WO1996037632A1 - Nozzle for blowing gas into molten metal and usage thereof - Google Patents

Nozzle for blowing gas into molten metal and usage thereof Download PDF

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Publication number
WO1996037632A1
WO1996037632A1 PCT/JP1996/001356 JP9601356W WO9637632A1 WO 1996037632 A1 WO1996037632 A1 WO 1996037632A1 JP 9601356 W JP9601356 W JP 9601356W WO 9637632 A1 WO9637632 A1 WO 9637632A1
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WO
WIPO (PCT)
Prior art keywords
furnace
nozzle
gas
gas injection
metal
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Application number
PCT/JP1996/001356
Other languages
French (fr)
Japanese (ja)
Inventor
Hiroshi Yamada
Original Assignee
Japan Casting & Forging Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Casting & Forging Corporation filed Critical Japan Casting & Forging Corporation
Priority to DE69615508T priority Critical patent/DE69615508T2/en
Priority to EP96914400A priority patent/EP0776983B1/en
Priority to JP53555896A priority patent/JP3894502B2/en
Publication of WO1996037632A1 publication Critical patent/WO1996037632A1/en
Priority to US08/788,986 priority patent/US5863490A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/48Bottoms or tuyéres of converters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases

Definitions

  • the present invention relates to a gas injection nozzle for molten metal in an electric furnace or other refining furnaces, and particularly to a gas injection nozzle for molten metal that can easily and promptly perform repairs at the time of loss due to loss of the nozzle. How to use.
  • FIG. 5 is an explanatory view of an example of a conventionally used gas injection nozzle.
  • FIG. 5 (a) is an example of a single pipe nozzle
  • FIG. 5 (b) is an example of a double pipe nozzle
  • FIG. Figure (c) is an example of a multi-tube buzzard
  • Figure 5 (d) is an example of a porous plug.
  • (10) is a gas supply pipe
  • (11) is a furnace bottom refractory
  • (12) is a blowing gas
  • (17) is a cooling gas supply pipe
  • (18) is a porous brick.
  • Fig. 5 (c) As a multi-tube nozzle, there is a refractory block in which a plurality of thin metal pipes are embedded. It is considered to be preferable because bubbles of blown gas of uniform size can be obtained, and it is widely used as a gas blow nozzle provided at the bottom of an electric furnace.
  • Japanese Patent Application Laid-Open No. 58-819337 discloses a means for simplifying buzzard repair work.
  • a refined gas blower comprising a nozzle made of a refractory having a through hole and a thin metal tube inserted into the through hole, wherein an annular gap is provided between the through hole and the thin metal tube. Plug "is disclosed.
  • Fig. 6 is an explanatory view of this purified gas blowing plug. As shown in Fig. 6 (a), a gap is provided between the refractory nozzle and the metal thin tube, and the metal thin tube and the gas supply tube are connected.
  • the annular gap should be large enough to prevent molten metal from leaking. At the time of repair, it is intended to simplify the work by replacing only the thin metal tubes.
  • the productivity is rarely reduced, and the work of replacement in a bad working environment can be reduced.
  • the goal is to provide a gas injection nozzle that does not leak and how to use it.
  • FIG. 1 is an explanatory view of an example of a gas injection nozzle of the present invention.
  • FIG. 1 (a) is an explanatory view of a longitudinal section of a gas injection nozzle
  • FIG. 1 (b) is an explanatory view of FIG. 1 (a).
  • Fig. 1 (c) shows the gas injection nozzle and the supply gas injection nozzle. It is explanatory drawing of the example of the connection part of a case.
  • the present invention relates to a refractory book (4) provided with pores (3) penetrating linearly from the inside of the furnace to the outside of the furnace, and a mounting bracket formed integrally with the refractory block (4).
  • the gas (12) is supplied to the outside of the furnace of the thin tube (2) of metal by blowing the gas (12) into the molten metal from the inner end of the furnace.
  • a gas injection nozzle for molten metal is supplied to the outside of the furnace of the thin tube (2) of metal by blowing the gas (12) into the molten metal from the inner end of the furnace.
  • One end of the mounting bracket (22) is a straight tube, and the other end is formed in a pan shape conforming to the shape of the bottom of the refractory block (4), and the refractory block (4) receives the mounting bracket (22). Fitted and adhered to the dish-shaped part.
  • the straight tubular end of the fitting (22) is connected to one end of a connecting fitting (23), and the other end of the connecting fitting (23) is connected to a gas blowing hose ( Linked to 15).
  • the end of the thin metal tube (2) penetrates the rubber (14) arranged in the connecting fitting (23) and protrudes toward the gas injection hose (15).
  • the gap between the outer circumference of the thin metal tube (2) and the inner surface of the connecting fitting (23) is sealed with rubber (14), and all the blowing gas (12) sent from the gas blowing hose (15) is made of metal. Is supplied into the thin tube (2).
  • Fig. 1 shows the case where there is one metal thin tube (2). Even if there are a plurality of thin tubes, the gap between the outer periphery of each thin tube and the inner surface of the connection fitting is similarly sealed with rubber, All blowing Charge gas can be distributed to each capillary.
  • the gas injection nozzle (1) of the present invention is mounted inside the tuyere brick (6) provided on the hearth refractory (11) and the support ring (21). And the metal fittings (20).
  • the size of the gap between the nozzle and the tuyere brick is not limited, but it is filled with irregular-shaped refractories such as mortar and castables.
  • the metal thin tube (2) for example, a stainless steel pipe having an inner diameter of 1 to 2 mm can be used, but the inner diameter and the number of the thin tubes can be appropriately selected according to the amount of gas to be blown.
  • the thin tube may be a single tube or a double tube.
  • the inner diameter of the pores (3) should be larger than the outer diameter of the thin metal tube in the range of 0 to 4 mm so that the thin metal tube (2) can slide.
  • FIG. 2 is an explanatory view of an example of a method of using the gas injection nozzle according to the present invention.
  • the gas injection nozzle (1) of the present invention is also used repeatedly, the inside of the furnace of the gas injection nozzle (1) and its surroundings have greater wear of refractories than other parts, as shown in FIG. 2 (a).
  • the wear part (8) is generated as described above.
  • the present invention slides the metal thin tube (2) upward in the small hole (3), and as shown in FIG. Protrude.
