WO1993006934A1 - Separation electrostatique de materiaux plastiques - Google Patents

Separation electrostatique de materiaux plastiques Download PDF

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Publication number
WO1993006934A1
WO1993006934A1 PCT/US1992/000184 US9200184W WO9306934A1 WO 1993006934 A1 WO1993006934 A1 WO 1993006934A1 US 9200184 W US9200184 W US 9200184W WO 9306934 A1 WO9306934 A1 WO 9306934A1
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WO
WIPO (PCT)
Prior art keywords
fragments
electrostatic
charged
materials
mixed
Prior art date
Application number
PCT/US1992/000184
Other languages
English (en)
Inventor
Martin H. Beck
George F. Rollend
Richard C. Nichols
John Muszynski
Original Assignee
Devtech Labs, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Devtech Labs, Inc. filed Critical Devtech Labs, Inc.
Publication of WO1993006934A1 publication Critical patent/WO1993006934A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C7/00—Separating solids from solids by electrostatic effect
    • B03C7/02—Separators
    • B03C7/12—Separators with material falling free
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C7/00—Separating solids from solids by electrostatic effect
    • B03C7/02—Separators
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0203—Separating plastics from plastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0262—Specific separating techniques using electrical caracteristics
    • B29B2017/0265—Electrostatic separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • This invention relates to the electrostatic separation of plastic materials.
  • Typical rigid household plastic packages are made of 5 plastic materials. Other plastic materials are used as well, but the 5 highest volume materials are:
  • plastic containers Some of the applications for the plastic containers are clear while some are colored (transparent -> opaque) .
  • An existing method to separate the different materials is to sort by hand. This method is costly and fraught with error as many applications utilize two or more plastic materials.
  • edible oil bottles are made from both PET and PVC materials. This method can only be used with whole bottles and preferably when they are not crushed.
  • Materials with densities ⁇ 1 g/cc generally are PE and PP.
  • the separation process generally is a float/sink operation where the lighter fractions float on water and are culled off while the heavier fraction sinks to the bottom.
  • the heavy fraction would generally constitute PET, PVC and PS.
  • the densities of these materials are very similar and in the case of PET and PVC they overlap.
  • typical PVC densities range from 1.25 to 1.36 g/cc while typical PET ranges from 1.32 to 1.39 g/cc.
  • a method of separating mixed fragments of different materials at least one said material being capable of carrying an electrostatic charge by which it can be caused to migrate under the influence of an electrostatic field sufficiently to separate it from at least one other said material, comprising the steps of inducing said electrostatic charge on said at least one said material, exposing the materials to an electrostatic field capable of causing migration of said at least one material relative to at least said one other said material, allowing said at least one material to migrate under the influence of said field thereby to separate said materials, and collecting the separated material fragments, wherein the induced electrostatic charge on said at least one material is sufficient to facilitate said migration while being insufficient for any oppositely charged fragments of said materials to be attracted to each other sufficiently to prevent said migration.
  • an apparatus for carrying out the above defined method comprising means for inducing said electrostatic charge on the fragments of said at least one material, means for producing an electrostatic field capable of causing migration of said charged fragments relative to at least one other said material, means for exposing said mixed fragments to said field, and means for collecting the separated material fragments.
  • Figure 1 is a diagrammatic side elevation of a first 10. experimental electrostatic plastic material separator
  • Figure 2 is a diagrammatic plan of the separator of Figure 1;
  • Figure 3 is a diagrammatic side elevation of a second experimental electrostatic plastic material separator
  • Figure 4 is a diagrammatic representation of a proposed commercial embodiment of an electrostatic plastic material separator
  • FIGS 5 to 9 diagrammatically illustrate various examples of possible electrode configurations; and 20 Figures 10 and 11 illustrate charge distributions of PVC and PET fragments.
  • an electrostatic separator 1 for separation of ground PVC and PET, or other commingled 5 plastic particles 2, each 5/8 inch or less in size.
  • the separator comprises an electrostatic precharging hopper 3, which is mounted at or near the top of an inclined sheet 4, wherein the hopper and the inclined sheet 4 are made up of insulating materials, preferably one of the plastic 0 materials to be separated (in this embodiment; PET) to assist in the transfer of electrons.
