WO1994004225A3 - Procede de detoxication de gaz de moutarde, polymeres d'ionene d'ammonium quaternaire contenant du soufre, et leur utilisation comme microbicides - Google Patents

Procede de detoxication de gaz de moutarde, polymeres d'ionene d'ammonium quaternaire contenant du soufre, et leur utilisation comme microbicides Download PDF

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Publication number
WO1994004225A3
WO1994004225A3 PCT/US1993/007046 US9307046W WO9404225A3 WO 1994004225 A3 WO1994004225 A3 WO 1994004225A3 US 9307046 W US9307046 W US 9307046W WO 9404225 A3 WO9404225 A3 WO 9404225A3
Authority
WO
WIPO (PCT)
Prior art keywords
quaternary ammonium
sulfur
ionene polymers
microbicides
detoxification
Prior art date
Application number
PCT/US1993/007046
Other languages
English (en)
Other versions
WO1994004225A2 (fr
Inventor
Wallace E. Puckett
Mark L. Zollinger
Fernando Del Corral
Original Assignee
Buckman Laboratories International, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/928,356 external-priority patent/US5401881A/en
Priority to JP6506282A priority Critical patent/JPH07502923A/ja
Priority to DK93919839T priority patent/DK0607420T3/da
Priority to AU49941/93A priority patent/AU663625B2/en
Priority to BR9305634A priority patent/BR9305634A/pt
Priority to EP93919839A priority patent/EP0607420B1/fr
Application filed by Buckman Laboratories International, Inc. filed Critical Buckman Laboratories International, Inc.
Priority to DE69321931T priority patent/DE69321931T2/de
Publication of WO1994004225A2 publication Critical patent/WO1994004225A2/fr
Priority to FI941659A priority patent/FI941659A/fi
Priority to NO941298A priority patent/NO941298L/no
Publication of WO1994004225A3 publication Critical patent/WO1994004225A3/fr
Priority to FI20002176A priority patent/FI20002176A/fi

Links

Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18Liquid substances or solutions comprising solids or dissolved gases
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/36Detoxification by using acid or alkaline reagents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/02Chemical warfare substances, e.g. cholinesterase inhibitors
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances
    • A62D2101/28Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/40Inorganic substances
    • A62D2101/47Inorganic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

Procédé de détoxication d'un gaz de moutarde par réaction avec une diamine bis-tertiaire, produisant des polymères d'ionène d'ammonium quaternaire. L'invention se rapporte également à des polymères d'ionène d'ammonium quaternaire contenant du soufre, pouvant être utilisés comme microbicides pour lutter contre la croissance de micro-organismes dans des systèmes aqueux et sur des surfaces, ainsi que pour inhiber la formation de dépôts visqueux dans des systèmes aqueux. Des compositions biocides contenant des doses efficaces des polymères d'ionène d'ammonium quaternaire contenant du soufre sont également décrites.
PCT/US1993/007046 1992-08-12 1993-07-30 Procede de detoxication de gaz de moutarde, polymeres d'ionene d'ammonium quaternaire contenant du soufre, et leur utilisation comme microbicides WO1994004225A2 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
DE69321931T DE69321931T2 (de) 1992-08-12 1993-07-30 Methode zur entgiftung von senfgas und schwefel enthaltende quarternäre ammonium-ionische-polymere
DK93919839T DK0607420T3 (da) 1992-08-12 1993-07-30 Fremgansmåde til afgiftning af sennepsgas, og svovlholdige kvaternære ammoniumionenpolymere
AU49941/93A AU663625B2 (en) 1992-08-12 1993-07-30 Method for the detoxification of mustard gas, sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
BR9305634A BR9305634A (pt) 1992-08-12 1993-07-30 Método para a destoxificação de um gás mostarda, polímero de loneno de amônio quaternário contendo enxofre, método para inibir o crescimento de microorganismos ou algas, método para inibir a formação de lodo, método para inibir o crescimento de microorganismos na superfície de uma substância e composiçao microbicida
EP93919839A EP0607420B1 (fr) 1992-08-12 1993-07-30 Procede de detoxication de gaz de moutarde et polymeres d'ionene d'ammonium quaternaire contenant du soufre
JP6506282A JPH07502923A (ja) 1992-08-12 1993-07-30 マスタードガスの解毒方法、硫黄−含有の第四アンモニウムイオネンポリマー及びそれの殺微生物剤としての使用
FI941659A FI941659A (fi) 1992-08-12 1994-04-11 Menetelmä sinappikaasun tekemiseksi myrkyttömäksi, rikkipitoisia kvaternaarisia ammoniumioneenipolymeerejä sekä niiden käyttäminen mikrobisideinä
NO941298A NO941298L (no) 1992-08-12 1994-04-11 Fremgangsmåte for detoksifisering av senepsgass, svovelholdige kvaternære ammoniumionenpolymere og deres anvendelse som mikrobicider
FI20002176A FI20002176A (fi) 1992-08-12 2000-10-02 Rikkipitoisia kvaternaarisia ammonium-ioneenipolymeerejä sekä niiden käyttäminen mikrobisideinä

