WO1994021755A3 - Use of ferrocene - Google Patents

Use of ferrocene Download PDF

Info

Publication number
WO1994021755A3
WO1994021755A3 PCT/EP1994/000803 EP9400803W WO9421755A3 WO 1994021755 A3 WO1994021755 A3 WO 1994021755A3 EP 9400803 W EP9400803 W EP 9400803W WO 9421755 A3 WO9421755 A3 WO 9421755A3
Authority
WO
WIPO (PCT)
Prior art keywords
ferrocene
sedimentation
auto
additive
heavy
Prior art date
Application number
PCT/EP1994/000803
Other languages
German (de)
French (fr)
Other versions
WO1994021755A2 (en
Inventor
Walter Thuenker
Gabriele Lohmann
Arnim Marschewski
Tage Ib Nielsen
Christian Luetzen
Original Assignee
Pluto Chem Betriebe
Svendborg Dampskibs As
Walter Thuenker
Gabriele Lohmann
Arnim Marschewski
Tage Ib Nielsen
Christian Luetzen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU63772/94A priority Critical patent/AU677388B2/en
Application filed by Pluto Chem Betriebe, Svendborg Dampskibs As, Walter Thuenker, Gabriele Lohmann, Arnim Marschewski, Tage Ib Nielsen, Christian Luetzen filed Critical Pluto Chem Betriebe
Priority to EP94911173A priority patent/EP0689577B1/en
Priority to DE59401861T priority patent/DE59401861D1/en
Priority to BR9405903A priority patent/BR9405903A/en
Priority to CA002156747A priority patent/CA2156747C/en
Priority to JP52063394A priority patent/JP3599337B2/en
Priority to KR1019950703731A priority patent/KR100274093B1/en
Priority to PL94310675A priority patent/PL177895B1/en
Publication of WO1994021755A2 publication Critical patent/WO1994021755A2/en
Publication of WO1994021755A3 publication Critical patent/WO1994021755A3/en
Priority to NO953659A priority patent/NO309777B1/en
Priority to FI954422A priority patent/FI119551B/en
Priority to GR970401140T priority patent/GR3023491T3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00Component parts, details or accessories, not otherwise provided for
    • F02B77/04Cleaning of, preventing corrosion or erosion in, or preventing unwanted deposits in, combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/301Organic compounds compounds not mentioned before (complexes) derived from metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture

Abstract

Described is the use of ferrocene and/or ferrocene derivatives as an additive to heavy-grade fuels for high-compression, auto-ignition internal combustion engines. This measure reduces functional impairment resulting from sedimentation in downstream units.
PCT/EP1994/000803 1993-03-20 1994-03-15 Use of ferrocene WO1994021755A2 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
JP52063394A JP3599337B2 (en) 1993-03-20 1994-03-15 High compression auto-ignition engine and method for reducing carbonaceous deposits on its accessories
EP94911173A EP0689577B1 (en) 1993-03-20 1994-03-15 Use of ferrocene
DE59401861T DE59401861D1 (en) 1993-03-20 1994-03-15 USE OF FERROCEN
BR9405903A BR9405903A (en) 1993-03-20 1994-03-15 Ferrocene application
CA002156747A CA2156747C (en) 1993-03-20 1994-03-15 Use of ferrocene as an additive in heavy grade fuels
AU63772/94A AU677388B2 (en) 1993-03-20 1994-03-15 Use of ferrocene
KR1019950703731A KR100274093B1 (en) 1993-03-20 1994-03-15 Use of ferrocene
PL94310675A PL177895B1 (en) 1993-03-20 1994-03-15 Application of ferrocene
NO953659A NO309777B1 (en) 1993-03-20 1995-09-15 Use of ferrocene and / or ferrocene derivatives
FI954422A FI119551B (en) 1993-03-20 1995-09-19 Use of ferrous metal
GR970401140T GR3023491T3 (en) 1993-03-20 1997-05-19 Use of ferrocene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4309066A DE4309066C2 (en) 1993-03-20 1993-03-20 Use of ferrocene
DEP4309066.4 1993-03-20

Publications (2)

Publication Number Publication Date
WO1994021755A2 WO1994021755A2 (en) 1994-09-29
WO1994021755A3 true WO1994021755A3 (en) 1994-12-08

