WO1996003974A1 - Compositions demaquillantes - Google Patents

Compositions demaquillantes Download PDF

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Publication number
WO1996003974A1
WO1996003974A1 PCT/US1995/008341 US9508341W WO9603974A1 WO 1996003974 A1 WO1996003974 A1 WO 1996003974A1 US 9508341 W US9508341 W US 9508341W WO 9603974 A1 WO9603974 A1 WO 9603974A1
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WO
WIPO (PCT)
Prior art keywords
oil
composition according
surfactant
nonionic
alkyl
Prior art date
Application number
PCT/US1995/008341
Other languages
English (en)
Inventor
Michel Joseph Marie Giret
Wendy Victoria Jane Richardson
Chantal Marie-Claude Bellemain
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP95924771A priority Critical patent/EP0777462A4/fr
Priority to MX9700668A priority patent/MX9700668A/es
Publication of WO1996003974A1 publication Critical patent/WO1996003974A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to cleansing compositions.
  • mild personal cleansing compositions with good skin feel attributes and foaming properties suitable for simultaneously cleansing and conditioning the skin and/or the hair and which may be used, for example, in the form of foam bath preparations, shower products, skin cleansers, hand, face and body cleansers, shampoos, etc.
  • Mild cosmetic compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low irritancy/good feel with respect to the skin, hair and the ocular mucosae.
  • Skin is made up of several layers of cells which coat and protect the keratin and collagen fibrous proteins that form the skeleton of its structure. The outermost of these layers, referred to as the stratum corneum, is known to be composed of 250 A protein bundles surrounded by 80 A thick layers. Hair similarly has a protective outer coating enclosing the hair fibre which is called the cuticle.
  • Anionic surfactants can penetrate the stratum corneum membrane and the cuticle and, by delipidization destroy membrane integrity.
  • oils in bathing compositions can provide post-use skin feel benefits.
  • incorporation of oils at levels sufficient to deliver consumer noticeable benefits has until now proved to be a challenge, particularly with respect to maintaining good lather characteristics in the presence of oil and avoiding unpleasant 'slimey'/ 1 greasy' water feel or appearance during use while still delivering a desirable after-use soft skin feel.
  • the subject of the present invention is a mild, foam-producing cleansing product suitable for personal cleansing of the skin or hair and which may be used as foam bath and shower products, skin cleansers and shampoos etc.
  • a detergent, personal cleansing or cosmetic composition comprising:
  • R9 is Cj_4 alkyl, and Rg is C7-C19 alkyl or alkenyl, or mixture thereof; and ⁇ 2 is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof,
  • auxiliary surfactant selected from other nonionic, anionic, zwitterionic and/or amphoteric surfactants and mixtures thereof;
  • auxiliary surfactant selected from other nonionic, anionic, zwitterionic and/or amphoteric surfactants and mixtures thereof;
  • ratio of auxiliary surfactant to oil dispersing nonionic surfactant is in the range of from 1 : 100 to about 1 : 1, preferably from about 1 :8 to about 1 :2 and the ratio of oil dispersing nonionic surfactant to perfume or cosmetic oil is from about 1 :20 to about 3:2, preferably from about 1 :6 about 1 :3, more preferably from about 1 :4 to about 1 :2.
  • the invention takes the form of a foam producing cleansing composition with superior skin feel characteristics, improved perceived dryness and assessed tightness and expertly graded dryness, combined with excellent lathering, good stability, cleansing ability and conditioning performance.
  • the cleansing compositions herein are based on a combination of particular oil dispersing nonionic surfactant , perfume or cosmetic oil and mild auxiliary surfactants , which in general terms can be selected from other nonionic, anionic, amphoteric and zwitterionic surfactants and mixtures thereof.
  • the total level of surfactant, inclusive of anionic, nonionic, zwitterionic, amphoteric and other surfactant components is preferably from about 1.6% to about 15%, more preferably from about 2% to about 12%, and especially from about 5% to about 10% by weight.
