WO1997021959A1

WO1997021959A1 - A method and a device for recovery of energy from media containing combustible substances even at low concentration

Info

Publication number: WO1997021959A1
Application number: PCT/SE1995/001476
Authority: WO
Inventors: Björn Heed; Åke KÄLLSTRAND
Original assignee: Megtec Systems Ab
Priority date: 1995-12-08
Filing date: 1995-12-08
Publication date: 1997-06-19
Also published as: EP0865592B1; IL119728A0; IL119728A; PL181258B1; EP0865592A1; PL328697A1; CN1205071A; CA2238096A1; CA2238096C; CN1145757C

Abstract

The invention relates to a method and device for recovery of energy from a medium containing combustible substances even at low concentrations. The method is characterized by raising the temperature of the medium in a regenerative combustor (8), i.e. a reversal flow direction combustion device wherein the combustion takes place in a warm zone, to the combustion temperature at which essentially all chemical energy of the combustible substances is transformed into thermal energy. The heated medium is then utilized for the production of a wanted form of energy.

Description

A METHOD AND A DEVICE FOR RECOVERY OF ENERGY FROM MEDIA CONTAINING COMBUSTIBLE SUBSTANCES EVEN AT LOW

CONCENTRATION

The subject invention relates generally to a method and a device for recovery of energy from media containing combustible substances even at low-concentrations, and more particularly to energy recovery in connection with the purification of said media by combustion of the combustible substances.

It is already known to purify exhaust fumes emanating for in¬ stance from painting and printing works and containing combustible substances, such as solvents, by heating the fumes up to the tem¬ perature of combustion of the combustible substances. However, this is an expensive process on account of the need to heat the entire flow of the exhaust medium. Owing to a "combustion exchanger", one em¬ bodiment of which is described for instance in connection with an ab- sorbtion technique in the Swedish Patent Specification 8903556-2, it is possible to reduce the costs associated with heating the exhaust fumes. In said Patent Specification the combustion exchanger is de¬ fined as an apparatus comprising a heat-accumulating bed which may be heated up to the spontaneous combustion temperature of the combustible substances and in which bed the combustible sub¬ stances, by reversing their direction of flow, attribute to sustaining the spontaneous combustion temperature inside the bed. An appara¬ tus of this type is described also in e.g. US-A-4, 741 ,690. When certain amounts of the combustible substances are present in the medium the heating of the medium inside the combustion exchanger may take place by the energy released from the spontaneous combustion of the substances inside the bed. Supplementary heating thus becomes nec¬ essary only to heat the bed to the spontaneous combustion tempera¬ ture when the plant is being started up or when the quantity of com¬ bustible substances is very small and insufficient to independently sustain the spontaneous combustion temperature inside the bed. Owing to the high efficiency of the combustion exchanger it is, however, comparatively rare that the amount of combustible sub¬ stances in the medium is insufficient, as in the latter case mentioned above. Thus, the amount of combustible substances usually is in excess of the amount required to sustain the spontaneous combus¬ tion temperature inside the bed. This leads to an increase of the heat in the bed, which in turn results in an increased demand for cooling of the bed in order to avoid damages thereto and to the surrounding area. In addition, the fact that the thermal energy developed in the combustion is not recovered is a problem as such, considering the high energy costs and environmenal aspects.

One purpose of the subject invention therefore is to provide a method and an apparatus allowing the surplus of thermal energy gen¬ erated in the combustion in a regenerative combustor, i.e. a reversal flow direction combustion device wherein the combustion takes place in a warm zone, which preferably is a combustion exhanger, to be made use of.

Another purpose of the method and the apparatus according to the invention is to provide not only energy recovery but jointly therewith control of the temperature in the regenerative combustor.

Another purpose of the method and the apparatus according to the invention is to eliminate toxic or climate-endagering or malodor¬ ous substances by burning them.

Yet another purpose of the invention is to recover, from the re- generative combustor, thermal energy of such a quality that it may be used primarily for high temperature output, for instance in the pro¬ duction of electricity.