  • Two strips of conductive material 6, 8, typically aluminum foil, are attached to the underside of the inclined sheet 4, positioned so that one strip 6 continuously traverses the two sides and the bottom edge of the sheet 4 while the second strip 8 is centrally located from the top edge of the sheet 4 extending therefrom toward the first strip bottom edge.
  • the strips 6, 8 are separated from one another by an insulating gap and are attached to an electric generator 12 by means of leads 10, the second strip 8 being attached to the negative terminal and the first strip 6 being attached to the positive terminal of the generator 12, thereby producing oppositely charged electrostatic poles defined by the strips 6 and 8.
  • Other configurations involving conductive strips are possible provided that separate, appropriately charged electrostatic fields are created.
  • the hopper 3 has a gate means 5 which can be opened to release the commingled particles allowing them to migrate down the inclined sheet 4.
  • a vibration device 14 enhances this migration by causing the commingled particles to bounce into the air as they proceed down the chute formed by the incline.
  • the sheet 4 has three collection holes 18 located on its lower half to collect separated particles wherein each hole 18 has a corresponding collection cup 20 placed underneath it to collect particles which drop through.
  • path diverters 21 are attached to the top of the inclined sheet 4 to assist in the separation and collection process. Diverters are not shown in Figure 1.
  • the commingled PVC and PET particles 2 are placed in the precharge hopper 3 where they receive an induced electrostatic charge causing the surface of the precharge hopper 3
  • the precharge hopper 3 is made from insulating material, preferably of a plastic material to be separated (PET in this embodiment) , to facilitate the transfer of electrons.
  • PET plastic material to be separated
  • the induced charge must be applied for a sufficient duration and at a sufficient strength to create opposite charges on the surfaces of the plastic particles but should not be great enough to cause ' the particles to attract one another, preventing separation. It has been found that a charge of between 3000 and 10,000 volts for a period of 30 seconds to 60 seconds produces adequate results.
  • the mixed particles 2 upon acquisition of the induced charge are released from the hopper 3 by opening the gate 5 allowing the particles to migrate down the inclined sheet 4 facilitated by the vibrating member 4 whose oscillations causes the particles to bounce into the air.
  • the conductive strips of aluminum foil 6, 8 placed on the underside of the inclined sheet act as positive and negative poles respectively, produce electrostatic fields of opposite polarity.
  • the mixed particles having acquired an induced charge, are attracted to oppositely charged poles, meaning that the positively charged PVC particles are drawn toward the negative pole 8, while the negatively charged PET particles are drawn toward positive pole 6.
  • This electrostatic attraction of unlike charged particles causes the central stream 15 of mixed PCT/PET particles to separate into divergent streams of pure PVC 17 and pure PET 16, respectively, while the remaining central stream 15 contains those mingled particles which either did not develop a sufficient induced charge while in the hopper 3, or developed too great a charge causing interparticular attraction. It has been found that separation is enhanced by using a thicker inclined sheet rather than a thinner, less insulating, sheet.
  • the particles are then collected by means of holes 18 with collector cups 20 placed underneath the holes to capture the separated PVC and PET particle streams 16, 17 as well as the mingled particle stream 15. These mingled particles may be recycled through another pass of the separator or set aside.
  • FIG. 3 discloses a second embodiment of an electrostatic separator 30 in which a precharge hopper 32 is suspended a vertical distance above and between two oppositely charged plates 34, 36, wherein the negative terminal of a generator 38 is attached to one plate 34 and the positive terminal of the generator 38 is attached to the other plate 36 as well as to the precharge hopper 32 by means of leads 40.
  • the vertical plates 34, 36 are composed of a conductive material, such as aluminum foil and are vertically supported by mount stands 35. The plates, therefore, define two oppositely charged electrostatic fields beneath suspended precharge hopper 32.
  • mixed PVC/PET, or other ground and commingled plastic particles are placed in the precharge hopper 32 and are electrostatic charged the precharge hopper 32 being composed of an insulating material, preferably of a plastic material to be separated (PET, in this embodiment) which allows free migration of electrons allowing the PVC particles to become positively charged and the PET particles to become negatively charged.
