WO1994012600A1 - Composition de nettoyage liquide multi-usage - Google Patents

Composition de nettoyage liquide multi-usage Download PDF

Info

Publication number
WO1994012600A1
WO1994012600A1 PCT/US1993/011294 US9311294W WO9412600A1 WO 1994012600 A1 WO1994012600 A1 WO 1994012600A1 US 9311294 W US9311294 W US 9311294W WO 9412600 A1 WO9412600 A1 WO 9412600A1
Authority
WO
WIPO (PCT)
Prior art keywords
nonionic surfactant
hlb
composition according
composition
weight
Prior art date
Application number
PCT/US1993/011294
Other languages
English (en)
Inventor
Stefano Scialla
Sergio Cardola
Dario Rapisarda
Marina Trani
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP6513291A priority Critical patent/JPH08503731A/ja
Priority to AU65156/94A priority patent/AU670374B2/en
Priority to NZ278814A priority patent/NZ278814A/en
Priority to US08/432,153 priority patent/US5536438A/en
Priority to EP94901627A priority patent/EP0670876A1/fr
Publication of WO1994012600A1 publication Critical patent/WO1994012600A1/fr
Priority to NO952057A priority patent/NO952057L/no
Priority to FI952539A priority patent/FI952539A0/fi

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to the field of detergent or cleaning compositions.
  • the compositions of the present invention are multi-purpose cleaning compositions which are suitable for use as hard-surface cleaners, carpet cleaners as well as in laundry applications.
  • cleaning compositions have been described in the art.
  • cleaning compositions can be divided into hard surface cleaning compositions and laundry cleaning compositions.
  • Cleaning compositions of these two types are traditionally very different in formulation and are sold as different products with different marketing concepts. These differences impose on the consumer to have to purchase and use at least two different products.
  • compositions of the two types above, especially hard surface cleaners can be divided into sub-types. Indeed, many different kinds of hard-surface cleaners are available, for instance bathroom cleaners, kitchen cleaners or floor cleaners
  • This vanety in formulation is rendered necessary by the difference in nature between the soils which can be found on laundry and on va ⁇ ous surfaces in kitchens, floors including carpets and bathroom.
  • kitchen soils comprise mainly edible oils
  • bathroom soils comprise mainly sebum and soap scum, also limescale
  • floor soils compnse mainly particulate soils and laundry may have many different soils and stains.
  • compositions according to the present invention should also be able to perform in a vanety of conditions, i.e. in hard and soft water. They should also provide satisfactory shine performance and surface safety when used as hard surface cleaners.
  • the present invention is an aqueous cleaning composition having a pH of from 0.5 to 6, said composition comprising from 2% to 40% by weight of the total composition of a nonionic surfactant system, whereby said nonionic surfactant system comprises:
  • At least one nonionic surfactant with an HLB of from 9 to 13 At least one nonionic surfactant with an HLB below 9
  • compositions according to the present invention are aqueous liquid cleaning compositions.
  • Said aqueous compositions have a pH as is of from 0.5 to 6, preferably 1 to 5, most preferably from 2 to 4.5.
  • the pH of the compositions can be adjusted by using organic or inorganic acids, or alkalinizing agents.
  • compositions according to the present invention further comprise a specific nonionic surfactant system comprising at least four nonionic surfactants.
  • Said nonionic surfactant system is efficient in cleaning a variety of different soils, and significant cooperation has been observed between the four different types of surfactants.
  • the nonionic surfactant system herein comprises a mixture of at least four different nonionic surfactants, each of which lies in a specified HLB (hydrophilic-lipophilic balance) range.
  • HLB hydrophilic-lipophilic balance
  • nonionic surfactant system according to the present invention comprises:
  • Suitable highly hydrophobic surfactants for use herein are Dobanol R 23-3, Lutensol R A03, Dobanol R 91-2.5 and Dobanol R 23-2.
  • compositions according to the present invention said nonionic surfactants belonging to the four classes described hereinabove act in synergy, particularly on kitchen dirt soils and bathtub soils. It is thus possible to use low total levels of said nonionic surfactant system.
  • the compositions according to the present invention comprise from 40% down to 2% by weight of the total composition of said nonionic surfactant system, preferably from 15% to 3%.
