WO1994027106A1 - Apparatus for countering deposition on a conduit - Google Patents
Apparatus for countering deposition on a conduit Download PDFInfo
- Publication number
- WO1994027106A1 WO1994027106A1 PCT/IE1994/000024 IE9400024W WO9427106A1 WO 1994027106 A1 WO1994027106 A1 WO 1994027106A1 IE 9400024 W IE9400024 W IE 9400024W WO 9427106 A1 WO9427106 A1 WO 9427106A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rod
- conduit
- groove
- elongate
- fluid
- Prior art date
Links
- 230000008021 deposition Effects 0.000 title claims abstract description 14
- 230000037431 insertion Effects 0.000 claims abstract description 5
- 238000003780 insertion Methods 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 3
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000012530 fluid Substances 0.000 description 45
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000007528 sand casting Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28G—CLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
- F28G1/00—Non-rotary, e.g. reciprocated, appliances
- F28G1/06—Non-rotary, e.g. reciprocated, appliances having coiled wire tools, i.e. basket type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/06—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media
- F28F13/12—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media by creating turbulence, e.g. by stirring, by increasing the force of circulation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
Definitions
- Bothersome mineral materials found in fluids would include calcium bicarbonate, calcium carbonate, calcium sulphate, magnesium sulphate, sodium salts, silica, alumina, iron and manganese salts and free sulphur.
- an elongate rod for countering deposition on a conduit the rod being adapted for insertion and location in the conduit, characterised in that the rod has a substantially helical, longitudinally extending groove.
- the rod is non-hollow and the groove is on an external surface of the rod.
- the rod is hollow and the groove is on an internal surface of the rod.
- the rod is provided with a longitudinally extending passageway therethrough, the groove being located about the passageway.
- the rod is additionally provided with a groove on the external surface of the rod.
- the rod is provided with end regions which serve to locate, in use, the rod in the conduit.
- the end regions are substantially triangular in cross-section, the apices of the end regions serving to locate, in use, the rod in the conduit.
- the rod comprises an alloy of copper, zinc, nickel and tin, and incidental impurities.
- the rod comprises, by weight, 40-50% copper, 20-30% zinc, 15-25% nickel and 9-15% tin, and incidental impurities.
- the invention also provides a combination of an elongate rod as hereinabove defined and a conduit adapted to receive the rod.
- a washer is provided, which washer is located, or is adapted to be located, within the conduit to secure the rod in the conduit.
- Figure 1 is a perspective view of a first embodiment of an elongate rod according to the invention in a partially cut-away conduit section;
- Figure 2 is a transverse section along line II-II of Figure 1 ;
- Figure 3 is a transverse section of a second embodiment of an elongate rod according to the invention.
- FIG. 1 and 2 of the accompanying drawings there is illustrated a first embodiment of an elongate rod 10 according to the invention for countering deposition on a conduit 12.
- the rod 10 is tapered at one end to form a head 14 to offer as little resistance as possible to fluid flow over the head 14 by promoting a smooth fluid pressure transition.
- the other end or tail 16 of the rod 10 is flat, thereby promoting a high local fluid pressure drop, which in turn aids in releasing acid-forming gases.
- the rod 10 Adjacent the head 14 and the tail 16, the rod 10 is provided with end regions 18, 20 which are substantially triangular in cross-section, with sides 22, 24, 26.
- the end regions 18, 20 include longitudinally extending apices 28, 30, 32 at the intersections of sides 22 and 24, 24 and 26, and 26 and 22.
- the apices 28, 30, 32 serve to locate, in use, the rod 10 in the conduit 12.
- Lugs may extend outwardly from, for example, apex 28 to accommodate variations in the inner diameter of the conduit 12 in which the rod 10 is to be inserted.
- a substantially helical groove 34 is provided on an external surface of the rod 10 intermediate the end regions 18, 20.
