WO1995010663A1 - A method and a material for making luminescent roads - Google Patents
A method and a material for making luminescent roads Download PDFInfo
- Publication number
- WO1995010663A1 WO1995010663A1 PCT/DK1994/000384 DK9400384W WO9510663A1 WO 1995010663 A1 WO1995010663 A1 WO 1995010663A1 DK 9400384 W DK9400384 W DK 9400384W WO 9510663 A1 WO9510663 A1 WO 9510663A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- luminiscent
- road
- granulate
- fluorescent
- sand
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims description 10
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- 239000008187 granular material Substances 0.000 claims abstract description 14
- 239000004576 sand Substances 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims abstract description 10
- 239000003973 paint Substances 0.000 claims abstract description 8
- 239000004567 concrete Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229920003023 plastic Polymers 0.000 claims abstract description 5
- 239000004033 plastic Substances 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002344 surface layer Substances 0.000 claims description 3
- 239000012764 mineral filler Substances 0.000 claims 2
- 239000004566 building material Substances 0.000 claims 1
- 230000000295 complement effect Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 11
- 150000001875 compounds Chemical class 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 239000004575 stone Substances 0.000 abstract description 3
- 239000005080 phosphorescent agent Substances 0.000 abstract description 2
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000013543 active substance Substances 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 3
- ALZOLUNSQWINIR-UHFFFAOYSA-N quinmerac Chemical compound OC(=O)C1=C(Cl)C=CC2=CC(C)=CN=C21 ALZOLUNSQWINIR-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- -1 acryl Chemical group 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229940032007 methylethyl ketone Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/085—Aggregate or filler materials therefor; Coloured reflecting or luminescent additives therefor
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
Definitions
- the present invention relates to a method for making a road surface of luminiscent type, primarily a surface being fluorescent by irradiation with ultravio ⁇ let light.
- SE-B 462,109 there has previously been experimented with the principle of making the road itself luminiscent by the use of vehicle lights or auxiliary lights with a high content of UV- light, as a significant improvement of the road sight is hereby achieved.
- the previous attempts have hardly ever left the laboratory phase, as it is crucial for the applicability of the concept that the desired character of the surface is achievable in an efficient and yet non-expensive way.
- the hitherto suggested solu ⁇ tions are either too weak or too expensive for practical applicability, and it is the purpose of the invention to suggest a technique which is suitable for use in prac ⁇ tice in an economic and efficient way.
- the granulate in question which can also contain for instance sand, will be coated by the binder in the road material, but after a slight wearing-off of the road surface, the granulate in the surface layer will be ex ⁇ posed and thus present the luminiscent effect.
- an aqueous solution of a lumini ⁇ scent agent will be applicable as a thin surface layer when it is compounded into an aqueous cement grout, which is applied as paint, preferably with a further content of sand or other wear resistant material.
- the paint will after setting make excellent adhesion to the base course, inter alia by being absorbed by depressions into the road surface.
- the invention is based on the consi ⁇ deration that generally - no matter whether the applied active agent is liquid or solid - it will be advantage ⁇ ous to incorporate the agent in an independent structu ⁇ ral matrix, inter alia because in the same matrix there may be other agents specially suited as concomitant agents, for instance a white dyestuff that may promote the reflection from an fluorescent agent without the said concomitant agent having to be present all over the road material.
- the effect of the active agent can be optimized in exactly the subareas where it occurs, just as the same subareas or macroparticles, for instance by said application of sand, may be adapted to appear as mechanically acceptable parts of a road layer.
- the remaining part of the road material which will normally constitute the major part of all the material, can then be prepared completely without considerations as to the desired special effects of the road surface.
- Cer ⁇ tain ones of the very inexpensive active substances may show disadvantages as to sta ⁇ bility or environmental effects, viz. by a noticeable content of heavy metals, but partly there may very well be found other and more acceptable active substances, and partly there may in some incidents be compensated for the disadvantageous capabilities by admixing compen ⁇ sating agents into the limited matrix, in which the active substance occurs.