  • the worn portion (8) is filled with a fire-resistant repair material (16) without closing the inside end of the thin metal tube (2).
  • the inner end of the metal tubule (2) protrudes further from the surface after completion of the filling of the repair material (16), but when the metal tubule (2) protrudes in this manner, Even if the worn part (8) is repaired with a normal in-furnace repair material using a normally used repair device such as a sand slinger, the inside end of the thin metal tube (2) is repaired. It is not buried in the material (16) and does not block.
  • the gas injection nozzle 1 of the present invention when used, the gas injection nozzle and its Can be easily repaired at the same time as the repair of the worn part of the hearth and the furnace wall, which is performed as a daily work, and the repair of the daily work extends the life of the gas injection nozzle and increases the gas injection.
  • the frequency of nozzle replacement is significantly reduced.
  • FIG. 3 is an explanatory view of an example of another gas injection nozzle of the present invention.
  • FIG. 3 (a) is an explanatory view of a longitudinal section of the gas injection nozzle
  • FIG. 3 (b) is FIG.
  • FIG. 3A is an explanatory view in which the gas injection nozzle of FIG.
  • the gas injection nozzle in Fig. 3 (a) is characterized in that the refractory block (4) is vertically divided into two sections, and the other structure is the gas injection nozzle in Fig. 1 (a). Same as nozzle.
  • the end of the mounting bracket (22) in Fig. 3 (a) is connected to the gas blowing hose (1) via the connecting bracket (23),
  • the outer circumference of the pipe (2) is sealed by the rubber (14) as in the case of the gas injection nozzle in FIG.
  • this nozzle is mounted inside the brick (6) provided on the hearth refractory (11), and the support ring (21) and the stopper (20) are installed. Is attached to the furnace skin (19). At this time, the size of the gap between the nozzle and the tuyere brick is not limited, but it is filled with irregular refractories such as mortar and castables.
  • FIG. 4 is an explanatory view of an example of a method of using another gas injection nozzle of the present invention shown in FIG.
  • the metal tubing (2) is slid upward through the pores (3) so that the end protrudes inside the furnace.
  • install the upper part (4a) hereinafter referred to as “repair brick” of the new refractory block, and fill the surrounding wear part (8) with the refractory repair material (16).
  • the nozzle life after the repair can be extended as compared with the case where the repair is performed using only the amorphous refractory repair material.
  • the metal tubule (2) does not protrude after the repair, the number of use of the tubule can be increased.
  • FIG. 1 is an explanatory view of an example of a gas injection nozzle of the present invention.
  • FIG. 2 is an explanatory diagram of an example of a method of using the gas injection nozzle according to the present invention.
  • FIG. 3 is an explanatory view of an example of another gas injection nozzle of the present invention.
  • FIG. 4 is an explanatory diagram of an example of a method of using another gas injection nozzle of the present invention.
  • FIG. 5 is an explanatory view of an example of a conventionally used gas injection nozzle.
  • FIG. 6 is an explanatory view of a conventional fine gas blowing plug.
  • a single hole (3) with an inner diameter of 5 mm through which a metal thin tube (2) is passed is provided, and gas is injected from the bottom of the furnace with an electric furnace.
  • the metal tubule (2) has an inner diameter of 2 mm, an outer diameter of 4 mm, and a length of 2 m.
  • the metal tubule (2) is supplied using the connection fitting (23) shown in Fig. 1 (c). Connected to gas injection hose (15).
  • the gas injection volume during melting and refining is 30-100 lZmin.
  • the supply gas injection hose (15) shown in Fig. 1 (c) was removed, and the tip of the metal thin tube (2) on the inside of the furnace was removed.
  • the metal tube is slid until it reaches the furnace bottom surface height after repair, and then the connection fitting (23) and the supply gas injection (15).
  • the repair material used was ordinary refractory repair material (16) used for hearth repair.
  • the gas was blown from the gas blowing nozzle while the repair material was being filled.
  • the metal tubing (2) was replaced with a new one, and further operations and repairs were performed.
  • molten metal was sometimes inserted into the gap between the pores (3) and the metal thin tube (2) and solidified. By hitting the metal tube (2) from below, the metal tube (2) could be easily slid.
  • the gas injection nozzle (1) When the erosion length of the gas injection nozzle (1) inside the furnace reached 300 mm, the gas injection nozzle (1) was replaced with a new one.
  • the nozzle can be used for more than 300 charges, and its life is remarkably improved compared to the conventional gas injection nozzle that was replaced every about 50 charges.
  • Table 1 shows an example of comparison of nozzle life with the gas injection nozzles in Fig. 1 and Fig. 3.
  • Case 1 in Table 1 shows a case where the nozzle with the split structure shown in Fig. 3 was used and repaired with a repair brick. After performing the gas injection operation for 170 to 200 hours, remove the eroded refractory block (upper part), slide the metal tube up above the repair brick, and then fire A repair brick of the same shape as the block (upper part) of the object was glued to the block (lower part) of the refractory with an adhesive. At this time, the gap between the thin metal tube and the pores of the repair brick was also filled with non-breathable refractory.
  • the eroded part of the tuyere brick (upper) was filled with irregular-shaped refractories to complete the first recovery.
  • the second to fifth repairs were performed every time the machine was used for 170 to 200 hours.
  • the tuyere bricks (upper) were also replaced during the even-numbered repairs.
  • the refractory block (upper part) and the repair bricks used had a length of 200 faces, but the remaining dimensions at the time of the repair were 50 to 100.
  • the nozzle was replaced for inspection after using it for 170 to 200 hours after the fifth repair, but the refractory block (lower part) did not show any erosion and could be used continuously. It was in a state.
  • Case 2 in Table 1 shows the case of using the monolithic nose ⁇ shown in Fig. 1 and repairing it only with irregular refractories. -After performing the gas injection operation for 170 to 200 hours, slide the metal thin tube upward to the height corresponding to the erosion loss part, and the erosion of the tuyere brick and the refractory block Repairs were made to fill the sections with irregular refractories.
