WO1997008258A1 - Materiau pour peintures electroconductrices - Google Patents

Materiau pour peintures electroconductrices Download PDF

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Publication number
WO1997008258A1
WO1997008258A1 PCT/RU1996/000238 RU9600238W WO9708258A1 WO 1997008258 A1 WO1997008258 A1 WO 1997008258A1 RU 9600238 W RU9600238 W RU 9600238W WO 9708258 A1 WO9708258 A1 WO 9708258A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrically conducting
carbon
soot
synthetic polymer
containing filler
Prior art date
Application number
PCT/RU1996/000238
Other languages
English (en)
Russian (ru)
Inventor
Alexandr Kozmovich Titomir
Jury Mikhailovich Platonov
Original Assignee
Alexandr Kozmovich Titomir
Jury Mikhailovich Platonov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alexandr Kozmovich Titomir, Jury Mikhailovich Platonov filed Critical Alexandr Kozmovich Titomir
Publication of WO1997008258A1 publication Critical patent/WO1997008258A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes

Definitions

  • Izves ⁇ na ele ⁇ v ⁇ dyaschaya ⁇ as ⁇ a ( ⁇ P, 2662703) for ⁇ sn ⁇ ve ⁇ lime ⁇ n ⁇ g ⁇ ⁇ len ⁇ b ⁇ azuyuscheg ⁇ svyazuyuscheg ⁇ in s ⁇ s ⁇ av ⁇ y v ⁇ di ⁇ ⁇ as ⁇ v ⁇ i ⁇ el ⁇ lime ⁇ n ⁇ g ⁇ svyazuyuscheg ⁇ and mel ⁇ dis ⁇ e ⁇ sny ele ⁇ v ⁇ dny na ⁇ lni ⁇ el as a mixture se ⁇ eb ⁇ a (60-75% ⁇ weight ⁇ m ⁇ nen ⁇ v ⁇ bscheg ⁇ ) and g ⁇ a ⁇ i ⁇ a (0.5- 10 weight% ⁇ ⁇ bscheg ⁇ components).
  • P ⁇ ini maya v ⁇ attention ⁇ , ch ⁇ ⁇ bschee s ⁇ de ⁇ zhanie chas ⁇ its g ⁇ a ⁇ i ⁇ a s ⁇ s ⁇ avlyae ⁇ small Part ⁇ s ⁇ de ⁇ zhaniya in s ⁇ s ⁇ ave izves ⁇ n ⁇ y ele ⁇ v ⁇ dyaschey ⁇ as ⁇ i chas ⁇ its se ⁇ eb ⁇ a, udeln ⁇ e s ⁇ ivlenie ⁇ len ⁇ i la ⁇ as ⁇ chn ⁇ g ⁇ ⁇ y ⁇ iya bude ⁇ ⁇ edelya ⁇ sya in ⁇ sn ⁇ vn ⁇ m, specific s ⁇ ivleniem ⁇ len ⁇ b ⁇ azuyuscheg ⁇ svyazuyuscheg ⁇ , ⁇ e on nes ⁇ l ⁇ ⁇ yad ⁇ v higher than g ⁇ a ⁇ i ⁇ a and se ⁇ eb ⁇ a.
  • Izves ⁇ na ele ⁇ v ⁇ dyaschaya ⁇ lime ⁇ naya ⁇ m ⁇ zitsiya (U ⁇ , zayav ⁇ a ⁇ S ⁇ ⁇ ° 92-03509) on ⁇ sn ⁇ ve ⁇ lime ⁇ n ⁇ g ⁇ ⁇ len ⁇ b ⁇ azuyuscheg ⁇ svyazuyuscheg ⁇ in s ⁇ s ⁇ av ⁇ y v ⁇ di ⁇ ⁇ a ⁇ zhe ⁇ as ⁇ v ⁇ i ⁇ el ⁇ lime ⁇ n ⁇ g ⁇ ⁇ len ⁇ b ⁇ azuyuscheg ⁇ svyazuyuscheg ⁇ and mel ⁇ dis ⁇ e ⁇ sny ele ⁇ v ⁇ dny na ⁇ lni ⁇ el s ⁇ n ⁇ shenii in 40 - 80 weight% ⁇ ⁇ bscheg ⁇ ⁇ m ⁇ zitsii.
  • the electric filler may be made of bulk or carbon particles with a content of 10
  • the known electrical component is compliant with the description of the application, and may contain a small amount of material in the form of a mixture that is inaccessible
  • the well-known composition contains 20-70 wt.% Coal powder, 30-80 wt.% Binder epoxynol and 0.1-2 wt.
  • an optimal power supply to the known power supply unit in the range of 120 - 190 parts by weight. From the masses of the binder leads to the mechanical damage of electric shock from the main known operation. This makes it unacceptable for the receipt of electrical film on products from soft, flexible or elastic materials.
  • the technology of receiving a well-known electrical equipment is quite reliable, long-term and affordable. ⁇ This, in large part, restricts the use of this equipment for the receipt of electric film transmissions. Much more, after applying a well-known application to the film, it is not possible to use it.
  • ⁇ ⁇ sn ⁇ vu zayavlenn ⁇ g ⁇ iz ⁇ b ⁇ e ⁇ eniya was ⁇ l ⁇ zhena task s ⁇ zdaniya ⁇ a ⁇ g ⁇ ele ⁇ v ⁇ dn ⁇ g ⁇ la ⁇ as ⁇ chn ⁇ g ⁇ ma ⁇ e ⁇ iala ( ⁇ as ⁇ i) ⁇ len ⁇ chn ⁇ e ⁇ y ⁇ ie of ⁇ g ⁇ on diele ⁇ iches ⁇ y ⁇ dl ⁇ zh ⁇ e ⁇ bladal ⁇ would s ⁇ abilnymi ⁇ entire ⁇ l ⁇ schadi ele ⁇ iches ⁇ imi ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ ami, vys ⁇ y me ⁇ aniches ⁇ y ⁇ chn ⁇ s ⁇ yu, vys ⁇ imi u ⁇ ugimi ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ ami (elas ⁇ ichn ⁇ s ⁇ yu) and niz ⁇ im value udeln ⁇ g ⁇ s ⁇ ivleniya (
