WO1996017590A1 - Compositions nettoyantes - Google Patents

Compositions nettoyantes Download PDF

Info

Publication number
WO1996017590A1
WO1996017590A1 PCT/US1995/015544 US9515544W WO9617590A1 WO 1996017590 A1 WO1996017590 A1 WO 1996017590A1 US 9515544 W US9515544 W US 9515544W WO 9617590 A1 WO9617590 A1 WO 9617590A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition according
weight
nonionic
composition
alkyl
Prior art date
Application number
PCT/US1995/015544
Other languages
English (en)
Inventor
Thomas Jefferson Dixon
Robert Raymond Schmidt
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP95942508A priority Critical patent/EP0804149A4/fr
Publication of WO1996017590A1 publication Critical patent/WO1996017590A1/fr
Priority to MXPA/A/1997/004124A priority patent/MXPA97004124A/xx

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds

Definitions

  • the subject of the present invention is a foam-producing, skin conditioning and cleansing product suitable for personal cleansing of the skin or hair which may be used as foam bath and shower products, skin cleansers and shampoos etc.
  • a personal cleansing composition comprising:
  • suitable oil-derived nonionic emulsifiers include ethoxylated derivatives of almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil, oil of ap ⁇ cot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, com oil, peach pit oil, poppyseed oil, pine oil, castor oil, soybean oil, avocado oil, safflower oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil.
  • compositions in the form of oil-in-water dispersions wherein the average size of the disperse phase particles is in the range from about 1 to about 150 microns, preferably from about 2 to about 50 microns.
  • particle size being measured by, for example, laser diffraction using, e.g. a Malvem Series 2600.
  • compositions preferably comprise a mixture of anionic and amphoteric surfactants and highly preferred systems also incorporate other nonionic and/or betaine surfactants.
  • Other suitable compositions within the scope of the invention comprise mixtures of anionic with one or more nonionic or betaine surfactants or mixture thereof; and mixtures of amphoteric with one or more nonionic or betaine surfactants or mixture thereof.
  • the level of each of the anionic and amphoteric surfactants is generally in the- range from about 1% to about 18%, preferably from about 2% to about 15%, and especially from about 3% to about 12% by weight of the composition.
  • the total level of surfactant inclusive of anionic, amphoteric, nonionic, betaine and other surfactant components and inclusive of nonionic emulsifier components, is from about 1% to about 40%, preferably from about 5% to about 30% , more preferably from about 10% to about 25%, most preferably from about 15% to about 20% by weight of composition.
  • materials preferred for use in the present invention include cocoamphocarboxypropionate, cocoamphocartooxy propionic acid, and especially cocoamphoacetate and cocoamphodiacetate (otherwise referred to as cocoamphocarboxyglycinate).
  • Specific commercial products include those sold under the trade names of Empigen CDL60 and CDR 60 (Albright & Wilson), Miranol C2M Cone. N.P., Miranol C2M Cone.
  • Miranol C2M SF Miranol CM Special (Miranol, Inc.); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); and Schercotic MS- 2 (Scher Chemicals).
  • a long chain alcohol can be reacted with glucose, in the presence of an acid catalyst to form the desired glucoside.
  • the alkylpolyglucosides can be prepared by a two step procedure in which a short chain alcohol (C-
  • the short chain alkylglucoside content of the final alkylpolyglucoside material should be less than 50%, preferably less than 10%, more preferably less than 5%, most preferably 0% of the alkylpolyglucoside.
  • compositions of the invention preferably also contain from about 0.5% to about 6%, preferably from about 1.5% to about 5% by weight of saturated acyl fatty acids having a weight average chain length of from 10 to 16, preferably from 12 to 14 carbon atoms. Highly preferred is myristic acid.
  • the fatty acid is valuable both from the viewpoint of providing emolliency benefits and also for controlling the viscosity of the final composition.
  • compositions according to the present invention may additionally contain a polymer agent or mixture of polymeric agents.
  • Polymeric agents are valuable in compositions according to the present invention for the enhancement of the creaminess and quality of the foam as provided by the mild surfactant system and for provision of additional skin feel benefits other than those delivered via the dispersed phase comprising a water soluble humectant, lipid and emulsifier.
  • Polymeric agents are present in the compositions according to the present invention at a level of from about 0.01% to about 5%, preferably from about 0.04% to about 2% and especially from about 0.05% to about 1 % by weight.
  • cationic and nonionic polysaccharides include cationic and nonionic polysaccharides; cationic and nonionic homopolymers and copolymers derived from acrylic and/or methacrylic acid; cationic and nonionic cellulose resins; cationic copolymers of dimethyldiallylammonium chloride and acrylic acid; cationic homopolymers of dimethyldiallylammonium chloride; cationic polyalkylene and ethoxypolyalkylene imines; quatemized siiicones, and mixtures thereof.
  • cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s.
  • R 9 is methyl
  • Z 2 is CH 2 (CHOH) CH 2 OH
  • compositions are made by pre-mixing the lipid, humectant and nonionic emulsifier and blending with the remainder of the formula as described above.
  • the compositions provide excellent skin conditioning performance, have good lather characteristics and are effective hair and skin cleansers.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Birds (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition nettoyante d'hygiène corporelle. Sa formule pondérale comprend (a) de 1 % à 40 % environ d'un ou de plusieurs agents tensioactifs appartenant au groupe constitué des agents tensioactifs non ioniques, anioniques, dipolaires et amphotères et de leurs mélanges, (b) de 0,05 % à 18 % environ de lipide, (c) de 0,5 % à 20 % environ d'un humectant et (d) d'eau pour le reste. Pour l'un des composants de cette composition, les valeurs moyennes respectives de x, de y et de z sont comprises entre 1 et 30 environ, entre 10 et 80 environ, et entre 1 et 30 environ. Cette composition, qui assure une excellente hydratation de la peau, présente une bonne structure de mousse, ce qui lui procure un bon pouvoir nettoyant pour la peau et les cheveux.
PCT/US1995/015544 1994-12-05 1995-11-30 Compositions nettoyantes WO1996017590A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP95942508A EP0804149A4 (fr) 1994-12-05 1995-11-30 Compositions nettoyantes
MXPA/A/1997/004124A MXPA97004124A (en) 1994-12-05 1997-06-04 Compositions for personal cleaning

