WO1994014728A1 - Corps ceramique fritte a ossature metallique - Google Patents

Corps ceramique fritte a ossature metallique Download PDF

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Publication number
WO1994014728A1
WO1994014728A1 PCT/JP1993/000185 JP9300185W WO9414728A1 WO 1994014728 A1 WO1994014728 A1 WO 1994014728A1 JP 9300185 W JP9300185 W JP 9300185W WO 9414728 A1 WO9414728 A1 WO 9414728A1
Authority
WO
WIPO (PCT)
Prior art keywords
sintered body
ceramic sintered
ceramic
metal
temperature
Prior art date
Application number
PCT/JP1993/000185
Other languages
English (en)
Japanese (ja)
Inventor
Hideo Ikami
Chisato Oota
Original Assignee
Yugengaisha Ado Seramikkusu Kenkyusho
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yugengaisha Ado Seramikkusu Kenkyusho filed Critical Yugengaisha Ado Seramikkusu Kenkyusho
Publication of WO1994014728A1 publication Critical patent/WO1994014728A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/71Ceramic products containing macroscopic reinforcing agents
    • C04B35/74Ceramic products containing macroscopic reinforcing agents containing shaped metallic materials
    • C04B35/76Fibres, filaments, whiskers, platelets, or the like

Definitions

  • a ceramic composition which is for example quartz general showed a greater expansion by transformation in the firing Atsushi Nobori process, if it exceeds 570 to 60 0 ° C the thermally expanded is 8 0 X 1 0 - becomes more than Te 7 Bruno , whereas, in the temperature below 600, RiNoboru thermally expanded by including the contraction of the clay component Ri dirt floor and the 5 0 ⁇ 6 0 X 1 0 7 Z ° C as low level, 1 000 ° C At the above sintering temperature, large sintering shrinkage of 5 to 10% is exhibited. Therefore, in the case of the conventional general ceramic composition, as shown in was example, if FIG.
  • a preferred ceramic composition for realizing a ceramic sintered body having a metal as a skeleton of the present invention is (CaO + Mg0 + A123) / Si02.
  • One or more molding aids composed of metal salts and hydraulic cements are contained in the raw material in an amount of 3 to 20% by weight of the raw material. Shown is a composition that is compounded and shrinks within 0.5% of shrinkage.
  • a metal salt such as sodium silicate or calcium silicate
  • the range of 3 to 10% by weight of the raw material is appropriate, and when it is 3% or less, sufficient molding strength is obtained. If it exceeds 10%, there is a problem in terms of economics. ⁇
  • hydraulic cements such as Portland cement and blast furnace cement are used, adjust in the range of 10 to 20% by weight.
  • the auxiliaries can be used alone or in admixture.
  • These metallic materials generally have a greater degree of thermal expansion than the above-mentioned composition, but in order to absorb this difference, an organic paste such as starch, polybutyl alcohol, or M.C. It is also effective to provide a coating of the material.
  • This organic glue material does not easily disappear when the oxygen content in the composition is low, and begins to carbonize at about 350 ° C. Even at 1200 ° C, the surface layer of the rebar as carbon is formed. To be retained. As long as this carbon remains, oxidation of the rebar does not proceed easily.When firing is completed, the incision is made and the state of the rebar surface is observed. Indicates a certain state.
  • the thickness of the organic glue layer may be 0.5% of the rebar diameter according to the results of the experiment, but considering the amount of residual carbon remaining on the surface layer and the absorption of stress due to the longitudinal expansion and contraction of the rebar, the diameter is It is desirable to set it to 1.0% or more. If the thickness of the coating film is required to be 0.05 mm or more, it is effective to mix charcoal powder and paper powder.
  • Starch and charcoal powder were mixed at a weight ratio of 1: 1. After adding 10 to 12 times the amount of water and heating to adjust the glue, it was applied to the rebar surface to a film thickness of about 0.2 mm and dried. .
  • a reinforcing bar (2) was buried almost at the center of the molded composition (1).
  • the crossing of the rebar (2) was loosely bound with a 1.0 mm diameter wire.
  • No. 1 and No. 2 were compacted at a pressure of 150 kg / cm 2 by the powder pressing method, and No. 3 was kneaded as a cement mortar by adding 30 to 50% of water. Then, it was subjected to vibration filling molding between the molds, and cured and cured in 60 steam atmospheres for 24 hours.
  • sintering shrinkage column of Table 2 indicates expansion and-indicates shrinkage.
  • the flexural strength shows the strength value at the time when a crack was found in the composition by observing the surface while applying a load to the center at a span of 200.
  • No. 1, No. 2 and No. 3 did not separate the rebar and the composition even under a load of 1000 kg / cm 2 .