- the special structural matrix carrying the luminiscent agent need not necessarily be based on a hydraulic material, as for instance also a plastic matrix of polyester, polyurethane, acryl plas ⁇ tics or another corresponding material with an admixed hardener and optionally an accociated hardening accele ⁇ rating agent.
- the same matrix may consist of a more or less transparent material in order to en ⁇ hance the effects of the active stuff.
- paraffin or transparent plastics may be used.
- suitable heat resistant dyestuffs even glass may be used, and generally ceramic matrixes such as for in ⁇ stance tile will be applicable.
- UV-lamps should be adapted for defiltration of UV-rays in the short-waved area of the spectrum, as these rays are dangerous, and therefore active agents must be elected, which are active in the remaining, long-waved area of the UV-spectru .
- the road materi ⁇ al itself may in principle be considered as a potential matrix for the luminiscent agent, almost no matter the kind or condition of this agent, when only the agent is resistant in the alkaline environments, but for good reasons it is preferred that the agent is only mixed into the top layer. This, however, will still be most suitable also for mixing into concrete or for instance by depression into the concrete surface.
- the matrix granulate may be produced by a direct moulding into pellet or macro particle shape, but also by crushing of a manufactured voluminous solid material. After or in connection with the crushing a sieving may take place, whereby the actual granulate is isolated from the more fine-grained material, and the latter fraction may, optionally, be used for scattering on a not yet set road surface.
- Example 1 serves to illustrate the embodiment con ⁇ sisting of a fluorescent, cement based granulate being mixed into an ordinary stone material, whereby the road material or the like thus produced becomes fluorescent.
- the applied powdered dyestuff is produced commer ⁇ cially by Swada Ltd., London.
- the dry components are mixed separately whereafter the water is added.
- the components are thereafter thoroughly mixed and grouted in slabs or the like, which, after setting, are crushed and sieved.
- the 8-12-fraction of a material produced by this recipe has been used for the making of a test road in full scale, whereby a surface treatment on an already existing road surface was effected, based on conventio ⁇ nal road building technique.
- the fluorescent granulate hereby constituted 40% of the total stone material, which consisted of bright granite.
- the layer showed a surprisingly powerful luminous effect, proved by test driving with a vehicle equipped with UV-lamps.
- Example 2 is a recipe of a plastic based granulate, which can be applied in the same way as the cement based granulate according to example 1.
- Example 2 is a recipe of a plastic based granulate, which can be applied in the same way as the cement based granulate according to example 1.
- Sand and dyestuff are mixed dry, whereafter these constituents are mixed into the polyester.
- the MEKP-solution is added, and the mass is moulded out.
- a mixture according to this recipe will harden by ambient air temperature, but the hardening may be expedited and the strength of the finished material be improved by a weak heating, for instance to 45°C. After hardening the material is crushed and sieved.
- Reaction compounds according to the recipes in examples 1 and 2 will also be qualified for grouting in minor parts, these being used in a corresponding way as a given fraction of crushed material. Thus energy con ⁇ sumption and waste at the crushing is saved.
- Example 3 illustrates the possible compound of a cement based paint for treatment of an existing road surface, whereby this is made fluorescent.
- the dry compounds are mixed thoroughly, whereafter water is added. Thereby a thin paste is produced, applicable as a paint.
- the noticeable content of sand makes the paint wear resistant, just as it will counter ⁇ act moulding shrinkage and crack formations in the paint layer.
- the degree of addition of dyestuff or matrix granulate in the road material may be adapted according to the desired effect, balanced with other relevant circumstances. It is even a theoretical possibility that a road can be made based solely on the matrix granulate with the use of a suit ⁇ able binder.
- Vehicles moving in one traffic lane of a two-way carriageway may be provided with a UV-light equipment which will also activate the opposite lane for general lightening thereof.
- a driver driving in the oppo ⁇ site direction when meeting a more or less blinding counterlight, may orient him- or herself better of the driving conditions further ahead.
- This effect may be further improved by the use of a phosphescent light sub ⁇ stance, or by the use of stationary means for an irradi ⁇ ation or any other actuation of the light substance.