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/928,356 US5401881A (en) 1992-08-12 1992-08-12 Sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US07/928,356 1992-08-12
US07/993,079 US5387717A (en) 1992-08-12 1992-12-18 Method for the detoxification of mustard gas, sulfur-containing quaternary ammonium ionene polymers and their use as microbicides
US07/993,079 1992-12-18

Publications (2)

Publication Number Publication Date
WO1994004225A2 WO1994004225A2 (fr) 1994-03-03
WO1994004225A3 true WO1994004225A3 (fr) 1994-05-26

Family

ID=27129960

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/007046 WO1994004225A2 (fr) 1992-08-12 1993-07-30 Procede de detoxication de gaz de moutarde, polymeres d'ionene d'ammonium quaternaire contenant du soufre, et leur utilisation comme microbicides

Country Status (15)

Country Link
US (2) US5387717A (fr)
EP (2) EP0827690B1 (fr)
JP (1) JPH07502923A (fr)
AT (2) ATE172883T1 (fr)
AU (1) AU663625B2 (fr)
BR (1) BR9305634A (fr)
CA (1) CA2121045A1 (fr)
DE (2) DE69329506T2 (fr)
DK (1) DK0607420T3 (fr)
ES (2) ES2125999T3 (fr)
FI (2) FI941659A (fr)
NO (1) NO941298L (fr)
NZ (1) NZ255655A (fr)
PT (1) PT827690E (fr)
WO (1) WO1994004225A2 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19528394A1 (de) * 1994-08-13 1996-02-15 Bluecher Hasso Von Verfahren zur Dekontaminierung von mit chemischen Kampfstoffen kontaminierter Haut oder Materialien
NZ286510A (en) * 1995-05-15 1998-06-26 Rohm & Haas Method of detoxifying biocide in waste water using a water soluble thio compound
US5574202A (en) * 1995-06-12 1996-11-12 Mark Pilipski Technique for processing poison gases
EA000631B1 (ru) * 1995-11-07 1999-12-29 Коммодор Эпплайд Текнолоджис, Инк. Способ и устройство для уничтожения химических боевых веществ
ZA9710751B (en) * 1996-12-12 1999-05-28 Commodore Applied Technologies Method for destroying energetic materials
US6203451B1 (en) 1999-01-13 2001-03-20 Acushnet Company Zwitter-ion and ionene golf ball forming compositions and methods
IN191232B (fr) * 1999-03-15 2003-10-11 Chief Controller Res & Dev
US6395383B1 (en) * 1999-12-13 2002-05-28 Gore Enterprise Holdings, Inc. Chemical protective covering
CN1612766B (zh) * 2001-10-01 2010-10-13 三帝公司 用于中和化学,生物和工业毒物的增强制剂
CA3005295C (fr) 2015-11-12 2023-09-05 Helsingin Yliopisto Procede de destruction de produits chimiques toxiques
US20190249360A1 (en) 2018-02-15 2019-08-15 Buckman Laboratories International, Inc. Method And System For Tagging Leather Or Hides Treated With Biocide And Identifying Same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4217914A (en) * 1974-05-16 1980-08-19 L'oreal Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin
US4874532A (en) * 1988-06-29 1989-10-17 Ppg Industries, Inc. Method for decontamination of toxic chemical agents
DD299706A7 (de) * 1981-11-16 1992-05-07 Hartmunt Dipl.-Ing-Chem. Wolthers Flüssigkeit zur Entgiftung toxischer Substanzen

