WO1994006403A1 - Shampoing capillaire traitant - Google Patents

Shampoing capillaire traitant Download PDF

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Publication number
WO1994006403A1
WO1994006403A1 PCT/US1993/008823 US9308823W WO9406403A1 WO 1994006403 A1 WO1994006403 A1 WO 1994006403A1 US 9308823 W US9308823 W US 9308823W WO 9406403 A1 WO9406403 A1 WO 9406403A1
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WO
WIPO (PCT)
Prior art keywords
hair conditioning
conditioning shampoo
shampoo according
weight
dispersing agent
Prior art date
Application number
PCT/US1993/008823
Other languages
English (en)
Inventor
Charles Reich
Wei-Ming Cheng
Clarence R. Robbins
Amrit Patel
Original Assignee
Colgate-Palmolive Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate-Palmolive Company filed Critical Colgate-Palmolive Company
Priority to AU49285/93A priority Critical patent/AU674340B2/en
Priority to EP93921663A priority patent/EP0661962A1/fr
Publication of WO1994006403A1 publication Critical patent/WO1994006403A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Definitions

  • the present invention relates to hair conditioning shampoo compositions which are useful to clean human hair while simultaneously conditioning it to render it more easily manageable (combable and relatively low static charge) after shampooing than if it had been washed with a conventional shampoo.
  • Hair conditioning shampoos are well known in the cosmetic art and are described in various patents and literature references. Considerable past research underlies efforts to discover new and better conditioning agents for incorporation into hair shampoos to provide so-called "two-in-one" formulations which cleanse the hair as well as provide a hair conditioning effect. These efforts have proved problematic since the combination of hair conditioning agents with the conventional ingredients found in shampoos often results in unstable compositions. The properties of hair conditioning agents and the other ingredients in typical shampoo formulations tend to be mutually antagonistic, rendering the simultaneous washing and conditioning of the hair difficult to achieve. Indeed, the hair- cleansing and hair conditioning properties of these "two-in-one" compositions are usually very inferior to those produced by the utilization of separate shampoo and conditioning formulations.
  • conditioning agents currently employed in shampoo compositions are silicones and other water-insoluble conditioning agents such as oils, waxes and various polymers.
  • cationic hair conditioning agents such as cationic quaternary synthetic and cellulose polymers, cationic polysaccharides, etc. It has been suggested, for example, to employ certain copolymers of acrylamide (or derivatives thereof) and dialkyl diallyl ammonium salts or terpolymers of acrylamide, acrylic acid and dialkyl diallyl ammonium salts as hair conditioning agents in shampoos.
  • Exemplary of such teachings are U.S. Patent Nos. 4,832,872, 4,477,375 and 4,240,450.
  • U.S. Patent Nos. 3,912,808, 3,986,825 and 4,027,008 disclose the use of these and similar polymers to modify the surface characteristics of hair in hair waving and straightening compositions, hair coloring compositions and hair bleaching compositions, respectively.
  • a vinyl-type cationic polymer including a copolymer of acrylamide or a derivative thereof and at least 50% of a dialkyl (C1-C5) diallyl ammonium salt monomer; or a terpolymer of acrylamide, acrylic acid and at least 30% of a dialkyl (C1 -C5) diallyl ammonium salt monomer; or a copolymer of at least 30% vinyl imidazolium methochloride and vinyl pyrrolidone or mixtures thereof having a hair conditioning effect and a charge density ranging between 150 and 400;
  • A-DADAA copolymers such as those copolymers of acrylamide or its derivatives and certain dialkyl diallyl ammonium salts (hereinafter "A-DADAA copolymers") or terpolymers of acrylamide, acrylic acid and dialkyl diallyl ammonium salts (hereinafter "A A-DADAA terpolymers”) or copolymers of vinyl imidazolium methochloride and vinyl pyrrolidone, or combinations of these polymers, when incorporated in shampoos with dispersed water-insoluble hair conditioning agents, provide enhanced hair conditioning benefits significantly greater than that provided by other commonly employed "two-in-one" compositions.
  • the charge density of a cationic polymer is given by the formula:
  • the "Charge Density" of a cationic polymer is a numerical value representing the number of positive charges in a particular cationic polymer.
  • the charge density as measured by the above ratio, is inversely proportional to the number of positive charges relative to the cation molecular weight, the greater the number of positive charges and hence the greater the charge density, the lower the numerical value of the above ratio.
  • a cationic polymer whose charge density as given by the above ratio is 150 will have a "greater” charge density (i.e., greater number of positive charges per unit of cation molecular weight) than a polymer having a measured "charge density” of 200.