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9424521.4 1994-12-05
GB9424521A GB9424521D0 (en) 1994-12-05 1994-12-05 Cleansing compositions

Publications (1)

Publication Number Publication Date
WO1996017590A1 true WO1996017590A1 (fr) 1996-06-13

Family

ID=10765441

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/015544 WO1996017590A1 (fr) 1994-12-05 1995-11-30 Compositions nettoyantes

Country Status (4)

Country Link
EP (1) EP0804149A4 (fr)
CN (1) CN1174501A (fr)
GB (1) GB9424521D0 (fr)
WO (1) WO1996017590A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916575A (en) * 1997-01-27 1999-06-29 The Procter & Gamble Company Cleaning products
DE19748921A1 (de) * 1997-10-30 1999-09-16 Stockhausen Chem Fab Gmbh Hautverträgliche Handreiniger, insbesondere Grobhandreiniger
EP0990436A2 (fr) * 1998-10-01 2000-04-05 Imaginative Research Associates, Inc. Gels et solutions claires et post-moussantes
EP1043386A1 (fr) * 1997-12-18 2000-10-11 Kao Corporation Composition detergente
GB2354439A (en) * 1999-09-23 2001-03-28 Procter & Gamble Skin care compositional
US6267973B1 (en) * 1993-12-14 2001-07-31 Merck Patent Gesellschaft Ectoin and ectoin derivatives as moisturizers in cosmetics
US7048910B2 (en) 2000-09-07 2006-05-23 Merck Patent Gmbh Use of ectoine or ectoine derivatives for oral care
US7459417B2 (en) 2002-05-10 2008-12-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair conditioning composition comprising a silicone oil and a poloxamer or poloxamine block copolymer
US7611698B2 (en) 2002-05-10 2009-11-03 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair conditioning compositions
US7981899B2 (en) 2002-03-28 2011-07-19 Merck Patent Gmbh Use of compatible solutes for inhibiting the release of ceramides
EP1148863B2 (fr) † 1999-02-05 2012-02-22 L'Oréal Compositions cosmetiques detergentes et utilisation
EP3460033A1 (fr) * 2017-09-25 2019-03-27 Henkel AG & Co. KGaA Composition de détergeant et de nettoyant liquide à limite d'écoulement
DE102007026862B4 (de) 2006-07-07 2022-06-30 Ajinomoto Co., Inc. Niedertemperaturstabile cremige Haut- oder Haarwaschzusammensetzung

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4902499A (en) * 1986-04-04 1990-02-20 The Procter & Gamble Company Hair care compositions containing a rigid silicone polymer
US5100657A (en) * 1990-05-01 1992-03-31 The Procter & Gamble Company Clean conditioning compositions for hair