Family

ID=6483399

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/000803 WO1994021755A2 (en) 1993-03-20 1994-03-15 Use of ferrocene

Country Status (19)

Country Link
EP (1) EP0689577B1 (en)
JP (1) JP3599337B2 (en)
KR (1) KR100274093B1 (en)
CN (1) CN1052034C (en)
AU (1) AU677388B2 (en)
BR (1) BR9405903A (en)
CA (1) CA2156747C (en)
DE (2) DE4309066C2 (en)
DK (1) DK0689577T3 (en)
ES (1) ES2099600T3 (en)
FI (1) FI119551B (en)
GR (1) GR3023491T3 (en)
IS (1) IS1813B (en)
NO (1) NO309777B1 (en)
NZ (1) NZ263179A (en)
PL (1) PL177895B1 (en)
SG (1) SG48900A1 (en)
WO (1) WO1994021755A2 (en)
ZA (1) ZA941941B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2274630T3 (en) * 1998-02-20 2007-05-16 John J. Kracklauer METHOD FOR PROVIDING AND MAINTAINING A CATALYTICALLY ACTIVE SURFACE ON AN INTERNAL COMBUSTION ENGINE.
GB0011908D0 (en) * 2000-05-16 2000-07-05 Infineum Int Ltd Process for operating diesel engines
DE10043144C1 (en) * 2000-08-31 2001-12-13 Octel Deutschland Gmbh Use of solutions of 2,2-bisferrocenylalkanes in an aromatic solvent as combustion-promoting diesel fuel additives
EP1752512A1 (en) 2005-08-09 2007-02-14 Infineum International Limited A method of reducing piston deposits, smoke or wear in a diesel engine
JP4131748B1 (en) * 2008-01-16 2008-08-13 株式会社タイホーコーザイ Fuel additive
ES2394922B1 (en) * 2011-06-20 2014-01-14 Juan Carlos PROCKIV CORZÓN COMPOSITE LIQUID ECOLOGICAL ADDITIVE FOR FOSSIL FUELS DERIVED FROM OIL.
WO2014165950A1 (en) * 2013-04-10 2014-10-16 Firmano Lino Junior Non-deposit forming catalytic additive for additive oil cracking, and for fuel octane increase and combustion

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265621A (en) * 1961-05-22 1966-08-09 Standard Oil Co Lubricants containing a hydrocarbon diester of 1, 1'-di-alpha-hydroxy-ethyl ferrocene
US3341311A (en) * 1953-07-27 1967-09-12 Du Pont Liquid hydrocarbon fuels
DE2502307A1 (en) * 1974-01-21 1975-07-31 Syntex Inc NEW LIQUID FUEL MIXTURES AND -PREPARATORS AND THEIR USE
US4389220A (en) * 1980-06-04 1983-06-21 Syntex (U.S.A.) Inc. Method of conditioning diesel engines
EP0359390A1 (en) * 1988-08-15 1990-03-21 Velino Ventures Inc. Improved combustion of liquid hydrocarbons
EP0375303A1 (en) * 1988-12-23 1990-06-27 Velino Ventures Inc. Engine cleaning additives for diesel fuel

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2807419C2 (en) * 1978-02-22 1979-07-05 Kloeckner-Werke Ag, 4100 Duisburg Process for operating blast furnaces
CN1034950A (en) * 1988-11-23 1989-08-23 兰州燃料炉具实验厂 The preparation of civilian heavy fuel oil (HFO) and special furnace set thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3341311A (en) * 1953-07-27 1967-09-12 Du Pont Liquid hydrocarbon fuels
US3265621A (en) * 1961-05-22 1966-08-09 Standard Oil Co Lubricants containing a hydrocarbon diester of 1, 1'-di-alpha-hydroxy-ethyl ferrocene
DE2502307A1 (en) * 1974-01-21 1975-07-31 Syntex Inc NEW LIQUID FUEL MIXTURES AND -PREPARATORS AND THEIR USE
US4389220A (en) * 1980-06-04 1983-06-21 Syntex (U.S.A.) Inc. Method of conditioning diesel engines
EP0359390A1 (en) * 1988-08-15 1990-03-21 Velino Ventures Inc. Improved combustion of liquid hydrocarbons
EP0375303A1 (en) * 1988-12-23 1990-06-27 Velino Ventures Inc. Engine cleaning additives for diesel fuel