  • the compositions preferably comprise a mixture of oil dispersing nonionic and anionic optionally with auxiliary nonionic, zwitterionic and/or amphoteric surfactants.
  • the total level of auxiliary surfactant is in the range from about 0.1% to about 5%, and especially from about 0.5% to about 4%, more preferably from about 1% to about 3.5%, most preferably from about 1.5% to about 2.5% by weight of the composition, while the level of oil dispersing nonionic surfactant is preferably from about 2% to about 9%, more preferably from about 4.5% to about 7% by weight.
  • the weight ratio of anionic surfactant : auxiliary nonionic, zwitterionic and/or amphoteric surfactant is in the range from about 1 :2 to about 6:1.
  • compositions within the scope of the invention comprise mixtures of nonionic surfactants, dispersible perfume or cosmetic oils and auxiliary anionic, zwitterionic and/or amphoteric surfactants, wherein the level of dispersible perfume or cosmetic oil is from about 6% to about 25%, preferably from about 10% to about 20%, more preferably from about 15% to about 20% by weight of the composition and the weight ratio of oil dispersing nonionic surfactant: dispersible perfume or cosmetic oil is in the range of from 1 :20 to about 3:2, preferably from about 1 :6 to about 1 :2, more preferably from about 1 :4 to about 1 :3.
  • Oil dispersing nonionic surfactants suitable for inclusion in the compositions according to the present invention have excellent oil dispersing characteristics as demonstrated by microscopy and Immersion tests.
  • a test matrix including the test nonionic and all other composition ingredients is prepared. A portion of this prototype is then viewed under a microscope using a Nikon Optipot-2 Videomicrowatcher.
  • Surfactants suitable for incorporation in the compositions according to the present invention typically produce homogeneous (opaque) product matrices in which the oil droplets have a diameter in the range of from about 5 microns to about 30 microns, preferably from about 10 microns to about 20 microns.
  • compositions which result in turbid (cloudy) solutions wherein no oil droplets are visible to the naked eye are regarded as demonstrating the desired behaviour, providing they additionally deliver the required skin feel. While the reasons for the skin feel benefits associated with the compositions according to the present invention are not clearly understood it is believed that the particular nonionic surfactants specified herein are able to substantially disperse a significant amount of oil into the composition matrix which leads to the skin feel advantage possibly due to the release of the oils onto the skin surface during bathing or showering.
  • Oil dispersing nonionic surfactants suitable for inclusion in the compositions according to the present invention are selected from C12- C18 polyhydroxy fatty acid amide surfactants, preferably C12-C16 polyhydroxy fatty acid amide surfactants, more preferably C12-C14 polyhydroxy fatty acid amide surfactants having the general formula (I).
  • the preferred polyhydroxy fatty acid amide surfactants are those in which Ro is Cj_4 alkyl, preferably methyl, and Rg is C7-C19 alkyl or alkenyl, more preferably straight-chain C9-C17 alkyl or alkenyl, or mixture thereof; and ⁇ 2 is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof.
  • Z2 preferably will be derived from a reducing sugar in a reductive amination reaction; more preferably Z2 is a glycityl.
  • Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose.
  • high dextrose corn syrup, high fructose corn syrup, and high maltose corn syrup can be utilized as well as the individual sugars listed above. These corn syrups may yield a mix of sugar components for Z2. It should be understood that it is by no means intended to exclude other suitable raw materials.
  • Z2 preferably will be selected from the group consisting of -CH2(CHOH) n -CH2 ⁇ H,-CH(CH2 ⁇ H)-(CHOH) n _ ⁇ - CH2OH, -CH2-(CHOH)2(CHOR')(CHOH)-CH2 ⁇ H, where n is an integer from 3 to 5, inclusive, and R' is H or a cyclic or aliphatic monosaccharide, and alkoxylated derivatives thereof. Most preferred are glycityls wherein n is 4, particularly -CH2-(CHOH)4-CH2 ⁇ H.
  • the most preferred polyhydroxy fatty acid amide has the formula Rg(CO)N(CH3)CH2(CHOH) CH2 ⁇ H wherein Rg is a Cl 1-C 17 straight chain alkyl or alkenyl group.