  • PET plastic material to be separated
  • the mixed PET/PVC particles upon receiving the induced electrostatic charge are allowed to free fall under the influence of gravity by opening of a gate 33 of the precharge hopper 32.
  • the negatively charged PVC particles are drawn toward the positive pole 34 and the positively charged PET particles are drawn toward the negatively charged pole 36 producing two divergent streams 42, 43 of pure PVC and pure PET respectively.
  • plates possessing equal and opposite charges of +60KV producing a total potential of 120KV will create horizontal displacement of greater than l/2cm for each 1cm of vertical drop.
  • the separated streams 42, 43 of form individual 44, 45 of charged PVC and PET particles which can then be collected.
  • the separator of Figures 1 and 2 was designed and run though, some modifications were made as results became apparent. Generally, 25 grams of PET and 25 grams of PVC were used in the trial. Three collections were made from each run; PET - PVC - MINGLINGS.
  • the refrigerated material has condensation that apparently forms on the surface giving problems while the room temperature material has absorbed moisture that causes some interference.
  • a “middle of the road” charge is required on the materials so they will have enough energy to jump to their respective (opposite charged) poles but not so much energy they are attracted to each other.
  • the generating device that was used is called a wimshurst generator. It is a handcranked device that allows a small electrostatic charge to be generated.
  • the leads were connected to the aluminum foil as noted in the sketch. In this manner we were able to create continuous and "wide" (as opposed to a point) poles. Handcranking the generator gave between 3,000 and 10,000 volts as measured with a handheld meter.
  • the second size particles were those put through a 5/8 inch screen.
  • the smaller sized particles separated easier than the larger size, however, the larger size did also separate although at a lower point on the inclined sheet. It was theorized that this is because a large enough charge could not be placed on the larger particles with the handheld device.
  • a commercial unit would probably generate 50,000 to 100,000 volts, thus, giving sufficient charges to be attracted quickly to its opposite pole.
  • a 2 liter soft drink bottle (PET) and a Windex bottle (PVC) were purchased.
  • the bottles were cut into small pieces of which 20 particles of each material were placed into a glass jar.
  • the jar was capped and shaken for 15+ seconds to induce a static charge on the surface of each particle.
  • the commingled material upon exposure to oppositely charged electrostatic fields, is divided into 3 streams: a) Positive pole attraction; b) Negative pole attraction; and c) "Minglings".
  • PET can exist in three separate states; amorphous biaxially oriented crystallized.
  • the PET and PVC separation tests have produced excellent results. 100% purification has been achieved on some tests with one pass.
  • PET/PC Fair PET/PS Poor
  • the system has good temperature range capability though highest humidity days deteriorates performance.
  • test results indicate that in commercial use the electrostatic separation of plastic fragments would preferably involve tumbling the mixed plastic fragments to induce the desired electrostatic charges on the surfaces thereof and allowing these charged fragments to free fall, initially as a curtain, between oppositely charged electrodes disposed on opposite sides of and parallel to the curtain to cause separation of the fragments by migration with positively charged fragments being attracted toward the negative electrode and negatively charged fragments being attracted toward the positively charged electrode.
  • the separated fragments would be collected in hoppers at the end of their free fall.
  • a hopper 50 is arranged, by means of a chute 51, to supply a stream of plastic fragments to the inlet end 52 of a charging drum 53.
  • the stream comprises a mixture of different plastic materials, the separation of which is desired.
  • the different materials involved are capable of carrying electrostatic charges of opposite polarities on their surfaces.
  • the particles are tumbled in the drum 53 to induce on their surfaces the desired electrostatic charge.
  • the drum is rotated about its longitudinal axis 54 by a motor 55 and belt 56 drive. Rotation of the drum is facilitated by support of the drum on four support rollers 57 (two only being shown) located to support the drum for rotation about the axis 54.
  • the rollers are supported by a frame 58 which also supports the hopper 50 and chute 51.