- laminar fluid flow is inhibited and helical fluid flow is promoted, thereby increasing fluid turbulence.
- Increased fluid turbulence and the attendant mixing effect enhances the extent of surface contact between the rod 10 and the fluid, thereby increasing the effective fluid contact area of the rod 10.
- the localised pressure drops aid in releasing dissolved acid-forming gases such as carbon dioxide and hydrogen sulphide which, it is thought, decrease scaling tendancies and influence the amount of precipitate formed.
- Increased turbulence also inhibits deposition on the rod itself.
- the rod 10 is preferably installed in the conduit 12 and is retained therein by a friction or press fit between the apices 28, 30, 32 and the inner wall 36 of the conduit 12.
- a second embodiment of a rod 110 is retained in the conduit 112 by a circumferential washer 38 welded or otherwise secured to the inner wall 136 of the conduit 112 adjacent the end region 118 of the rod 110.
- the rod 110 preferably has a shoulder (not shown) on the end region 118, so that the head 114 projects through the washer 38 with the shoulder engaging the inwardly facing surface of the washer 38.
- the rod 110 may also be provided with a circumferential washer (not shown) welded or otherwise secured to the inner wall 136 of the conduit 112 adjacent the end region 120.
- the rod 110 has a central longitudinally extending passageway 40, which constitutes an additional fluid flow channel.
- the passageway 40 has a substantially helical groove 42 therein. In use, as fluid flows along the groove 42 of the passageway 40, helical fluid flow is promoted and thus fluid turbulence is increased.
- the rod 10, 110 is inserted in the conduit 12, 112 and retained in place by, for example, washers or welding and, thus retained, is installed in a fluid flow system, such as a water well, or a steam boiler, without having to modify the fluid flow system.
- a fluid flow system such as a water well, or a steam boiler
- the diameter of the conduit 12, 112 corresponds to the diameter of the tubing of the fluid flow system, unless a smaller diameter conduit 12, 112 is necessary to ensure a minimum flow rate over the rod 10, 110.
- the conduit 12, 112 may have means, such as external threads (not shown), for installing the conduit 12, 112 in the fluid flow system with the rod 10, 110 already positioned in the conduit 12, 112.
- the conduit 12, 112 may be welded or otherwise fluid-tightly inserted and secured into the fluid flow system.
- the fluid is caused to flow over the head 14, 114 of the rod 10, 110, whereupon it divides over the head 14, 114 to flow through three channels 44, 144; 46, 1 6; 48, 148 bounded by the sides 22, 122; 24, 124; 26, 126 and the inner wall 36, 136. Fluid is then caused to flow along the substantially helical groove 34, 134. If a central passageway 40 is present, fluid is also caused to flow along the substantially helical groove 42. Turbulent flow and localised pressure fluid rises and drops occur, causing mixing and extensive contact between the fluid and the rod 10, 110, so that polarisation of the minerals in the fluid occurs. Efficient polarisation is achieved by virtue of the substantially helical configuration of the groove 34, 134 and the groove 42, if present, which grooves promote turbulent flow and afford a large surface area for fluid contact.
- the washer 38 is only shown in connection with the hollow rod 110 shown in Figure 3, it can equally well be employed with the solid rod 10 shown in Figures 1 and 2.
- the rod 10 shown in Figures 1 and 2 may have a longitudinally extending passageway with a groove therein similar to the passageway 40/groove 42 shown in Figure 3.
- the rod according to the invention shown in Figure 3 may not necessarily have the groove 134 in the external surface of the rod 110 and the rod is so shaped that fluid flow is primarily directed through the passageway 40.
- Such a rod could take the form of a hollow tube, having the groove 42 on its inner surface and adapted to engage the conduit 12, 112 at its outer surface.
- the rod 10, 110 can be manufactured in lengths of from about 20cm to 1 metre and in widths suitable for insertion in conduits having internal diameters ranging from 0.8cm to 35cm. Generally, the length of the rod increases as the diameter of the rod increases.
