partially controlled by frying the potato strips to bulk moisture contents that are preferably equal to or greater than about 40%, more preferably equal to or greater than about 42%, and most preferably equal to or greater than about 44%. Moisture migration can also be minimized during frozen storage by hydrating the crust region prior to frozen storage in order to increase the crust Aw and, thereby, reduce or eliminate the Aw differential between the internal core and the crust, which is the driving force for moisture transfer. Hydration of the crust region can be accomplished by application of water, a water mist, an aqueous solution, or an aqueous dispersion to the surface of the par-fry. Preferably a spraying process is used to hydrate the crust region of the par-fries.
Moisture migration from the internal core to the crust region during oven finishing can be minimized by employing oven-finishing conditions that rapidly and/or preferentially dry the surface of the French fry. This can be achieved by selecting oven conditions (temperature, air velocity) that yield a relatively high surface heat transfer coefficient at oven temperature. Higher surface heat transfer coefficients are desirable because this will lead to faster cooking time and the formation of a more distinct and crisp low-moisture crust region. Preferable surface heat transfer coefficients at oven temperature are from about 50 to about 400 watts/m2°C. Preferential drying of the surface of the par-fry can also be achieved by enrobing the par-fries with an edible fat or oil, which increases the conduction of heat from the surrounding air to the fry surface during oven baking. Desired thermal conductivities at oven temperatures of the crust region of the par-fry are from about 0.1 to about 0.3 watts/m°C. Desired thermal conductivities of the high-moisture internal core are from about 0.4 to about 0.7 watts/m°C. Enrobing par- fries with fat or oil also serves the purpose of providing an added barrier to moisture loss from the internal core as the enrobing oil is partially absorbed into the outer crust region during baking. The surface of the par-fry may also be modified to improve the absorption of radiant heat from the oven. A typical method of accomplishing this would be to alter the color, porosity, and/or reflectivity of the par- fry surface.
Thermal conductivities and surface heat transfer coefficients can be calculated as follows.
Surface heat transfer coefficient
The general equation for heat transfer across an interface is well known: Qt = UA (T2 - Tj) - ΔHW + Qr where:
Qt = amount of heat transferred across the boundary (watts, or equivalent energy unit). U = surface heat transfer coefficient (watts/m - C or equivalent)
2 A = surface area of the boundary region (m or equivalent)
T2 = Temperature on the hot side of the boundary ( C or equivalent)
Ti = Temperature on the cooler side of the boundary ( C or equivalent)
ΔHW = heat lost due to evaporation of water from the surface 4 4
Qr = radiative heat transfer = AFσ(T2 - T| ) where F is the shape factor and σ is the Stefan-Boltzman constant.
A careful measurement of temperature on either side of the boundary versus time as well as the moisture level on either side of the boundary versus time, and the temperature of any infrared heating source to which the surface is directly expose will allow calculation of the surface heat transfer coefficient (U).
Thermal Conductivity
Thermal conductivity for a food material with a crust can be calculated once U, T2 and T| are known. k = UL(T2-T,)/(TrTi) k = thermal conductivity (W7m-°C or equivalent) L = crust thickness (m or equivalent) T, = reference temperature
While not wishing to be bound by theory, it is believed that prior art oven fries lack the desirable textural dichotomy associated with high-quality deep-fried French fries because the par-fry attributes (moisture; fat; surface fat; thermal properties) and oven-finishing conditions are not optimized for producing a finished oven fry with a moist interior and a crisp low-moisture crust. For example, many commercial or prior art par-fries are so high in moisture content that upon the recommended oven baking the oven-finished fry is not sufficiently low in bulk moisture content or the crust region has not been sufficiently dehydrated to yield a crisp surface texture. While using more rigorous oven conditions may remove water from the surface of the fries and may improve the crispness of the crust, excessive internal moisture transfer from the internal core to the surface often occurs simultaneously, resulting in oven- finished French fries having one or more of the following textural deficiencies: a tough surface texture; an interior that is perceived as excessively dry; and/or an excessively crunchy overall texture (i.e., the oven- finished fries do not possess the desired textural dichotomy associated with deep fried French fries).
Other methods may also be used to control water migration and water distribution of the par-fries. However "the preferred method, as described above, comprises controlling the bulk moisture and thermal properties (i.e., thermal conductivity of the high-moisture internal core, thermal conductivity of the crust region, and the surface heat transfer coefficient) of the par-fries. The bulk moisture of the par- fries may be controlled by the process conditions used in producing the par-fries; e.g., the conditions used for dehydrating the potato strips before frying; the par-frying conditions; and the level, if any, of surface hydration of the par-fries. The thermal properties of the par-fries may be the modified likewise and additionally may be modified by application of various ingredients onto the surface of the par-fries (e.g., enrobing with oil; coating with hydrocolloids; etc.). The par-fries useful in the present invention have a bulk moisture of greater than about 30%. Typically the bulk moisture is from about 38% to about 58%, preferably from about 40% to about 56%, more preferably from about 42% to about 54% and even more preferably from about 44% to about 50% bulk moisture.
The bulk moisture and thermal properties of the par-fries provide a method for controlling moisture loss from par-fried potato strips during oven finishing such that the resulting French Fries have substantially the same textural dichotomy as deep fried French fries. Further, the bulk moisture and thermal properties of the par-fries indicate how the par-fry processing conditions and oven-finishing conditions may be altered to insure optimum textural characteristics in the oven-finished French fry.
Another embodiment of the present invention is the oven-finished French fries. The oven- finished French fries of the present invention may be baked in various types of ovens, including a forced air convection oven, hot air impingement oven, infrared oven, a combination of infrared radiation and convection oven, a toaster, a toaster oven, a microwave oven, a combination microwave and forced air convection oven, or a conventional home oven. The baking time is less than or equal to about 15 minutes, preferably less than or equal to about 10 minutes, more preferably less than or equal to about 5 minutes, and most preferably less than or equal to about 3 minutes. Upon removal from the oven, the baked fries may optionally be coated with oil to further enhance flavor and mouthfeel. Preferably the oil used for coating the baked fries is a flavored or conditioned oil. The oil may be applied to the surface of the baked fries by methods known in the art; e.g., by spraying warm oil onto the surface or by rapid immersion of the fries into a reservoir of warm oil. The oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries in that they possess a combination of attributes, in particular, a certain Texture Value, bulk moisture, internal moisture, surface Aw, and total fat that renders them virtually indistinguishable from French fries that have been finished by deep-fat frying. Further, the oven-finished French fries of the present invention can be differentiated from commercial and prior art oven-finished French fries based on subjective evaluation (i.e., expert sensory panelists).
