WO1995033785A1 - Curable compositions - Google Patents
Curable compositions Download PDFInfo
- Publication number
- WO1995033785A1 WO1995033785A1 PCT/GB1995/001303 GB9501303W WO9533785A1 WO 1995033785 A1 WO1995033785 A1 WO 1995033785A1 GB 9501303 W GB9501303 W GB 9501303W WO 9533785 A1 WO9533785 A1 WO 9533785A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rubber
- curable composition
- epoxy resin
- composition according
- epoxy
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
- Y10T428/24995—Two or more layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31525—Next to glass or quartz
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/697—Containing at least two chemically different strand or fiber materials
Definitions
- a number of approaches have been used to improve the mechanical properties of the resin systems both in the bulk resin system and in the interlaminar regions in laminated fibre-reinforced composite materials.
- these include the addition of rubbers, thermoplastics, particulate fillers, interlaminar tougheners etc, often in combination.
- the particles are filtered by the fibres and remain on the prepreg surface to act as interlaminar toughening agents.
- the particles, presumably preformed, may be applied directly to the surface of the prepregs.
- EP-A-559437 is concerned with a particular problem arising when fabricating honeycomb reinforcing structures which are covered with resin-impregnated fabrics; that is porosity in the fabrics which it solves by crushing the impregnated fabric to achieve a certain cover factor K p as defined therein.
- the liquid rubber systems whether present as added or as a reaction product or alone or together with a solid rubber, or solid rubber systems do not adequately overcome the problem of porosity.
- EP-A-559437 discloses crushing fabrics impregnated with a composition of epoxy resin, pre-curing agent and solid rubber either without reactive groups or with reactive groups. The preferred composition adds the solid rubber in a lightly cross-linked state.
- the toughening effect is achieved by the generation of relatively large, infusible rubber particles which phase separated from the epoxy resin during curing.
- curable compositions which have pre-formed rubber particles eg US-A-4977215 and US-A-4977218
- the fibres have a filtering effect on the particles which effectively limits the toughening effect of the rubber to the interlaminar regions of the composite materials. Consequently, the intralaminar properties of such composite materials are enhanced, as a result of the presence of the rubber toughening agent, to a considerably lesser extent.
- the objects of the invention are achieved by the provision of a curable composition in which a solid rubber has been pre-reacted in situ with at least a proportion of an epoxy resin present in the composition.
- the reaction producing the reaction product occurs primarily between the rubber and oligomeric epoxy species present in the epoxy resin.
- the reaction product comprises either rubber reacted with at least a proportion of a mixture of both of said epoxy resin components; or, alternatively, rubber reacted with at least a proportion of one or other of said epoxy resin components.
- the reaction product comprises rubber reacted only with at least a proportion of said first epoxy resin component.
- the epoxy resin components comprise glycidyl derivative of one or more of: aromatic diamines aromatic monoprimary amines aminophenols polyhydric phenols polyhydric alcohols polycarboxylic acids.
- At least two curing agents are used, the first of the curing agents being capable of reacting with epoxy groups and of promoting reaction between hydroxyl groups and epoxy groups.
- said first curing agent is dicyanodiamide.
- the total amine content of the curing agent is in the range 70-110% of the stoichiometric requirement of the epoxy resin component.
- a catalyst for the epoxy resin component/curing agent reaction may also be used. If such a catalyst is used, it is typically a Lewis acid, for example boron trifluoride, conveniently as a derivative with an amine such as piperidine or methyl ethylamine. Alternatively it can be basic, for example an imidazole or amine.
- the rubber used to prepare the reaction product is selected from olefin, diene and nitrile rubbers and copolymers and terpolymers thereof which have pendant reactive groups, especially carboxylic groups. Particularly preferred are diene-nitrile copolymers having carboxylic groups. A particular preferred rubber is acrylonitrile/butadiene rubber having carboxylic groups. Preferably, the carboxylic groups are provided by a termonomer such as methacrylic acid. Preferably, the rubber contains at least 1 wt % preferably at least 2 wt % and more especially at least 2.25wt
- Particularly preferred rubbers are the acrylonitrile/butadiene/ methacrylic acid rubbers available from Nippon Zeon under the trade name Hycar, especially Hycar 1472 (now available under the trade name NIPOL 1472) which has 3.75 wt % of carboxylic groups (ie 1 per 1200 M .