- groove(s) may be cut into the rod according to the invention or, alternatively, extend outwardly from the rod according to the invention.
- the rod's dimensions are ideally chosen to prevent any significant drop in the flow rate, or pressure, of the fluid flowing through the conduit 12, 112. It will also be appreciated that, as the diameter of the rod increases, the rods become quite massive and may become an impediment or restriction to flow through the conduit. Accordingly, it may be desirable that a longitudinally extending passageway is formed in the rod (as is shown in Figure 3) to provide an additional fluid flow channel and, at the same time, an additional surface area.
- the rod 10 or 110 is preferably formed of an alloy of copper, zinc, nickel and tin by melting the alloy at between 1 ,000-1 ,500°C and then sand casting the rods to the desired shape.
- Preferred rod compositions comprise, by weight, 40-50% copper, 20-30% zinc, 15-25% nickel and 9-15% tin, and incidental impurities. Rods having compositions in the aforementioned ranges have been found to be non-sacrificial or only slowly sacrificial with expected useful lives in normal use of up to about 10 years.
- the mechanism of operation is that the alloy has a very high surface activity, due to a reaction between the phases of the alloy, which promotes a rise in pH very close to the rod's surface and attracts mineral ions to the rod's surface, thereby triggering the early formation of, for example, calcium carbonate seed crystals by creating local areas of supersaturation in the fluid. It is believed that the precipitated calcium carbonate is in the form of stable aragonite crystals, which are unlikely to be deposited on conduits or, if deposited, are more easily removed than the calcite crystals which are normally formed.
- the volume taken up by the elongate rod according to the present invention is reduced, when compared with the elongate rod as claimed in our earlier Irish Patent Specification No. 39035. This reduces the obstruction and the amount of head loss in the fluid flow system, so that less pump energy is required to pump the fluid around the fluid flow system.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94914538A EP0707702A1 (en) | 1993-05-07 | 1994-05-06 | Apparatus for countering deposition on a conduit |
AU66875/94A AU6687594A (en) | 1993-05-07 | 1994-05-06 | Apparatus for countering deposition on a conduit |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IE930345 | 1993-05-07 | ||
IE930345 | 1993-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994027106A1 true WO1994027106A1 (en) | 1994-11-24 |
Family
ID=11039958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IE1994/000024 WO1994027106A1 (en) | 1993-05-07 | 1994-05-06 | Apparatus for countering deposition on a conduit |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0707702A1 (enrdf_load_stackoverflow) |
AU (1) | AU6687594A (enrdf_load_stackoverflow) |
IN (1) | IN184672B (enrdf_load_stackoverflow) |
WO (1) | WO1994027106A1 (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0770845A3 (de) * | 1995-10-26 | 1998-12-02 | Sgl Technik Gmbh | Rohr für Wärmeaustauscher mit wirbelerzeugenden Stromstörungselementen |
EP1008826A1 (fr) * | 1998-12-07 | 2000-06-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Vaporisateur à film ruisselant et installations de distillation d'air correspondantes |
CN1657189B (zh) * | 2004-02-16 | 2010-05-12 | 湖南工业大学 | 一种管内污垢旋转清洗件固定机构的动力矩强化装置 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1770208A (en) * | 1924-02-29 | 1930-07-08 | Babcock & Wilcox Co | Air heater |
