WO1995034281A1 - Preparations de rasage aqueuses douces - Google Patents

Preparations de rasage aqueuses douces Download PDF

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Publication number
WO1995034281A1
WO1995034281A1 PCT/EP1995/002145 EP9502145W WO9534281A1 WO 1995034281 A1 WO1995034281 A1 WO 1995034281A1 EP 9502145 W EP9502145 W EP 9502145W WO 9534281 A1 WO9534281 A1 WO 9534281A1
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
alkenyl
preparations
alcohol
carbon atoms
Prior art date
Application number
PCT/EP1995/002145
Other languages
German (de)
English (en)
Inventor
Willi Breitzke
Annette Schwarz
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Publication of WO1995034281A1 publication Critical patent/WO1995034281A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/02—Shaving preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear

Definitions

  • the invention relates to mild aqueous shaving preparations with a content of alkyl and / or alkenyl oligoglycosides, alkyl and / or alkenyl sulfates and polyols and the use of such mixtures for the preparation of the preparations.
  • Shaving creams are mostly sold in tubes. In the application, one presses a little cream onto a moistened shaving brush and then soaped the body parts to be shaved.
  • Conventional shaving creams have the disadvantage of cementing at temperatures above room temperature, as occurs, for example, in summer or in hot countries. This lack of deformability, for example, makes it no longer possible to apply it from a tube.
  • EP-Bl 0070074 discloses foaming surfactant mixtures which, in addition to alkyl oligoglucosides, contain anionic surfactants with sulfate, sulfonate or carboxylate groups. The mixtures form stable foams and are suitable, for example, for shaving creams.
  • Japanese patent application JP 91/131 68 ⁇ (Kao) relates to foaming compositions containing alkyl oligoglycosides and a blowing agent; reference is made to the use of this mixture in shaving foams.
  • alkyl oligoglucosides are known to be extremely skin-friendly. for use in soap-free shaving creams, however, neither the foaming power is sufficient nor the deformability at higher storage temperatures.
  • the foam formation can be increased, but the dermatological tolerance of the preparations decreases significantly; moreover, these mixtures do not show satisfactory deformability either.
  • the object of the present invention was therefore to develop mild, pH-neutral aqueous shaving preparations which are distinguished both by improved deformability at temperatures up to 45 ° C. and by advantageous foaming power.
  • these preparations should be homogeneous, have a good consistency and an attractive gloss.
  • the invention relates to mild aqueous shaving preparations containing
  • the surfactants in the preparations according to the invention are synergistically enhanced with regard to their foaming power and their skin-cosmetic tolerance.
  • the proportion of alkyl and / or alkenyl oligoglycosides, alkyl and / or alkenyl sulfates and polyols according to the invention also ensures that no undesirably high viscosities occur in the preparation of the shaving creams and that production can be carried out using simple stirrers ; homogenization as an additional processing step can therefore be dispensed with.
  • the preparations cannot be cemented even at temperatures above 30 to 40 ° C. and can be easily deformed, so that, for example, application from a tube is easily possible.
  • the agents according to the invention are pH-neutral, homogeneous, have a nice gloss and a particularly creamy consistency.
  • shaving preparations which contain components a) to c) in the following amounts have proven to be optimal:
  • Alkyl and alkenyl oligoglycosides are known substances which can be obtained by the relevant processes in preparative organic chemistry.
  • the alkyl and / or alkylene oligoglycosides follow the formula (I),
  • R 1 represents alkyl and / or alkenyl radicals having 6 to 22 carbon atoms
  • G represents a sugar radical having 5 or 6 carbon atoms
  • p represents numbers from 1 to 10.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the alkyl or alkenyl radical R ⁇ can be derived from primary alcohols having 6 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxo synthesis. Alkyl oligoglucosides are preferred
  • the alkyl or alkenyl radical R1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and their technical Mixtures that can be obtained as described above. Alkyl oligoglucosides based on hydrogenated Ci2 / l4 -Ko ⁇ osa H ⁇ n ° l m i 't a DP 1 to 3
  • Alkyl and / or alkenyl sulfates are to be understood as meaning the sulfation products of primary alcohols which follow the formula (II)
  • R 2 for a linear or branched, aliphatic alkyl and / or alkenyl radical with 6 to 22, preferably 12 to 18 carbon atoms and X for an alkyl and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium? Glucammonium stands.
  • alkyl sulfates that can be used for the purposes of the invention are the sulfation products of capron alcohol, caprylic alcohol, capric alcohol, 2-ethylhexyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palm oleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elayl alcohol, elaalyl alcohol , Arachyl alcohol, gadoleyl alcohol, behenyl alcohol and erucyl alcohol and their technical mixtures, which are obtained by high pressure hydrogenation of technical methyl ester fractions or aldehydes from the Roelen oxo synthesis.
  • the sulfation products can preferably be used in the form of their alkali metal salts, and in particular their sodium salts.
  • polyols with 3 to 6 carbon atoms and 2 to 6 hydroxyl groups for example ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, glycerin , Erythritol, pentaerythritol, trimethylolpropane, sorbitol, anhydrosorbitol, cyclohexanetriol, inositol.
  • Propylene glycols and glycerol alone or mixtures of these polyols with sorbitol and / or butylene glycol are preferred.
  • Glycerol is preferably used as the polyol component which keeps the shaving preparations moist.
  • the shaving preparations according to the invention can also contain other customary auxiliaries and additives.
  • auxiliaries and additives include perfume oils, superfatting agents such as cetyl alcohol, lanolin, stearyl alcohol, lecithin, isopropyl myristate, vase line or paraffin oil; softening agents such as sodium metasulfate or potassium metasulfate; Consistency regulators such as polyethylene glycols or their esters; Lubricants such as mineral oils; Stabilizers such as methyl cellulose or polyvinyl pyrrolidone.
  • the shaving preparations can be protected against microbial spoilage by adding microbicidal substances.
  • the proportion of optional auxiliaries and additives in the preparations can be 0.5 to 10% by weight; the proportion of components a) to c) is reduced accordingly. All percentage ranges are understood with the proviso that they add up to 100% by weight.
  • the shaving preparations according to the invention are produced, for example, by placing the surfactant ingredients as concentrates or aqueous solutions in a mixing container, heating with stirring and metering in the polyol and, if appropriate, other ingredients and the remaining water in portions.
  • the active substance content of the preparations can be 60 to 85, preferably 70 to 80% by weight.
  • aqueous shaving preparations according to the invention are pH-neutral, foam-strong, deformable even at higher storage temperatures and have a particularly high level of skin-cosmetic compatibility. They can also be produced and filled without viscosity problems.
  • Another object of the invention therefore relates to the use of mixtures containing
  • Ci2 / i4 coconut fatty alcohol 2EO ether sulfate sodium salt 70% by weight aqueous paste.
  • Cutina ( R ) FS45 Fatty acid mixture of the following C chain distribution: 51% C16: 0; 2% C17: 0; 44.5% C18: 0; 0.5% C18: 1; 2% ⁇ C16; the number after the colon indicates the number of double bonds.
  • the input materials are sales products from Henkel KGaA, Düsseldorf / FRG. II. Examples of application technology
  • Shaving creams were produced in the following manner in accordance with the compositions given in Table 1:
  • the ingredients of the formulations R1 to R4 and R7 were homogeneously mixed in the order given at room temperature with stirring.
  • the fatty acids were placed in a container and heated to 80 ° C.
  • Glycerin and optionally sodium hydroxide solution or potassium hydroxide solution were added in portions with stirring, the mass becoming homogeneous. After adding the remaining water, the mixture was allowed to cool and the perfume oil was metered in.
  • the creams Rl to R4 according to the invention had significantly better skin cosmetic tolerance than the comparative formulations R5 to R7; and *** The creams R1 to R4 according to the invention were still easily deformable even at 45 ° C., while the comparative formulas R5 to R7 had set in cement-like form even at significantly lower temperatures (see Table 3). Easily deformable is understood to mean that a shaving cream can easily be pressed out of a tube by hand. All percentages are% by weight.
  • the foaming power of the recipes was determined using the whipped foam method according to DIN 53 902, Part B.
  • the results on base foam and foam disintegration are summarized in Table 2.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des préparations de rasage aqueuses douces qui contiennent: (a) entre 30 et 70 % en poids d'oligoglycosides d'alkyl et/ou d'alcényl; (b) entre 10 et 40 % en poids de sulfates d'alkyle et/ou d'alcényle et (c) entre 15 et 35 % en poids de polyols ayant entre 3 et 6 atomes de carbone et entre 2 et 6 groupes hydroxyle, dans chaque cas, rapporté au volume de substance active des préparations. Les préparations peuvent éventuellement contenir des additifs et adjuvants classiques.
PCT/EP1995/002145 1994-06-13 1995-06-06 Preparations de rasage aqueuses douces WO1995034281A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4420515.5 1994-06-13
DE19944420515 DE4420515A1 (de) 1994-06-13 1994-06-13 Milde wäßrige Rasierpräparate

