WO1994026860A1 - Silver-corrosion protection agent (ii) - Google Patents
Silver-corrosion protection agent (ii) Download PDFInfo
- Publication number
- WO1994026860A1 WO1994026860A1 PCT/EP1994/001387 EP9401387W WO9426860A1 WO 1994026860 A1 WO1994026860 A1 WO 1994026860A1 EP 9401387 W EP9401387 W EP 9401387W WO 9426860 A1 WO9426860 A1 WO 9426860A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- silver
- composition according
- alkyl
- agent
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0042—Reducing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C11D3/048—Nitrates or nitrites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/122—Sulfur-containing, e.g. sulfates, sulfites or gypsum
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2058—Dihydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
Definitions
- active oxygen compounds are mainly used in modern low-alkaline machine dishwashing detergents of the new generation of detergents together with bleach activators.
- These modern agents generally consist of the following functional components: builder component (complexing agent / dispersant), alkali carrier, bleaching system (bleach + bleach activator), enzymes and wetting agents (surfactants).
- Coupler and / or developer compounds known from oxidative dyeing are also particularly suitable.
- the organic redox-active substances described above are particularly suitable for preventing silver corrosion if they are contained in alkaline cleaners for the automatic cleaning of dishes. This is all the more surprising since the effectiveness of these silver corrosion protection agents is not impaired by the presence of oxygen-based bleaching agents usually present in lower-alkaline cleaners.
- the organic redox-active substances are preferably present in the compositions according to the invention in a total amount of 0.05 to 6% by weight, preferably 0.2 to 2.5% by weight, based on the total composition.
- polymeric alkali metal phosphates which may be in the form of their alkaline neutral or acidic sodium or potassium salts.
- examples include: tetrasodium diphosphate, disodium dihydrogen diphosphate, pentasodium triphosphate, so-called sodium hexametaphosphate and the corresponding potassium salts or mixtures of sodium hexametaphosphate and the corresponding potassium salts or mixtures of sodium and potassium salts.
- the amounts of phosphate are in the range of up to about 30% by weight, based on the total agent; however, the agents according to the invention are preferably free of such phosphates.
- the agents according to the invention preferably additionally contain the alkali carriers contained in conventional low-alkaline machine dishwashing detergents, such as. B. alkali silicates, alkali carbonates and / or alkali hydrogen carbonates.
- Alkali silicates can be present in amounts of up to 30% by weight all the means.
- the use of the highly alkaline metasilicates as alkali carriers is preferably dispensed with.
- surfactants in particular low-foaming nonionic surfactants, can also be added to the agents according to the invention, which improve the detachment of fatty food residues, as wetting agents, as granulating aids or as dispersing aids for better, homogeneous distribution of the aforementioned silver corrosion inhibitors in the washing liquor and on the Silver surfaces serve.
- Their amount is then up to 5% by weight, preferably up to 2% by weight.
- Extremely low-foam connections are usually used. These preferably include Ci2-Cl8 _ alkyl polyethylene glycol polypropylene glycol ether, each containing up to 8 moles of ethylene oxide and propylene oxide units in the molecule.
- the pre-granules are then mixed with the still missing components of the dishwashing detergent, including organic redox-active substances, to form the finished product.
- the mixing time is both in the preliminary stage of the compacting mixture under the influence of liquid components and in the subsequent final mixture with the other components in the range of a few minutes, for example in the range of 1 to 5 minutes.
- Ci2-Ci4-fatty alcohol ethoxylate (2E0) (Dehydol LS2 from Henkel) 1 0.75 1 1 0.75 1 1 0.75 1
- Trisodium citrate dihydrate 25 43 38 25 43 38 24 43 38 24
- the low-alkaline basic product (see above) was first dissolved and the solution heated to 65 ° C.
- the bleach and the bleach activator were used immediately before the measurement and / or the silver anticorrosive agent is added.