  • compositions of the invention additionally include a dispersible perfume or cosmetic oil or a mixture thereof at levels of from about 4.5% to about 30%, preferably from about 10% to about 25%, more preferably from about 15% to about 20% by weight.
  • a dispersible perfume or cosmetic oil or a mixture thereof at levels of from about 4.5% to about 30%, preferably from about 10% to about 25%, more preferably from about 15% to about 20% by weight.
  • Addition of such oils or waxes can provide emolliency, mildness and rinsibility characteristics to personal cleansing compositions according to the invention. It is a feature of the invention, however, that such oil based compositions have excellent in-use and post-use skin feel in combination with good emolliency and mildness together with desirable physical attributes possibly due to the release of the oil moieties into the cleansing water. Physically, preferred compositions of this type take the form of an opaque solution which becomes turbid upon dispersion in water.
  • compositions according to the invention including a perfume or cosmetic oil
  • the weight ratio of nonionic surfactant to oil is from about 1 :20 to about 3:2, more preferably from about 1 :6 to about 1 :2 and especially from about 1 :4 to about 1:3.
  • Suitable cosmetic oils for use herein can be selected from water-insoluble silicones inclusive of non- volatile polyalkyl and polyaryl siloxane gums and fluids, volatile cyclic and linear polyalkylsiloxanes, polyalkoxylated silicones, amino and quaternary ammonium modified silicones, rigid cross- linked and reinforced silicones and mixtures thereof, -C24 esters of Cg- C30 fatty acids such as isopropyl myristate and cetyl ricinoleate, beeswax, saturated and unsaturated fatty alcohols such as behenyl alcohol, hydrocarbons such as mineral oils, petrolatum and squalene, fatty sorbitan esters (see US-A-3988255, Seiden, issued October 26th 1976), lanolin and oil-like lanolin derivatives, animal and vegetable triglycerides such as almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oiL, oil of apri
  • the most preferred perfume or cosmetic oil is mineral oil.
  • Anionic surfactants suitable for inclusion in the compositions of the invention can generally be described as mild synthetic detergent surfactants and include ethoxylated alkyl sulfates, alkyl glyceryl ether sulfonates, methyl acyl taurates, fatty acyl glycinates, N-acyl glutamates, acyl isethionates, alkyl sulfosuccinates, alpha-sulfonated fatty acids, their salts and/or their esters, alkyl ethoxy carboxylates, alkyl phosphate esters, ethoxylated alkyl phosphate esters, acyl sarcosinates and fatty acid/protein condensates, and mixtures thereof.
  • Alkyl and or acyl chain lengths for these surfactants are Cg-C22 > preferably Cio-Cig.
  • Particularly preferred are the alkyl sulfates containing from about 2 to 6, preferably 2 to 4 moles of ethylene oxide, such as sodium laureth-2 sulfate, sodium laureth-3 sulfate and magnesium sodium laureth- 3.6 sulfate.
  • the anionic surfactant contains at least about 50%, especially at least about 75% by weight of ethoxylated alkyl sulfate.
  • compositions for use herein suitably also contain an amphoteric surfactant.
  • Amphoteric surfactants suitable for use in the compositions of the invention include:
  • R] is C7-C22 alkyl or alkenyl
  • R2 is hydrogen or CH2Z
  • each Z is independently CO2M or CH2CO2M
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium; and/or ammonium derivatives of formula (HI)
  • R ⁇ , R2 and Z are as defined above;
  • n and m are numbers from 1 to 4, and R ⁇ and M are independently selected from the groups specified above;
  • Suitable amphoteric surfactants of type (a) are marketed under the trade name Miranol and Empigen and are understood to comprise a complex mixture of species. Traditionally, the Miranols have been described as having the general formula II, although the CTFA Cosmetic Ingredient Dictionary, 4th Edition indicates the non-cyclic structure III. In practice, a complex mixture of cyclic and non-cyclic species is likely to exist and both definitions are given here for sake of completeness. Preferred for use herein, however, are the non-cyclic species.
  • suitable amphoteric surfactants of type (a) include compounds of formula II and/or III in which R ⁇ is CgHi 7 (especially iso- capryl), C9H19 and C 1 1H23 alkyl.