- a phosphorescence would be active during the dark hours, solely by the influence of the daylight irradiation.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Road Paving Structures (AREA)
- Road Signs Or Road Markings (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU78080/94A AU7808094A (en) | 1993-10-13 | 1994-10-13 | A method and a material for making luminescent roads |
DK041396A DK41396A (da) | 1993-10-13 | 1996-04-11 | Fremgangsmåde og materiale til frembringelse af luminiscerende veje |
NO961431A NO961431L (no) | 1993-10-13 | 1996-04-11 | Fremgangsmåte og materiale for fremstilling av luminescerende veier |
SE9601417A SE9601417L (sv) | 1993-10-13 | 1996-04-12 | Förfarande och material för framställning av luminiscerande vägar |
FI961609A FI961609A (sv) | 1993-10-13 | 1996-04-12 | Förfarande och material för framställning av luminiscerande vägar |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK1147/93 | 1993-10-13 | ||
DK931147A DK114793D0 (da) | 1993-10-13 | 1993-10-13 | Vejbelaegning af fluorscerende type, og materialer dertil |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995010663A1 true WO1995010663A1 (en) | 1995-04-20 |
Family
ID=8101541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DK1994/000384 WO1995010663A1 (en) | 1993-10-13 | 1994-10-13 | A method and a material for making luminescent roads |
Country Status (6)
Country | Link |
---|---|
AU (1) | AU7808094A (sv) |
DK (1) | DK114793D0 (sv) |
FI (1) | FI961609A (sv) |
NO (1) | NO961431L (sv) |
SE (1) | SE9601417L (sv) |
WO (1) | WO1995010663A1 (sv) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811663A1 (fr) | 2000-07-13 | 2002-01-18 | Commenplus | Materiau luminescent de ragreage et procede de mise en place d'un tel materiau |
US8562864B2 (en) | 2008-06-24 | 2013-10-22 | Shell Oil Company | Asphalt mixture |
PL423018A1 (pl) * | 2017-09-29 | 2019-04-08 | Wojciech Kempa | Fluorescencyjna nawierzchnia betonowa drogi |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4172063A (en) * | 1976-12-06 | 1979-10-23 | Brill Robert O | Abrasion resistant reflective marking composition |
WO1993011302A1 (fr) * | 1991-12-03 | 1993-06-10 | Jean Noel Dubois | Composition bitumineuse phosphorescente |
WO1993018233A1 (de) * | 1992-03-06 | 1993-09-16 | Plastiroute S.A. | Reflexkörper aus durchsichtigem material zum aufbringen auf verkehrsflächen oder verkehrsleitflächen |
-
1993
- 1993-10-13 DK DK931147A patent/DK114793D0/da not_active Application Discontinuation
-
1994
- 1994-10-13 WO PCT/DK1994/000384 patent/WO1995010663A1/en active Application Filing
- 1994-10-13 AU AU78080/94A patent/AU7808094A/en not_active Abandoned
-
1996
- 1996-04-11 NO NO961431A patent/NO961431L/no unknown
- 1996-04-12 FI FI961609A patent/FI961609A/sv unknown
- 1996-04-12 SE SE9601417A patent/SE9601417L/sv not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4172063A (en) * | 1976-12-06 | 1979-10-23 | Brill Robert O | Abrasion resistant reflective marking composition |
WO1993011302A1 (fr) * | 1991-12-03 | 1993-06-10 | Jean Noel Dubois | Composition bitumineuse phosphorescente |
WO1993018233A1 (de) * | 1992-03-06 | 1993-09-16 | Plastiroute S.A. | Reflexkörper aus durchsichtigem material zum aufbringen auf verkehrsflächen oder verkehrsleitflächen |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811663A1 (fr) | 2000-07-13 | 2002-01-18 | Commenplus | Materiau luminescent de ragreage et procede de mise en place d'un tel materiau |