Texture Value
A critical attribute of the present invention is the Texture Value of the oven-finished French fries. This value is dependent on a combination of factors such as moisture content, crispness of the crust, degree of dehydration of the crust, and other physical properties of the fries. The Texture Value is determined by the use of a Texture Analyzer equipped with a rectangular, blunt steel plate probe. A compression test is run in which the plate compresses the French fry while the force of resistance is measured (see section on analytical test methods for details). The force (grams) vs. time (sec) data is plotted to produce a force deformation curve. Two textural parameters obtained from the force deformation curves are used to characterize the texture of French fries, average maximum force (grams) and average area (gram sec) within the first 1/3 of the compression test. We have found both of these parameters to correlate with the crispness of French fries and either one may be designated as the Texture Value. High quality oven-finished French fries of the present invention exhibit distinctive textural dichotomy and are characterized by a Texture Value (i.e., maximum force or area) of at least about 200. Preferably the Texture Value is from about 210 to about 1000, more preferably from about 220 to about 600, and even more preferably from about 240 to about 500. Further, the oven-finished French fries of the present invention have a ratio of the average area to the average maximum force of at least 1.0, preferably 1.04 or greater, more preferably 1.08 or greater, even more preferably 1.12 or greater, and most preferably 1.16 or greater. Commercial oven-finished fries prepared according to the manufacturer's oven instructions lack dichotomous textural characteristics as found in the fries of the present invention. Typically the average maximum force (grams) and the average area (gram sec) for commercial and prior- art oven fries are below 200 and the ratio of the average area to the average maximum force is about 1.0 or less.
Over-cooked commercial oven fries may exhibit an average maximum force or area of at least about 200 or greater. However, the oven-finished fries of the present invention can be distinguished from the overcooked commercial oven fries based on the bulk and/or internal moisture and based on the fact that the ratio of the average area to the average maximum force of the overcooked commercial oven fries generally remains at about 1.0 or less.
Bulk Moisture
Another critical attribute of the present invention is the bulk moisture content of the oven-finished French fries. Bulk moisture is the total amount of water in the fries of the present invention. The oven- finished French fries of the present invention have a bulk moisture of from about 32% to about 50%. Shoestring cut, oven-finished French fries of the present invention have a bulk moisture of from about 32% to about 46%. Preferably the bulk moisture of shoestring-cut, oven-finished French fries should be from about 33% to about 44%, and more preferably the bulk moisture should be from about 34% to about 40%. Thicker-cut oven-finished French fries of the present invention (e.g. regular cut, crinkle-cut and steak fries) typically have a bulk moisture of from about 35% to about 50%. Preferably the thicker-cut oven-finished French fries have a bulk moisture of from about 38% to about 48% and more preferably from about 40% to about 46%. The bulk moisture of the products herein can be measured using well- known techniques and commercially available instruments. An oven-finished French fry with a bulk moisture much greater than about 50% will not have developed a sufficient crust structure to yield the desired textural dichotomy (i.e., the fries will lack crispness). At a bulk moisture much less than about 32% the oven- finished fries can become too dry. Keeping the bulk moisture of the oven-finished fries of the present invention at a level between about 32% and 50% allows production of oven fries that possess both a low-moisture, crisp crust region as well as a high-moisture internal core. Internal Moisture
The internal moisture content is also an important characteristic of the present invention. The internal moisture content of oven-finished French fries is the moisture content of the interior starch matrix. As mentioned before the interior portion (i.e., core) is well cooked, tender, mealy and moist, yet free from sogginess. The oven-finished French fries of the present invention have an internal moisture of from about 55% to about 80%, preferably from about 60% to about 77%, more preferably from about 63% to about 75%.
Surface Aw of the Crust
A distinguishing characteristic of the oven-finished fries of the present invention is the exterior crust. The exterior crust is comprised of dehydrated gelatinized starch and oil or fat. Preferably, the exterior crust has substantially the same composition as the crust of deep fried French fries made from raw potatoes. However, the crust may contain ingredients typically applied to the surface of potato strips such as starches, hydrocolloids, gums, flavorings and the like.
It is important that the outer crust region is crisp and relatively low in water activity (Aw). The texture of fried and baked food products is known to be related in part to the Aw of the product. Crisp textures are generally associated with Aw values less than or equal to about 0.55. The surface Aw is a measurement of the water activity of the crust region of the oven-finished French fries (see section on analytical test methods for details concerning surface Aw measurement). The surface Aw is equal to the vapor pressure of water in the outer crust region divided by the vapor pressure of pure water at the same temperature.
The oven-finished French fries of the present invention preferably have a surface Aw of less than or equal to about 0.55, preferably from about 0.10 to about 0.52, more preferably from about 0.15 to about 0.5, and even more preferably from about 0.2 to about 0.45.
Total Fat
Edible oil, natural or synthetic, is generally on the surface and within the crust region of the oven- finished French fry of the type disclosed in the present invention. Edible oils contribute to the flavor, lubricity and texture of the oven-finished French fry. The edible oils or fats present on the surface and within the crust region of the oven-finished French fry are well known by one skilled in the art and include but are not limited to beef tallow, lard, cottonseed oil, canola, soybean oil, corn oil, palm oil, fish oil, safflower oil, sunflower oil, coconut oil, peanut oil, medium chain triglycerides, structured triglycerides containing a combination of short or medium chain fatty acids and long chain fatty acids (e.g. Caprenin- like) and the like or combinations thereof. The oils may be conditioned or flavored, see Flavored Vegetable Oils as a Substitute for Beef Tallow in Deep Frying Applications, Food Technology, pp 90-94 (1989) and U.S. Patent 5,104,678 (Yang et al.) The oils may be partially or completely hydrogenated or modified otherwise. Additionally non- toxic, fatty materials having properties similar to triglycerides such as sucrose polyesters and Oiean™, from the Procter and Gamble Company, and reduced calorie fats, polyol fatty acid polyesters, and diversely esterified polyol polyesters or combinations of regular fats and fat substitutes may also be present on the surface and/or within the crust region of the oven-finished French fries.