Also Published As

Publication number Publication date
NO953659L (en) 1995-09-15
AU6377294A (en) 1994-10-11
PL177895B1 (en) 2000-01-31
EP0689577B1 (en) 1997-02-26
PL310675A1 (en) 1995-12-27
DK0689577T3 (en) 1997-03-17
FI954422A (en) 1995-09-19
IS4140A (en) 1994-09-21
DE4309066A1 (en) 1994-09-22
CN1119455A (en) 1996-03-27
BR9405903A (en) 1995-12-26
DE4309066C2 (en) 1995-07-20
FI119551B (en) 2008-12-31
WO1994021755A2 (en) 1994-09-29
NZ263179A (en) 1996-11-26
JP3599337B2 (en) 2004-12-08
KR100274093B1 (en) 2000-12-15
CA2156747C (en) 2005-06-07
DE59401861D1 (en) 1997-04-03
AU677388B2 (en) 1997-04-24
EP0689577A1 (en) 1996-01-03
NO309777B1 (en) 2001-03-26
SG48900A1 (en) 1998-05-18
CA2156747A1 (en) 1994-09-29
NO953659D0 (en) 1995-09-15
CN1052034C (en) 2000-05-03
FI954422A0 (en) 1995-09-19
JPH08508763A (en) 1996-09-17
IS1813B (en) 2002-07-08
GR3023491T3 (en) 1997-08-29
ZA941941B (en) 1995-01-16
ES2099600T3 (en) 1997-05-16

Similar Documents

Publication Publication Date Title
AU6204490A (en) Connector block for injectors for internal combustion engine and junction terminal for use with the same connector block
AU566822B2 (en) Fuel delivery to internal combustion engines
GR3030188T3 (en) Use of reaction products of polyolefins and nitrogen oxides or mixtures of nitrogen oxides and oxygen as fuel additives
EP0744413A3 (en) Preparation of polyalkenyl succinic acid derivatives and the use thereof as lubricating oil and fuel additives
NZ231761A (en) Addition of ferrocene to diesel fuel and its use in reducing particulate emissions from the engine
IL84954A0 (en) Dioxalanes and thio analogs,derivatives thereof and lubricants and fuels containing same
CA2294728A1 (en) Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels
AU4270589A (en) An ignition plug for use in internal combustion engines and an ignition process by the use thereof
AU1979899A (en) Use of polyalfaolefins (pao) derived from 1-dodecene or 1-tetradecene to improvethermal stability in engine oil in an internal combustion engine
AU3558689A (en) High pressure gasifier and diesel-cycle internal combustion engine system
WO1994021755A3 (en) Use of ferrocene
AU3247089A (en) Glow plug for internal combustion engine
IE41772L (en) Combustion engine fuels
UA32576C2 (en) Rotary type combustion engine
GB9016600D0 (en) Improvements in or relating to an internal combustion engine
AU5231996A (en) Fuel injected internal combustion engine with improved combustion
AU2194692A (en) Fuel oil treatment
AU7753987A (en) Injection device for introducing fuels in the combustion chamber of an internal combustion engine
AU689481B2 (en) Fuel for internal combustion engines and turbines
AU6435094A (en) Improvements relating to ignition leads used in conjunction with internal combustion engines
SU595529A1 (en) Internal combustion engine with compression ignition
IE802701L (en) A complex with an additive for fuels
AU7884287A (en) Improvements relating to fuel injection systems for internal combustion engines
ES2095797A1 (en) Combustible product
AU5106293A (en) Fuel additives for spark ignition engines and fuels containing them

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 94191475.5

Country of ref document: CN

AK Designated states

Kind code of ref document: A2

Designated state(s): AU BR CA CN FI JP KP KR NO NZ PL US

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

AK Designated states

Kind code of ref document: A3

Designated state(s): AU BR CA CN FI JP KP KR NO NZ PL US

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 263179

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: 2156747

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 1994911173

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 1995 525551

Country of ref document: US

Date of ref document: 19950919

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 954422

Country of ref document: FI

WWP Wipo information: published in national office

Ref document number: 1994911173

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1994911173

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 1997 837082

Country of ref document: US

Date of ref document: 19970414

Kind code of ref document: A