  • “mid charge density” is meant a charge density greater than 200 and less than 400, and by “high charge density” is meant a charge density ranging between 150 and 200.
  • any vinyl-type cationic polymer having a hair conditioning effect which can be crafted having a charge density ranging between 150 and 400 may be employed in the practice of the invention.
  • exemplary of such cationic polymers are dimethyldiallyl ammonium chloride/acrylamide copolymer containing at least 50% dimethyldiallyl ammonium chloride monomer (Merquat 28 ⁇ TM 5 which has a charge density of 179.5, and Calgon Corp.'s Merquat 55 ⁇ T s which has a charge density of 232.5); dimethyldiallyl ammonium chloride/acrylic acid/acryamide terpolymers containing at least 30% dimethyldiallyl ammonium chloride monomer (Calgon Corp.'s Merquat 333 ⁇ T 5 which has a charge density of 304.5); and vinylimidazolium methochloride/vinyl pyrrolidone copolymers containing at least 30% vinylimidazolium (BASF's Luviquat HM552
  • the preferred cationic polymers are Merquat 550 and Luviquat HM 552.
  • the dispersing agent and the water-insoluble hair conditioning agent combine to lend stability to the final emulsion or suspension product, as well as lessen the effects of the mutual antagonism between the anionic and cationic components of the composition.
  • the result is a stable "two-in-one" hair conditioning shampoo, wherein the normally incompatible hair cleansing component and conditioning agents can function free of interference from each other to achieve their full effect.
  • vinyl-type copolymers such as Merquat 550
  • other common cationic polymeric hair conditioning agents such as the cationic cellulosic polymers of the Polymer JR type
  • the vinyl-type cationic polymers disclosed herein may be incorporated in the aqueous shampoo system in amounts ranging from about 0.01 to about 5% by weight, it is preferred to utilize an amount of such polymers in the range of from about 0.1 to about 2% by weight.
  • Any anionic surfactant commonly employed in shampoos may be utilized in the practice of the invention.
  • Suitable anionic detergents include those described in McCutcheon's Detergents and Emulsifiers. North American ed., published in 1984. Exemplary of these anionic detergents are alkyl sulfates, alkyl ether sulfates, ethoxylated and propoxylated alkyl ether sulfates containing 1 to 10 ethylene oxide or propylene oxide units per molecule and mixtures thereof wherein said alkyl groups contain 8 to 18 carbon atoms and may be unsaturated, e.g., alkyl ether sulfonates, alpha-olefin sulfonates, alkyl aryl sulfonates or combinations thereof.
  • the amount of surfactant incorporated in the shampoo may vary from about 5 to about 40% by weight, it is preferred to employ from about 5 to about 30% by weight thereof.
  • any of the well known water-insoluble hair conditioning agents conventionally employed in aqueous shampoos may be used in conjunction with the vinyl-type cationic polymers described above in the practice of the invention.
  • suitable water- insoluble conditioning agents are silicones, aminosilicones, polyalkylenes and oxidized derivatives thereof, paraffins, petrolatums, microcrystalline waxes, CI 8-C36 (mixed) fatty acids and mixed triglycerides thereof and stearyl stearates (and other higher esters), as well as mixtures thereof.
  • organosilicon compounds and the silicones that may be employed in the practice of the present invention include any of those which are hair conditioning agents intended for use in conditioning shampoos, various of which have been described in the patents mentioned hereinabove. They are preferably of non-volatile types. It has been found that the polyalkyl and/or polyaryl siloxanes are effective, with polydimethyl siloxane (CTFA designation: "dimethicone") being especially preferred. Aminosilicones are also effective conditioning agents in the compositions of this invention, and are even more effective than are conventional silicones and, with respect to these aminosilicones, the present special types described herein are better yet. Thus, it is much preferred to utilize an aminosilicone of the formula:
  • R 1 , R 2 , R 3 , R 5 , R 6 and R 7 are alkyls of 1 to 6 carbon atoms, and most preferably of 1 carbon atom each.
  • R4 is -R8-NH-CH2CH2- NH2
  • ⁇ is alkylene of 3 to 6 carbon atoms and most preferably is an isobutyl group
  • y is an average number in the range of 1 to 10, more preferably less than 5 and most preferably 1 , which is of an amine equivalent in the range of 4,000 to 60,000.
  • x is in the range of 200 or 300 to 10,000, more preferably 500 to 10,000 and most preferably 750 to 800 or 850, e.g., about 800, and y is in the range of 1 to 10, more preferably being less than 5 and most preferably being about 1.
  • the amine equivalent of such aminosilicone is preferably in the range of 5,000 to 50,000, and more preferably 10,000 to 40,000.
  • the molar percentage of amine is about 0.125
  • the degree of polymerization is about 800
  • x is 797