  • the frequency of shutting down the furnace for replacing the gas injection nozzle is reduced, so that the productivity is rarely reduced, and the replacement work in a bad working environment is reduced. can do. Further, since the structure of the nozzle is simple, the nozzle can be manufactured at low cost.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

A nozzle for blowing a gas into a molten metal in a stable manner without causing the leakage of gas from its periphery, which has a simple structure and a long life, so that it does not require frequent replacements. The gas blowing nozzle comprises a refractory block formed unitarily with a metallic mounting member and provided with a small diameter through hole therein, and a small-diameter metallic gas blowing tube inserted slidably through the small-diameter hole. When the gas blowing nozzle and the surrounding refractory are worn, the metallic gas blowing tube is extended into the interior of a furnace, and a worn portion is repaired by packing a repairing material therein.

Description

明 細 書 溶融金属へのガス吹込みノズノレ及びその使用方法 [技術分野]  Description Gas injection into molten metal and its use [Technical field]
本発明は、 電気炉その他の精鍊炉内の溶融金属へのガス吹込みノズルに関し、 とくに、 ノズ レ損耗時の補修を簡便かつ迅速に行うことができる溶融金属へのガ ス吹込みノズノレ及びその使用方法に関する。  TECHNICAL FIELD The present invention relates to a gas injection nozzle for molten metal in an electric furnace or other refining furnaces, and particularly to a gas injection nozzle for molten metal that can easily and promptly perform repairs at the time of loss due to loss of the nozzle. How to use.
[背景技術]  [Background technology]
第 5図は従来から使用されているガス吹込みノズルの例の説明図で、 第 5図 ( a ) は単管ノズルの例、 第 5図 (b ) は 2重管ノズルの例、 第 5図 (c ) は多 管ノスリレの例、 第 5図 (d ) はポーラスプラグの例である。 図中(1 0 )はガス供 給管、 (1 1 )は炉底耐火物、 (1 2 )は吹込ガス、 (1 7 )は冷却ガス供給管、 ( 1 8 )はポーラス煉瓦である。 これ等の中で第 5図 (c ) 多管ノスレとしては、 複数本の細い金属管を埋め込んだ耐火物ブロックのものがあるが、 この多管ノズ ルを用いると溶融金属中に微細で且つ大きさが揃った吹込みガスの気泡が得られ るために好ましいと考えられており、 電気炉の炉底に設けるガス吹込みノズルと して広く使用されている。  FIG. 5 is an explanatory view of an example of a conventionally used gas injection nozzle. FIG. 5 (a) is an example of a single pipe nozzle, FIG. 5 (b) is an example of a double pipe nozzle, FIG. Figure (c) is an example of a multi-tube buzzard, and Figure 5 (d) is an example of a porous plug. In the figure, (10) is a gas supply pipe, (11) is a furnace bottom refractory, (12) is a blowing gas, (17) is a cooling gas supply pipe, and (18) is a porous brick. Among them, Fig. 5 (c) As a multi-tube nozzle, there is a refractory block in which a plurality of thin metal pipes are embedded. It is considered to be preferable because bubbles of blown gas of uniform size can be obtained, and it is widely used as a gas blow nozzle provided at the bottom of an electric furnace.
ガス吹込みノズルを用いて溶融金属内へガスを吹き込むと、 炉内側のガス吹込 みノズ Λの周辺は溶融金属が強く流動するために、 他部よりも耐火物の損耗が大 きく、 使用を繰り返すと例えば第 2図 (a ) にみられるような損耗部(8 )が発生 する。 損耗が進み損耗部( 8 )が大きくなるとガス吹込みノズルを取リ替える補修 を行うが、 しかしこの補修は炉を休止させて行うために炉の生産性を低下させる ことになるし、 また補修作業の環境は悪い。 このためにガス吹込みノズルを頻繁 に取リ替える補修は好ましくない。 When gas is injected into the molten metal using the gas injection nozzle, the molten metal flows strongly around the gas injection nozzle 内側 inside the furnace, and the refractory is more worn away than other parts. When repeated, a worn portion (8) as shown in FIG. 2 (a) is generated. When the wear progresses and the worn part (8) becomes large, repairs are performed to replace the gas injection nozzle. However, this repair reduces the productivity of the furnace because the furnace is stopped and repairs are performed. The working environment is bad. For this purpose, frequently use gas injection nozzles. It is not preferable to replace it with a new one.
ノスリレの補修作業を簡便にする手段として、 特開昭 5 8— 8 1 9 3 7号公報に Japanese Patent Application Laid-Open No. 58-819337 discloses a means for simplifying buzzard repair work.
「貫通孔を有する耐火物製のノズルと該貫通孔に挿入した金属製細管とからなリ、 該貫通孔と該金属製細管との間に環状すき間を設けたことを特徴とする精鍊ガス 吹込みプラグ」 が開示されている。 A refined gas blower comprising a nozzle made of a refractory having a through hole and a thin metal tube inserted into the through hole, wherein an annular gap is provided between the through hole and the thin metal tube. Plug "is disclosed.
第 6図はこの精鍊ガス吹込みプラグの説明図で、 第 6図 (a ) に示すように、 耐火物製ノズルと金属製細管との間にすき間を設け、 金属製細管とガス供給管を 連結し、 環状すき間は溶融金属が漏洩しない程度の大きさとする。 補修に際して は、 金属製細管のみを交換することにより、 作業の簡略化を図ろうとするもので ある。  Fig. 6 is an explanatory view of this purified gas blowing plug. As shown in Fig. 6 (a), a gap is provided between the refractory nozzle and the metal thin tube, and the metal thin tube and the gas supply tube are connected. The annular gap should be large enough to prevent molten metal from leaking. At the time of repair, it is intended to simplify the work by replacing only the thin metal tubes.
しかし、 このような構造のノズルでガスの吹込みを行うと、 溶融金属の圧力が かかった状態では、 第 6図 (b ) に示すように、 ガスは溶融金属中に入らず細管 と耐火物貫通孔のすき間ヘリークする。 とくに電気炉炉底からのガス吹込みのよ うにガス吹込み流量が少ない場合には、 僅かなすき間であってもガスは通り易い すき間の方へリークし、 溶融金属中に入らなくなる。 前記公報においては、 かか る問題を解決する手段は示されていない。  However, when gas is injected with a nozzle having such a structure, when the pressure of the molten metal is applied, as shown in Fig. 6 (b), the gas does not enter the molten metal and the thin tube and the refractory It leaks into the gap of the through hole. In particular, when the gas injection flow rate is small, such as when gas is injected from the bottom of an electric furnace, the gas leaks to the easy-to-pass gap even with a small gap, and does not enter the molten metal. The publication does not disclose any means for solving such a problem.
