WO1994004241A3 - Polymerized polysiloxane membrane for oxygen sensing device - Google Patents
Polymerized polysiloxane membrane for oxygen sensing device Download PDFInfo
- Publication number
- WO1994004241A3 WO1994004241A3 PCT/US1993/006983 US9306983W WO9404241A3 WO 1994004241 A3 WO1994004241 A3 WO 1994004241A3 US 9306983 W US9306983 W US 9306983W WO 9404241 A3 WO9404241 A3 WO 9404241A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- membrane
- oxygen
- sensing device
- permselective
- deposited
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/40—Semi-permeable membranes or partitions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
A single layer membrane (18) comprising a siloxane monomer and which is permselective for oxygen is described. The siloxane monomer is polymerized directly onto a non-porous support material (20) by glow discharge polymerization to form a membrane thereon. The resulting membrane has an oxygen content of between about 10 % and 60 % and is highly permselective for oxygen. The membrane can be deposited upon electrochemical or optical sensors, thereby forming an oxygen sensing device that is resistant to fouling, contamination and interferences. Such a membrane deposited upon a sensor exhibits high conformity and adhesion to the sensor, as well as excellent uniformity, freedom from defects, and durability. An electrochemical sensing device comprising a working electrode (12), a counter electrode (14), and a reference or auxiliary electrode (16), which are contiguous with the permselective membrane, is also described.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU49935/93A AU4993593A (en) | 1992-08-12 | 1993-08-10 | Polymerized polysiloxane membrane for oxygen sensing device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US92908892A | 1992-08-12 | 1992-08-12 | |
US07/929,088 | 1992-08-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1994004241A2 WO1994004241A2 (en) | 1994-03-03 |
WO1994004241A3 true WO1994004241A3 (en) | 1994-04-14 |
Family
ID=25457305
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1993/006983 WO1994004241A2 (en) | 1992-08-12 | 1993-08-10 | Polymerized polysiloxane membrane for oxygen sensing device |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU4993593A (en) |
WO (1) | WO1994004241A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5439736A (en) * | 1994-01-21 | 1995-08-08 | Neomecs Incorporated | Gas plasma polymerized permselective membrane |
US5560800A (en) * | 1994-08-31 | 1996-10-01 | Mobil Oil Corporation | Protective coating for pressure-activated adhesives |
JP3495116B2 (en) * | 1994-10-31 | 2004-02-09 | 東レ・ダウコーニング・シリコーン株式会社 | Water repellent thin film and method for producing the same |
DE19831770C2 (en) * | 1998-07-15 | 2001-12-13 | Inst Chemo Biosensorik | Process for the production of a sensor membrane |
JP2000298111A (en) * | 1999-04-15 | 2000-10-24 | Sentan Kagaku Gijutsu Incubation Center:Kk | Biosensor |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3775308A (en) * | 1972-05-18 | 1973-11-27 | Interior | Method for preparation of composite semipermeable membrane |
US3847652A (en) * | 1972-12-08 | 1974-11-12 | Nasa | Method of preparing water purification membranes |
US4236987A (en) * | 1977-11-14 | 1980-12-02 | Dr. E. Fresenius Chemisch Pharmazeutische Industrie Kg Apparatebau Kg | Electrode having membrane with ion selective properties |
US4269682A (en) * | 1977-12-12 | 1981-05-26 | Kuraray Co., Ltd. | Reference electrode of insulated gate field effect transistor |
GB2121314A (en) * | 1982-05-28 | 1983-12-21 | Sumitomo Electric Industries | Selectively gas-permeable composite membranes and process for the production thereof |
US4655880A (en) * | 1983-08-01 | 1987-04-07 | Case Western Reserve University | Apparatus and method for sensing species, substances and substrates using oxidase |
US5002652A (en) * | 1988-06-10 | 1991-03-26 | Abbott Laboratories | Plasma polymerized polysiloxane membrane |
-
1993
- 1993-08-10 AU AU49935/93A patent/AU4993593A/en not_active Abandoned
- 1993-08-10 WO PCT/US1993/006983 patent/WO1994004241A2/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3775308A (en) * | 1972-05-18 | 1973-11-27 | Interior | Method for preparation of composite semipermeable membrane |
US3847652A (en) * | 1972-12-08 | 1974-11-12 | Nasa | Method of preparing water purification membranes |
US4236987A (en) * | 1977-11-14 | 1980-12-02 | Dr. E. Fresenius Chemisch Pharmazeutische Industrie Kg Apparatebau Kg | Electrode having membrane with ion selective properties |
US4269682A (en) * | 1977-12-12 | 1981-05-26 | Kuraray Co., Ltd. | Reference electrode of insulated gate field effect transistor |
GB2121314A (en) * | 1982-05-28 | 1983-12-21 | Sumitomo Electric Industries | Selectively gas-permeable composite membranes and process for the production thereof |
US4655880A (en) * | 1983-08-01 | 1987-04-07 | Case Western Reserve University | Apparatus and method for sensing species, substances and substrates using oxidase |
US5002652A (en) * | 1988-06-10 | 1991-03-26 | Abbott Laboratories | Plasma polymerized polysiloxane membrane |
Non-Patent Citations (2)
Title |
---|
Biomat., Med. Dev., Art. Org., Colter et al, "Reduction of Progesterone Release Rate Through Silicone Membranes by Plasma Polymerization". vol. 5(1), 1977, see pages 13-24 * |
Trans. Am. Soc. Artif. Intern. Organs, A.S. Chawla, "Preparation of Silicone Coated Biomaterials Using Plasma Polymerization and Their Preliminary Evalutions", vol. XXV, 1979, see page 287-290. * |
Also Published As
Publication number | Publication date |
---|---|
WO1994004241A2 (en) | 1994-03-03 |
AU4993593A (en) | 1994-03-15 |
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