WO1997025727A1 - Distributed gap electrical choke - Google Patents
Distributed gap electrical choke Download PDFInfo
- Publication number
- WO1997025727A1 WO1997025727A1 PCT/US1997/000178 US9700178W WO9725727A1 WO 1997025727 A1 WO1997025727 A1 WO 1997025727A1 US 9700178 W US9700178 W US 9700178W WO 9725727 A1 WO9725727 A1 WO 9725727A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- choke
- recited
- annealing
- temperature
- core
- Prior art date
Links
- 238000000137 annealing Methods 0.000 claims abstract description 30
- 230000035699 permeability Effects 0.000 claims abstract description 29
- 230000005291 magnetic effect Effects 0.000 claims abstract description 19
- 238000002425 crystallisation Methods 0.000 claims abstract description 16
- 230000008025 crystallization Effects 0.000 claims abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 7
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract 6
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 230000004907 flux Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 5
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 abstract description 3
- 239000011162 core material Substances 0.000 description 31
- 238000004626 scanning electron microscopy Methods 0.000 description 4
- 230000005294 ferromagnetic effect Effects 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 230000005415 magnetization Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/24—Magnetic cores
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/04—Fixed inductances of the signal type with magnetic core
- H01F17/06—Fixed inductances of the signal type with magnetic core with core substantially closed in itself, e.g. toroid
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15308—Amorphous metallic alloys, e.g. glassy metals based on Fe/Ni
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/24—Magnetic cores
- H01F27/25—Magnetic cores made from strips or ribbons
Definitions
- This invention relates to an amorphous metal magnetic core with a distributed gap for electrical choke applications; and more particularly to a method for annealing the amorphous core to create the distributed gap therein.
- An electrical choke is an energy storage inductor.
- the magnetic flux in the air gap remains the same as in the ferromagnetic core material.
- the permeability of the air ⁇ l
- the gap can be discrete or distributed.
- a distributed gap can be introduced by using ferromagnetic powder held together with nonmagnetic binder or by partially crystallizing an amorphous alloy.
- an electrical choke is made based on heat treating Fe- base amorphous cores.
- the maximum permeability is reduced to between 1/50 and 1/30 of the original value, (for maximum permeability of 40,000 this treatment results in values ranging from about 800 and 1300) and the amorphous cores exhibit a degree of crystallization, which does not exceed 10% of the volume.
- the present invention provides electrical chokes having sizes ranging from about 8 mm to 45 mm OD with permeabilities in the range of 100 to 400 and low core losses (less than 70 W/kg at 100 kHz and 0. IT).
- the magnetic properties are maintained under DC bias (at least 40% of the initial permeability is maintained at a DC bias field of 3980 A m or 50 Oe ).
- the present invention a method for heat treating Fe base amorphous alloys in a controlled way to partially crystallize the bulk of the amorphous ribbon and generate microgaps in the cores. As a result of the distributed gaps, the aforementioned properties are achieved.
- the present invention requires certain annealing temperature and time parameters and degree of control of these parameters in order to achieve the desired choke properties.
- Figure 1 is a graph depicting the relation between the permeability of the core and the annealing temperature, the different curves describing material with different crystallization temperatures
- Figure 2 is a graph depicting the relation between the permeability of the cores and the annealing temperature for different annealing times;
- Figure 3 is a graph depicting the loading configuration of the cores for the annealing in order to achieve temperature uniformity within a few degrees;
- Figure 4 is a graph depicting core loss in W/kg of the cores as a function of the DC bias field and the frequency;
- Figure 5 is a graph depicting the permeability of the cores under DC bias field conditions
- Figure 6 depicts a typical cross-sectional Scanning Electron Microscopy (SEM) picture of the ribbon after the annealing; and Figure 7 describes the permeability as a function of the volume percent of crystallinity.
- SEM Scanning Electron Microscopy
- Fig. 1 depicts the permeability of the annealed Fe-base magnetic core as a function of the annealing temperature.