[発明の開示]  [Disclosure of the Invention]
本発明は、 ガス吹込みノズルの取り替えの頻度が少ないために生産性を低下さ せることが少なく、 また悪い作業環境での取リ替えの作業を軽減することができ、 かつノズル周辺からガスがリークすることのないガス吹込みノズルと、 その使用 方法の提供を課題としている。  According to the present invention, since the frequency of replacement of the gas injection nozzle is low, the productivity is rarely reduced, and the work of replacement in a bad working environment can be reduced. The goal is to provide a gas injection nozzle that does not leak and how to use it.
第 1図は本発明のガス吹込みノズルの例の説明図で、 第 1図 (a ) はガス吹込 みノズノレの縦断面の説明図、 第 1図 (b ) は第 1図 (a ) のガス吹込みノズルを 炉底に配設した説明図、 第 1図 (c ) はガス吹込みノズルと供給ガスの吹込みホ ースの連結部の例の説明図である。 FIG. 1 is an explanatory view of an example of a gas injection nozzle of the present invention. FIG. 1 (a) is an explanatory view of a longitudinal section of a gas injection nozzle, and FIG. 1 (b) is an explanatory view of FIG. 1 (a). Fig. 1 (c) shows the gas injection nozzle and the supply gas injection nozzle. It is explanatory drawing of the example of the connection part of a case.
本発明は、 炉内側から炉外側に直線状に貫通した細孔(3)を設けた耐火物のブ ック(4)と、 該耐火物のブロック(4)と一体に形成された取付金具(22)と、 前 記耐火物のプロック( 4 )の細孔( 3 )内に該細孔( 3 )を貫通して摺動可能に配され た金属の細管(2)と、 前記取付金具(22)の端部をガスみ吹込ホース(15)に連 結する連結金具(23)とを有し、 前記金属の細管(2)の炉外側の端部を前記連結 金具(23)に配したゴム(14)に挿通して、 該金属の細管(2)の炉外側に吹込ガ ス(12)を供給し炉内側の端部から溶融金属中に吹込ガス(1 2)を吹込むことを 特徴とする、 溶融金属へのガス吹込みノズルである。  The present invention relates to a refractory book (4) provided with pores (3) penetrating linearly from the inside of the furnace to the outside of the furnace, and a mounting bracket formed integrally with the refractory block (4). (22); a metal thin tube (2) slidably disposed through the pores (3) in the pores (3) of the refractory block (4); A connection fitting (23) for connecting an end of the metal tube (22) to the gas blowing hose (15); and a furnace outside end of the thin metal tube (2) being connected to the connection fitting (23). The gas (12) is supplied to the outside of the furnace of the thin tube (2) of metal by blowing the gas (12) into the molten metal from the inner end of the furnace. A gas injection nozzle for molten metal.
取付金具(22)の一端は直管状で、 他端は耐火物のブロック(4)の底部の形状 にならつた受け皿状に形成され、 耐火物のブロック(4)は取付金具(22)の受け 皿状の部分に嵌合され接着される。 このように耐火物のプロック(4 )と取付金具 (22)とを一体に形成することにより、 第 6図 (b) に示すような、 金属の細管 ( 2 )と耐火物のプロック(4 )との間隙からの吹込ガスの、リ -クを防止することが できる。  One end of the mounting bracket (22) is a straight tube, and the other end is formed in a pan shape conforming to the shape of the bottom of the refractory block (4), and the refractory block (4) receives the mounting bracket (22). Fitted and adhered to the dish-shaped part. By integrally forming the refractory block (4) and the mounting bracket (22) in this way, as shown in FIG. 6 (b), the metal thin tube (2) and the refractory block (4) are formed. Leakage of the gas blown from the gap with the air can be prevented.
第 1図 (c) にみられるように、 取付金具(22)の直管状の端部は、 連結金具 (23)の一端に連結され、 連結金具(23)の他端はガス吹込みホース(15)に連 結される。  As can be seen in FIG. 1 (c), the straight tubular end of the fitting (22) is connected to one end of a connecting fitting (23), and the other end of the connecting fitting (23) is connected to a gas blowing hose ( Linked to 15).
金属の細管(2)の端部は、 連結金具(23)に配されたゴム(14)を挿通して、 ガス吹込みホース( 15 )側へ突出している。 金属の細管( 2 )の外周と連結金具( 23)の内面の間隙はゴム( 14)によリ密封され、 ガス吹込みホース( 1 5)から 送られた全ての吹込ガス(12)は金属の細管(2)内に供給される。  The end of the thin metal tube (2) penetrates the rubber (14) arranged in the connecting fitting (23) and protrudes toward the gas injection hose (15). The gap between the outer circumference of the thin metal tube (2) and the inner surface of the connecting fitting (23) is sealed with rubber (14), and all the blowing gas (12) sent from the gas blowing hose (15) is made of metal. Is supplied into the thin tube (2).
第 1図は、 金属の細管(2)が 1本の場合を示しているが、 細管が複数であって も、 同様に各細管の外周と連結金具の内面との間隙をゴムでシールし、 全ての吹 込ガスを各細管に分配することができる。 Fig. 1 shows the case where there is one metal thin tube (2). Even if there are a plurality of thin tubes, the gap between the outer periphery of each thin tube and the inner surface of the connection fitting is similarly sealed with rubber, All blowing Charge gas can be distributed to each capillary.
本発明のガス吹込みノズル(1)は第 1図 (b) に示す如く、 炉底耐火物(1 1) に設けた羽口煉瓦(6)の内側に装着し、 支持リング(2 1)と止め金具(20)によ リ炉の鉄皮(1 9)に取りつけられる。 この際、 ノズルと羽口煉瓦の隙間の寸法は 限定しないが、 モルタルやキャスタブル等の不定形耐火物を充填する。  As shown in FIG. 1 (b), the gas injection nozzle (1) of the present invention is mounted inside the tuyere brick (6) provided on the hearth refractory (11) and the support ring (21). And the metal fittings (20). At this time, the size of the gap between the nozzle and the tuyere brick is not limited, but it is filled with irregular-shaped refractories such as mortar and castables.