- the electrochemical measurement was then carried out. During the electrochemical experiments, the electrolyte solutions were heated to 65 ° C and flushed with air.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK94917579T DK0697036T3 (en) | 1993-05-08 | 1994-05-02 | Silver corrosion protection agent II |
PL94311624A PL177935B1 (en) | 1993-05-08 | 1994-05-02 | Agent for protecting silver ii against corrosion |
DE59408548T DE59408548D1 (en) | 1993-05-08 | 1994-05-02 | SILVER CORROSION PROTECTIVE II |
EP94917579A EP0697036B1 (en) | 1993-05-08 | 1994-05-02 | Silver-corrosion protection agent (ii) |
JP6524888A JPH08509778A (en) | 1993-05-08 | 1994-05-02 | Silver corrosion protection agent (▲ II ▼) |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19934315397 DE4315397A1 (en) | 1993-05-08 | 1993-05-08 | Cleaning composition preventing tarnishing of table silver in dishwashing machines |
DEP4315397.6 | 1993-05-08 | ||
DE19934338724 DE4338724A1 (en) | 1993-11-12 | 1993-11-12 | Organic redox substances used in dishwashing compsns. |
DEP4338724.1 | 1993-11-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994026860A1 true WO1994026860A1 (en) | 1994-11-24 |
Family
ID=25925738
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/001387 WO1994026860A1 (en) | 1993-05-08 | 1994-05-02 | Silver-corrosion protection agent (ii) |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0697036B1 (en) |
JP (1) | JPH08509778A (en) |
AT (1) | ATE182615T1 (en) |
CA (1) | CA2162459A1 (en) |
CZ (1) | CZ287850B6 (en) |
DE (1) | DE59408548D1 (en) |
DK (1) | DK0697036T3 (en) |
ES (1) | ES2134944T3 (en) |
HU (2) | HU218008B (en) |
PL (1) | PL177935B1 (en) |
WO (1) | WO1994026860A1 (en) |
Cited By (168)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995017493A1 (en) * | 1993-12-23 | 1995-06-29 | Henkel Kommanditgesellschaft Auf Aktien | Enzyme preparation containing a corrosion protecting agent for silver |
US5468410A (en) * | 1993-10-14 | 1995-11-21 | Angevaare; Petrus A. | Purine class compounds in detergent compositions |
US5480576A (en) * | 1993-10-14 | 1996-01-02 | Lever Brothers Company, Division Of Conopco, Inc. | 1,3-N azole containing detergent compositions |
WO1996022353A1 (en) * | 1995-01-20 | 1996-07-25 | Henkel Kommanditgesellschaft Auf Aktien | Cleaning product containing an anti-corrosion agent for silver |
WO1996037596A1 (en) * | 1995-05-22 | 1996-11-28 | Henkel Kommanditgesellschaft Auf Aktien | Diswasher detergent with agents providing protection against the corrosion of silver |
WO1996037593A1 (en) * | 1995-05-22 | 1996-11-28 | Henkel Kommanditgesellschaft Auf Aktien | Acid granulates containing redox-active substances |
EP0826768A1 (en) * | 1996-08-07 | 1998-03-04 | Henkel Kommanditgesellschaft auf Aktien | Granular components containing benzotriazole for automatic dishwashing compositions, and method of making them |
WO1999054431A1 (en) * | 1998-04-22 | 1999-10-28 | Henkel Kommanditgesellschaft Auf Aktien | Coated detergent components |
EP0842257B1 (en) * | 1995-07-13 | 2000-12-27 | Benckiser N.V. | Dish washer product in tablet form |
WO2001023507A1 (en) * | 1999-09-30 | 2001-04-05 | Henkel Kommanditgesellschaft Auf Aktien | Machine-based silver cleaning agents |
WO2005105966A1 (en) * | 2004-04-28 | 2005-11-10 | The Procter & Gamble Company | Antioxidant compositions |
WO2006018107A1 (en) * | 2004-08-18 | 2006-02-23 | Henkel Kommanditgesellschaft Auf Aktien | Detergents and cleaning agents comprising a rinsing agent and sulphurous amino acids |
WO2007141527A1 (en) | 2006-06-07 | 2007-12-13 | Reckitt Benckiser N. V. | Detergent composition |
WO2008087420A1 (en) | 2007-01-18 | 2008-07-24 | Reckitt Benckiser N.V. | Dosage element and a method of manufacturing a dosage element |