- the permeability was measured with an induction bridge at 10 kHz frequency , 8-turn jig and 100 mV ac excitation
- the annealing time was kept constant at 6 hrs. All the cores were annealed in an inert gas atmosphere.
- the different curves represent Fe-base alloys with small variations in the chemical composition and consequently small changes in their crystallization temperature.
- the crystallization temperatures were measured by Differential Scanning Calorimetry (DSC).
- DSC Differential Scanning Calorimetry
- Fig. 2 depicts the permeability of the annealed Fe-base cores with the same chemical composition as a function of the annealing temperature.
- the different curves represent different annealing times. The plot indicates that for temperatures higher than 450 °C the effect of the annealing temperature dominates the effect of the annealing time.
- Typical magnetic characterization data for the chokes such as core loss and DC bias are shown in Figs. 4 and 5.
- the core loss data are plotted as a function of the DC bias field and the different curves represent different measuring frequencies.
- the data shown are for cores with 25 mm OD.
- An important parameter forthe choke performance is the percent of the initial permeability that remains when the core is driven by a DC bias field.
- Fig. 5 depicts a typical DC bias curve for a core having 35 mm OD.
- SEM scanning electron microscopy
- XRD XRD
- the volume percent of the crystallization was determined from both the SEM and XRD data and is plotted in Fig. 7 as a function of permeability. For permeabilities in the range of 100 to 400 bulk crystallization in the range of 5 to 30% is required.
Abstract
An electrical choke has a magnetic core with a distributed gap. The magnetic core is composed of an iron based, rapidly solidified metallic alloy. The distributed gap configuration is produced by an annealing treatment which causes partial crystallization of the amorphous alloy. As a result of the annealing treatment, the magnetic core exhibits permeability in the range of 100 to 400, low core loss (i.e. less than 70 W/Kg at 100 kHz and 0.1T) and excellent DC bias behavior (at least 40% of the initial permeability is maintained at a DC bias field of 3980 A/m or 50 Oe).
Description
DISTRIBUTED GAP ELECTRICAL CHOKE
BACKGROUND OF THE INVENTION
1. Field Of The Invention :
This invention relates to an amorphous metal magnetic core with a distributed gap for electrical choke applications; and more particularly to a method for annealing the amorphous core to create the distributed gap therein.
2. Description Of The Prior Art:
An electrical choke is an energy storage inductor. For a toroidal shaped inductor the stored energy is W=l/2 [(B2Aelm)/(2μoUτ)] where B is the magnetic flux density, A« is the effective magnetic area of the core, lm is the mean magnetic path length, μ is the peπneability of the free space and μ, is the relative permeability in the material.
By introducing a small air gap in the toroid, the magnetic flux in the air gap remains the same as in the ferromagnetic core material. However, since the permeability of the air (μ~l) is significantly lower than in the typical ferromagnetic material (μ -several thousands) the magnetic field strength(H) in the gap becomes much higher than in the rest of the core (H=B/μ). The energy stored per unit volume in the magnetic field is W=1/2(BH), indicating it is primarily concentrated in the air gap. In other words, the energy storage capacity of the core is enhanced by the introduction of the gap. The gap can be discrete or distributed. A distributed gap can be introduced by using ferromagnetic powder held together with nonmagnetic binder or by partially crystallizing an amorphous alloy. In the second case, ferromagnetic crystalline phases separate and are surrounded by nonmagnetic matrix. This partial crystallization mechanism is utilized in connection with the choke of the present invention.
Electrical chokes based on the principle of annealing Fe-base amorphous cores have been described in GB 2, 1 11,919k and USP 4,812, 181 In US patent 4,812, 181 there is disclosed a method for achieving flat magnetization loop by subjecting Fe base amorphous cores to a long term (more than 10 hrs) anneal at temperatures higher than 410 °C. The method disclosed therein includes the step of crystallizing the surface of the amorphous ribbon, thereby applying stress on the amorphous bulk of the ribbon.