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368187A (en) * 1981-08-03 1983-01-11 Eli Lilly And Company Sensitive-skin care regime
GB2143841A (en) * 1983-07-26 1985-02-20 Wilkinson Sword Ltd Soap compositions
US5002680A (en) * 1985-03-01 1991-03-26 The Procter & Gamble Company Mild skin cleansing aerosol mousse with skin feel and moisturization benefits
EP0587797B1 (fr) * 1991-06-07 1995-03-01 Minnesota Mining And Manufacturing Company Composition de shampooing desinfectant pour animaux
JPH0656646A (ja) * 1992-02-20 1994-03-01 Suikoushiya:Kk 浴用剤組成物
GB2297761A (en) * 1994-12-05 1996-08-14 Procter & Gamble Personal cleaning compositions
GB2297762A (en) * 1994-12-05 1996-08-14 Procter & Gamble Personal cleaning compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4902499A (en) * 1986-04-04 1990-02-20 The Procter & Gamble Company Hair care compositions containing a rigid silicone polymer
US5100657A (en) * 1990-05-01 1992-03-31 The Procter & Gamble Company Clean conditioning compositions for hair

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0804149A4 *

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6403112B2 (en) 1993-12-14 2002-06-11 Merck Patent Gesellschaft Mit Beschrankter Ectoin and ectoin derivatives as moisturizers in cosmetics
US6267973B1 (en) * 1993-12-14 2001-07-31 Merck Patent Gesellschaft Ectoin and ectoin derivatives as moisturizers in cosmetics
US5916575A (en) * 1997-01-27 1999-06-29 The Procter & Gamble Company Cleaning products
DE19748921C2 (de) * 1997-10-30 2001-02-22 Stockhausen Chem Fab Gmbh Hautverträgliche Handreiniger, insbesondere Grobhandreiniger
DE19748921A1 (de) * 1997-10-30 1999-09-16 Stockhausen Chem Fab Gmbh Hautverträgliche Handreiniger, insbesondere Grobhandreiniger
US6376438B1 (en) 1997-10-30 2002-04-23 Stockhausen Gmbh & Co. Kg Skin-compatible hand cleanser, especially a course hand cleanser
US6551971B2 (en) 1997-12-18 2003-04-22 Kao Corporation Detergent composition comprising an amphoteric surfactant system
EP1043386A1 (fr) * 1997-12-18 2000-10-11 Kao Corporation Composition detergente
US6432896B1 (en) 1997-12-18 2002-08-13 Kao Corporation Detergent composition comprising an amphoteric surfactant system
EP1043386A4 (fr) * 1997-12-18 2001-08-01 Kao Corp Composition detergente
EP1266652A1 (fr) * 1998-10-01 2002-12-18 Imaginative Research Associates, Inc. Gels et solutions claires et post-moussantes
EP0990436A2 (fr) * 1998-10-01 2000-04-05 Imaginative Research Associates, Inc. Gels et solutions claires et post-moussantes
EP0990436A3 (fr) * 1998-10-01 2000-05-17 Imaginative Research Associates, Inc. Gels et solutions claires et post-moussantes
EP1148863B2 (fr) † 1999-02-05 2012-02-22 L'Oréal Compositions cosmetiques detergentes et utilisation
GB2354439A (en) * 1999-09-23 2001-03-28 Procter & Gamble Skin care compositional
US7048910B2 (en) 2000-09-07 2006-05-23 Merck Patent Gmbh Use of ectoine or ectoine derivatives for oral care
US7981899B2 (en) 2002-03-28 2011-07-19 Merck Patent Gmbh Use of compatible solutes for inhibiting the release of ceramides
US7459417B2 (en) 2002-05-10 2008-12-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair conditioning composition comprising a silicone oil and a poloxamer or poloxamine block copolymer
US7611698B2 (en) 2002-05-10 2009-11-03 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Hair conditioning compositions
DE102007026862B4 (de) 2006-07-07 2022-06-30 Ajinomoto Co., Inc. Niedertemperaturstabile cremige Haut- oder Haarwaschzusammensetzung
EP3460033A1 (fr) * 2017-09-25 2019-03-27 Henkel AG & Co. KGaA Composition de détergeant et de nettoyant liquide à limite d'écoulement

Also Published As

Publication number Publication date
CN1174501A (zh) 1998-02-25
MX9704124A (es) 1997-09-30
GB9424521D0 (en) 1995-01-25
EP0804149A4 (fr) 2000-07-19
EP0804149A1 (fr) 1997-11-05

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