  • R ⁇ is C9H19, Z is CO2M and R2 is H; the compounds in which R ⁇ is C ⁇ 1H23, Z is CO2M and R2 is CH2CO2M; and the compounds in which R ⁇ is Ci 1H23, Z is CO2M and R2 is H.
  • materials preferred for use in the present invention include cocoamphocarboxypropionate, cocoamphocarboxy propionic acid, and especially cocoamphoacetate and cocoamphodiacetate (otherwise referred to as cocoamphocarboxyglycinate).
  • Specific commercial products include those sold under the trade names of Empigen CDL60 and CDR 60 (Albright & Wilson), Miranol H2M Cone. Miranol C2M Cone. N.P., Miranol C2M Cone.
  • Miranol C2M SF Miranol CM Special (Rh ⁇ ne- Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); and Schercotic MS-2 (Scher Chemicals).
  • amphoteric surfactants of this type are manufactured and sold in the form of electroneutral complexes with, for example, hydroxide counterions or with anionic sulfate or sulfonate surfactants, especially those of the sulfated Cg- Cig alcohol, Cg-Cjg ethoxylated alcohol or Cg-Cig acyl glyceride types.
  • anionic sulfate or sulfonate surfactants especially those of the sulfated Cg- Cig alcohol, Cg-Cjg ethoxylated alcohol or Cg-Cig acyl glyceride types.
  • compositions which are essentially free of (non-ethoxy lated) sulfated alcohol surfactants are essentially free of (non-ethoxy lated) sulfated alcohol surfactants.
  • concentrations and weight ratios of the amphoteric surfactants are based herein on the uncomplexed forms of the surfactants
  • amphoteric surfactants of type (b) include salts, especially the triethanolammonium salts and salts of N-lauryl-beta-amino propionic acid and N-lauryl-imino-dipropionic acid. Such materials are sold under the trade name Deriphat by Henkel and Mirataine by Rh ⁇ ne- Poulenc. Amphoterics preferred for use herein, however, are those of formula II and/or III.
  • the compositions of the invention may also include auxiliary nonionic surfactant.
  • Suitable auxiliary nonionic surfactants for use herein can be selected from C12-C14 fatty acid mono-and diethanolamides and sucrose polyester surfactants, water soluble vegetable and animal-derived emollients (oil derived) such as triglycerides with a polyglycol chain inserted; ethoxylated mono and di-glycerides, polyethoxylated lanolins and shea butter derivatives and mixtures thereof.
  • oil derived auxiliary nonionic surfactants for use herein have the general formula (VI)
  • n is from about 5 to about 200, preferably from about 20 to about 100, more preferably from about 30 to about 85, and wherein R comprises an aliphatic radical having on average from about 5 to 20 carbon atoms, preferably from about 9 to 18 carbon atoms.
  • Suitable ethoxylated oils and fats of this class include polyethyleneglycol derivatives of glyceryl cocoate, glyceryl caproate, glyceryl caprylate, glyceryl tallowate, glyceryl palmate, glyceryl stearate, glyceryl laurate, glyceryl oleate, glyceryl ricinoleate, and glyceryl fatty esters derived from triglycerides, such as palm oil, almond oil, and corn oil, preferably glyceryl tallowate and glyceryl cocoate.
  • Suitable oil derived auxiliary nonionic surfactants of this class are available from Croda Inc. (New York, USA) under their Crovol line of materials such as Crovol EP40 (PEG 20 evening primrose glyceride), Crovol EP 70 (PEG 60 evening primrose glyceride) Crovol A-40 (PEG 20 almond glyceride), Crovol A-70 (PEG 60 almond glyceride), Crovol M-40 (PEG 20 maize glyceride), Crovol M-70 (PEG 60 maize glyceride), Crovol PK-40 (PEG 12 palm kernel glyceride), and Crovol PK-70 (PEG 45 palm kernel glyceride) and under their Solan range of materials such as Solan E, E50 and X polyethoxylated lanolins.
  • Crovol EP40 PEG 20 evening primrose glyceride
  • Crovol EP 70 PEG 60 evening primrose glyceride
  • Crovol A-40 PEG 20 almond glyceride
  • Varonic LI 2 PEG 28 glyceryl tallowate
  • Varonic LI 420 PEG 200 glyceryl tallowate
  • Varonic LI 63 and 67 PEG 30 and PEG 80 glyceryl cocoates
  • auxiliary nonionic surfactants derived from composite vegetable fats extracted from the fruit of the Shea Tree (Butyrospermum Karkii Kotschy) and derivatives thereof.
  • This vegetable fat known as Shea Butter is widely used in Central Africa for a variety of means such as soap making and as a barrier cream, it is marketed by Sederma (78610 Le Perray En Yvelines, France).