These and other purposes are achieved in accordance with the invention by means of a method and an apparatus defined in the characterizing clauses of the appended claims.

One embodiment of the subject invention will be described in closer detail in the following with reference to the accompanying drawings, wherein:

Fig. 1 schematically in a view from above illustrates an appara- tus in accordance with the invention for purification of exhaust or ventilation air from a coal mine. Fig. 2 is a schematical lateral view of a combustion exchanger according to the invention.

The apparatus illustrated in Fig. 1 is used to purify a medium, in the subject case the exhaust or ventilation air from a coal mine. Exhaust air of this kind usually contains combustible substances, i.a. combustible methane gas. Exhaust air is carried from a mine shaft 1 via a fan 2 and a valve 3 to a stack 4, or, via a fan 5 to a stack 6 when the inventive apparatus, generally designated by reference 7, is not used. In accordance with the embodiment illustrated the device 7 ac¬ cording to the invention comprises four combustion exchangers, the exchangers being designated generally by references 8, 8-, 8^π, 8^m, 8^IV, but it could of course include a larger or smaller number of combus¬ tion exchangers, depending on the field of usage. Via a process fan 9, which is common to all the combustion exchangers, and a valve 10, one for each combustion exchanger, each combustion exchanger 8 is connected to a plurality of inlet ducts 1 1 and a plurality of outlet ducts 12. In accordance with the embodiment shown there are nine inlet ducts and nine outlet ducts but the number of inlet and outlet ducts could be varied. Each inlet duct 1 1 and each outlet duct 12 is equipped with a damping device, generally designated by references 13 and 14, respectively. By way of a valve 15, one for each combus¬ tion exchanger 8, the outlet ducts 12 lead to the stack 6. The single fan 9 can also be replaced by e.g. four fans, one each for each com- bustion exchanger.

Fig. 2 is a schematical cross-sectional view through a combus¬ tion exchanger 8. The damping devices 13 and 14 are formed with dampers 18 and 19, respectively, which are movable vertically be¬ tween two sealing positions in which each damper sealingly abuts against its channels 16 and 17, respectively. The two dampers 18 and 19 never seal off the same channel and in the position illustrated in continuous lines the damper 18 seals off the entrance 20 to channel 17 whereas the damper 19 seals off the exit 21 from channel 16. Con¬ sequently, the medium containing combustible substances is carried via the inlet duct 11 through the entrance 22 of channel 16 into the bed 23 of the combustion exchanger wherein the substances are burnt in a manner known per se, whereupon the flow continues out through channel 17 and through its exit 24 to the outlet duct 12. This flow is illustrated schematically by continuous arrows 25 in Fig. 2. In a manner known per se the flow direction through the bed 23 of the combustion exchanger should be reversed from time to time to avoid that the heat front of the bed 23 moves too close to one of the chan¬ nels 16, 17. Upon such reversal, the dampers 18 and 19 are moved to the positions illustrated in Fig. 2 in discontinuous lines and the flow associated with these damper positions is illustrated schematically by means of the dotted-line arrows 26. Obviously, the valves 10, 15 may be used to stop the flow to and from a combustion exchanger, for instances during servicing, for re¬ pairs and the like. It is further understood that valve 3 could be a valve which, depending on the flow through the fan 9, opens or closes the flow to the stack 4 in order to ensure that the shaft 1 is always ventilated, independently of the flow through the device 7.

In the area of the centre of the bed 23, the area known as the combustion zone, there is a heating device 27, which could be electri¬ cally heated, with the aid of which the bed could be heated to the spontaneous combustion temperature of the combustible substances, for instance when the combustion exchanger is to be started up.