- the rubber has an M w of at least 30000, preferably at least 100000 and especially at least 150000.
- the rubber is soluble or at least highly swellable in the epoxy resin.
- the curable composition comprises 1 to 20 wt %, preferably 1 to 10 wt %, and more especially 3 to 6 wt %, of rubber based on the total weight of epoxy resin, curing agent and reaction product in said composition.
- the curable composition comprises 4.0 to 8.0 wt %, more especially 4.5 to 7.0 wt %, of rubber based on the total weight rubber and said first epoxy resin component.
- said reaction product may contain all of said first epoxy resin; alternatively, said reaction product may contain only a proportion of said first epoxy resin.
- the prereaction of the rubber with at least a proportion of said epoxy resin in situ enables a significant degree of control over the viscoelastic properties of the resultant curable composition to be exercised.
- the viscoelastic properties can be varied by varying the ratio of rubber to epoxy resin.
- the rubber to epoxy resin ratios of between 1:1 and 1 :20 preferably between 1:2.5 and 1:17 and especially between 1:2.5 and 1:16.5 are to be used.
- small variations in the rubber to epoxy resin ratio have a significant effect on the viscoelastic properties of the resultant curable composition.
- the curable composition according to the invention may also contain other toughening agents such as thermoplastics optionally having reactive groups; other fillers such as fumed silica; aggregates, eg glass beads; polytetrafluoroethylene; graphite; boron nitride; mica; talc; vermiculite; nucleating agents; and stabilisers.
- additional components will have an effect on the viscoelastic properties of the composition which has to be taken into account when formulating the reaction product.
- the invention includes composite material comprising the curable composition according to the invention and fibre reinforcement.
- the fibres may be any suitable fibres such as glass, carbon or organic polymers, preferably, the fibres are carbon fibres, especially graphite fibres.
- Graphite fibres which have been found to be especially useful in the invention are those supplied by Amoco under the trade designations T650-35, T650-42 and T300; those supplied by Toray under the trade designation T800-HB; and those supplied by Hercules under the trade designations AS4, AU4, IM 8 and IM 7.
- the fibres may be short or chopped fibres, typically of mean fibre length not more than 20 mm, for example about 6mm.
- the fibres are continuous and may, for example, be unidirectionally-disposed fibres or a woven fabric, ie the composite material comprises a prepreg. Combinations of both short and/or chopped fibres and continuous fibres may be utilised.
- the fibres may be sized or unsized.
- the total of the aforementioned other toughening agents, fillers, aggregates etc in the curable composition and the fibre reinforcement of any composite material comprising said curable composition should be such that the curable composition or composite material contains at least 20% by volume of such materials and/or reinforcing fibres.
- the percentages of fibres and such other materials are calculated on the total composition after curing.
- the invention also includes composite materials comprising prepregs according to the invention laminated together by heat and pressure, for example by autoclave, compression moulding or by heated rollers, at a temperature above the curing temperature of the curable composition.
- the resulting multi-ply laminated composite material may be anisotropic in which the fibres are oriented essentially parallel to one another or quasi-isotropic in each ply of which the fibres are oriented at an angle, conveniently 45° as in most quasi-isotropic laminates but possibly for example 30° or 60° or 90° or intermediately, to those in the plies above and below. Orientations which are between anisotropic and quasi-isotropic, and combination laminates, may be used.
- Suitable laminated composite materials contain at least four, preferably at least eight, plies.
- the invention also includes a composite material comprising prepreg according to the invention laid up on at least one side, and preferably with both opposed sides, of a honeycomb reinforcing component such as Nomex honeycomb available from Hexel, optionally with an adhesive layer interposed between the prepreg and the honeycomb component.