  • ethoxylated derivatives of Shea butter available from Karlshamn Chemical Co. (Columbos, Ohio, USA) under their Lipex range of chemicals, such as Lipex 102 E-75 (ethoxylated mono, di-glycerides of Shea butter).
  • ethoxylated derivatives of Mango, Cocoa and Illipe butter may be used in compositions according to the invention. Although these are classified as ethoxylated nonionic surfactants it is understood that a certain proportion may remain as non-ethoxylated vegetable oil or fat.
  • suitable oil-derived nonionic surfactants include ethoxylated derivatives of almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil, oil of apricot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, corn oil, peach pit oil, poppyseed oil, pine oil, castor oil, soybean oil, avocado oil, safflower oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil.
  • Oil derived auxiliary nonionic surfactants highly preferred for use herein from the viewpoint of optimum mildness and skin feel characteristics are PEG 60 evening primrose triglycerides; PEG 55 lanolin polyethoxylated derivatives and ethoxylated derivatives of Shea butter.
  • compositions herein preferably also contain a zwitterionic surfactant.
  • Betaine surfactants suitable for inclusion in the composition of the invention include alkyl betaines of the formula R5R-6R7N "l” (CH2)nM (VII) and amido betaines of the formula (VIII)
  • R5 is C 12-C22 alkyl or alkenyl
  • R and R7 are independently C ⁇ - C3 alkyl
  • M is H
  • alkali metal alkaline earth metal
  • ammonium alkanolammonium
  • n, m are each numbers from 1 to 4.
  • Preferred betaines include cocoamidopropyldimethylcarboxymethyl betaine, laurylamidopropyldimethylcarboxymethyl betaine and Tego betaine.
  • compositions of the invention may also contain a cationic or nonionic polymeric skin or hair conditioning agent at a level from about 0.01% to about 5%, preferably from about 0.04% to about 2% and especially from about 0.05% to about 1%.
  • the polymer is found to be valuable for enhancing the creaminess and quality of the foam as well as providing a hair or skin conditioning utility.
  • Suitable polymers are high molecular weight materials (mass-average molecular weight determined, for instance, by light scattering, being generally from about 2,000 to about 3,000,000, preferably from about 5,000 to about 1,000,000).
  • Useful polymers are the cationic, nonionic, amphoteric, and anionic polymers useful in the cosmetic field. Preferred are cationic and nonionic polymers used in the cosmetic fields as hair or skin conditioning agents.
  • Representative classes of polymers include cationic and nonionic polysaccharides; cationic and nonionic homopolymers and copolymers derived from acrylic and/or methacrylic acid; cationic and nonionic cellulose resins; cationic copolymers of dimethyldiallylammonium chloride and acrylic acid; cationic homopolymers of dimethyldiallylammonium chloride; cationic polyalkylene and ethoxypolyalkylene imines; quaternized silicones, and mixtures thereof.
  • cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.1 1 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8- 1.1) in addition to the above-specified cationic groups, and quaternized cellulose ethers available commercially under the trade names Ucare Polymer JR and Celquat.
  • cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.1 1 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8- 1.1) in addition to the above-specified cationic groups
  • Suitable cationic polymers are homopolymers of dimethyldiallylammonium chloride available commercially under the trade name Merquat 100, copolymers of dimethyl aminoethylmethacrylate and acrylamide, copolymers of dimethyldiallylammonium chloride and acrylamide, available commercially under the trade names Merquat 550 and Merquat S, quaternized vinyl pyrrol idone aery late or methacrylate copolymers of amino alcohol available commercially under the trade name Gafquat, and polyalkyleneimines such as polyethylenimine and ethoxylated polyethylenimine.
  • Nonionic polymers suitable for use in the compositions according to the present invention include any conventioally used nonionic polymer and preferably those of the Pluronic and Synperonic group of polyoxyethylene polyoxypropylene block copolymers available from BASF, such as Pluronic L-121 and ICI, such as synperonic PE-F127.