金属の細管( 2 )としては、 例えば内径が 1〜 2 mmのステンレス鋼のパイプを 使用することができるがこの細管の内径や数は吹込ガス量に応じて適宜選定する ことができる。 また細管は単管でもよく 2重管であってもよい。 また細孔(3)の 内径は金属の細管( 2)を摺動可能にするため、 金属の細管の外径よリも 0〜4 m mの範囲で大きくする。  As the metal thin tube (2), for example, a stainless steel pipe having an inner diameter of 1 to 2 mm can be used, but the inner diameter and the number of the thin tubes can be appropriately selected according to the amount of gas to be blown. The thin tube may be a single tube or a double tube. The inner diameter of the pores (3) should be larger than the outer diameter of the thin metal tube in the range of 0 to 4 mm so that the thin metal tube (2) can slide.
第 2図は本発明のガス吹込みノズ^の使用方法の例の説明図である。 本発明の ガス吹込みノズル( 1 )も使用を繰り返すと、 ガス吹込みノズル( 1 )の炉内側やそ の周辺は他部よりも耐火物の損耗が大きく、 第 2図 (a) に示す如く損耗部(8) が発生する。 この損耗部( 8 )を補修するに際して本発明 は金属の細管( 2 )を細 孔(3)内を上方に摺動させて、 第 2図 (b) に示す如く、 端部を炉内側に突出せ しめる。  FIG. 2 is an explanatory view of an example of a method of using the gas injection nozzle according to the present invention. When the gas injection nozzle (1) of the present invention is also used repeatedly, the inside of the furnace of the gas injection nozzle (1) and its surroundings have greater wear of refractories than other parts, as shown in FIG. 2 (a). The wear part (8) is generated as described above. In repairing the worn part (8), the present invention slides the metal thin tube (2) upward in the small hole (3), and as shown in FIG. Protrude.
次に金属の細管(2)の炉内側の端部を閉塞させることなく、 第 2図 (c) に示 す如く該損耗部( 8 )に耐火性補修材( 1 6 )を充填する。 この例では金属の細管( 2)の炉内側の端部は、 補修材( 16)の充填完了後の表面よリも更に突出させる が、 金属の細管(2)をこのように突出させると、 通常使用する補修装置例えばサ ンドスリンガー等を使用して、通常の炉内補修材でこの損耗部(8)の補修を行つ ても、 金属の細管(2)の炉内側の端部は補修材(1 6)に埋まることがなく、 閉塞 することがない。  Next, as shown in FIG. 2 (c), the worn portion (8) is filled with a fire-resistant repair material (16) without closing the inside end of the thin metal tube (2). In this example, the inner end of the metal tubule (2) protrudes further from the surface after completion of the filling of the repair material (16), but when the metal tubule (2) protrudes in this manner, Even if the worn part (8) is repaired with a normal in-furnace repair material using a normally used repair device such as a sand slinger, the inside end of the thin metal tube (2) is repaired. It is not buried in the material (16) and does not block.
このため、 本発明のガス吹込みノズルし 1)を用いると、 ガス吹込みノズルやそ の周辺は、 日常作業として行う他の炉床ゃ炉壁の損耗部の補修と同時に、 簡易に 補修することができ、 この日常作業の補修によりガス吹込みノズルの寿命は延長 し、 ガス吹込みノズルの取り替え頻度は顕著に減少する。 Therefore, when the gas injection nozzle 1) of the present invention is used, the gas injection nozzle and its Can be easily repaired at the same time as the repair of the worn part of the hearth and the furnace wall, which is performed as a daily work, and the repair of the daily work extends the life of the gas injection nozzle and increases the gas injection. The frequency of nozzle replacement is significantly reduced.
また第 2図 (c) の如くに補修した後で、 溶融金属へのガス吹込みを行うと、 金属の細管(2)の突出した部分は直ちに溶損し、 溶融金属へのガスの吹込み口は、 第 1図 (b) で示したガスの吹込み口と同じ形状になる。 従って第 1図 (b) の 場合と同じように溶融金属への安定したガス吹込みを行なうことができる。  When gas is injected into the molten metal after repairing as shown in Fig. 2 (c), the protruding part of the thin metal tube (2) is immediately melted and damaged, and the gas injection port into the molten metal is injected. Has the same shape as the gas inlet shown in Fig. 1 (b). Therefore, stable gas injection into the molten metal can be performed as in the case of FIG. 1 (b).
第 3図は、 本発明の他のガス吹込みノズルの例の説明図で、 第 3図 (a) はガ ス吹込みノズルの縦断面の説明図、 第 3図 (b) は第 3図 (a) のガス吹込みノ ズルを炉底に配設した説明図である。  FIG. 3 is an explanatory view of an example of another gas injection nozzle of the present invention. FIG. 3 (a) is an explanatory view of a longitudinal section of the gas injection nozzle, and FIG. 3 (b) is FIG. FIG. 3A is an explanatory view in which the gas injection nozzle of FIG.
第 3図 (a) のガス吹込みノズルは、 耐火物のブロック(4)が上下方向に 2儸 に分割されていることが特徴で、 その他の構造は第 1図 (a) のガス吹込みノズ ルと同じである。 第 3図 (a) の取付金具(22)の端部が、 第 1図 (c) に示す ように、 連結金具(23)を介してガス吹込みホース(1 )に連結され、 金属の細 管(2)の外周がゴム(14)により密封されていることも、 第 1図のガス吹込みノ ズルの場合と同様である。  The gas injection nozzle in Fig. 3 (a) is characterized in that the refractory block (4) is vertically divided into two sections, and the other structure is the gas injection nozzle in Fig. 1 (a). Same as nozzle. As shown in Fig. 1 (c), the end of the mounting bracket (22) in Fig. 3 (a) is connected to the gas blowing hose (1) via the connecting bracket (23), The outer circumference of the pipe (2) is sealed by the rubber (14) as in the case of the gas injection nozzle in FIG.
また、 本ノズルも第 3図 (b) に示す如く、 炉底耐火物(1 1)に設けた羽ロ煉 瓦(6)の内側に装着し、 支持リング(21)と止め金具(20)により炉の鉄皮(1 9)に取りつけられる。 この際、 ノズルと羽口煉瓦の隙間の寸法は限定しないが、 モルタルやキャスタブル等の不定形耐火物を充填する。  Also, as shown in Fig. 3 (b), this nozzle is mounted inside the brick (6) provided on the hearth refractory (11), and the support ring (21) and the stopper (20) are installed. Is attached to the furnace skin (19). At this time, the size of the gap between the nozzle and the tuyere brick is not limited, but it is filled with irregular refractories such as mortar and castables.