US8562864B2 (en) | 2008-06-24 | 2013-10-22 | Shell Oil Company | Asphalt mixture |
PL423018A1 (pl) * | 2017-09-29 | 2019-04-08 | Wojciech Kempa | Fluorescencyjna nawierzchnia betonowa drogi |
Also Published As
Publication number | Publication date |
---|---|
NO961431L (no) | 1996-05-13 |
FI961609A0 (sv) | 1996-04-12 |
AU7808094A (en) | 1995-05-04 |
FI961609A (sv) | 1996-04-12 |
SE9601417L (sv) | 1996-05-13 |
DK114793D0 (da) | 1993-10-13 |
SE9601417D0 (sv) | 1996-04-12 |
NO961431D0 (no) | 1996-04-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR102282837B1 (ko) | 친환경 아크릴계 폴리머 콘크리트 미끄럼방지, 피톤치드 발산 및 축광 투수포장재 조성물 및 이를 이용한 폴리머 콘크리트 미끄럼방지, 피톤치드 발산 및 축광 투수블록 및 이를 이용한 투수포장 시공공법 | |
US4402749A (en) | Cementitious compositions with early high strength development and methods for controlling setting rate | |
JP2022530330A (ja) | 改善された照明を備えた舗装ブロック | |
CN102431246A (zh) | 防滑透水路垫及其制作工艺 | |
KR102271974B1 (ko) | 차열 성능이 우수한 미끄럼방지포장재 및 이의 제조방법 | |
WO1995010663A1 (en) | A method and a material for making luminescent roads | |
KR101117781B1 (ko) | 칼라 주입 모르타르 및 이를 이용한 칼라 콘크리트 포장방법 | |
KR100951413B1 (ko) | 무색소 비시멘트계 콘크리트 조성물 및 이를 이용한 콘크리트 포장 시공방법 | |
KR101609360B1 (ko) | 포장 조성물 및 이의 시공방법 | |
CN202208874U (zh) | 防滑透水路垫 | |
EP3204343B1 (en) | Surface provided with a pattern of luminescent elements | |
KR101011504B1 (ko) | 칼라 밀크 그라우트 및 이를 이용한 조기개통식 콘크리트 포장방법 | |
JPH11181707A (ja) | 透水性樹脂舗装材を使用しての舗装方法とブロック製造方法。 | |
US11725140B2 (en) | Photoluminescent premixed compositions, related methods and uses | |
KR100916939B1 (ko) | 칼라 아스팔트 | |
KR100690393B1 (ko) | 도로포장용 표층 아스콘의 시공방법 | |
EP0380704B1 (en) | Cement/asphalt mixture and process for its production | |
EP2644341B1 (en) | Method for manufacturing a reflective construction element. | |
KR20060033761A (ko) | 형광성 또는 야광성 물질을 함유하는 석재 | |
KR19990007693A (ko) | 고유동성(高流動性) 투수콘크리트 | |
JPH08119706A (ja) | 発光性材料の製造方法 | |
JPH06294104A (ja) | 透水性樹脂薄層舗装及び同舗装の施工方法 | |
CN109504255A (zh) | 一种用于道路施工区的彩色反光交通标线涂料及其制备方法 | |
KR100383365B1 (ko) | 자연석 돌출형 아스팔트 콘크리트 박층 포장방법 | |
CA3123128C (en) | Photoluminescent sand |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AM AT AT AU BB BG BR BY CA CH CN CZ CZ DE DE DK DK ES FI FI GB GE HU JP KE KG KP KR KZ LK LT LU LV MD MG MN MW NL NO NZ PL PT RO RU SD SE SI SK SK TJ TT UA US UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE MW SD SZ AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 96014170 Country of ref document: SE Ref document number: 961609 Country of ref document: FI |
|
ENP | Entry into the national phase |
Ref country code: US Ref document number: 1996 628732 Date of ref document: 19960415 Kind code of ref document: A Format of ref document f/p: F |
|
WWP | Wipo information: published in national office |
Ref document number: 96014170 Country of ref document: SE |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
122 | Ep: pct application non-entry in european phase | ||
NENP | Non-entry into the national phase |
Ref country code: CA |
|
ENP | Entry into the national phase |
Ref country code: US Ref document number: 1997 953502 Date of ref document: 19971017 Kind code of ref document: A Format of ref document f/p: F |