  • Anionic polymers suitable herein include hydrophobically-modified cross- linked polymers of acrylic acid having amphipathic properties as marketed by B F Goodrich under the trade name Pemulen TRI and Pemulen TR2; and the carboxyvinyl polymers sold by B F Goodrich under the trade mark Carbopol and which consist of polymers of acrylic acid cross-linked with polyallyl sucrose or polyallyl pentaeyrthritol, for example, Carbopol .934, 940 and 950.
  • the viscosity of the final composition (Brookfield RVT, Spindle 5, 50 rpm, 25°C, neat) is preferably at least about 500 cps, more preferably from about 1 ,000 to about 10,000 cps, especially from about 2,000 to about 6,000 cps.
  • the cleansing compositions can optionally include a hair or skin moisturizer which is soluble in the cleansing composition matrix.
  • the preferred level of moisturizer is from about 0.5% to about 20% by weight.
  • the moisturizer is selected from:
  • nonocclusive moisturizers are glycerine, polyethylene glycol, propylene glycol, sorbitol, polyethylene glycol and propylene glycol ethers of methyl glucose (e.g. methyl glucam-20), polyethylene glycol and propylene glycol ethers of lanolin alcohol (e.g. Solulan-75), sodium pyrrolidone carboxylic acid, lactic acid, urea, L- proline, guanidine, pyrrolidone, hydrolyzed protein and other collagen- derived proteins, aloe vera gel and acetamide MEA and mixtures thereof.
  • glycerine is highly preferred.
  • compositions according to the present invention additionally include a stabilising agent at a level of from 0.1% to about 15%, preferably from 1% to about 12%, more preferably from about 5% to about 10% by weight.
  • Stabilising agents suitable for use in the compositions according to the present invention are selected from ethylene glycol distearate (EGDS), Xanthan gum and Veegum (magnesium aluminium mineral with carboxy methyl cellulose)
  • a number of additional optional materials can be added to the cleansing compositions.
  • Such materials include proteins and polypeptides and derivatives thereof; water- solubilizable preservatives such as DMDM Hydantoin, Germall 1 15, methyl, ethyl, propyl and butyl esters of hydroxybenzoic acid, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2- nitropropane-l,3-diol), sodium.
  • viscosity control agents such as magnesium sulfate and other electrolytes; colouring agents; pearlescers and opacifiers such as ethylene glycol distearate, Ti ⁇ 2 and Ti ⁇ 2-coated mica; perfumes and perfume solubilizers; and zeolites such as Valfour BV400 and derivatives thereof and Ca- ⁇ /Mg*-* '1" sequestrants such as polycarboxylates, amino polycarboxylates, polyphosphates, polyhosphonates, amino polyphosphonates and gluconates etc and ph adjusting agents such as citric acid and salts thereof.
  • Water is also present at a level preferably of from about 30% to about 89.9% preferably at least about 50% by weight of the compositions herein.
  • the pH of the compositions is preferably from about 4 to about 8.
  • Amphoteric Empigen CDL 60 an aqueous mixture of 23.5% cocoamphoacetate (in which R ⁇ is coconut alkyl, R2 is H, and Z is C ⁇ 2Na) and 1.35% cocoamphodiacetate (in which Ri is coconut alkyl, R2 is CH2C02Na and Z is C ⁇ 2Na).
  • Solan Solan (RTM) E PEG 55 lanolin
  • Suspension aid 2 Veegum Plus;Magnesium aluminium silicate mineral with carboxy methyl cellulose marketed by R.T. Vanderbilt Co. Inc.
  • Examples I to VII The following are personal cleansing compositions in the form of shower gel or bath foam products and which are representative of the present invention:
  • Stabiliser 1 5.0 7.5 7.5 - 10.0
  • Compositions I to VII are prepared by first mixing the water and any anionic surfactant followed by addition of stabilising agent at elevated temperature (for EGDS, 75°C and for Veegum 40°C). The nonionic surfactants and the remaining matrix ingredients including the dispersible oils (bar any perfume and preservative) are then added. After cooling to ambient temperature the remaining water, preservative and perfume are added.
  • compositions have a viscosity (Brookfieid RVT, Spindle 5, 50 rpm, 25°C, neat) in the range from 1 ,000 to 10,000 cps.
  • the products provide excellent in-use and efficacy benefits including skin feel during and after use, skin conditioning, mildness, stability, cleansing, lathering, good water-feel and appearance and rinsibility.