In the area of the combustion zone there is also a drain or di¬ verting means 28 which is used to divert a part flow of the heated medium after combustion. In accordance with this embodiment, the diverting means 28 is a perforated tube extending along the bed 23 of the combustion zone but could also be configured differently, for in¬ stance as a means arranged to suck medium directly through the wall 29 of the bed 23. In accordance with the illustrated embodiment the diverting means 28 is in turn connected to a steam boiler 30, illus¬ trated schematically in Fig. 1. Medium diverted by the diverting means 28 is carried through the steam boiler 30 to the stack 6 via a fan 31 which compensates for the pressure drop inside the boiler.

Because the spontaneous combustion temperature in the com¬ bustion exchanger is approximately 1000°C in accordance with the embodiment described, according to which the combustible substance preferably consists of methane gas emanating from a coal mine, medium diverted directly from the combustion zone may be efficiently made use of in the steam boiler 30 to generate electric energy by us- ing a steam turbine and a generator. This electric energy could be used in accordance with the embodiment above for instance to oper¬ ate one fan or several fans 2, 5, 9 and 31. Because in mining it is ab¬ solutely necessary that the galleries are ventilated at all times on ac- count of the risks of explosion, it is essential that at least one of the fans 2, 5 permenantly is in function, i.e. also in the case of failure of the electricity mains. Otherwise, the mine has to be evacuated, which is a difficult, time-consuming and costly operation. Owing to the in¬ vention such fans may be operated in a cost-efficient manner without the mine having to rely on supply of electricity from an external dis¬ tribution network. In addition, surplus electric energy generated by the steam boiler, turbine and generator could be sold. The inventive device and method thus make it economically advantageous and technically possible to protect the environment by means of combus- tion inside the bed 23 and at the same time to produce electric en¬ ergy.

In coal mines the methane gas concentration in the exhaust air normally amounts to maximum 20% L.E.L. (Low Explosion Limit). It has proved possible to construct the combustion exchanger in a man- ner allowing a thermal efficiency rate of 98% to be achieved. This means that a combustion exchanger is self-sufficient with respect to sustaining the spontaneous combustion temperature inside the combustion zone when the methane gas concentration in the me¬ dium exceeds 0.1% (2% L.E.L.). Application of the invention thus likewise makes it possible to recover electric energy also from media having a low concentration of combustible substances, which has hitherto not been practically possible. In addition, the amount of medium diverted by the diverting device 28 could be used to control the temperature inside the bed 23 in order to avoid that the combus- tion zone becomes too wide and for instance comes into contact with the bed-surrounding housing, which in itself could involve risks for burns and also unnecessary energy losses. With the inventive device it is also easy to control the diverted energy by varying the diverted flow in order to compensate for any variations in the amounts of combus- tible substance in the media moving through the bed 23. The com¬ bustion process is also very clean, since no prompt and/or t ermal NOx is produced in a flame during the combustion. It is understood that it is quite possible to modify the described embodiment somewhat. For instance, the number of combustion ex¬ changers 8 as also the number of diverting means 28 in each bed 23 could be varied. The damping devices 13, 14 obviously could be con- figured differently as to details from those shown as long as they pro¬ duce a change of flow direction inside the bed 23. In addition, the channels 16, 17 could be differently shaped and could for instance consist of perforated tubes arranged inside the bed 23, a combustion zone being established between them, for instance as described in the Swedish Patent Specification 9103634-3. It is also understood that instead of a combustion exchanger, any regenerative combustor could be used.