- a honeycomb reinforcing component such as Nomex honeycomb available from Hexel
- a process for making a curable composition as hereinbefore defined comprises forming a reaction mixture of said rubber, at least a proportion of said epoxy resin, a catalyst capable of promoting a reaction between epoxy groups and the reactive groups of said rubber and a polar solvent , said rubber, said epoxy resin and said catalyst comprising between 25 and 75 wt %, preferably between 35 and 65 wt %, more especially between 40 and 50 wt %, of the reaction mixture, heating the mixture to effect said reaction, cooling the resultant mixture to substantially ambient temperature and adding the remaining proportion, if any, of said epoxy resin and said first and second curing agents to the mixture and substantially removing the solvent therefrom.
- the mixture is heated to a temperature in the range 40°C to 80°C, preferably under reflux.
- the curable composition was made by preparing the reaction product in situ from a reaction mixture containing:- a) the rubber and all of the first epoxy resin component (Reaction Route A); b) the rubber and all of the second epoxy resin component (Reaction Route B); or c) the rubber and all of both the first and the second epoxy resin components (Reaction Route C); followed by the addition of the remaining ingredients.
- the method was as follows:- a) the respective epoxy resin component(s) was predissolved in acetone together with ETPI and the rubber; b) the solution was stirred and heated under reflux for 2 hours; c) the solution was then cooled to ⁇ 40°C and the remaining first epoxy resin component, if any, together with the second epoxy resin component was added and allowed to solubilise with stirring for 30 minutes; d) DICY was then added to the mixture and it was stirred for a further 30 minutes; and e) the solvent was then removed by placing the solution in a vacuum oven for 30 minutes at 50°C and ⁇ 10 mm Hg.
- the reaction solution on cooling to room temperature, was poured into a large crystallising dish to allow the bulk of the MEK to evaporate off.
- the resultant blocked rubber was then leached with propan-2-ol to remove the excess phenylglycidylether. Finally, the blocked rubber was dried for 20 hours at 60°C in a vacuum oven.
- the degree of reaction (100% in this case ) was assessed by titration as described above and by FTIR.
- the 20%, 40% and 55% blocked rubbers were obtained by a similar procedure.
- the appropriate number of plies were cut to size from the prepreg and laid up. The number of plies and their dimensions were dependant on the type of mechanical test to be performed.
- Transflexural Strength (TFS), Modulus, Tg determination, Short Beam Shear (SBS) and morphology required a test panel of 16 plies ( [0] 1 ⁇ ) and dimensions of 6 inches by 4 inches (152.4mm by 101.6mm).
- Toughness (G measurement required a test panel of 20 plies ( [0] 20 ) with dimensions of 14 inches by 6 inches (355.6mm by 152.4mm).
- the plies were laid up by sequentially ironing them together with an iron set at 50°C.
- Flexural Modulus was determined using test specimens were cut from a [0] 16 panel that had a nominal thickness of 2mm. The dimensions of the specimens were 140mm x 10mm . Testing was carried out on an Instron 6022 machine set up in 3 point bend mode with a support span of 100mm , thus giving a span to depth ratio of 50:1. The test was performed at a rate of 1mm/min. The test was manually stopped when the central deflection was equal to the specimen thickness(approx 2mm). An average of 4 specimens was taken as the final result.
- Short Beam Shear was determined using test specimens which were machined from a [0] 24 panel with a nominal thickness of 3mm.
- the specimen size used was 25mm x 10mm (0° in 25mm direction) and these were cut using a diamond saw.
- the test was carried out on a Instron 6022 testing machine with a three point bend set up using a support span of 15mm giving a span to depth ratio of 5:1.
- the test speed used was 1mm/min and an average of 8 samples was taken to give the final result. The mode of failure was also recorded.
- G j - Testing The G 1c testing was determined using panels used for this test were
- the rubber to be used was solvated in acetone.