第 4図は、 第 3図に示す本発明の他のガス吹込みノズルの使用方法の例の説明 図である。 第 4図 (a) に示すような損耗部(8)を補修するに際して、 金属の細 管(2)を細孔(3)内を上方に摺動させて、 端部を炉内側に突出せしめ、 溶損した 耐火物のブロックの上側部分(4 a)を取り除く。 次いで、 第 4図 (b) に示す如 く、 新しい耐火物のブロックの上側部分(4 a) (以下「補修用煉瓦」という)を装着 し、 その周囲の損耗部(8)に耐火性補修材(1 6)を充填する。 その後、 金属の細 管(2)の上端が補修用煉瓦(4 a)の上面と同じ高さになるまで、 細管を下方に摺 動させる。 FIG. 4 is an explanatory view of an example of a method of using another gas injection nozzle of the present invention shown in FIG. When repairing the worn part (8) as shown in Fig. 4 (a), the metal tubing (2) is slid upward through the pores (3) so that the end protrudes inside the furnace. Remove the upper part (4a) of the damaged refractory block. Next, as shown in Fig. 4 (b) Then, install the upper part (4a) (hereinafter referred to as “repair brick”) of the new refractory block, and fill the surrounding wear part (8) with the refractory repair material (16). Then, slide the metal tube (2) downward until the upper end of the metal tube (2) is flush with the upper surface of the repair brick (4a).
このように補修用煉瓦を用いることにより、 不定形の耐火性補修材料のみで補 修した場合より、 補修後のノズルライフを延長することができる。 また、 補修後 に金属の細管(2)が突出していないため、 細管の使用回数を増すことができる。  By using the repair brick in this way, the nozzle life after the repair can be extended as compared with the case where the repair is performed using only the amorphous refractory repair material. In addition, since the metal tubule (2) does not protrude after the repair, the number of use of the tubule can be increased.
[図面の簡単な説明]  [Brief description of drawings]
第 1図は本発明のガス吹込みノズルの例の説明図である。  FIG. 1 is an explanatory view of an example of a gas injection nozzle of the present invention.
第 2図は本発明のガス吹込みノズ^^の使用方法の例の説明図である。  FIG. 2 is an explanatory diagram of an example of a method of using the gas injection nozzle according to the present invention.
第 3図は本発明の他のガス吹込みノズルの例の説明図である。  FIG. 3 is an explanatory view of an example of another gas injection nozzle of the present invention.
第 4図は本発明の他のガス吹込みノズルの使用方法の例の説明図である。 第 5図は従来から使用されているガス吹込みノズルの例の説明図である。 第 6図は従来の精鍊ガス吹込みプラグの説明図である  FIG. 4 is an explanatory diagram of an example of a method of using another gas injection nozzle of the present invention. FIG. 5 is an explanatory view of an example of a conventionally used gas injection nozzle. FIG. 6 is an explanatory view of a conventional fine gas blowing plug.
[発明を実施するための最良の形態]  [Best Mode for Carrying Out the Invention]
第 1図 (a) で示した耐火物のブロック(4)に、 金属の細管(2)を通す内径 5 mmの細孔( 3 )を一本設け、 電気炉で炉底からのガス吹込み用のノズルとして使 用した。 金属の細管(2)は内径 2 m m、 外径 4mm、 長さ 2 mのものを使用し、 金属の細管(2)は第 1図 (c) で示した連結金具(23)を用いて供給ガス吹込み ホース(1 5)に連結した。  In the refractory block (4) shown in Fig. 1 (a), a single hole (3) with an inner diameter of 5 mm through which a metal thin tube (2) is passed is provided, and gas is injected from the bottom of the furnace with an electric furnace. Used as a nozzle for The metal tubule (2) has an inner diameter of 2 mm, an outer diameter of 4 mm, and a length of 2 m. The metal tubule (2) is supplied using the connection fitting (23) shown in Fig. 1 (c). Connected to gas injection hose (15).
溶解 ·精鍊時のガス吹込み量は 30〜100 lZminである。 ガス吹込みノズ ノレ(1)の炉内側が約 200mm損耗した時点で第 1図 (c) の供給ガス吹込みホ ース(1 5)を外し、 金属の細管(2)の炉内側の先端が補修後の炉底表面高さにな るまで金属の細管をスライドさせた後再び連結金具(23)と供給ガス吹込みホー ス(1 5 )を連結した。 補修材としては炉床の補修に用いる通常の不定形耐火物の 補修材(1 6 )を用いた。 尚金属の細管(2 )の炉内側の端部の閉塞を防止するため に、 補修材を充填している間もガス吹込みノズルから吹込みガスを流した。 The gas injection volume during melting and refining is 30-100 lZmin. When the inside of the furnace of the gas injection nozzle (1) has worn out by about 200 mm, the supply gas injection hose (15) shown in Fig. 1 (c) was removed, and the tip of the metal thin tube (2) on the inside of the furnace was removed. The metal tube is slid until it reaches the furnace bottom surface height after repair, and then the connection fitting (23) and the supply gas injection (15). The repair material used was ordinary refractory repair material (16) used for hearth repair. In order to prevent the end of the inside of the furnace of the metal thin tube (2) from being clogged, the gas was blown from the gas blowing nozzle while the repair material was being filled.
この補修操作を 4〜 5回繰り返した後、 金属の細管( 2 )を新しいものに取リ替 え、 更に操業や上記の補修を行った。 金属の細管(2 )をスライドさせる際や新し いものに取り替える際に、 細孔(3 )と金属の細管(2 )の隙間に溶融金属が差し込 んで凝固している場合もあったが、 下方より金属の細管(2 )を叩くことによって、 金属の細管(2 )を容易にスライドさせることができた。  After repeating this repair operation 4 to 5 times, the metal tubing (2) was replaced with a new one, and further operations and repairs were performed. When sliding the metal thin tube (2) or replacing it with a new one, molten metal was sometimes inserted into the gap between the pores (3) and the metal thin tube (2) and solidified. By hitting the metal tube (2) from below, the metal tube (2) could be easily slid.