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Manufacturing Of Tubular Articles Or Embedded Moulded Articles (AREA)

Abstract

Corps céramique fritté dans lequel un matériau métallique linéaire, en forme de baguette ou à mailles est entièrement noyé selon une disposition d'ossature prédéterminée. L'invention se rapporte à un corps céramique fritté dans lequel une ossature métallique comprenant des barres de renforcement ou autres est entièrement noyée, un tel noyage de l'ossature métallique étant considéré comme impossible à réaliser selon les techniques classiques. On obtient ainsi un matériau de construction d'une fiabilité supérieure du point de vue de la robustesse, la céramique présentant également une résistance supérieure par rapport aux conditions atmosphériques.
PCT/JP1993/000185 1992-12-28 1993-02-12 Corps ceramique fritte a ossature metallique WO1994014728A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP4/348009 1992-12-28
JP34800992A JP3202376B2 (ja) 1992-12-28 1992-12-28 金属を骨格とした陶磁器質焼結体

Publications (1)

Publication Number Publication Date
WO1994014728A1 true WO1994014728A1 (fr) 1994-07-07

Family

ID=18394125

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1993/000185 WO1994014728A1 (fr) 1992-12-28 1993-02-12 Corps ceramique fritte a ossature metallique

Country Status (3)

Country Link
JP (1) JP3202376B2 (fr)
CN (1) CN1088898A (fr)
WO (1) WO1994014728A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112723856A (zh) * 2020-12-25 2021-04-30 唐山北方瓷都陶瓷集团卫生陶瓷有限责任公司 一种低变形的陶瓷素坯及其制备工艺

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103474312B (zh) * 2013-09-09 2016-08-10 电子科技大学 一种行波管夹持杆及其制备方法
CN106045472B (zh) * 2016-05-27 2018-10-30 江西萍乡龙发实业股份有限公司 一种复合材料生态陶瓷透水砖的制备方法
CN106321626A (zh) * 2016-10-17 2017-01-11 北京动力机械研究所 一种作动器用耐高温关节轴承
CN106851871A (zh) * 2017-01-13 2017-06-13 杭州格拉思康科技有限公司 层状陶瓷电热元件
CN109574638A (zh) * 2018-12-29 2019-04-05 山东天汇研磨耐磨技术开发有限公司 一种应用了金属橡胶的高结合力陶瓷段及其制造方法
CN110614483B (zh) * 2019-10-22 2021-04-06 苏师大半导体材料与设备研究院(邳州)有限公司 一种陶瓷搅拌器的生产工艺
CN112142484A (zh) * 2020-09-18 2020-12-29 株洲三达电子制造有限公司 一种陶瓷传感器用陶瓷制备方法
CN116283322A (zh) * 2023-04-10 2023-06-23 广东丰鑫智能科技有限公司 一种大型结构陶瓷配方

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57111284A (en) * 1980-12-29 1982-07-10 Onoda Cement Co Ltd Reinforcing bar-containing refractory brick and manufacture
WO1990003339A1 (fr) * 1988-09-30 1990-04-05 Vesuvius France S.A. Recipient pour metaux en fusion, materiau pour ce recipient et procede de fabrication du materiau

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57111284A (en) * 1980-12-29 1982-07-10 Onoda Cement Co Ltd Reinforcing bar-containing refractory brick and manufacture
WO1990003339A1 (fr) * 1988-09-30 1990-04-05 Vesuvius France S.A. Recipient pour metaux en fusion, materiau pour ce recipient et procede de fabrication du materiau

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112723856A (zh) * 2020-12-25 2021-04-30 唐山北方瓷都陶瓷集团卫生陶瓷有限责任公司 一种低变形的陶瓷素坯及其制备工艺

Also Published As

Publication number Publication date
JPH06191957A (ja) 1994-07-12
CN1088898A (zh) 1994-07-06
JP3202376B2 (ja) 2001-08-27

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