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL103060C (fr) * 1956-10-10
US3874870A (en) * 1973-12-18 1975-04-01 Mill Master Onyx Corp Microbiocidal polymeric quarternary ammonium compounds
US4025627A (en) * 1973-12-18 1977-05-24 Millmaster Onyx Corporation Microbiocidal polymeric quaternary ammonium compounds
DK659674A (fr) * 1974-01-25 1975-09-29 Calgon Corp
US4046750A (en) * 1974-09-30 1977-09-06 California Institute Of Technology Ionene modified small polymeric beads
US3931319A (en) * 1974-10-29 1976-01-06 Millmaster Onyx Corporation Capped polymers
US4027020A (en) * 1974-10-29 1977-05-31 Millmaster Onyx Corporation Randomly terminated capped polymers
US4506081A (en) * 1982-09-02 1985-03-19 Buckman Laboratories, Inc. Polymeric quaternary ammonium compounds and their uses
ZA905554B (en) * 1989-09-27 1991-04-24 Buckman Labor Inc Synergistic combinations of ionenes with hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine in controlling fungal and bacterial growth in synthetic metalworking fluid
AR243854A1 (es) * 1989-10-12 1993-09-30 Buckman Labor Inc Proceso para inhibir la adhesion de celulas bacterianas a superficies solidas y controlar la contaminacion biologica en circuitos acuosos.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4217914A (en) * 1974-05-16 1980-08-19 L'oreal Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin
DD299706A7 (de) * 1981-11-16 1992-05-07 Hartmunt Dipl.-Ing-Chem. Wolthers Flüssigkeit zur Entgiftung toxischer Substanzen
US4874532A (en) * 1988-06-29 1989-10-17 Ppg Industries, Inc. Method for decontamination of toxic chemical agents

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 112, no. 15, 9 April 1990, Columbus, Ohio, US; abstract no. 133993d, GU, WEIZHANG ET AL: "Decontamination system for a rapid destruction of mustard gas" *
PROC. INT. SYMP. PROT. CHEM. WARF. AGENTS, 3RD, ISSUE PB89-225379, 327-30. SWED. DEF. RES. ESTABL.: UMEA, SWED., 1989 *

Also Published As

Publication number Publication date
EP0607420A1 (fr) 1994-07-27
US5387717A (en) 1995-02-07
EP0827690A2 (fr) 1998-03-11
NO941298D0 (no) 1994-04-11
ES2151225T3 (es) 2000-12-16
NO941298L (no) 1994-04-11
ES2125999T3 (es) 1999-03-16
PT827690E (pt) 2001-01-31
AU663625B2 (en) 1995-10-12
FI941659A0 (fi) 1994-04-11
EP0827690B1 (fr) 2000-09-27
US5703131A (en) 1997-12-30
DK0607420T3 (da) 1999-07-19
NZ255655A (en) 1997-02-24
DE69329506D1 (de) 2000-11-02
FI20002176A (fi) 2000-10-02
JPH07502923A (ja) 1995-03-30
DE69321931D1 (de) 1998-12-10
EP0827690A3 (fr) 1998-03-18
ATE196590T1 (de) 2000-10-15
EP0607420B1 (fr) 1998-11-04
CA2121045A1 (fr) 1994-03-03
AU4994193A (en) 1994-03-15
BR9305634A (pt) 1996-01-02
ATE172883T1 (de) 1998-11-15
WO1994004225A2 (fr) 1994-03-03
FI941659A (fi) 1994-04-11
DE69329506T2 (de) 2001-02-08
DE69321931T2 (de) 1999-04-01

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