Publications (1)

Publication Number Publication Date
WO1995034281A1 true WO1995034281A1 (fr) 1995-12-21

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ID=6520404

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/002145 WO1995034281A1 (fr) 1994-06-13 1995-06-06 Preparations de rasage aqueuses douces

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DE (1) DE4420515A1 (fr)
WO (1) WO1995034281A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19704635A1 (de) * 1997-02-07 1998-08-13 Henkel Kgaa Schäumende Rasiercreme
DE19918189A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
PL2036972T3 (pl) 2007-09-14 2012-07-31 Cognis Ip Man Gmbh Silnie stężony preparat siarczanu alkoholu tłuszczowego

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0070074A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions moussantes contenant des agents tensio-actifs
WO1992013055A1 (fr) * 1991-01-29 1992-08-06 Henkel Kommanditgesellschaft Auf Aktien Produits liquides de lavage
WO1993008250A1 (fr) * 1991-10-15 1993-04-29 Henkel Kommanditgesellschaft Auf Aktien Preparations tensioactives visqueuses aqueuses
WO1993023512A1 (fr) * 1992-05-18 1993-11-25 Henkel Kommanditgesellschaft Auf Aktien Melanges de tensioactifs doux
DE4328355A1 (de) * 1993-08-24 1995-03-02 Henkel Kgaa Milde wäßrige Rasierpräparate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0070074A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions moussantes contenant des agents tensio-actifs
WO1992013055A1 (fr) * 1991-01-29 1992-08-06 Henkel Kommanditgesellschaft Auf Aktien Produits liquides de lavage
WO1993008250A1 (fr) * 1991-10-15 1993-04-29 Henkel Kommanditgesellschaft Auf Aktien Preparations tensioactives visqueuses aqueuses
WO1993023512A1 (fr) * 1992-05-18 1993-11-25 Henkel Kommanditgesellschaft Auf Aktien Melanges de tensioactifs doux
DE4328355A1 (de) * 1993-08-24 1995-03-02 Henkel Kgaa Milde wäßrige Rasierpräparate

Also Published As

Publication number Publication date
DE4420515A1 (de) 1995-12-14

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