Some preferred oils are soybean oil and corn oil. The total amount of oil or fat present in and on the oven-finished French fries of the present invention is from about 8% to about 25%. Shoestring French fries of the present invention typically have from about 12% to about 25% total fat, preferably from about 13% to about 23% fat, and more preferably from about 14% to about 20% total fat. Thicker-cut oven- finished French fries (e.g. regular cut, crinkle-cut and steak fries) typically have a total fat level of from about 8% to about 22%. Preferably the thicker-cut oven-finished French fries have a total fat level of from about 10% to about 20%, and more preferably from about 12% to about 18%.
Preferably the edible fat or oil present on the surface and within the crust region of the oven- finished French fries of the present invention has a free fatty acid level of about 0.8% or less.
Additional Ingredients
Flavoring agents, such as salt, pepper, butter, onion, or garlic may be added to the par-fries or the oven-finished fries oil to enhance the flavor or modify the flavor to any desired taste. One skilled in the art will readily appreciate that the aforementioned listing of flavoring agents is in no way exhaustive, but is merely suggestive of the wide range of additives which are suitable for use in the practice of the present invention.
Other ingredients known in the art may also be added to the edible fats and oils used to fry and/or enrobe the par-fried potato strips, including antioxidants such as TBHQ, chelating agents such as citric acid, and antifoaming agents such as dimethylpolysiloxane.
The oven-finished French fries of the present invention can also be distinguished from commercial and prior-art oven fries based on sensory evaluation and Nuclear Magnetic Resonance (NMR) Imaging. Sensory evaluation reveals that the oven-finished French fries of the present invention possess a desirable "textural dichotomy (i.e., a crisp surface surrounding a moist interior) typically associated with deep-fried French fries. Commercial and prior-art oven fries do not typically display this desired textural dichotomy. NMR imaging provides a cross-sectional image depicting the moisture and fat distribution within the fries. The high-quality oven-finished French fries of the present invention are characterized by NMR images that appear qualitatively similar to the images of deep-fried French fries, i.e., both products are characterized by images that reveal a high moisture internal core surrounded by a low moisture crust region that contains the fat. In contrast, NMR images of commercial oven fries typically appear qualitatively different; i.e., the dichotomous feature of a low-moisture crust surrounding a high-moisture core is not as readily apparent. - I I -
Accordingly, the disclosed embodiments are considered in all respects to be illustrative and not restrictive The scope of the invention is indicated by the appended claims
ANALYTICAL TEST METHODS
A number of parameters are used to characterize elements of the par-fried potato strips and the oven-finished French fries of the present mvention They are quantified by particular experimental analytical procedures Each of these procedures is described in detail as follows
Bulk Moisture Content Test
Moisture content of par-fried potato strips and finished French fries is determined by a forced air oven method as follows
1 Uniformly grind up a representative sample of potato strips or French fries in a blender or conventional food processor
2 Accurately weigh approximately 5 grams of ground sample (weight "A") mto a previously tared metal pan or dish
3 Place the metal dish containmg the sample in a forced air convection oven at 105°C for 2 hours
4 After 2 hours, remove the metal dish containing the dried sample and allow to cool to room temperature tn a desiccator over a desiccant such as anhydrous calcium sulfate
5 Re-weigh the dish containing the dried sample and calculate the weight of the dried sample (weight "B") by subtracting the dish tare weight
6 Calculate the percent moisture of the sample as follows
% Moisture = [(A - B) / (A)] x 100
French Fry Texture Value Test
The Texture Value of finished French fries, which correlates with crispness of the fries, is measured with a TA-XT2 Texture Analyzer (version 05 16 equipped with 25-1 load cell, Texture Technologies Corp , Scarsdale, NY) The Texture Analyzer is linked to a standard personal computer (e g IBM 433DX) that records the data via a software program called XT RA Dimension (version 3 7H, Texture Technologies Corp , Scarsdale, NY)
The Texture Analyzer is configured with a rectangular, blunt steel plate probe (2 5-3 0 mm thickness, 70 mm width, 90 mm length) that is fastened vertically to the mam arm A "Compression Test" on a smgle French fry will be run to generate a plot of Force (grams) vs Time (sec), from which the Texture Value is obtamed Procedure for Set-up and Calibration of the Texture Analyzer
1. Set-up the Texture Analyzer as follows:
Mode: Measure Force in Compression
Option: Return to Start
Force Units: Grams
Time Units: Seconds
Distance Format: Strain
Pre-Test Speed: 2.0 mm/sec
Probe Test Speed: 1.0 mm/sec
Post-Test Speed: 10 mm/sec
Strain: 85.0%
Trigger Type: Auto 10
2. Set the texture method as follows:
Graph Type: Force vs. Time
Auto-Scaling: Off
Force Scaling Max: 5000 grams
Force Scaling Min: 0 grams
Peak Confirmation: On
Force Threshold: 20 grams
File Type: Lotus 1-2-3
Display and Export: Plotted points
Acquisition Rate: 200 pps
Force Units: Grams
Contact Area: 1.00 mm2
Contact Force: 5.0 grams
Calibrate the force by placing a 5 kg weight on the calibration platform and press the "calibrate" button on the Texture Analyzer key pad.
Calibrate the probe distance from the base plate with a probe starting distance from the plate of 10 mm for shoestring-cut fries (increase probe starting distance to 15 mm for thick-cut or steak fries). Ensure that the bottom surface of the probe is parallel to the surface of the base plate.
Procedure for Sample Measurements
1. Immediately following removal of finish-cooked French fries from a fryer (deep-fried) or oven
(oven-baked), place the batch of fries under a heat lamp for 1 minute prior to beginning the texture analysis. The air temperature under the heat lamp is between about 130°F and about 180°F (about 54.3°C to about 82.2°C).
2. After the 1 minute hold time has elapsed, place a single French fry flat on the base plate of the Texture Analyzer (oriented peφendicular to the probe width). Initiate the Compression Test (1.0 mm/sec probe speed) while manually holding the ends of the French fry flush against the base plate.
3. The resulting Force (grams) vs. Time (sec) data is saved for later analysis. Nine additional fry samples from the same batch are tested in an identical manner. The ten fry samples from each batch are selected randomly. Texture analysis of the ten fry samples should be completed within 3-4 minutes. (3-4 minutes after Step 1).
4. Steps #l-#3 are repeated for each new batch of French fries. Generally, 5 to 10 batches of each type of French fry are evaluated in this manner.
Data Analysis
1. The "Force vs. Time" plot for each individual French fry sample is evaluated for the following:
• Maximum Force (grams) within the first 1/3 of the test.
• Area (gram sec) under the curve within the first 1/3 of the test.
(e.g. if the Compression Test requires 6 seconds to complete, the Maximum Force and Area are obtained from the 0-2 second time period)