  • Longitudinally extending vanes 59 are disposed on the inner periphery of the drum 53 to cause the fragments in the drum to tumble as the drum is rotated thereby to induce the electrostatic charge.
  • the axis 54 of the rotation of the drum 53 is inclined downwardly, from the inlet end 52 to an outlet end 60, at an angle which, together with the quantity of fragments being supplied from the hopper and the rate of tumbling rotation of the fragments, will result in a desired residence time of each fragment in the drum chosen to achieve the desired electrostatic charge on the surface of the fragments as they pass through the drum from the inlet end to the outlet end.
  • the charged stream of fragments leaving the outlet end 60 of the drum 53 is fed onto the upper surface of a distributor plate 61 over which the fragments pass to a straight curtain forming edge 62.
  • the slope and shape of the plate 61 is chosen to facilitate distribution of fragments passing thereover so that they form a substantially even curtain of fragments as they fall from the straight edge 62.
  • the passage and distribution of the fragments over the plate 61 is facilitated by a vibrator 63 mounted on the frame 58 and connected to the plate 61 to vibrate that plate.
  • the edge 12 is disposed substantially evenly between the top edges of two parallel flat plate electrodes 64 and 65, with electrode 64 being connected to the positive terminal and electrode 65 being connected to the negative terminal of a high voltage generator 66 for generating positive and negative electrostatic fields.
  • the edge 62 is parallel to the planes of the electrodes 64 and 65 and the electrodes 64 and 65 extend downward on either side of the curtain free falling from the edge 62. As the charged fragments of the curtain free fall between the electrodes those with a positive charge are attracted toward and will migrate toward the negative electrode 65 while those with a negative charge will be attracted toward and will migrate toward the positive electrode 64 thereby separating the positive charged fragments from the negatively charged fragments.
  • hopper 67, 68 and 69 Between the lower ends of electrodes 64 and 65 are disposed collection hoppers 67, 68 and 69 with the hopper 67 being disposed to receive substantially only negatively charged fragments, hopper 68 being disposed to receive substantially only positively charged fragments and hopper 69 being disposed between hoppers 67 and 68 to receive commingled fragments which have failed to separate. These commingled fragments may be recycled to hopper 50 for further separation treatment in the apparatus or otherwise disposed of. Separation efficiencies have been achieved which indicate that the hopper 69 may be unnecessary and thus not needed in commercial application.
  • the location of the division between the hoppers 67, 68 and, if present, 69 is chosen in dependence upon the magnitude of the charge induced in the different fragments with the consequent difference in migration which will be achieved while under the influence of the electrostatic fields generated by the electrodes 64 and 65.
  • the hoppers 67, 68 and 69 have respective outlet ducts 70, 71 and 72 through which the fragments collected in the hoppers may be extracted by, for example, suction or screw conveyor means extending into the hoppers through the ducts for onward passage to later stages of the recycling process or disposal of unwanted fragments.
  • the length of the free fall of the fragments is chosen to prevent them from migrating the entire distance to either of the electrodes thereby preventing the fragments from attaching themselves to either electrode while ensuring that they migrate a sufficient horizontal distance to fall into the desired hopper 67 or 68.
  • the curtain is shown by the arrows indicated as 73 with positively charged fragments migrating as generally indicated by arrows 74 and negatively charged fragments migrating as generally indicated by arrows 75.
  • Commingled fragments which have not separated are indicated by arrow 76.
  • FIG. 5 a single electrode corresponding to positive electrode 64 is used.
  • This electrode is cylindrical with concentric hoppers 67 and 68 disposed at the bottom and inside of thereof.
  • a stream of charged fragments are allowed to free fall along the central axis of the cylindrical electrode.
  • the negatively charged fragments e.g. PVC
  • Fragments e.g. PVC
  • PET which do not carry a charge or which are positively charged free fall along the axis of the electrode as a result of not being attracted by the electrostatic field generated by the electrode or, in the case of the positively charged fragments, as a result of the repulsion by that electromagnetic field, into the central hopper 68.
  • a variation of this design involves an arrangement in which a cylindrical outer electrode surrounds an inner electrode which is concentric with the outer cylindrical electrode and of opposite polarity thereto. The hoppers would be appropriately positioned to receive their respective supply of positively and negatively charged fragments in this arrangement.