DE1779583A1 (de) * | 1968-08-29 | 1971-10-07 | Pintsch Bamag Ag | Wendelfoermiger Leitkoerper fuer Rauchrohre |
FR2273252A1 (en) * | 1974-05-29 | 1975-12-26 | Stein Industrie | Heat exchanger with nest of tubes - inner tube carries staggered sloping plates forming zig-zag path for hot gases |
FR2439630A1 (fr) * | 1978-10-23 | 1980-05-23 | Montage Cie Indle | Dispositif de nettoyage de tubes conduisant des gaz charges d'impuretes et d'epuration des gaz |
EP0174254A1 (fr) * | 1984-08-31 | 1986-03-12 | Compagnie De Raffinage Et De Distribution Total France | Dispositif mécanique destinés à améliorer les transferts thermiques et à prévenir l'encrassement des échangeurs de chaleur |
EP0233092A1 (fr) * | 1986-01-10 | 1987-08-19 | COMPAGNIE DE RAFFINAGE ET DE DISTRIBUTION TOTAL FRANCE: Société Anonyme dite | Dispositif de maintien en position d'une extrêmité d'un élément mobile, entraîné en rotation dans un tube, et application de ce dispositif |
GB2200201A (en) * | 1987-01-21 | 1988-07-27 | United Carr Ltd Trw | Vehicle radiator turbulator |
US4820422A (en) * | 1985-02-05 | 1989-04-11 | Envirecon Services Limited | Method for countering scale formation in fluid conduits |
-
1994
- 1994-05-06 EP EP94914538A patent/EP0707702A1/en not_active Withdrawn
- 1994-05-06 IN IN378MA1994 patent/IN184672B/en unknown
- 1994-05-06 AU AU66875/94A patent/AU6687594A/en not_active Abandoned
- 1994-05-06 WO PCT/IE1994/000024 patent/WO1994027106A1/en not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1770208A (en) * | 1924-02-29 | 1930-07-08 | Babcock & Wilcox Co | Air heater |
DE1779583A1 (de) * | 1968-08-29 | 1971-10-07 | Pintsch Bamag Ag | Wendelfoermiger Leitkoerper fuer Rauchrohre |
FR2273252A1 (en) * | 1974-05-29 | 1975-12-26 | Stein Industrie | Heat exchanger with nest of tubes - inner tube carries staggered sloping plates forming zig-zag path for hot gases |
FR2439630A1 (fr) * | 1978-10-23 | 1980-05-23 | Montage Cie Indle | Dispositif de nettoyage de tubes conduisant des gaz charges d'impuretes et d'epuration des gaz |
EP0174254A1 (fr) * | 1984-08-31 | 1986-03-12 | Compagnie De Raffinage Et De Distribution Total France | Dispositif mécanique destinés à améliorer les transferts thermiques et à prévenir l'encrassement des échangeurs de chaleur |
US4820422A (en) * | 1985-02-05 | 1989-04-11 | Envirecon Services Limited | Method for countering scale formation in fluid conduits |
EP0233092A1 (fr) * | 1986-01-10 | 1987-08-19 | COMPAGNIE DE RAFFINAGE ET DE DISTRIBUTION TOTAL FRANCE: Société Anonyme dite | Dispositif de maintien en position d'une extrêmité d'un élément mobile, entraîné en rotation dans un tube, et application de ce dispositif |
GB2200201A (en) * | 1987-01-21 | 1988-07-27 | United Carr Ltd Trw | Vehicle radiator turbulator |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0770845A3 (de) * | 1995-10-26 | 1998-12-02 | Sgl Technik Gmbh | Rohr für Wärmeaustauscher mit wirbelerzeugenden Stromstörungselementen |
EP1008826A1 (fr) * | 1998-12-07 | 2000-06-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Vaporisateur à film ruisselant et installations de distillation d'air correspondantes |
US6695043B1 (en) | 1998-12-07 | 2004-02-24 | L'air Liquide - Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Falling-film evaporator and corresponding air distillation plants |
CN1657189B (zh) * | 2004-02-16 | 2010-05-12 | 湖南工业大学 | 一种管内污垢旋转清洗件固定机构的动力矩强化装置 |
Also Published As
Publication number | Publication date |
---|---|
IN184672B (enrdf_load_stackoverflow) | 2000-09-23 |
AU6687594A (en) | 1994-12-12 |
EP0707702A1 (en) | 1996-04-24 |
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