- the rubber solution, MY9663 and ETPI were mixed for 10 minutes until homogeneous. This mixture was then heated to reflux (approx 57°C) and held for 2 hours. The solution had approximately 45% resin solids during the reflux. After the two hour reflux, the heating apparatus was removed and the Epon 828 and Epon 1001 F were added immediately to the solution. This was allowed to mix until the solid 1001F had completely dissolved into the solution. With the solution mixed well and cooled to approaching room temperature, the DDS and DICY were added to the mixture. 0.01 % by weight Aerosil 974 (fumed silica available from De Gussa) was also added at this point and allowed to mix until homogeneous.
- the impregnated fabric was then transferred to the tape line and compacted under the following set of conditions:
- compositions according to the invention perform surprisingly well in this test which is considered especially important in the aerospace industry since aerospace vehicles are frequently subjected to very low temperatures during flights.
- a porosity panel was also prepared in which fabric was bonded to a honeycomb structure using the layup illustrated in Figure 6.
- the panel was consolidated by being placed into a bag, as illustrated in Figure 7, and autoclaved.
- the panels are sectioned into two equal halves from which a 1 inch (25.4mm) wide strip is then cut and mounted in epoxy resin.
- the specimen is then polished to a high surface finish and the number of pores along the length of the panel are counted using a light microscope. If any
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/750,394 US6013730A (en) | 1994-06-07 | 1995-06-06 | At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent |
AU26256/95A AU689902B2 (en) | 1994-06-07 | 1995-06-06 | Curable compositions |
EP95921054A EP0764180B9 (en) | 1994-06-07 | 1995-06-06 | Curable compositions |
DE69533358T DE69533358T2 (en) | 1994-06-07 | 1995-06-06 | HARDENABLE COMPOSITIONS |
CA002192368A CA2192368C (en) | 1994-06-07 | 1995-06-06 | Curable compositions |
AT95921054T ATE273337T1 (en) | 1994-06-07 | 1995-06-06 | CURABLE COMPOSITIONS |
JP50056196A JP4397970B2 (en) | 1994-06-07 | 1995-06-06 | Curable composition |
DK95921054T DK0764180T3 (en) | 1995-06-06 | 1995-06-06 | Hardenable compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9411367.7 | 1994-06-07 | ||
GB9411367A GB9411367D0 (en) | 1994-06-07 | 1994-06-07 | Curable Composites |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995033785A1 true WO1995033785A1 (en) | 1995-12-14 |
Family
ID=10756315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1995/001303 WO1995033785A1 (en) | 1994-06-07 | 1995-06-06 | Curable compositions |
Country Status (12)
Country | Link |
---|---|
US (2) | US6013730A (en) |
EP (1) | EP0764180B9 (en) |
JP (1) | JP4397970B2 (en) |
KR (1) | KR100341666B1 (en) |
AT (1) | ATE273337T1 (en) |
AU (1) | AU689902B2 (en) |
CA (1) | CA2192368C (en) |
DE (1) | DE69533358T2 (en) |
ES (1) | ES2227549T3 (en) |
GB (1) | GB9411367D0 (en) |
MX (1) | MX9606181A (en) |
WO (1) | WO1995033785A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
KR970703378A (en) | 1997-07-03 |
CA2192368A1 (en) | 1995-12-14 |
US6242083B1 (en) | 2001-06-05 |
EP0764180B9 (en) | 2005-03-02 |
MX9606181A (en) | 1998-06-30 |
JPH10501020A (en) | 1998-01-27 |
AU2625695A (en) | 1996-01-04 |
US6013730A (en) | 2000-01-11 |
ATE273337T1 (en) | 2004-08-15 |
EP0764180B1 (en) | 2004-08-11 |
KR100341666B1 (en) | 2003-01-14 |
GB9411367D0 (en) | 1994-07-27 |
AU689902B2 (en) | 1998-04-09 |
ES2227549T3 (en) | 2005-04-01 |
JP4397970B2 (en) | 2010-01-13 |
CA2192368C (en) | 2007-11-20 |
DE69533358T2 (en) | 2004-12-30 |
EP0764180A1 (en) | 1997-03-26 |
DE69533358D1 (en) | 2004-09-16 |
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