ガス吹込みノズル( 1 )の炉内側の溶損長さが 3 0 0 mmになった時点で、 ガス 吹込みノズル( 1 )を新たなものに取リ替えたが、 本発明のガス吹込みノズルは 3 0 0チャージ以上に亘つて使用できるものであり、 約 5 0チャージ毎に取り替え ていた従来のガス吹込みノズノレに比べて、 寿命が顕著に向上した。  When the erosion length of the gas injection nozzle (1) inside the furnace reached 300 mm, the gas injection nozzle (1) was replaced with a new one. The nozzle can be used for more than 300 charges, and its life is remarkably improved compared to the conventional gas injection nozzle that was replaced every about 50 charges.
つぎに、 第 3図に示す分割構造のガス吹込みノズルでのノズフレライフの改善効 果について調査した。 第 1表に、 第 1図および第 3図のガス吹込みノズルでのノ ズルラィフの比較の例を示す。  Next, the effect of improving the nozzle life with the gas injection nozzle having the split structure shown in Fig. 3 was investigated. Table 1 shows an example of comparison of nozzle life with the gas injection nozzles in Fig. 1 and Fig. 3.
1 1
Figure imgf000009_0001
第 1表のケース 1は、 第 3図に示す分割構造のノズルを使用し、 補修用煉瓦で 補修した場合である。 1 7 0から 2 0 0時間ガス吹込み操業を行った後、 溶損した耐火物のブロック (上部)を取り除き、 補修用煉瓦の上面より上まで金属の細管を摺動させた後、 耐 火物のプロック(上部)と同じ形状の補修用煉瓦を耐火物のプロック(下部)の上に 接着剤で接着させた。 この際、 金属の細管と補修用煉瓦の細孔との間隙も非通気 性の耐火物で充填した。
Figure imgf000009_0001
Case 1 in Table 1 shows a case where the nozzle with the split structure shown in Fig. 3 was used and repaired with a repair brick. After performing the gas injection operation for 170 to 200 hours, remove the eroded refractory block (upper part), slide the metal tube up above the repair brick, and then fire A repair brick of the same shape as the block (upper part) of the object was glued to the block (lower part) of the refractory with an adhesive. At this time, the gap between the thin metal tube and the pores of the repair brick was also filled with non-breathable refractory.
その後、 羽口煉瓦 (上段)の溶損部を不定形耐火物で充填して 1回目の捕修を完 了した。 さらに 1 7 0から 2 0 0時間使用する度に 2回目から 5回目の補修を行 つた。 偶数回目の補修時には羽口煉瓦 (上段)も取り替えた。  After that, the eroded part of the tuyere brick (upper) was filled with irregular-shaped refractories to complete the first recovery. The second to fifth repairs were performed every time the machine was used for 170 to 200 hours. The tuyere bricks (upper) were also replaced during the even-numbered repairs.
耐火物のブロック(上部)および補修用煉瓦は長さ 2 0 0顏のものを使用したが、 補修時の残寸法は 5 0から 1 0 0雇であった。 また、 5回目の補修後 1 7 0から 2 0 0時間使用して検査のためにノズルを取り替えたが、 耐火物のブロック(下 部)には溶損等は全く認められず,継続使用可能な状態であつた。  The refractory block (upper part) and the repair bricks used had a length of 200 faces, but the remaining dimensions at the time of the repair were 50 to 100. In addition, the nozzle was replaced for inspection after using it for 170 to 200 hours after the fifth repair, but the refractory block (lower part) did not show any erosion and could be used continuously. It was in a state.
第 1表のケース 2は、 第 1図に示す一体構造のノズ^を使用し、 不定形耐火物 だけで補修した場合である。 - 1 7 0から 2 0 0時間ガス吹込み操業を行った後、 ノズノレ溶損部に相当する高 さより上まで金属の細管を上方へ摺動させ、 羽口煉瓦および耐火物のブロックの 溶損部に不定形耐火物を充填する補修を行つた。  Case 2 in Table 1 shows the case of using the monolithic nose ^ shown in Fig. 1 and repairing it only with irregular refractories. -After performing the gas injection operation for 170 to 200 hours, slide the metal thin tube upward to the height corresponding to the erosion loss part, and the erosion of the tuyere brick and the refractory block Repairs were made to fill the sections with irregular refractories.
その後 8 0から 1 0 0時間使用毎に同様の補修を 3回行い、 さらに 8 0から 1 0 0時間使用後にノズノレと羽口煉瓦 (上部)を取替えた。 この時点のノズルの溶損 寸法は 2 5 0から 3 0 0醒であり羽口煉瓦(中段)の溶損は認められないが、 この まま補修を繰り返して使用を継続した場合には羽口煉瓦 (中段)まで溶損して、 こ の煉瓦までの ¾ίり替え作業が所定の修理時間内では困難となるために、 その前に ノズソレと羽口煉瓦 (上段)の取り替えを実施した。  After that, the same repair was carried out three times every use for 80 to 100 hours, and after 80 to 100 hours use, the Nozunore and tuyere brick (upper part) were replaced. At this point, the nozzle erosion size was 250 to 300, and no erosion of the tuyere brick (middle) was observed. However, if the repair was repeated and the use continued, the tuyere brick was used. Before the repair work was completed, replacement of the Nozose and tuyere bricks (upper) was carried out because the bricks were melted down to the middle (middle) and it was difficult to replace the bricks within the specified repair time.
第 1表に見られるように、 ケース 1の分割構造のノズルでは、 1回補修当りの ライフおよび標準補修回数が増し、 1個のノズルの卜一タルのノズルラィフを大 幅に延長することができた。 As can be seen in Table 1, the nozzle with the split structure in Case 1 The service life and the number of standard repairs were increased, and the total nozzle life of one nozzle could be greatly extended.
[産業上の利用可能性]  [Industrial applicability]
本発明のガス吹込みノズルを用いると、 ガス吹込みノズルを取り替えるための 炉の休止の頻度が少なくなるために生産性を低下させることが少なく、 また悪い 作業環境での取リ替え作業を軽減することができる。 またノズルの構造が簡単で あるので安価にノズルの製造を行うことができる。  When the gas injection nozzle of the present invention is used, the frequency of shutting down the furnace for replacing the gas injection nozzle is reduced, so that the productivity is rarely reduced, and the replacement work in a bad working environment is reduced. can do. Further, since the structure of the nozzle is simple, the nozzle can be manufactured at low cost.