  • y is one and the molecular weight is about 60,000 daltons. Because molecular weights of high polymers sometimes vary, depending on the measurement technique utilized, it is suggested that primary reference should be to the formula for identification of the aminosilicones described, rather than placing primary reli ⁇ ance on the molecular weights provided.
  • the polyalkylenes that may be employed in the present invention as water-insoluble conditioning agents are preferably those of a molecular weight in the range of 1,000 to 5,000, more preferably 1,000 to 4,000 and most preferably 2,000 to 2,500, e.g., about 2,000. Oxidized versions of these polyalkylene polymers may also be used which create larger hydrocarbons with terminal carboxyl groups.
  • the alkylenes of these polymers will usually be ethylene, it is within the scope of the present invention to employ polymers of hydrocarbons of 2 to 5 carbon atoms each, and preferably 2 to 3 carbon atoms, in which the molecular weight range may be from 1,000 to 10,000 or even more under some conditions.
  • the polymers will be of ethylene and/or propylene, and almost always of ethylene.
  • Paraffins that may be utilized will normally be of chain lengths of 20 to 50 carbon atoms, and preferably 20 to 40 carbon atoms, and isoparaffins can be of chain lengths in the range of 12 to 16 carbon atoms, and preferably 13 to 14 carbon atoms.
  • the petrolatums are petroleum jellies or mineral jellies which melt in the range of 38°C to 60°C and the microcrystalline waxes are of an average molecular weight in the range of about 500 to 800 (which is about twice that of the paraffins).
  • Ci ⁇ -36 fatty acid triglycerides are higher triglycerides which are available from Croda Chemical Corporation under the tradename Syncrowax HGL-C.
  • the CTFA designation for this material is C18-36 Acid Triglyceride.
  • Stearyl stearate which is representative of useful esters of both higher fatty alcohols and higher fatty acids, is available from Inolex Corporation as Lexol SS. This and related compounds such as other high fatty esters may also act as stabilizers for the shampoo composition, pre- venting settling out of components and phase separations.
  • water-insoluble conditioning agents can be incorporated in the shampoos of the invention in amounts ranging from about 0.1 to about 10% by weight, it is preferred to utilize from about 0.1 to about 5% by weight thereof.
  • Suitable dispersing agents include long chain saturated primary aliphatic alcohols or derivatives thereof. Additionally useful dispersing agents include long chain acyl derivatives, long chain alkyl dimethyl amine oxides, cross-linked anionic synthetic polymers, polysaccharides or quaternized derivatives thereof. Suitable long chain primary aliphatic alcohols which may constitute the dispersing agent in the shampoo of the invention are saturated compounds with the hydroxy group being terminally located.
  • Such alcohols will normally be of a distribution of homologous alcohols and typically all are of even numbers of carbon atoms, averaging 24 to 45 carbon atoms (on a weight basis), preferably 28 to 42 carbon atoms, and more preferably about 30 to 40 carbon atoms.
  • the average number of carbon atoms in the chain is less than 24, the desired effectiveness of such alcohols in the present formulations is decreased, with the stabilization, fiber conditioning and pearlescing actions being diminished.
  • chain length is more than 45 carbon atoms, e.g., of an average of about 50 carbon atoms, such alcohols are not satisfactorily disper- sible in the described compositions.
  • alkoxylated alcohols are preferred, and the most preferred of these are the ethoxylated alcohols which will normally contain up to about 20 ethoxy groups per mole, e.g., about 10 to 20.
  • the alcohols which are the preferred embodiments of the invention normally will be employed alone or in mixture with related compounds from the "derivatives" group, with the alcohol being the major proportion of the total "alcohol plus derivatives" content.
  • Examples of commercial materials which may be employed in the present compositions are those manufactured by Petrolite Corporation and sold through their Petrolite Specialty Polymers Group under the name UnilinT Alcohols as described in the technical bulletin of the Petrolite Corporation entitled UnilinT M Alcohols copyrighted in 1985 and identified as SP-1040.
  • Such alcohols may be 75 to 90%, e.g., 80 to 85%, of the commercial product, with the balance of such products being substantially all saturated hydrocarbons of corresponding chain lengths.
  • the distribution curve for the alcohol is substantially bell-shaped, with no chain length of alcohol being more than 10% of the total content thereof and with the corresponding hydrocarbon content being of a substantially flat distribution curve, with about 1 or 2% of each of the hydrocarbons being present.
  • Such distribution curves, as bar graphs, are provided in the Petrolite bulletin mentioned above.
  • the alcohols as bar graphs, are provided in the Petrolite bulletin mentioned above.
  • 550 is an ethoxylated such alcohol having an average of 40 carbon atoms in the alkyl chain, ethoxylated with up to 20 ethoxy groups, e.g., 13.