In GB 2, 117,979 , an electrical choke is made based on heat treating Fe- base amorphous cores. The maximum permeability is reduced to between 1/50 and 1/30 of the original value, (for maximum permeability of 40,000 this treatment results in values ranging from about 800 and 1300) and the amorphous cores exhibit a degree of crystallization, which does not exceed 10% of the volume.
For applications in power supplies for notebook computers and other small devices there is a need for a very small size electrical choke with very low permeability (100-300), very low core losses, high saturation magnetization and which can sustain high DC bias magnetic fields.
SUMMARY OF THE INVENTION
The present invention provides electrical chokes having sizes ranging from about 8 mm to 45 mm OD with permeabilities in the range of 100 to 400 and low core losses (less than 70 W/kg at 100 kHz and 0. IT). Advantageously, the magnetic properties are maintained under DC bias (at least 40% of the initial permeability is maintained at a DC bias field of 3980 A m or 50 Oe ).
In addition, there is provided by the present invention a method for heat treating Fe base amorphous alloys in a controlled way to partially crystallize the bulk of the amorphous ribbon and generate microgaps in the cores. As a result of the distributed gaps, the aforementioned properties are achieved.
More specifically, there is provided in accordance with the invention a unique correlation between the degree of crystallization and the permeability
values. In order to achieve permeability in.the range of 100 to 400, bulk crystallization of the amorphous core is required, preferably of the order of 10 to 25% of the core volume.
In addition, the present invention requires certain annealing temperature and time parameters and degree of control of these parameters in order to achieve the desired choke properties.
BRIEF DESCRD7TION OF THE DRAWINGS
The invention will be more fully understood and further advantages will become apparent when reference is had to the following detailed description and the accompanying drawings, in which:
Figure 1 is a graph depicting the relation between the permeability of the core and the annealing temperature, the different curves describing material with different crystallization temperatures; Figure 2 is a graph depicting the relation between the permeability of the cores and the annealing temperature for different annealing times;
Figure 3 is a graph depicting the loading configuration of the cores for the annealing in order to achieve temperature uniformity within a few degrees;
Figure 4 is a graph depicting core loss in W/kg of the cores as a function of the DC bias field and the frequency;
Figure 5 is a graph depicting the permeability of the cores under DC bias field conditions;
Figure 6 depicts a typical cross-sectional Scanning Electron Microscopy (SEM) picture of the ribbon after the annealing; and Figure 7 describes the permeability as a function of the volume percent of crystallinity.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Fig. 1 depicts the permeability of the annealed Fe-base magnetic core as a function of the annealing temperature. The permeability was measured with an induction bridge at 10 kHz frequency , 8-turn jig and 100 mV ac excitation The annealing time was kept constant at 6 hrs. All the cores were annealed in an inert gas atmosphere. The different curves represent Fe-base alloys with small variations in the chemical composition and consequently small changes in their crystallization temperature. The crystallization temperatures were measured by Differential Scanning Calorimetry (DSC). A reduction in the permeability is observed with increasing annealing temperature for a constant annealing time. For a given annealing temperature the permeabilities scale according to the crystallization temperature, i.e. the permeability is highest for the alloy with the highest crystallization temperature.
Fig. 2 depicts the permeability of the annealed Fe-base cores with the same chemical composition as a function of the annealing temperature. The different curves represent different annealing times. The plot indicates that for temperatures higher than 450 °C the effect of the annealing temperature dominates the effect of the annealing time.
The appropriate annealing temperature and time combination are selected for an Fe-B-Si base amorphous alloy on the basis of the information in Figs. 1 and 2. This selection can be made provided the crystallization temperature (Tx) and or chemical composition of the alloy is known. For example, for FegoBuSio which has T*=507 °C in order to achieve permeabilities in the range of 100 to 400 annealing temperatures in the range of 420 to 425 °C for 6 hrs are appropriate.