  • nonionic surfactant system wherein the weight ratio of highly hydrophilic surfactant to hydrophilic surfactant is at most 1 :1.5, and wherein the combined amount of said highly hydrophilic and hydrophilic surfactant in the total composition is at least 2% by weight, preferably at least 2.5%.
  • nonionic surfactant system wherein the weight ratio of highly hydrophobic to hydrophobic surfactant is from 1.5:1 to 2.5:1 , preferably 2:1 , and wherein the combined amount of said hydrophobic and highly hydrophobic nonionic surfactant in the total composition is at least 1.5% by weight.
  • compositions according to the present invention may further comprise additional nonionic surfactants, i.e. there can be more than one surfactant in each class hereinabove.
  • additional nonionic surfactants i.e. there can be more than one surfactant in each class hereinabove.
  • the compositions according to the present invention do not require the use of an anionic surfactant system. Accordingly, the compositions according to the present invention are preferably free of anionic surfactants.
  • compositions herein presents a good suds profile and therefore does not require the use of a suds suppressing ingredient. It has been found that, for an optimum suds profile, it is preferable to use a nonionic surfactant system according to the present invention wherein the weight ratio of the sum of the highly hydrophilic and hydrophilic surfactants to the highly hydrophobic surfactant is of 1.5:1 or more.
  • suds suppressing systems such as 2-alkyl alkanols, as described for instance in DE 40 21 265 and co-pending European patent application 92870174.7.
  • suitable compounds are commercially available, for instance in the ISOFOL ( ⁇ > series such as ISOFOL @ 12 (2-butyl octanol) and ISOFOL @ 16 (2-hexyl decanol).
  • Preferred 2-alkyl alkanols for use herein have an alkyl chain comprising from 6 to 16 cartoon atoms, preferably 8 to 12, and a terminal hydroxy group, said alkyl chain being substituted in the ⁇ position by an alkyl chain comprising from 1 to 10 carbon atoms, preferably 2 to 8, more preferably 3 to 6.
  • an alkyl chain comprising from 1 to 10 carbon atoms, preferably 2 to 8, more preferably 3 to 6.
  • the selected brighteners belong to the class of distyryl diphenyl brighteners, in particular 4-4'-bis [2-2' styryl sulfonate] biphenyl, commercially available from Ciba-Geigy under the trade name Tinopal CBS-X @.
  • the appropriate amount of brightener to be used depends on the particulars of the surfactant system and the 2-alkyl alkanol chosen, but can be determined by simple trial and error.
  • compositions herein preferably comprise from 2% to 15% by weight of the total composition of hydrogen peroxide or a source thereof.
  • the presence of hydrogen peroxide provides strong cleaning benefits which are particularly noticeable in laundry applications.
  • the nonionic surfactant system for use in the compositions according to the present invention is remarkably compatible with hydrogen peroxide in that good hydrogen peroxide storage stability was observed, even in the absence of hydrogen peroxide stabilizers.
  • ingredients which are typically sensitive to hydrogen peroxide such as dyes or brighteners, appear to be stable upon storage in the compositions according to the present invention without having to add stabilizers for that purpose.
  • the compositions according to the present invention may further comprise a variety of optional ingredients such as builders, solvents, perfumes and dyes.
  • compositions according to the present invention can be used as a household cleaner in the bathroom or in the kitchen, and can also be used as a laundry detergent or as a laundry detergent booster.
  • the compositions according to the present invention are easy to rinse and provide good shine characteristics on the cleaned surfaces.
  • the compositions according to the present invention, especially when formulated with hydrogen peroxide, are also particularly effective as carpet cleaners. If used as carpet cleaners, the compositions according to the present invention are advantageously dispensed with a spray dispenser and left to act on said carpets.
  • compositions were made by mixing the listed ingredients in the listed proportions (weight % unless otherwise specified).
  • the compositions in the examples were tested and proved satisfactory on cleaning laundry, kitchen dirt soils as well as bathtub soils. Furthermore, the stability of hydrogen peroxide, brightener and dye was monitored and proved satisfactory at 50°c for two weeks.
  • compositions were clear products with more than 90% transmittance at 600nm at room temperature.
  • (1) is a distyryl diphenyl brightener commercially available from Ciba-Geigy.
  • (2) is a dye commercially available from Hoechst.