  • Suitable long chain acyl derivatives useful as dispersing agents in the shampoos of the invention include those described in
  • U.S. Patent No. 4,741,855 the entire content of which is incorporated herein by reference, e.g., ethylene glycol esters of fatty acids having from about 16 to about 22 carbon atoms.
  • Other acyl derivatives which are useful are alkanolamides of fatty acids having from about 16 to about 22 carbon atoms, preferably about 16 to 18 carbon atoms, e.g., stearic monoethanolamide, stearic diethanolamide, stearic monoisopropanolamide, stearic monoethanolamide stearate, etc.
  • long chain esters of long chain fatty acids such as stearyl stearate, cetyl palmitate, etc.
  • glyceryl esters e.g., glyceryl distearate
  • long chain esters of long chain alkanolamides e.g., stearamide DEA distearate, stearamide MEA stearate, etc.
  • dispersing agents include the alkyl (Cl 6- C22) dimethyl amine oxides, e.g., stearyl dimethyl amine oxide.
  • Cross-linked anionic synthetic polymers may also be used as dispersing agents in the practice of the invention.
  • Exemplary of such polymers are polymers of acrylic or methacrylic acid or their derivatives or copolymers with other olefinic comonomers or olefinic compounds with a lipophilic side group or polymers of vinyl sulfonic acid or derivatives or copolymers thereof with other conventional monomers compatible with the objects of the present invention, i.e., polyvinyl sulfate or polystyrene sulfonate.
  • Useful dispersing agents also include polysaccharides as well as quaternized derivatives thereof, e.g., hydroxyethylcellulose or methylcellulose, guar gum, xanthan gum or quaternary derivatives of the above such as Polymer JR or cationic guar gum.
  • suitable dispersing agents are the alkyl dimethyl amine oxides, the alkyl group having from about 8 to about 18 carbon atoms. Additional suitable dispersing agents are those described in U.S. Patent No. 4,997,641 and U.S. patent application Serial No.
  • the shampoos herein may also contain a variety of non- essential optional components or adjuvants suitable for rendering such compositions more acceptable to the consumer.
  • These conventional adjuvants are well known to those skilled in the art and include those set forth in the Hartnett Patent No. 4,997,641.
  • the present shampoo no complex procedures have to be followed, but to obtain best stability, viscosity and appearance, and greatest conditioning activity, it will be desirable to form a dispersion of the water-soluble anionic detergent(s) and adjuvants in water at an elevated temperature such as 70°C to 95°C, melt together and/or dissolve lipophilic materials such as quaternary ammonium salt, hydrocarbons including polyethylene, mineral oil, microcrystalline wax, petrolatum, paraffin and isoparaffin, long chain alcohol and/or "derivative," Ci ⁇ -36 fatty acids and/or triglyceride and higher fatty ester, e.g., stearyl stearate, to produce a melt or liquid mix at elevated temperature and admix the two mixes at such elevated temperature, after which heated silicone and/or aminosilicone may be admixed with the resulting mix (it may sometimes also be included with the lipophiles), with the various mixings taking place with the parts to be mixed being at approximately the same temperature.
  • an elevated temperature
  • the silicone or aminosilicone it is sometimes desirable for the silicone or aminosilicone to be mixed in after the main pre- mixing to promote better stability of the product.
  • adjuvants those which are water-soluble and/or dispersible may be mixed in with the aqueous phase materials and those which are not water-soluble or dispersible in the aqueous medium may be blended in with the lipophilic materials such as the hydrocarbons, or in some instances may be added to the mixture of the hydrophilic and lipophilic materials either before or after cooling to room temperature.
  • perfume will be added to the other mixed components after cooling to room temperature, but the silicone and/or aminosilicone will usually be added at elevated temperature and before such cooling.
  • the perfume is added to the cooled composition to avoid losses thereof due to volatilizations of components and to prevent any degradation due to heating it.
  • the procedure described is not followed, as when the various components of the compositions are blended indiscriminately, less stable products can result which can separate on storage.
  • Virgin or bleached European hair was made into 3.5 g tresses and washed with 20% sodium lauryl sulfate solution. Each tress was treated with the desired conditioning shampoo for one minute, then rinsed one minute under running tap water set at 105°F. Three replicates were employed in the test for each shampoo. Panelists were asked to rank the wet tresses in terms of ease of combing and then to assign a rating for each tress on a scale of one to ten, with ten being the easiest to comb. The results were analyzed using the Friedman test for ranking data and Fisher's PLSD method for rating differences at 95% confidence levels.