Abstract

Démaquillant comprenant (a) entre 1,5 et 10 % environ en poids d'un agent tensio-actif non ionique dispersant l'huile sélectionné à partir d'agents tensio-actifs d'amide d'acide gras C12-C18 présentant la formule (I) où R9 est C1-4 alkyle, et R8 est C7-C19 alkyle ou alkényle, ou un mélange de ces derniers; et Z2 est un polyhydroxyhydrocarbyle ayant une chaîne hydrocarbyle linéaire avec au moins 3 hydroxyles directement liés à la chaîne, ou un dérivé alkoxylé de ces derniers; (b) entre 0,1 et 5 % en poids d'agents tensio-actifs auxiliaires sélectionnés à partir d'agents tensio-actifs non ioniques, anioniques, zwiterioniques et/ou amphotériques et des mélanges de ces derniers; (c) entre 4,5 et 30 % environ en poids d'un parfum ou d'une huile cosmétique dans laquelle le parfum ou l'huile cosmétique peut se disperser dans l'agent tensio-actif non ionique dispersant l'huile; et, (d) de l'eau. Dans cette composition le rapport d'agents tensio-actifs auxiliaires sur les agents tensio-actifs non ioniques dispersant l'huile est compris entre 1/100 et 1/1 et le rapport d'agents tensio-actifs non ioniques dispersant l'huile sur le parfum ou l'huile cosmétique est compris entre 1/20 et 3/2 environ. Les produits démaquillants sont très doux, et présentent des avantages en matière de conditionnement lors de leur utilisation et après l'utilisation, de stabilité, moussage et rinçage.
PCT/US1995/008341 1994-07-30 1995-06-30 Compositions demaquillantes WO1996003974A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP95924771A EP0777462A4 (fr) 1994-07-30 1995-06-30 Compositions demaquillantes
MX9700668A MX9700668A (es) 1994-07-30 1995-06-30 Composiciones de limpieza.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9415452.3 1994-07-30
GB9415452A GB9415452D0 (en) 1994-07-30 1994-07-30 Cleansing compositions

Publications (1)

Publication Number Publication Date
WO1996003974A1 true WO1996003974A1 (fr) 1996-02-15

Family

ID=10759183

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/008341 WO1996003974A1 (fr) 1994-07-30 1995-06-30 Compositions demaquillantes

Country Status (6)

Country Link
EP (1) EP0777462A4 (fr)
CN (1) CN1113645C (fr)
EG (1) EG20879A (fr)
GB (1) GB9415452D0 (fr)
MX (1) MX9700668A (fr)
WO (1) WO1996003974A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916575A (en) * 1997-01-27 1999-06-29 The Procter & Gamble Company Cleaning products
WO2013178683A3 (fr) * 2012-05-30 2014-07-03 Clariant International Ltd. Composition contenant de la n-méthyl-n-acylglucamine
WO2013178679A3 (fr) * 2012-05-30 2014-07-10 Clariant International Ltd. Composition contenant de la n-méthyl-n-acylglucamine
US9622951B2 (en) 2012-10-29 2017-04-18 The Procter & Gamble Company Personal care compositions
US10772324B2 (en) 2012-11-03 2020-09-15 Clariant International Ltd. Aqueous adjuvant-compositions
US10813862B2 (en) 2012-05-30 2020-10-27 Clariant International Ltd. Use of N-methyl-N-acylglucamines as solubilizers
US10920080B2 (en) 2015-10-09 2021-02-16 Clariant International Ltd. N-Alkyl glucamine-based universal pigment dispersions
US10961484B2 (en) 2015-10-09 2021-03-30 Clariant International Ltd. Compositions comprising sugar amine and fatty acid
US11220603B2 (en) 2016-05-09 2022-01-11 Clariant International Ltd. Stabilizers for silicate paints
US11425904B2 (en) 2014-04-23 2022-08-30 Clariant International Ltd. Use of aqueous drift-reducing compositions