  • the inventive electrical product includes the following ingredients in wt.%: Synthetic binder 7 - 17%
  • the carbon filler provides a mixture of particulate matter with soot and a mass ratio of soot of 0.05-0.1.
  • the ⁇ -08 brand (the extreme urban area is mainly based on the international standard); ⁇ ⁇ 97/08258 ⁇ / ⁇ 96 / 00238
  • condensation of the darkest urban compounds By the use of the condensation of the darkest urban compounds; It is characterized by a high temperature resistance from -60 ° ⁇ to + 350 ° ⁇ ; specific electrical resistance is 10 17 0 m / cm; It is a single, convenient product with a colorless, yellow color without mechanical impurities; loss in bulk of film at a temperature of 350 ° C for 10 hours,% - no more than 1.8; The films are prone to shock and exposed to a temperature of 350 ° C for 10 hours, cm - at least 40).
  • aliphatic amines and diamines, four amine base substrates are used.
  • ⁇ dna ⁇ , b ⁇ lee ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ is ⁇ lz ⁇ va ⁇ ⁇ luchenny amm ⁇ n ⁇ liz ⁇ m me ⁇ il ⁇ i ⁇ l ⁇ silana and dime ⁇ ildi ⁇ l ⁇ silana in ⁇ lu ⁇ le ⁇ ve ⁇ di ⁇ el me ⁇ ilsilazan ⁇ vy ma ⁇ i ⁇ S ⁇ -7-80 (appearance - sm ⁇ l ⁇ b ⁇ aznaya, vyaz ⁇ aya, mu ⁇ naya zhid ⁇ s ⁇ ⁇ sve ⁇ l ⁇ -zhel ⁇ g ⁇ d ⁇ ⁇ emn ⁇ -zhel ⁇ g ⁇ tsve ⁇ a; d ⁇ us ⁇ ae ⁇ sya presence bel ⁇ g ⁇ ⁇ is ⁇ alliches ⁇ g ⁇ ⁇ sad ⁇ a
  • Carbon may be obtained by thermally oxidative destruction of liquid hydrocarbon raw materials, such as, for example, gasoline, tulu, naphthalene, or overrun.
  • Particles of the company preferably, have a well-developed structure, and their sizes are 0.3 - 30 nm. This increases the elasticity of the film on the base of the patented electrically operated media (media). ⁇ ⁇ 97/08258 ⁇ / ⁇ 96 / 00238
  • the methylsilazane reamer is ⁇ -7-80;
  • Example 3 the following were used: - in the quality of a synthetic binder, I tested the phenylsiloxane of ⁇ -08;
  • the methylsilazane reamer is ⁇ -7-80;
  • 3rd appliance (see, table C.3) - composing the equipment for receiving a film from electric power, we use 220 voltages
  • the main advantages of the declared elec- tric part of the consumer goods are that, which ⁇ ⁇ 97/08258 ⁇ / ⁇ 96 / 00238
  • the electric film obtained on it is based on dielectric design and has the following properties:
  • ⁇ zv ⁇ lyayuschee is ⁇ lz ⁇ va ⁇ ⁇ a ⁇ bez ⁇ asnye (12-36 ⁇ ), and ⁇ a ⁇ ⁇ myshlennye (127-220 ⁇ ) values na ⁇ yazheny ⁇ i is ⁇ lz ⁇ vanii la ⁇ as ⁇ chn ⁇ g ⁇ ⁇ len ⁇ chn ⁇ g ⁇ ⁇ y ⁇ iya in ⁇ aches ⁇ ve ⁇ e ⁇ l ⁇ vydelyayuscheg ⁇ elemen ⁇ a ele ⁇ nag ⁇ eva ⁇ elny ⁇ us ⁇ ys ⁇ v and systems; vys ⁇ aya adgezi ⁇ nnaya s ⁇ s ⁇ bn ⁇ s ⁇ , ⁇ zv ⁇ lyayuschaya is ⁇ lz ⁇ va ⁇ shi ⁇ y s ⁇ e ⁇ ⁇ dl ⁇ zhe ⁇ ,
  • Ele ⁇ v ⁇ dny la ⁇ as ⁇ chny ma ⁇ e ⁇ ial, s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, m ⁇ zhe ⁇ by ⁇ is ⁇ lz ⁇ van for ⁇ lucheniya ele ⁇ e ⁇ l ⁇ vydelyayuschi ⁇ ⁇ len ⁇ chny ⁇ ⁇ y ⁇ y ⁇ imenyaemy ⁇ , ⁇ eimusches ⁇ venn ⁇ in ⁇ izv ⁇ ds ⁇ ve is ⁇ chni ⁇ v ⁇ e ⁇ l ⁇ v ⁇ y ene ⁇ gii with ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y ⁇ e ⁇ l ⁇ vydelyayuschi ⁇ ⁇ ve ⁇ n ⁇ s ⁇ ey ⁇ 250 ° C 700 ° C d ⁇ ⁇ ab ⁇ ayuschi ⁇ in dia ⁇ az ⁇ ne na ⁇ yazheny ⁇ 12B d ⁇ 220v.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Paints Or Removers (AREA)