Abstract

L'invention concerne des compositions de nettoyage liquides multi-usage légèrement acides contenant un système spécifique d'agents tensioactifs non ioniques. Ledit système d'agents tensioactifs non ioniques contient au moins quatre agents tensioactifs non ioniques appartenant à quatre classes de rapport hydro-lipophile. Les compositions selon l'invention peuvent être utilisées en tant que détergents lessiviels ou produits de nettoyage de surfaces dures pour cuisines, salles de bains, sols et moquettes.
PCT/US1993/011294 1992-11-26 1993-11-19 Composition de nettoyage liquide multi-usage WO1994012600A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP6513291A JPH08503731A (ja) 1992-11-26 1993-11-19 多目的液状クリーニング組成物
AU65156/94A AU670374B2 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition
NZ278814A NZ278814A (en) 1992-11-26 1993-11-19 Liquid cleaning composition; comprises a non-ionic surfactant system with at least four non-ionic surfactants belonging to four hlb classes
US08/432,153 US5536438A (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition comprising nonionic surfactants of different HLB values
EP94901627A EP0670876A1 (fr) 1992-11-26 1993-11-19 Composition de nettoyage liquide multi-usage
NO952057A NO952057L (no) 1992-11-26 1995-05-24 Fleranvendelig flytende rengjöringsmiddelblanding
FI952539A FI952539A0 (fi) 1992-11-26 1995-05-24 Monikäyttöinen nestemäinen puhdistuskoostumus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP92870191A EP0598973A1 (fr) 1992-11-26 1992-11-26 Composition de nettoyage liquide pour tous usages
EP92870191.1 1992-11-26

Publications (1)

Publication Number Publication Date
WO1994012600A1 true WO1994012600A1 (fr) 1994-06-09

Family

ID=8212287

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/011294 WO1994012600A1 (fr) 1992-11-26 1993-11-19 Composition de nettoyage liquide multi-usage

Country Status (9)

Country Link
EP (2) EP0598973A1 (fr)
JP (1) JPH08503731A (fr)
AU (1) AU670374B2 (fr)
CA (1) CA2148810C (fr)
FI (1) FI952539A0 (fr)
NO (1) NO952057L (fr)
NZ (1) NZ278814A (fr)
RU (1) RU95113462A (fr)
WO (1) WO1994012600A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0686691A1 (fr) * 1994-06-10 1995-12-13 The Procter & Gamble Company Emulsions aqueuses avec des agents de blanchiment
EP0687726A1 (fr) * 1994-06-17 1995-12-20 The Procter & Gamble Company Compositions de blanchiment
US5501816A (en) * 1994-07-12 1996-03-26 Basf Corporation Aqueous based solvent free degreaser composition
WO2000029542A1 (fr) * 1998-11-13 2000-05-25 Colgate-Palmolive Company Compositions de cristaux liquides contenant un 2-alkyl alcanol et un abrasif
US6620774B1 (en) 1999-01-26 2003-09-16 The Procter & Gamble Company Bleaching composition comprising substantially linear nonionic surfactants
EP2963101A1 (fr) * 2014-07-04 2016-01-06 Kolb Distribution Ltd. Agents de nettoyage pour surfaces dures

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0666308B1 (fr) * 1994-02-03 2000-08-09 The Procter & Gamble Company Compositions nettoyantes liquides pour tous usages
US5902354A (en) * 1994-04-12 1999-05-11 The Procter & Gamble Company Bleaching compositions
US5634979A (en) * 1994-12-22 1997-06-03 Henkel Corporation Composition and method for degreasing metal surfaces
DE19523117A1 (de) * 1995-06-26 1997-01-02 Henkel Ecolab Gmbh & Co Ohg Wäßriges saures Reinigungsmittel
US5767055A (en) * 1996-02-23 1998-06-16 The Clorox Company Apparatus for surface cleaning
DE19750455C1 (de) * 1997-11-14 1999-04-29 Henkel Kgaa Verwendung von peroxidhaltigen Zubereitungen
GB0004769D0 (en) * 2000-03-01 2000-04-19 Reckitt & Colmann Prod Ltd Improvements in or relating to organic compositions
EP1149945A1 (fr) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Composition pour le prétraitement de matériaux fibreux
DE102005034752A1 (de) * 2005-07-21 2007-01-25 Henkel Kgaa Reinigungs- und Pflegemittel mit verbesserter Emulgierfähigkeit
JP5567255B2 (ja) * 2008-06-04 2014-08-06 花王株式会社 衣料用液体漂白剤組成物
JP5463026B2 (ja) * 2008-12-11 2014-04-09 花王株式会社 抗菌剤組成物
US8933131B2 (en) 2010-01-12 2015-01-13 The Procter & Gamble Company Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
JP5815750B2 (ja) 2011-02-17 2015-11-17 ザ プロクター アンド ギャンブルカンパニー Ｃ１０〜ｃ１３アルキルフェニルスルホネートの混合物を含む組成物
EP2675784B1 (fr) 2011-02-17 2017-09-13 The Procter and Gamble Company Sulfonates d'alkylphényle linéaires d'origine biologique
WO2014095793A1 (fr) * 2012-12-19 2014-06-26 Akzo Nobel Chemicals International B.V. Utilisation d'un alcool éthoxylé en tant qu'hydrotrope pour un adduit d'oxyde d'alkylène d'un alcool
DE102016117674A1 (de) 2016-09-20 2018-03-22 Bundesdruckerei Gmbh Verfahren zur Herstellung eines Sicherheits- oder Wertprodukts mit einem diffraktiven Sicherheitselement
WO2020229160A1 (fr) 2019-05-16 2020-11-19 Unilever Plc Composition de blanchisserie