2. After analysis of the "Force vs. Time" data for all ten French fry samples selected from a given batch, the ten Maximum Force values are averaged and the ten Area values are averaged. A computer program written in Excel automates the task of analyzing the Force vs. Time data for each fry sample and averaging the Maximum Force and Area values for each batch of fries.
3. Remaining batches of a particular French fry type are analyzed in a similar manner (5-10 batches are tested; 10 fries/batch are analyzed). The Maximum Force and Area values for each batch are then averaged to yield an overall average Maximum Force (grams) and Area (gram sec) for that particular fry type.
4. For the puφose of this invention, either the overall average Maximum Force or Area may be designated as the French fry Texture Value. Both texture measurements correlate to crispness of finished French fries.
Determination of the Internal Moisture Content of French Fries
Internal moisture content of finished French fries, i.e. moisture content of the interior starch matrix, is determined as follows: 1. Immediately following removal of finish-cooked French fries from a fryer (deep-fried) or oven (oven-baked), immerse the fries in liquid N2 for 20 seconds to completely freeze the products and stabilize the internal moisture distribution.
2. Store the frozen French fries at about -1 12°F (-80°C) until analysis.
3. Remove several fries from the freezer and place on a stainless steel tray. Allow the fries to warm slightly for several minutes at room temperature to facilitate removal of the crust.
4. Carefully cut off the crust on one side of each frozen fry with a razor blade. Rotate the fries and repeat this procedure until the crust has been removed from all four sides.
5. Collect the frozen interior starch matrix (white solidified material) and immediately place in a capped glass vial. Take care only to collect the interior starch matrix; do not include any crust remnants.
6. Repeat steps #3-#5 until approximately 5 grams of frozen interior starch matrix is collected. This may require about 15-20 fries.
7. Accurately weigh approximately 5 grams of the interior starch matrix (weight "A") into a previously tared metal pan or dish.
8. Place the metal dish containing the interior starch matrix in a forced air convection oven at 105° C for 2 hours.
9. After 2 hours, remove the metal dish containing the dried sample and allow to cool to room temperature in a desiccator over a desiccant such as anhydrous calcium sulfate.
10. Re-weigh the dish containing the dried sample and calculate the weight of the dried sample (weight "B") by subtracting the dish tare weight.
1 1. Calculate the percent moisture of the interior starch matrix as follows: % internal moisture = [(A - B) / (A)] x 100
Determination of the Surface Water Activity (Awl of French Fries
Surface Aw of finished French fries is determined as follows:
1. Immediately following removal of finish-cooked French fries from a fryer (deep-fried) or oven (oven-baked), immerse the fries in liquid N2 for 20 seconds to completely freeze the products and stabilize the internal moisture distribution.
2. Store the frozen French fries at about -1 12°F (-80σC) until analysis.
3. Transfer a bag of French fries (-0.5-1 lb.) from the -112°F (-80°C) freezer to a cooler containing dry ice; ensure the bag is thoroughly packed in dry ice in order to maintain the fries in a frozen state at low temperature. 4 Remove one French fry at a tune from the sample bag and rapidly scrape the surface of the fry with a single-edged razor blade Collect the surface shavings onto a stainless steel tray and immediately transfer the shavmgs to a capped glass vial
Take care only to collect surface shavmgs from the outer crust region of the French fry, do not scrape so hard such that the crust region is penetrated and the interior starch matrix core is exposed
5 Repeat step #4 until approximately 0 3-0 7 gram of surface shavmgs is collected, this will requσe scraping about 10-20 frozen fries
6 Determine the water activity (Aw) of the surface shavmgs using a Rotronic Hygroskop Model DT relative humidity meter (Rotronic Instrument Coφ , Huntington, NY), as follows a Transfer the surface shavmgs to a plastic Aw dish (Rotronic Instrument Coφ ) b Immediately place the Aw dish containing the surface shavings mto one of the humidity cells of the Hygroskop Model DT relative humidity meter and close the cell cover tightly c Allow the meter reading to stabilize (wait 1 hour or longer) before recording the reading and temperature d Convert the stabilized meter reading to % Relative Humidity (RH) usmg a previously prepared calibration graph (meter reading vs %RH) prepared with the followmg RH standards
1 1% RH Saturated solution of Lithium Chlonde (see Greenspan, L , 1977, J
Res Natl Bur Stand , Section A, 81 A 89)
35% RH Standard solution from Rotronic Instrument Coφ
50% RH Standard solution from Rotronic Instrument Coφ
65% RH Standard solution from Rotronic Instrument Coφ e Convert %RH of the surface shavings to Surface Aw as follows
Surface Aw = [%RH / 100]
Total Fat Content Test
Total fat content of par-fried potato stnps, and finished French fries is determined by a solvent extraction method as follows
Apparatus
1 Soxtec HT6 extraction system, unit includes heatmg block and cooling condenser
2 Recirculating water bath for cooling condenser
3 Recirculating oil bath for heating block
4 Extraction beakers 5. Extraction thimbles, 26 mm (Fisher TCI 522-0018).
6. Nitrogen purging gas
7. Vacuum drying oven
8. Analytical balance (4 place)
9. Dispensing pipette (50 ml)
Materials
1. Methylene chloride (Baker 9315-33)
2. Boiling stones (Chemware PTFE Fisher 09-191-20)
3. Silicone oil (Fisher TC 1000-2779)
4. Glass wool (Fisher 1 1 -390)
Procedure
1. Uniformly grind a representative sample of potato strips or French fries in a blender or conventional food processor.
2. Accurately weigh (to four places) a piece of glass wool (sufficient in size to contain sample pieces in the thimble) and the extraction thimble; record weight of thimble + glass wool (weight "A").
3. Load the ground sample into the thimble and cap the loaded thimble with the pre-weighed piece of glass wool.
4. Accurately weigh (to four places) and record the weight of the ground sample, thimble, + glass wool (weight "B").
5. Place two or more boiling stones into an extraction beaker and weigh (to four places); record weight of extraction beaker + boiling stones (weight "C").
6. Place loaded thimbles on the extraction unit and raise the thimbles to rinse position.
7. Pipette 50 ml of methylene chloride into each pre-weighed extraction beaker with boiling stones.
8. Set oil heating bath to 1 10°C and water cooling bath to 28.3°C and allow temperatures to equilibrate.
9. Lower the loaded thimbles into the extraction beaker containing the solvent and allow to boil in the solvent for 60 minutes with the condenser's pet cock in the open position.
10. Raise the thimbles to the rinsing position and rinse for 60 minutes.
1 1. Turn the condenser's pet cock to the closed position and allow the solvent to evaporate for 60 minutes. Turn the nitrogen purging gas on to aid the evaporation. 12. Transfer the beaker to a vacuum oven, pre-warmed to 120°C, for 30 minutes at full vacuum (about 30 mm Hg pressure or less).
13. Allow the beaker to cool to room temperature and weigh (to four places); record the weight of the beaker + boiling stones + extracted fat (weight "D").
14. Calculate percent total fat as follows:
% Fat = [(D - C) / (B - A)] x 100
EXAMPLES Example 1
Two oven-finished French fry products and one deep-fried French fry product are prepared as follows:
A. Oven-finished French fries according to the present invention:
Frozen shoestring-cut par-fried potato strips are an acceptable starting product (e.g., Simplot Par- Fries; J. R. Simplot Co., Caldwell, ID). A typical processing history may include: sorted and graded Russet Burbank potatoes are peeled, washed, trimmed and cut axially into shoestring strips (0.25 inch square cross-section). The potato strips are blanched in hot water or steam and partially dried with hot air such that the potato strips are reduced in weight by about 15%. The partially dried strips are then par-fried in partially-hydrogenated soybean oil (Iodine Value of about 67) for about 50 seconds at an oil temperature of about 375°F (190.5°C). The par-fried potato strips are then cooled and frozen in a blast freezer at -30°F (-34.4°C) and packaged. The par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
About 1 lb. of the frozen par-fried potato strips are further processed by deep frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and corn oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 290°F (143.3°C). The resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds. The moisture content of the resulting par-fry is about 47% and the fat content is about 15%. Immediately after being frozen the par-fries are enrobed with oil by immersing in liquid vegetable oil (conditioned Primex 108) having a temperature of about 335°F (~168°C) for about 1-3 seconds. The resulting oil-enrobed par-fries are again frozen by immersion in liquid nitrogen. The frozen par-fries are packed into sealed foil-laminate bags and stored at normal freezer temperatures of approximately 0°F (-18 °C) to about -20°F (-29°C). The oil-enrobed par-fries contain about 9% surface fat by weight of the fries. The total fat level is about 22% and the bulk moisture level is about 43%.
About 128 grams of the above frozen oil-enrobed par-fries are placed on an open wire mesh oven tray in a single layer and then baked at a temperature of about 400°F (204°C) in a forced air convection oven (Wells Manufacturing Co.; Model No. M42003S) for about 1 minute. Then the fries are transferred to a solid stainless steel oven tray in a single layer and baked an additional 1.5 minutes. A turbulent hot airflow exists within the oven chamber. The air velocity at the center of the oven chamber (immediately above the product bed) is about 900 feet per minute (274 meters per minute). Upon removal from the oven, the fries are immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by sensory testing.
B. Commercial oven-finished French fries:
Frozen retail Ore-Ida® "Shoestrings" French fried potatoes (Ore-Ida Foods, Inc., Boise, ID) are purchased at a local grocery store. The fries comprise about 63% moisture and about 6% fat. The fries are baked in a conventional home oven (General Electric) as follows: approximately 8 oz. of frozen fries are spread uniformly in a single layer over a 9" x 13" solid cooking sheet and baked for about 10 minutes at a temperature of about 450°F (232°C). Upon removal from the oven, the fries are immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by sensory testing.
C. Deep-fried French fries (McDonald's™ French fries; "gold standard"):
The frozen shoestring-cut par-fried potato strips used as the starting par-fry for preparation of product "A" of this example (Simplot Par-fries; J. R. Simplot Co.; Caldwell, ID) are further processed by deep-frying. The par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
About 1.5 lb. of the frozen par-fried potato strips are allowed to thaw for about 1 hour at room temperature (70°F; 21.1°C) and then are deep-fried in a 45 lb. foodservice frying kettle containing conditioned Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and corn oil available from the Procter & Gamble Co.) for about 3 minutes at an oil temperature of about 335°F ( 168°C). Upon removal from the fryer, the deep-fried French fries are immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by sensory testing.
The above French fry products (A, B and C) are evaluated for bulk moisture, total fat, internal moisture content, surface Aw and Texture Value. The results are shown in the following table:
Figure imgf000020_0001
The above data show that the oven-finished French fries according to the present invention (A) have technical attributes that are very similar to deep-fried French fries (C) that are considered the "gold standard." The commercial oven-finished French fries (B) fall outside the desired ranges for surface Aw and the textural parameters (maximum force, area, and ratio of area to maximum force).
The above French fry products are also evaluated for flavor and texture by sensory testing. A panel of -40 trained individuals rate the products for various sensory attributes on a scale of 1 to 9. Two sensory tests are run, evaluating each of the oven fry products directly against the deep-fried French fries. Following are the sensory test results; each numerical value is the average rating for that attribute.
Figure imgf000021_0001
Note. Within each sensory test, attribute ratings with letter superscripts are significantly different at a 95% confidence level.
The sensory test results reveal that the oven-finished French fries according to the present invention (A) have flavor and textural attributes very similar to the deep-fried French fries (C). In particular, the oven-finished French fries according to the present invention possess the desired textural dichotomy, i.e., a moist interior and a crisp crust, that is typically associated with deep-fried French fries. In contrast, the commercial oven fries (B) do not possess the desired textural dichotomy as revealed by a significantly lower surface crispness rating.
Example 2
Two oven-finished French fry products and one deep-fried French fry product are prepared as follows:
D. Oven-finished French fries according to the present invention:
The frozen shoestring-cut par-fried potato strips used as the starting par-fry in Example 1 A are an acceptable starting product for this example (Simplot Par-Fries; J. R. Simplot Co.; Caldwell, ID). The par- fried potato strips have a moisture content of about 64% and a fat content of about 6%. About 1 lb. of the frozen par-fried potato strips are further processed by deep frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 290°F (143.3°C). The resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds. The moisture content of the resulting par-fry is about 48% and the fat content is about 14%. The frozen par-fries are packaged into foil-laminate bags and stored at about 0°F (-18°C).
The frozen par-fries are baked in a double impingement oven (Wolverine Coφoration, Merrimac, MA; Model 2.0 x 051 pilot plant Jetzone™ oven) equipped with a continuous conveyor. The par-fries are arranged in a single layer on an open wire mesh tray that is placed on the oven conveyor belt. Hot air impinges on the product from both the top and bottom, delivered from two banks of tubes located above and below the conveyor belt. The air velocity measured at the product bed is about 5,500 feet per minute (1,676 meters per minute). The air temperature within the oven chamber is 450°F (232°C) and the conveyor speed is adjusted such that the residence time in the oven is 1.25 minutes. Immediately after exiting the oven, the fries are lightly sprayed with warm (~I 50°F) conditioned Primex 108 vegetable oil; about 3% oil by weight of the fries is sprayed onto the surface. The oven-finished fries are then immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by tasting.
E. Commercial oven-finished French fries:
Frozen samples of the Ore-Ida® Vend Fry® for use in the Ore-Ida French Fry Vendor™ (shoestring-cut; Ore-Ida Foods, Inc., Boise, ID) are obtained from a local distributor and stored at 0°F (-18 °C) or lower. The frozen Ore-Ida® Vend fries are loaded into the freezer compartment of an Ore-Ida Model 890 French Fry Vendor™ vending machine (Crane National Vendors, Division of Unidynamics Coφ., Bridgeton, MO). The Vend fries are baked in the French Fry Vendor™ according to the manufacturer's recommendations: about 3.5 oz. of frozen Vend fries are deposited into a rotating basket and then baked for about 40 seconds with forced hot air at 465°F (240°C) blowing through the basket. Upon completion of the baking cycle, the oven-finished fries are automatically dispensed and then immediately evaluated for various technical attributes or are salted, and evaluated for flavor and texture by tasting.
F. Deep-fried French fries (McDonald's™ French fries: "gold standard"):
The frozen shoestring-cut par-fried potato strips used as the starting par-fry for preparation of product "D" of this example (Simplot Par-fries; J.R. Simplot Co.; Caldwell, ID) are further processed by deep-frying. The par-fried potato strips have a moisture content of about 64% and a fat content of about 6%.
About 1.5 lb. of the frozen par-fried potato strips are allowed to thaw for about 1 hour at room temperature (70°F; 2I . TC) and then are deep-fried in a 45 lb. foodservice frying kettle containing conditioned Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co ) for about 3 minutes at an oil temperature of about 335°F (168°C) Upon removal from the fryer, the deep-fried French fries are immediately evaluated for various technical attributes or are salted and evaluated for flavor and texture by tasting
The above French fry products (D, E and F) are evaluated for bulk moisture, total fat, internal moisture content, surface Aw and Texture Value The results are shown m the following table
Figure imgf000023_0001
The above data show that the oven-finished French fries accordmg to the present invention (D) have technical attnbutes that are very similar to deep-fried French fries (F) that are considered the "gold standard " The commercial oven-finished French fries (E) fall outside the desired ranges for surface Aw and the textural parameters (maximum force, area, and ratio of area to maximum force)
The above French fry products are also evaluated for flavor and texture by tasting The oven- finished French fries accordmg to the present invention (D) have a flavor and texture similar to the "gold standard" deep-fried French fries (F) In particular, the oven-finished French fries of the present invention possess the desired textural dichotomy, i e , a moist interior and a crisp crust, that is typically associated with deep-fried French fries In contrast, the commercial oven fries (E) lack sufficient crispness and do not possess the desired textural dichotomy.
Example 3
A non-digestible fat composition is used to prepare the par-fried potato strips in the following example The non-digestible fat composition is Olean™, from the Procter & Gamble Company, which comprises a blend of liquid and solid sucrose polyester Sorted and graded Russet Burbank potatoes are peeled, washed, trimmed and cut axially mto shoestring stπps (0 25 mch square cross-section) The potato strips are blanched in hot water or steam and partially dried with hot air such that the potato strips are reduced in weight by about 15% The partially dried strips are then par-fried in Olean™ for about 60 seconds at an oil temperature of about 375°F (190 5°C) The par-fried potato strips are then cooled and frozen m a blast freezer at -30°F (-34 4°C) and packaged The par-fried potato strips have a moisture content of about 64% and a fat content of about 8% About 1 lb. of the packaged frozen par-fried potato strips are further processed by frying in a 45 lb. oil capacity foodservice frying kettle containing Olean™ for about 3 minutes at a temperature of about 300°F ( I49°C). The resulting par-fried potato strips are immediately frozen by immersion in liquid nitrogen for 20 seconds, packaged in foil laminate bags, and stored at normal freezer temperatures of approximately 0°F (-17.8°C). The par-fried potato strips have about 46% moisture and about 20% fat.
About 128 grams of the frozen par- fries are placed on an open wire mesh oven tray in a single layer and then baked at a temperature of about 400°F (204°C) in a forced air convection oven (Wells Manufacturing Co., Model No. M42003S) for about 2.5 minutes. A turbulent air flow exists within the oven chamber, with an air velocity at the center of the oven chamber just above the product bed of about 900 feet per minute (274 meters per minute). The fries are then transferred to an open wire mesh basket in a single layer and the basket placed within the treatment zone of a high velocity impingement oven (manufactured by Industrial Combustion Services, Inc., Tyrone, GA). Hot air at 375°F is directed onto the surface of the fries at a velocity of about 5,000 feet per minute (1,524 meters per minute). The fries are held in the impingement oven for 15 seconds.
The resulting reduced calorie oven finished French fries have a texture and flavor very similar to gold standard deep-fried French fries. The finished fries have a bulk moisture content of about 35%, a total fat content of about 15%, an internal moisture content of about 72%, a surface Aw of about 0.4, and a Texture Value of about 250.
Example 4
The frozen shoestring-cut par-fried potato strips used as the starting par- fry in Example 1 A are an acceptable starting product for this example (Simplot Par-Fries; J. R. Simplot Co.; Caldwell, ID). The par- fried potato strips have a moisture content of about 64% and a fat content of about 6%.
About 1 lb. of the frozen par-fried potato strips are further processed by frying in a 45 lb. oil capacity foodservice frying kettle containing Primex 108 vegetable oil (blend of partially hydrogenated soybean oil and com oil available from the Procter & Gamble Co.) for about 3 minutes at a temperature of about 335°F (168.3°C). The resulting par-fries are immediately frozen by immersion in liquid nitrogen for 20 seconds, and then equilibrated to about 0°F (-17.8°C). The par-fries have about 38% moisture and about 17% fat. The frozen par-fries are then surface hydrated by spraying a fine mist of water at ~70°F (21.1°C) onto the surface of the par-fries. During the hydration process, the frozen par-fries are tumbled in order to achieve a uniform application of water onto the surface of the par-fries. Spraying of the water mist is continued until about 7% (by weight of the par-fries) of water is applied to the surface of the par- fries. The frozen hydrated par-fries are then stored at between 0°F (-17.8°C) and 20°F (-6.7°C). The hydrated par-fries comprise about 43% bulk moisture and about 15% total fat. Hydration of the par-fry surface increases the Aw of the crust region, thereby reducing or eliminating the Aw differential between the internal core and the crust region, which is the driving force for moisture migration during frozen storage.
About 128 grams of the frozen, hydrated par-fries are prepared for consumption by baking in a forced air convection oven (Wells Manufacturing Co.; Model No. M42003S). The hydrated par- fries are arranged in a single layer on an open wire mesh oven tray and baked for 1.5 minutes at an air temperature of about 425°F (2I8.3°C). A turbulent hot air flow exists within the oven chamber. The air velocity at the center of the oven chamber (immediately above the product bed) is about 900 feet per minute (274 meters per minute). The oven-finished French fries have a desirable textural dichotomy, i.e., a crisp surface texture and moist interior. The finished fries have a bulk moisture content of about 39%, a total fat content of about 16%, an internal moisture content of about 72%, a surface Aw of about 0.4, and a Texture Value of about 290 (maximum force = 237 grams; area = 289 gram sec; ratio of area to maximum force = 1.22).