Referring again to Fig. 1, reproducibility and uniformity for a given permeability value are obtained when a temperature variation of less than one or two degrees is maintained. Special loading configurations have been developed for the annealing process so that the uniformity and reproducibility of the temperature in the oven are established. For a box type inert gas oven wire mesh Al plates(2)
are stacked according to Fig. 3 and the arrangement is placed in the center of the oven. The Al plates are the substrates that hold the cores(l) during the anneal.
Typical magnetic characterization data for the chokes, such as core loss and DC bias are shown in Figs. 4 and 5. The core loss data are plotted as a function of the DC bias field and the different curves represent different measuring frequencies. The data shown are for cores with 25 mm OD. An important parameter forthe choke performance is the percent of the initial permeability that remains when the core is driven by a DC bias field. Fig. 5 depicts a typical DC bias curve for a core having 35 mm OD. Cross-sectional scanning electron microscopy (SEM) and x-ray diffraction
(XRD) were performed to determine the distribution and percent crystallization of the annealed cores. Fig. 6 depicts a typical cross-sectional SEM indicating that both the bulk of the alloy and the surface are crystallized. This is readily distinguished from the method described in US patent 4,812,181, in which only the surface is crystallized.
The volume percent of the crystallization was determined from both the SEM and XRD data and is plotted in Fig. 7 as a function of permeability. For permeabilities in the range of 100 to 400 bulk crystallization in the range of 5 to 30% is required. Having thus described the invention in rather full detail, it will be understood that such detail need not be strictly adhered to but that further changes and modifications may suggest themselves to one skilled in the art, all falling within the scope of the invention as defined by the subjoined claims.
Claims
What is claimed is:
1 An electrical choke, comprising a magnetic core having a distributed gap, said magnetic core consisting essentially of an Fe -base amoφhous metal alloy that is partially crystallized.
2. An electrical choke as recited by claim I, having a permeability ranging from about 100 to 400 at 10 kHz, 40% of the initial permeability being maintained at DC bias magnetic field of 3980 A/m ( 50 Oe), a core loss less than 70 W/kg at 100 kHz and 0. IT bias magnetic field, and a high saturation flux density.
3. A method for producing an electrical choke having a core composed of an amoφhous metal alloy, comprising the step of: annealing the choke in a protective atmosphere at temperature and time parameters that depend upon the crystallization temperature and chemical composition of the amoφhous metal alloy, said time and temperature parameters being selected for a specific iron-based alloy in accordance with data from Figures 1 and 2.
4. A method for producing an electrical choke, as recited by claim 3, wherein said amoφhous metal alloy is Fe«>Bι ιSi<> , said annealing temperature is
425 °C and said annealing time is about 6-8 hrs.
5. A method for producing an electrical choke, as recited by claim 3, wherein said amoφhous metal alloy is 
said annealing temperature is 455 °C and said annealing time is about 4 hrs.
6. A method for producing an electrical choke, as recited by claim 3, wherein said annealing step is carried out in the absence of a magnetic field.
7. A method for producing an electrical choke, as recited by claim 3, wherein said temperature is controlled to within about 2-5 degrees Centigrade during said annealing step, whereby said choke, after said anneal exhibits substantially constant permeability.
8. A method as recited in claim 7, wherein said annealing step is carried out in a box type convection oven and said cores are arranged within said oven in the manner depicted by Figure 3 to thereby control said temperature within about 2 to
5 degrees Centigrade.
9. An electrical choke produced in accordance with the method recited in claim 3, said choke, upon being annealed, being partially crystallized so that substantially all of the amoφhous metal therein is about 10 to 25% crystalline.
10. An electrical choke produced in accordance with the method recited in claim 3, wherein said partial crystallization causes formation of αFe and Fe2B crystal therein.