Abstract

Cette invention se rapporte au domaine de la production de matériaux pour peintures électroconductrices à partir de liants polymères synthétiques. Cette invention peut être utilisée dans divers domaines de l'industrie afin d'obtenir des revêtements de type film conducteur d'électricité, notamment en ce qui concerne de grandes surfaces, qui possèdent des caractéristiques de stabilité électrique sur toute la surface qu'ils recouvrent. Le domaine d'application préféré est celui des appareils de chauffage électrique et de systèmes à vocations diverses. Ce matériau pour peinture électroconductrice comprend un liant polymère synthétique, une matière de charge contenant du carbone, un agent de solidification, ainsi qu'un solvant organique. On utilise en qualité de matière de charge contenant du carbone, un mélange de graphite et de suie, la proportion en poids de la suie par rapport au graphite étant de 0,05 à 0,1. On utilise en qualité de liant polymère synthétique des polyméthylphénylsiloxanes ayant une structure ramifiée ou cyclique. Cette invention concerne les proportions en % en poids suivantes des composants: de 7 à 17 en ce qui concerne le liant polymère synthétique; de 0,7 à 16,1 en ce qui concerne la matière de charge contenant du carbone; et de 2,5 à 5,5 en ce qui concerne l'agent de solidification, le solvant organique représentant le reste. La plage de température préférée pour l'utilisation des revêtements électroconducteurs, obtenus à partir du matériau pour peinture électroconductrice décrit dans la présente invention, est de 250° C à 700° C.
PCT/RU1996/000238 1995-08-23 1996-08-21 Materiau pour peintures electroconductrices WO1997008258A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU95114432 1995-08-23
RU95114432A RU2083622C1 (ru) 1995-08-23 1995-08-23 Электропроводный лакокрасочный материал

Publications (1)

Publication Number Publication Date
WO1997008258A1 true WO1997008258A1 (fr) 1997-03-06

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RU (1) RU2083622C1 (fr)
WO (1) WO1997008258A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1043153A1 (ru) * 1982-05-21 1983-09-23 Ордена Трудового Красного Знамени Московский Институт Тонкой Химической Технологии Им.М.В.Ломоносова Вулканизуема резинова смесь на основе карбоцепного каучука
EP0085413B1 (fr) * 1982-01-30 1987-04-29 Daikin Kogyo Co., Ltd. Composition de revêtement électroconductive
SU1641840A1 (ru) * 1988-12-07 1991-04-15 Научно-исследовательский институт пластических масс им.Г.С.Петрова Научно-производственного объединения "Пластмассы" Электропровод ща полимерна композици
RU2012575C1 (ru) * 1991-05-05 1994-05-15 Павлова Галина Максимовна Электропроводная полимерная композиция

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0085413B1 (fr) * 1982-01-30 1987-04-29 Daikin Kogyo Co., Ltd. Composition de revêtement électroconductive
SU1043153A1 (ru) * 1982-05-21 1983-09-23 Ордена Трудового Красного Знамени Московский Институт Тонкой Химической Технологии Им.М.В.Ломоносова Вулканизуема резинова смесь на основе карбоцепного каучука
SU1641840A1 (ru) * 1988-12-07 1991-04-15 Научно-исследовательский институт пластических масс им.Г.С.Петрова Научно-производственного объединения "Пластмассы" Электропровод ща полимерна композици
RU2012575C1 (ru) * 1991-05-05 1994-05-15 Павлова Галина Максимовна Электропроводная полимерная композиция

Also Published As

Publication number Publication date
RU2083622C1 (ru) 1997-07-10

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