Claims

What is claimed is:
1. Oven-finished French fried potato product comprising: a) from 32% to 50% bulk moisture; b) from 8% to 25% total fat; and c) a Texture Value of at least 200; wherein said Texture Value is the maximum force (grams) or the area (gram sec) under the force deformation curve during the first one-third of a compression test.
2. The product of Claim 1 wherein said oven-finished fries have a bulk moisture of from 33% to 44%, a total fat of from 13% to 23% and a Texture Value of from 210 to 1,000.
3. The product of Claim 1 or 2 wherein said oven-finished French fries have a surface water activity of less than or equal to 0.55 and an internal moisture of from 55% to 80%.
4. The product of Claim 3 wherein said oven-finished French fries are shoestring- cut fries.
5. The product of Claim 1, 2, 3 or 4 having a surface heat transfer coefficient at oven temperatures of from 50 to 400 watts/m2°C.
6. The product of Claim 1, 2, 3 or 4 having thermal conductivity of the crust region at oven temperatures of from 0.1 to 0.3 watts/m°C.
7. A product according to Claim 1, 2, 3, 4, 5 or 6 having a thermal conductivity of the inner core of from 0.4 to 0.7 watts/m°C.
8. A product according to Claim 7 wherein the ratio of the average area to average maximum force is at least 1.0 in the Texture Value Measurement.
9. A product according to Claim 8 wherein the surface Aw is less than or equal to 0.55.
PCT/US1997/006395 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture WO1997040711A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP9538955A JPH11508148A (en) 1996-04-29 1997-04-16 Oven-baked French fries with deep fry taste and feel
EP97921230A EP0906034A1 (en) 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture
NZ332275A NZ332275A (en) 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture
IL12663297A IL126632A0 (en) 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture
AU27330/97A AU724894B2 (en) 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture
BR9710164-8A BR9710164A (en) 1996-04-29 1997-04-16 Oven-roasted fries having a deep frying flavor and texture.
KR1019980708661A KR20000065080A (en) 1996-04-29 1997-04-16 Oven-baked French fries with deep-fried flavor and texture
NO984915A NO984915L (en) 1996-04-29 1998-10-22 Oven fried french fries with well-flavored and good texture

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63954496A 1996-04-29 1996-04-29
US08/639,544 1996-04-29

Publications (1)

Publication Number Publication Date
WO1997040711A1 true WO1997040711A1 (en) 1997-11-06

Family

ID=24564538

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/006395 WO1997040711A1 (en) 1996-04-29 1997-04-16 Oven-baked french fries having deep-fried taste and texture

Country Status (18)

Country Link
EP (1) EP0906034A1 (en)
JP (1) JPH11508148A (en)
KR (1) KR20000065080A (en)
CN (1) CN1219849A (en)
AR (1) AR006902A1 (en)
AU (1) AU724894B2 (en)
BR (1) BR9710164A (en)
CA (1) CA2251899A1 (en)
CO (1) CO4761044A1 (en)
CZ (1) CZ343898A3 (en)
IL (1) IL126632A0 (en)
MA (1) MA24152A1 (en)
NO (1) NO984915L (en)
NZ (1) NZ332275A (en)
PE (1) PE62998A1 (en)
TW (1) TW366267B (en)
WO (1) WO1997040711A1 (en)
ZA (1) ZA973543B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999021436A1 (en) * 1997-10-29 1999-05-06 The Procter & Gamble Company Storage stable par-fries having reduced levels of pyrazine
WO1999042000A1 (en) * 1998-02-23 1999-08-26 The Procter & Gamble Company Oven finishing system for food products
WO2000008953A1 (en) * 1998-08-13 2000-02-24 The Procter & Gamble Company Oven-baked french fries having extended hold time
WO2001003518A1 (en) * 1999-07-09 2001-01-18 The Procter & Gamble Company Oven-baked french fries comprising 2,4-decadienal and/or methional
WO2021170845A1 (en) 2020-02-27 2021-09-02 Baeten & Co. Edible products

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2670722C (en) * 2007-05-07 2015-09-29 Nonpareil Corporation Baked potato products and process for preparing same