11. An electrical choke as recited by claim 6, in which said core is coated with a thin high temperature resin which electrically insulates said core and maintains core integrity.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT97901927T ATE215727T1 (en) | 1996-01-11 | 1997-01-08 | ELECTRICAL THROTTLE WITH DISTRIBUTED GAP |
| DK97901927T DK0873567T3 (en) | 1996-01-11 | 1997-01-08 | Electric choke coil with distributed slot |
| DE69711599T DE69711599T2 (en) | 1996-01-11 | 1997-01-08 | ELECTRIC THROTTLE WITH DISTRIBUTED GAP |
| EP97901927A EP0873567B1 (en) | 1996-01-11 | 1997-01-08 | Distributed gap electrical choke |
| JP52533897A JP4629165B2 (en) | 1996-01-11 | 1997-01-08 | Distributed gap electric choke |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58478796A | 1996-01-11 | 1996-01-11 | |
| US08/584,787 | 1996-01-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1997025727A1 true WO1997025727A1 (en) | 1997-07-17 |
Family
ID=24338791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1997/000178 WO1997025727A1 (en) | 1996-01-11 | 1997-01-08 | Distributed gap electrical choke |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0873567B1 (en) |
| JP (2) | JP4629165B2 (en) |
| KR (1) | KR100452535B1 (en) |
| CN (1) | CN1114217C (en) |
| AT (1) | ATE215727T1 (en) |
| DE (1) | DE69711599T2 (en) |
| DK (1) | DK0873567T3 (en) |
| TW (1) | TW351816B (en) |
| WO (1) | WO1997025727A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998041997A1 (en) * | 1997-03-18 | 1998-09-24 | Alliedsignal Inc. | Electrical choke |
| JP2002508585A (en) * | 1998-03-27 | 2002-03-19 | アライドシグナル・インコーポレイテッド | Dry transformer having a substantially rectangular resin-enclosed coil |
| WO2018228736A1 (en) * | 2017-06-14 | 2018-12-20 | Sma Solar Technology Ag | Coil and electrical or electronic device having such a coil |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69942334D1 (en) | 1998-03-02 | 2010-06-17 | Massachusetts Inst Technology | POLY ZINC FINGER PROTEINS WITH IMPROVED LINKERS |
| US6534261B1 (en) | 1999-01-12 | 2003-03-18 | Sangamo Biosciences, Inc. | Regulation of endogenous gene expression in cells using zinc finger proteins |
| DE60023936T2 (en) | 1999-12-06 | 2006-05-24 | Sangamo Biosciences Inc., Richmond | METHODS OF USING RANDOMIZED ZINCFINGER PROTEIN LIBRARIES FOR IDENTIFYING GENERAL FUNCTIONS |
| AU2002241946B2 (en) | 2001-01-22 | 2007-04-26 | Sangamo Therapeutics, Inc. | Modified zinc finger binding proteins |
| US7262054B2 (en) | 2002-01-22 | 2007-08-28 | Sangamo Biosciences, Inc. | Zinc finger proteins for DNA binding and gene regulation in plants |
| US7541909B2 (en) * | 2002-02-08 | 2009-06-02 | Metglas, Inc. | Filter circuit having an Fe-based core |
| DE102004024337A1 (en) * | 2004-05-17 | 2005-12-22 | Vacuumschmelze Gmbh & Co. Kg | Process for producing nanocrystalline current transformer cores, magnetic cores produced by this process, and current transformers with same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4300950A (en) * | 1978-04-20 | 1981-11-17 | General Electric Company | Amorphous metal alloys and ribbons thereof |
| GB2117979A (en) * | 1982-04-01 | 1983-10-19 | Telcon Metals Ltd | Electrical chokes |
| EP0513385A1 (en) * | 1990-11-30 | 1992-11-19 | Mitsui Petrochemical Industries, Ltd. | Iron-base soft magnetic alloy |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62186506A (en) * | 1986-02-12 | 1987-08-14 | Meidensha Electric Mfg Co Ltd | Annealing method of amorphous iron core |