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5009814A (en) * 1987-04-08 1991-04-23 Huls Aktiengesellschaft Use of n-polyhydroxyalkyl fatty acid amides as thickening agents for liquid aqueous surfactant systems
US5104642A (en) * 1990-04-06 1992-04-14 The Procter & Gamble Company Hair styling compositions containing particular hair styling polymers and non-aqueous solvents

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1036225A (zh) * 1988-03-30 1989-10-11 王孟钟 无水洗手剂
BR9106921A (pt) * 1990-09-28 1993-08-03 Procter & Gamble Composicoes de xampu melhoradas
EP0636166A4 (fr) * 1992-03-25 1999-02-03 Procter & Gamble Compositions de nettoyage.
CN1103809C (zh) * 1995-05-27 2003-03-26 普罗克特和甘保尔公司 包含特定非包藏液体多元醇脂肪酸多酯的水性个人清洁组合物

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5009814A (en) * 1987-04-08 1991-04-23 Huls Aktiengesellschaft Use of n-polyhydroxyalkyl fatty acid amides as thickening agents for liquid aqueous surfactant systems
US5104642A (en) * 1990-04-06 1992-04-14 The Procter & Gamble Company Hair styling compositions containing particular hair styling polymers and non-aqueous solvents

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0777462A4 *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916575A (en) * 1997-01-27 1999-06-29 The Procter & Gamble Company Cleaning products
US10864275B2 (en) * 2012-05-30 2020-12-15 Clariant International Ltd. N-methyl-N-acylglucamine-containing composition
WO2013178683A3 (fr) * 2012-05-30 2014-07-03 Clariant International Ltd. Composition contenant de la n-méthyl-n-acylglucamine
WO2013178679A3 (fr) * 2012-05-30 2014-07-10 Clariant International Ltd. Composition contenant de la n-méthyl-n-acylglucamine
US20150125415A1 (en) * 2012-05-30 2015-05-07 Clariant Finance (Bvi) Limited N-Methyl-N-Acylglucamine-Containing Composition
US10265253B2 (en) 2012-05-30 2019-04-23 Clariant International Ltd. N-methyl-N-acylglucamine-containing composition
US10813862B2 (en) 2012-05-30 2020-10-27 Clariant International Ltd. Use of N-methyl-N-acylglucamines as solubilizers
US9622951B2 (en) 2012-10-29 2017-04-18 The Procter & Gamble Company Personal care compositions
US10772324B2 (en) 2012-11-03 2020-09-15 Clariant International Ltd. Aqueous adjuvant-compositions
US11425904B2 (en) 2014-04-23 2022-08-30 Clariant International Ltd. Use of aqueous drift-reducing compositions
US10920080B2 (en) 2015-10-09 2021-02-16 Clariant International Ltd. N-Alkyl glucamine-based universal pigment dispersions
US10961484B2 (en) 2015-10-09 2021-03-30 Clariant International Ltd. Compositions comprising sugar amine and fatty acid
US11220603B2 (en) 2016-05-09 2022-01-11 Clariant International Ltd. Stabilizers for silicate paints

Also Published As

Publication number Publication date
EP0777462A1 (fr) 1997-06-11
MX9700668A (es) 1997-04-30
EP0777462A4 (fr) 2000-01-05
CN1155239A (zh) 1997-07-23
EG20879A (en) 2000-05-31
GB9415452D0 (en) 1994-09-21
CN1113645C (zh) 2003-07-09

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