Claims

請 求 の 範 囲 The scope of the claims
1 . 炉内側から炉外側に直線状に貫通した細孔( 3 )を設けた耐火物のプロック( 4 )と、 該耐火物のブロック(4 )と一体に形成された取付金具(2 2 )と、 前記耐 火物のプロック(4 )の細孔( 3 )内に該細孔( 3 )を貫通して摺動可能に配された金 属の細管(2 )と、 前記取付金具(2 2 )の端部をガス吹込みホース(1 5 )に連結す る連結金具(2 3 )とを有し、 前記金属の細管(2 )の炉外側の端部を前記連結金具 ( 2 3 )に配したゴム(1 4 )に挿通して、 該金属の細管(2 )の炉外側に吹込ガス( 1 2 )を供給し炉内側の端部から溶融金属中に吹込ガスを吹込むことを特徴とす る、 溶融金属へのガス吹込みノズル。 1. Refractory block (4) provided with pores (3) linearly penetrating from inside the furnace to outside of the furnace, and mounting bracket (2 2) integrally formed with the refractory block (4) A metal thin tube (2) slidably disposed in the pores (3) of the refractory block (4) through the pores (3); and the mounting bracket (2). A connection fitting (23) for connecting an end of the metal tube (2) to a gas injection hose (15); and a furnace fitting end (23) of the metal thin tube (2) on the outside of the furnace. The gas (1 2) is supplied to the outside of the furnace of the metal thin tube (2) by passing through the rubber (1 4) arranged in the furnace, and the blowing gas is blown into the molten metal from the end inside the furnace. Characterized by gas injection nozzles for molten metal.
2. 請求の範囲第 1項の溶融金属へのガス吹込みノズルを配設した炉において、 炉内側の該ガス吹込みノズルとその周辺の損耗部( 8 )を補修するに際して、 前記 金属の細管(2 )を前記細孔(3 )内を摺動させて炉内側に突出せしめ、 該金属の細 管( 2 )の炉内側の端部の閉塞を防止して該損耗部( 8 )に耐火性補修材( 1 6 )を充 填することを特徴とする、 溶融金属へのガス吹込みノズルの使用方法。  2. In a furnace provided with a gas injection nozzle for molten metal according to claim 1, when repairing the gas injection nozzle on the inner side of the furnace and a worn part (8) around the nozzle, the metal thin tube is used. (2) slides inside the pores (3) to protrude inside the furnace, prevents the end of the metal tubule (2) inside the furnace from being clogged, and fires the worn part (8) A method for using a gas injection nozzle for molten metal, characterized by filling a repair material (16).
3 . 請求の範囲第 1項の溶融金属へのガス吹込みノズルにおいて、 前記耐火物の ブロック( 4 )が上下方向に 2個以上に分割されていることを特徴とする、 溶融金 属へのガス吹込みノズソレ。  3. The gas injection nozzle for molten metal according to claim 1, wherein said refractory block (4) is vertically divided into two or more blocks. Gas injection nozzle.
4 . 請求の範囲第 3項の溶融金属へのガス吹込みノスリレを配設した炉において、 炉内側の該ガス吹込みノズルとその周辺の損耗部(8 )を補修するに際して、 前記 金属の細管( 2 )を前記細孔( 3 )内を摺動させて炉内側に突出せしめ、 該金属の細 管( 2 )の炉内側の端部の閉塞を防止してノズル損耗部( 8 )に補修用の耐火物のブ ロックを継ぎ足し、 その周辺の損耗部(8 )に耐火性補修材(1 6 )を充填すること を特徴とする、 溶融金属へのガス吹込みノスレの使用方法。  4. In a furnace provided with a gas blowing nozzle for molten metal according to claim 3, wherein the gas blowing nozzle inside the furnace and a worn part (8) around the nozzle are repaired, (2) is slid inside the pores (3) to protrude into the furnace, prevents the end of the metal tubule (2) inside the furnace from being clogged, and repairs the worn part of the nozzle (8). A method of using a gas blown nozzle for molten metal, characterized by adding a refractory block for use and filling a worn part (8) with a refractory repair material (16) around the refractory block.
PCT/JP1996/001356 1995-05-25 1996-05-23 Nozzle for blowing gas into molten metal and usage thereof WO1996037632A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE69615508T DE69615508T2 (en) 1995-05-25 1996-05-23 NOZZLE FOR INJECTING GAS IN MELT AND ITS USE
EP96914400A EP0776983B1 (en) 1995-05-25 1996-05-23 Nozzle for blowing gas into molten metal and usage thereof
JP53555896A JP3894502B2 (en) 1995-05-25 1996-05-23 Gas injection nozzle for molten metal and method of using the same
US08/788,986 US5863490A (en) 1995-05-25 1997-01-24 Gas blast nozzle for molten metal and method of using the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP12610795 1995-05-25
JP7/126107 1995-05-25
JP7/324447 1995-12-13
JP7324447A JPH0941024A (en) 1995-05-25 1995-12-13 Gas blowing nozzle into molten metal and its using method thereof

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Publication Number Publication Date
WO1996037632A1 true WO1996037632A1 (en) 1996-11-28

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EP (1) EP0776983B1 (en)
JP (2) JPH0941024A (en)
KR (1) KR100349870B1 (en)
CN (1) CN1053015C (en)
CA (1) CA2195541A1 (en)
DE (1) DE69615508T2 (en)
WO (1) WO1996037632A1 (en)

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Also Published As

Publication number Publication date
KR970704892A (en) 1997-09-06
JP3894502B2 (en) 2007-03-22
DE69615508T2 (en) 2002-05-29
JPH0941024A (en) 1997-02-10
KR100349870B1 (en) 2003-01-06
CN1053015C (en) 2000-05-31
EP0776983B1 (en) 2001-09-26
EP0776983A4 (en) 1998-09-09
CN1154720A (en) 1997-07-16
DE69615508D1 (en) 2001-10-31
CA2195541A1 (en) 1996-11-28
EP0776983A1 (en) 1997-06-04

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