The heating medium could of course also be used to produce other forms of energy than electric energy and the diverting means 28 could in this case also be connected to other types of energy-produc¬ tion installations than a steam boiler 30. For instance, the heated medium could be used to heat another medium, such as water, in which case the thermal energy in said second medium is instead used for instance in a district heating system. Furthermore, the thermal energy of the heated medium could in this case be recovered by means of a diverting means in the form of at least one pipe which al¬ lows a corresponding flow of the second medium and which is dis¬ posed inside the combustion zone of a regenerative combustor, pref¬ erably the bed (23) of a combustion exchanger. The device and method according to the invention are not either limited to use in mining operations but could also be used for in¬ stance in ventilation installations in the production of paints, in printing works, coating and lamination processes, the production of chemicals and pharmaceutical products, animal breeding installa- tions, digestion plants, at waste deposits, and in the production of plastics and tyres, in other words in connection with such plants and processes wherein some kind of hydrocarbon compounds, such as solvents, styrene, plastic smokes, fumes from fuel tanks, fumes from fish-processing industries, diesel-engine or natural-gas soot, or com- bustible inorganic substances, i.e. carbon monoxide, e.g. from pro¬ duction of electric-furnace steel, or hydrogen, e.g. from chemical in¬ dustries, are present in the medium to be transferred through the re- generative combustor, which preferably is a combustion exchanger. All kinds of combustible substances, i.e. also malodorous or toxic emanations from various processes or from degassifications or gas escapes can be efficiently eliminated from the medium whilst generat- ing energy. It is also easily understood that the invention need not be used in combination with the stacks 4, 6, the fans 2, 5 or the valve 3 as illustrated in Fig. 1 , but that it could instead be used in any instal¬ lation wherein the medium meets with the above-mentioned require¬ ments. All such varieties and modifications that are encompassed by the basic inventive idea could however be regarded to be covered by the scope of protection of the appended claims.

Claims

1. A method of recovering energy from a medium containing combustible substances even at low concentrations, c h a r a c ¬ t e r i s e d by raising the temperature of the medium in a regen¬ erative combustor (8), i.e. a reversal flow direction combustion device wherein the combustion takes place in a warm zone, preferably a combustion exchanger (8), to the combustion temperature at which essentially all chemical energy of the combustible substances is transformed into thermal energy, and by utilizing the heated medium for the production of a wanted form of energy.

2. A method as claimed in claim 1, c h a r a c t e r i s e d by diverting, after the combustion of the combustible substances, at least a portion of the energy from the regenerative combustor (8) for use in the production of energy.

3. A method as claimed in claim 2, c h a r a c t e r i s e d by diverting at least a part flow of the medium from the regenerative combustor (8).

4. A method as claimed in claim 3, c h a r a c t e r i s e d by utilizing the diverted medium in a steam boiler (30), followed by a turbine and a generator, for the production of electric energy.

5. A method as claimed in any one of claims 1-4, c h a r ¬ a c t e r i s e d in that the medium is a gas.

6. A device for use in performing the method according to any one of claims 3-5, c h a r a c t e r i s e d in that the regenera¬ tive combustor (8) comprises a diverting means (28) for diverting the heated medium.

7. A device as claimed in claim 6, c h a r a c t e r i s e d in that the diverting means (28) is arranged to divert medium from the area of the combustion zone of the regenerative combustor (8), pref¬ erably the bed (23) of a combustion exchanger (8).

8. A device according to claim 7, c h a r a c t e r i s e d in that the diverting means (28) comprises at least one perforated tube which is positioned in the combustion zone and which is connected to an energy-production installation.

9. A device as claimed in claim 8, c h a r a c t e r i s e d in that the energy-production installation is a steam boiler (30), fol¬ lowed by a turbine and a generator.

10. The use of the method and /or the device in accordance with anyone of the above claims for mining operations, wherein the medium is a mine gas.

1 1. The application of the method and/ or the device in accord¬ ance with anyone of claims 1-9 in a digestion plant, wherein the medium is a digestion gas.

12. The application of the method and/ or the device according to anyone of claims 1 -9 in a production plant, wherein the medium is an exhaust gas.

13. The application of the method and/ or the device according to anyone of claims 1-9 in an animal production plant, e.g. a breeding installation, wherein the medium is an exhaust gas.

14. The application of the method and /or the device according to any one of the claims 1-9 in any kind of gas escapes, seepings or bleedings, e.g. natural gas bleedings from the soil, wherein the medi¬ um is a mixture of a combustible substance in air.

15. The application of the method and /or the device according to any one of the claims 1-9 in any kind of escpaes or bleedings from an industrial process, e.g. evaporative losses from processing or sto¬ rage or distribution of combustible substances wherein the medium is a mixture of the substance in air.