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2215902A1 (en) * 1973-02-01 1974-08-30 American Potato Co
US3865964A (en) * 1971-03-15 1975-02-11 Ore Ida Foods Coating the surface of frozen, fried french fries with atomized fat globules
DE2713935A1 (en) * 1976-03-30 1977-10-20 Mccain Foods Ltd PROCESS FOR PRODUCING FROZEN FRENCH FRIES
US4109020A (en) * 1977-07-01 1978-08-22 The United States Of America As Represented By The Secretary Of The Army Method of producing crisp reheated french fried potatoes
GB2078081A (en) * 1980-06-26 1982-01-06 Lamb Weston Inc A process for preparing frozen french fried potatoes for oven reheating
US4325295A (en) * 1979-02-21 1982-04-20 Heat And Control, Inc. Apparatus for preparing french fried potatoes
US4542030A (en) * 1983-11-25 1985-09-17 Ore-Ida Foods, Inc. Process for preparing low calorie french fry product
US4551340A (en) * 1980-12-02 1985-11-05 General Foods Corporation Process for preparing frozen par-fried potatoes
US4590080A (en) * 1983-03-28 1986-05-20 J. R. Simplot Company Process for preparing parfried and frozen potato products
DE3814587A1 (en) * 1988-04-29 1989-11-09 Eckardt Kg Pfanni Werk Otto Process for the production of deep-frozen french fries
WO1991000023A1 (en) * 1989-06-30 1991-01-10 Horizons International Foods, Inc. Oven-reheatable french fried potatoes and process of preparing
WO1994005165A1 (en) * 1992-08-28 1994-03-17 The Procter & Gamble Company Reduced calorie french fries and other high moisture fat-coated foods having reduced greasiness

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3865964A (en) * 1971-03-15 1975-02-11 Ore Ida Foods Coating the surface of frozen, fried french fries with atomized fat globules
FR2215902A1 (en) * 1973-02-01 1974-08-30 American Potato Co
DE2713935A1 (en) * 1976-03-30 1977-10-20 Mccain Foods Ltd PROCESS FOR PRODUCING FROZEN FRENCH FRIES
US4109020A (en) * 1977-07-01 1978-08-22 The United States Of America As Represented By The Secretary Of The Army Method of producing crisp reheated french fried potatoes
US4325295A (en) * 1979-02-21 1982-04-20 Heat And Control, Inc. Apparatus for preparing french fried potatoes
GB2078081A (en) * 1980-06-26 1982-01-06 Lamb Weston Inc A process for preparing frozen french fried potatoes for oven reheating
US4551340A (en) * 1980-12-02 1985-11-05 General Foods Corporation Process for preparing frozen par-fried potatoes
US4590080A (en) * 1983-03-28 1986-05-20 J. R. Simplot Company Process for preparing parfried and frozen potato products
US4542030A (en) * 1983-11-25 1985-09-17 Ore-Ida Foods, Inc. Process for preparing low calorie french fry product
DE3814587A1 (en) * 1988-04-29 1989-11-09 Eckardt Kg Pfanni Werk Otto Process for the production of deep-frozen french fries
WO1991000023A1 (en) * 1989-06-30 1991-01-10 Horizons International Foods, Inc. Oven-reheatable french fried potatoes and process of preparing
WO1994005165A1 (en) * 1992-08-28 1994-03-17 The Procter & Gamble Company Reduced calorie french fries and other high moisture fat-coated foods having reduced greasiness

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999021436A1 (en) * 1997-10-29 1999-05-06 The Procter & Gamble Company Storage stable par-fries having reduced levels of pyrazine
WO1999042000A1 (en) * 1998-02-23 1999-08-26 The Procter & Gamble Company Oven finishing system for food products
WO2000008953A1 (en) * 1998-08-13 2000-02-24 The Procter & Gamble Company Oven-baked french fries having extended hold time
WO2001003518A1 (en) * 1999-07-09 2001-01-18 The Procter & Gamble Company Oven-baked french fries comprising 2,4-decadienal and/or methional
WO2021170845A1 (en) 2020-02-27 2021-09-02 Baeten & Co. Edible products
BE1028100A1 (en) 2020-02-27 2021-09-20 Baeten & Co Edible products

Also Published As

Publication number Publication date
CN1219849A (en) 1999-06-16
ZA973543B (en) 1997-12-04
NZ332275A (en) 2000-05-26
KR20000065080A (en) 2000-11-06
CZ343898A3 (en) 1999-03-17
EP0906034A1 (en) 1999-04-07
NO984915D0 (en) 1998-10-22
MA24152A1 (en) 1997-12-31
IL126632A0 (en) 1999-08-17
AU2733097A (en) 1997-11-19
AU724894B2 (en) 2000-10-05
BR9710164A (en) 1999-09-28
TW366267B (en) 1999-08-11
PE62998A1 (en) 1998-10-30
CA2251899A1 (en) 1997-11-06
NO984915L (en) 1998-12-10
JPH11508148A (en) 1999-07-21
CO4761044A1 (en) 1999-04-27
AR006902A1 (en) 1999-09-29

Similar Documents

Publication Publication Date Title
US5997938A (en) Process for preparing improved oven-finished french fries
US20020001663A1 (en) Oven-baked French fries having extended hold time
US6013296A (en) Forced air convection oven process for finishing french fries
AU725115B2 (en) Process for preparing frozen par-fried potato strips having deep fried texture when oven finished
TW383214B (en) Oil enrobed par-fried potato strips
AU724894B2 (en) Oven-baked french fries having deep-fried taste and texture
JP2018520705A (en) Method for preparing dried crunch potato as a consumer
USH2091H1 (en) Oven-baked french fries having extended hold time
WO2001003518A1 (en) Oven-baked french fries comprising 2,4-decadienal and/or methional
MXPA98008980A (en) French potatoes cooked in oven, which has the texture of a freido process in abundante ace
MXPA98008979A (en) Process for the preparation of fresh potatoes to lafrancesa, improved when cooking is completed porhorne
WO2022038100A1 (en) Method for producing a par-fried chip

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 97195021.0

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG UZ VN YU AM AZ BY KG KZ MD RU TJ TM

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 332275

Country of ref document: NZ

ENP Entry into the national phase

Ref document number: 2251899

Country of ref document: CA

Ref document number: 2251899

Country of ref document: CA

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 1997921230

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1199800890

Country of ref document: VN

WWE Wipo information: entry into national phase

Ref document number: PV1998-3438

Country of ref document: CZ

WWE Wipo information: entry into national phase

Ref document number: 1998/02174

Country of ref document: TR

ENP Entry into the national phase

Ref document number: 1997 538955

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: PA/a/1998/008980

Country of ref document: MX

Ref document number: 1019980708661

Country of ref document: KR

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: PV1998-3438

Country of ref document: CZ

WWP Wipo information: published in national office

Ref document number: 1997921230

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1019980708661

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 1019980708661

Country of ref document: KR

WWW Wipo information: withdrawn in national office

Ref document number: 1997921230

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: PV1998-3438

Country of ref document: CZ