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US5154850A (en) * 1989-07-18 1992-10-13 Kao Corporation Neutral liquid detergent composition

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DK132960A (fr) * 1970-03-31
GB2011944B (en) * 1978-01-09 1982-06-09 Unilever Ltd Liquid detergent composition
US4764302A (en) * 1986-10-21 1988-08-16 The Clorox Company Thickening system for incorporating fluorescent whitening agents
DE3818062A1 (de) * 1988-05-27 1989-12-07 Henkel Kgaa Schaumdrueckende alkylpolyglykolether fuer reinigungsmittel (i)
US5008030A (en) * 1989-01-17 1991-04-16 Colgate-Palmolive Co. Acidic disinfectant all-purpose liquid cleaning composition
DE3928600A1 (de) * 1989-08-30 1991-03-07 Henkel Kgaa Schaumdaempfende mehrstoffgemische mit tensidcharakter fuer die maschinelle geschirr- und flaschenreinigung
DE4028138A1 (de) * 1990-09-05 1992-03-12 Huels Chemische Werke Ag Viskose saeurehaltige reinigungsmittel
TW291496B (fr) * 1991-02-01 1996-11-21 Hoechst Ag
DE69224389T2 (de) * 1992-11-16 1998-08-13 Procter & Gamble Reinigungs- und Bleichmittelzusammensetzungen
DE69321562T3 (de) * 1992-11-26 2002-04-18 Procter & Gamble Reinigungsmittelzusammensetzungen mit einer Kombination aus stark hydrophilen und stark hydrophoben nichtionischen Tensiden

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Publication number Priority date Publication date Assignee Title
US5154850A (en) * 1989-07-18 1992-10-13 Kao Corporation Neutral liquid detergent composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0670876A4 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0686691A1 (fr) * 1994-06-10 1995-12-13 The Procter & Gamble Company Emulsions aqueuses avec des agents de blanchiment
EP0687726A1 (fr) * 1994-06-17 1995-12-20 The Procter & Gamble Company Compositions de blanchiment
US5501816A (en) * 1994-07-12 1996-03-26 Basf Corporation Aqueous based solvent free degreaser composition
WO2000029542A1 (fr) * 1998-11-13 2000-05-25 Colgate-Palmolive Company Compositions de cristaux liquides contenant un 2-alkyl alcanol et un abrasif
US6620774B1 (en) 1999-01-26 2003-09-16 The Procter & Gamble Company Bleaching composition comprising substantially linear nonionic surfactants
EP2963101A1 (fr) * 2014-07-04 2016-01-06 Kolb Distribution Ltd. Agents de nettoyage pour surfaces dures
EP2963100A1 (fr) * 2014-07-04 2016-01-06 Kolb Distribution Ltd. Compositions aqueuses de rinçage

Also Published As

Publication number Publication date
CA2148810A1 (fr) 1994-06-09
NZ278814A (en) 1998-05-27
NO952057D0 (no) 1995-05-24
RU95113462A (ru) 1997-03-20
EP0598973A1 (fr) 1994-06-01
JPH08503731A (ja) 1996-04-23
EP0670876A4 (fr) 1995-06-02
EP0670876A1 (fr) 1995-09-13
NO952057L (no) 1995-05-24
CA2148810C (fr) 1999-01-19
AU6515694A (en) 1994-06-22
FI952539A (fi) 1995-05-24
AU670374B2 (en) 1996-07-11
FI952539A0 (fi) 1995-05-24

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