Abstract

Le shampoing capillaire traitant selon l'invention se présente sous forme d'émulsion stable ou de suspension et se compose de: (i) 5 à 40 % en poids d'un polymère cationique de type vinylique contenant un copolymère d'acrylamide ou un dérivé de celui-ci et un sel d'ammonium de dialkyl (C1-C5)diallyle; ou un terpolymère d'acrylamide, de l'acide acrylique ou un sel d'ammonium de dialkyl (C1-C5)diallyle; ou un copolymère de méthochlorure de vinylimidazolium et de pyrrolidone vinylique ou des mélanges de ceux-ci ayant un effet traitant et présentant une densité de charge comprise entre 150 et 400; (iii) 0,1 à 10 % en poids d'au moins un agent de traitement capillaire dispersé, insoluble dans l'eau; (iv) 0,5 à 10 % en poids d'au moins un agent dispersant servant à stabiliser l'émulsion; et (v) de l'eau.
PCT/US1993/008823 1992-09-22 1993-09-22 Shampoing capillaire traitant WO1994006403A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU49285/93A AU674340B2 (en) 1992-09-22 1993-09-22 Hair conditioning shampoo
EP93921663A EP0661962A1 (fr) 1992-09-22 1993-09-22 Shampoing capillaire traitant

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US94851792A 1992-09-22 1992-09-22
US07/948,517 1992-09-22
US11841293A 1993-09-13 1993-09-13
US08/118,412 1993-09-13

Publications (1)

Publication Number Publication Date
WO1994006403A1 true WO1994006403A1 (fr) 1994-03-31

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Application Number Title Priority Date Filing Date
PCT/US1993/008823 WO1994006403A1 (fr) 1992-09-22 1993-09-22 Shampoing capillaire traitant

Country Status (5)