| DE3611527A1 (en) * | 1986-04-05 | 1987-10-08 | Vacuumschmelze Gmbh | METHOD FOR OBTAINING A FLAT MAGNETIZING LOOP IN AMORPHOUS CORES BY A HEAT TREATMENT |
| JP2868121B2 (en) * | 1987-07-28 | 1999-03-10 | 日立金属株式会社 | Method for producing Fe-based magnetic alloy core |
| JP3322407B2 (en) * | 1990-11-30 | 2002-09-09 | 三井化学株式会社 | Fe-based soft magnetic alloy |
| JPH04341544A (en) * | 1991-05-17 | 1992-11-27 | Mitsui Petrochem Ind Ltd | Fe base soft magnetic alloy |
| US5252144A (en) * | 1991-11-04 | 1993-10-12 | Allied Signal Inc. | Heat treatment process and soft magnetic alloys produced thereby |
-
1997
- 1997-01-08 CN CN97191661A patent/CN1114217C/en not_active Expired - Fee Related
- 1997-01-08 EP EP97901927A patent/EP0873567B1/en not_active Expired - Lifetime
- 1997-01-08 KR KR10-1998-0704870A patent/KR100452535B1/en not_active IP Right Cessation
- 1997-01-08 JP JP52533897A patent/JP4629165B2/en not_active Expired - Fee Related
- 1997-01-08 AT AT97901927T patent/ATE215727T1/en active
- 1997-01-08 DK DK97901927T patent/DK0873567T3/en active
- 1997-01-08 WO PCT/US1997/000178 patent/WO1997025727A1/en active IP Right Grant
- 1997-01-08 DE DE69711599T patent/DE69711599T2/en not_active Expired - Lifetime
- 1997-01-20 TW TW086100556A patent/TW351816B/en not_active IP Right Cessation
-
2010
- 2010-09-16 JP JP2010207490A patent/JP4990389B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4300950A (en) * | 1978-04-20 | 1981-11-17 | General Electric Company | Amorphous metal alloys and ribbons thereof |
| GB2117979A (en) * | 1982-04-01 | 1983-10-19 | Telcon Metals Ltd | Electrical chokes |
| EP0513385A1 (en) * | 1990-11-30 | 1992-11-19 | Mitsui Petrochemical Industries, Ltd. | Iron-base soft magnetic alloy |
Non-Patent Citations (2)
| Title |
|---|
| R.V.MAJOR ET AL: "Development of amorphous Fe-B based alloys for Choke and Inductor Applications", IEEE TRANSACTIONS ON MAGNETICS, vol. 20, no. 5, September 1984 (1984-09-01), NEW YORK US, pages 1415 - 1416, XP002030239 * |
| SINGHAL R ET AL: "CRYSTALLIZATION OF GLASSY FE80B20-XSIX(O X 12) ALLOYS", JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, vol. 115, no. 2 / 03, 11 September 1992 (1992-09-11), pages 245 - 249, XP000329941 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998041997A1 (en) * | 1997-03-18 | 1998-09-24 | Alliedsignal Inc. | Electrical choke |
| JP2002508585A (en) * | 1998-03-27 | 2002-03-19 | アライドシグナル・インコーポレイテッド | Dry transformer having a substantially rectangular resin-enclosed coil |
| WO2018228736A1 (en) * | 2017-06-14 | 2018-12-20 | Sma Solar Technology Ag | Coil and electrical or electronic device having such a coil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1114217C (en) | 2003-07-09 |
| EP0873567B1 (en) | 2002-04-03 |
| KR100452535B1 (en) | 2004-12-17 |
| DE69711599D1 (en) | 2002-05-08 |
| JP4629165B2 (en) | 2011-02-09 |
| EP0873567A1 (en) | 1998-10-28 |
| CN1208497A (en) | 1999-02-17 |
| TW351816B (en) | 1999-02-01 |
| JP2011061210A (en) | 2011-03-24 |
| JP2000503169A (en) | 2000-03-14 |
| DE69711599T2 (en) | 2002-10-31 |
| DK0873567T3 (en) | 2002-07-01 |
| ATE215727T1 (en) | 2002-04-15 |
| JP4990389B2 (en) | 2012-08-01 |
| KR19990076747A (en) | 1999-10-15 |
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