WO2009040544A1 (en) | 2007-09-28 | 2009-04-02 | Reckitt Benckiser N.V. | Detergent composition |
EP2100949A1 (en) | 2008-03-14 | 2009-09-16 | The Procter and Gamble Company | Automatic dishwashing detergent composition |
EP2100948A1 (en) | 2008-03-14 | 2009-09-16 | The Procter and Gamble Company | Automatic dishwashing detergent composition |
EP2166092A1 (en) | 2008-09-18 | 2010-03-24 | The Procter and Gamble Company | Detergent composition |
WO2010043854A1 (en) | 2008-10-14 | 2010-04-22 | Reckitt Benckiser N.V. | Dishwashing composition |
EP2216393A1 (en) | 2009-02-09 | 2010-08-11 | The Procter & Gamble Company | Detergent composition |
WO2010116139A1 (en) | 2009-04-09 | 2010-10-14 | Reckitt Benckiser N.V. | Detergent composition |
EP2261313A2 (en) | 2005-11-07 | 2010-12-15 | Reckitt Benckiser N.V. | Composition |
WO2011001170A1 (en) | 2009-07-02 | 2011-01-06 | Reckitt Benckiser N.V. | Compositions |
WO2011027170A2 (en) | 2009-09-07 | 2011-03-10 | Reckitt Benckiser N.V. | Detergent composition |
EP2031093A3 (en) * | 2007-08-31 | 2011-04-13 | Clariant Finance (BVI) Limited | Corrosion inhibitors containing non-ionic tensides |
WO2011042737A1 (en) | 2009-10-09 | 2011-04-14 | Reckitt Benckiser N.V. | Detergent composition |
EP2031094A3 (en) * | 2007-08-31 | 2011-04-20 | Clariant Finance (BVI) Limited | Corrosion inhibitors containing anionic tensides |
EP2333040A1 (en) | 2009-12-10 | 2011-06-15 | The Procter & Gamble Company | Detergent composition |
WO2011072099A2 (en) | 2009-12-09 | 2011-06-16 | Danisco Us Inc. | Compositions and methods comprising protease variants |
WO2011071994A2 (en) | 2009-12-10 | 2011-06-16 | The Procter & Gamble Company | Detergent composition |
WO2011071997A1 (en) | 2009-12-10 | 2011-06-16 | The Procter & Gamble Company | Automatic dishwashing product and use thereof |
WO2011084417A1 (en) | 2009-12-21 | 2011-07-14 | Danisco Us Inc. | Detergent compositions containing geobacillus stearothermophilus lipase and methods of use thereof |
WO2011084599A1 (en) | 2009-12-21 | 2011-07-14 | Danisco Us Inc. | Detergent compositions containing bacillus subtilis lipase and methods of use thereof |
WO2011084319A1 (en) | 2009-12-10 | 2011-07-14 | The Procter & Gamble Company | Detergent composition |
WO2011084412A1 (en) | 2009-12-21 | 2011-07-14 | Danisco Us Inc. | Detergent compositions containing thermobifida fusca lipase and methods of use thereof |
EP2361964A1 (en) | 2010-02-25 | 2011-08-31 | The Procter & Gamble Company | Detergent composition |
WO2011110849A1 (en) | 2010-03-09 | 2011-09-15 | Reckitt Benckiser N.V. | Detergent composition |
WO2011130222A2 (en) | 2010-04-15 | 2011-10-20 | Danisco Us Inc. | Compositions and methods comprising variant proteases |
WO2011150157A2 (en) | 2010-05-28 | 2011-12-01 | Danisco Us Inc. | Detergent compositions containing streptomyces griseus lipase and methods of use thereof |
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Also Published As
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DK0697036T3 (en) | 2000-01-31 |
HUT73025A (en) | 1996-06-28 |
CZ287850B6 (en) | 2001-02-14 |
ES2134944T3 (en) | 1999-10-16 |
ATE182615T1 (en) | 1999-08-15 |
HU9503200D0 (en) | 1996-01-29 |
EP0697036B1 (en) | 1999-07-28 |
DE59408548D1 (en) | 1999-09-02 |
PL311624A1 (en) | 1996-03-04 |
HU218008B (en) | 2000-05-28 |
CA2162459A1 (en) | 1994-11-24 |
JPH08509778A (en) | 1996-10-15 |
HU218021B (en) | 2000-05-28 |
EP0697036A1 (en) | 1996-02-21 |
CZ262595A3 (en) | 1996-02-14 |
HUT73028A (en) | 1996-06-28 |
HU9503201D0 (en) | 1995-12-28 |
PL177935B1 (en) | 2000-01-31 |
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