Country Link
EP (1) EP0661962A1 (fr)
CN (1) CN1087513A (fr)
AU (1) AU674340B2 (fr)
MX (1) MX9305744A (fr)
WO (1) WO1994006403A1 (fr)

Cited By (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995034271A1 (fr) * 1994-06-15 1995-12-21 Wella Aktiengesellschaft Shampooing capillaire conferant une bonne tenue a la chevelure
EP0715843A1 (fr) * 1994-12-07 1996-06-12 Basf Aktiengesellschaft Copolymères quaternisés comme agents dans des compositions cosmétiques pour la mise en forme des cheveux
WO1996032919A1 (fr) * 1995-04-21 1996-10-24 The Procter & Gamble Company Shampooings comportant un agent d'apres-shampooing de silicone insoluble et un polymere cationique
FR2761597A1 (fr) * 1997-04-07 1998-10-09 Oreal Compositions cosmetiques detergentes et utilisation
FR2761598A1 (fr) * 1997-04-07 1998-10-09 Oreal Compositions cosmetiques detergentes et utilisation
WO1998044897A1 (fr) * 1997-04-07 1998-10-15 L'oreal Compositions cosmetiques contenant un polymere cationique de faible masse moleculaire et une silicone et leurs utilisations
WO1998050007A1 (fr) * 1997-05-05 1998-11-12 The Procter & Gamble Company Compositions de shampooing donnant du corps aux cheveux et contenant des polymeres de coiffage cationique
FR2768616A1 (fr) * 1997-09-25 1999-03-26 Oreal Compositions cosmetiques detergentes et utilisation
EP0974335A1 (fr) * 1998-07-23 2000-01-26 L'oreal Compositions cosmétiques détergentes et utilisation
US6040282A (en) * 1998-02-03 2000-03-21 The Procter & Gamble Company Styling shampoo compositions which deliver improved hair curl retention and hair feel
US6177390B1 (en) 1998-02-03 2001-01-23 The Procter & Gamble Company Styling shampoo compositions which deliver improved hair curl retention and hair feel
FR2798853A1 (fr) * 1999-09-29 2001-03-30 Oreal Composition de lavage des matieres keratiniques, a base d'un agent tensio-actif detergent, d'un polymere cationique de vinyllactame et d'un terpolymere acrylique
FR2798849A1 (fr) * 1999-09-29 2001-03-30 Oreal Composition de lavage des matieres keratiniques, a base d'un agent tensio actif detergent, d'un homopolymere de dialkyl diallyl ammonium et d'un terpolymere acrylique
FR2798846A1 (fr) * 1999-09-29 2001-03-30 Oreal Composition de lavage des matieres keratiniques, a base d'un agent tensio-actif detergent, d'un polyorganosiloxane, d'un polymere cationique et d'un terpolymere acrylique
US6248317B1 (en) 1996-10-25 2001-06-19 The Procter & Gamble Company Styling shampoo compositions with improved styling polymer deposition
US6355231B1 (en) 1997-10-16 2002-03-12 Basf Aktiengesellschaft Use of cationic copolymers of unsaturated acids and N-vinylimidazolium salts in cosmetic hair formulations
US6383996B1 (en) * 1999-09-29 2002-05-07 L'oreal Antidandruff composition for treating the hair and the scalp, based on an antidandruff agent and an acrylic terpolymer
US6383993B1 (en) * 1999-09-29 2002-05-07 L'oreal Composition for washing keratin materials, based on a detergent surfactant, a cationic galactomannan gum and an acrylic terpolymer
US6383994B1 (en) * 1999-09-29 2002-05-07 L'oreal Composition for washing keratin materials, based on detergent surfactant, an functionalized silicone and an acrylic terpolymer
US6432894B1 (en) * 1999-09-29 2002-08-13 L'oreal Composition for washing keratin materials, based on a detergent surfactant, a polyorganosiloxane and an acrylic terpolymer
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EP0661962A1 (fr) 1995-07-12
AU674340B2 (en) 1996-12-19
AU4928593A (en) 1994-04-12
MX9305744A (es) 1994-05-31
CN1087513A (zh) 1994-06-08

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