  • Such a design in essence amounts to a modification of the arrangement of Figure 4 in which the electrodes are wrapped around form concentric cylindrical electrodes.
  • the curtain would be a circular curtain created, for example, by a right conical distributor plate positioned to receive a stream of charged fragments centrally on its pointed upper end and to create the curtain at its circular lower periphery. It will be appreciated that while certain electrodes are described herein as positive and other electrodes are described herein as negative these could be reversed in any configuration as would be appropriate with the polarity of electrostatic charges of the fragments to be separated.
  • a single planar electrode 64 is energized to create a positive electrostatic field which attracts negatively charged (e.g. PVC) fragments of a curtain 73 in order that they migrate horizontally to be collected in hopper 67 while positively charged fragments or fragments carrying no charge fall into hopper 64 with some repulsion resulting in migration of the positively charged fragments away from the electrode 64.
  • a variation of Figure 6 is shown in Figure 7 in which two positively charged electrodes attract negatively charged fragments from a curtain or stream for collection in hopper 67 while positively charged fragments or fragments having no charge fall into hopper 68.
  • the present invention is also applicable to the separation of fragments all of which can carry a charge of the same polarity.
  • the requirement in such a process is that the fragments to be separated must carry magnitudes of charge sufficiently different for attraction or repulsion by an electrostatic field to cause different degrees of migration normal to the free fall direction thereby to facilitate the desired separation.
  • Figure 8 illustrates such an arrangement in which a positively charged electrode 64 generates a positive electrostatic field which causes separation of a curtain 73 of fragments all of which are negatively charged with fragments of different materials being charged to different negative magnitudes of charge respectively.
  • Electrodes which are vertically cylindrical or flat.
  • electrodes could be curved or sloped outwardly relative to the curtain stream of charged fragments to maximize attraction and/or repulsion of the charged fragments while avoiding the possible migration of those fragments onto the electrodes concerned as they free fall (see Figure 9) .
  • Figure 10 illustrates the charged distribution in nanocoulombs (nC) achieved with a mixture of 90% PET and 10% PVC fragments not exceeding 1/4 inch maximum dimension in which the fragments were hand tumbled for 20 seconds to achieve an electrostatic charge on the surfaces thereof. This figure illustrates that 100% separation of the PET and PVC can be achieved if the division between hopper 67 and 68 is placed at a location where fragments having a charge of 0.1 nC will land after their free fall.
  • Figure 11 illustrates the distribution of charge for large particles (all between 1/8 to 1/4 inch maximum dimension) with the few fragments in the gap between the PVC and PET being of PVC.
  • the desired separation of PET and PVC can be achieved.
  • Further tests illustrate that separation is excellent with relative humidities are kept to no more than 40%.
  • Significant degredation and performance occurs with relative humidities exceeding 70%. Satisfactory performance is expected to be achieved with relative humidities of 50% or less.
  • the desired purity of achieving less than 100 ppm of PVC in the PET output can be achieved with PET/PVC mixes which contain up to 10% of PVC.
  • drums volume is typically 0.17 cubic meters with the fragments occupying approximately 3/4 of the drum.

Abstract

Appareil et procédé servant à séparer des fragments mélangés de différents matériaux plastiques (2), les matériaux (2) à séparer étant susceptibles de porter différentes charges électrostatiques. Les charges sont produites dans les fragments mélangés par une trémie de précharge (3, 32) ou par un passage dans un tambour (53). Les fragments chargés sont ensuite exposés à au moins un champ électrostatique dans lequel ils sont séparés par migration sous l'influence du champ. Le champ peut être créé le long d'une feuille inclinée (4) ou dans un passage à chute libre. Les fragments de matériaux séparés sont ensuite recueillis.
PCT/US1992/000184 1991-09-30 1992-01-10 Separation electrostatique de materiaux plastiques WO1993006934A1 (fr)

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US76908891A 1991-09-30 1991-09-30
US769,088 1991-09-30

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WO1993006934A1 true WO1993006934A1 (fr) 1993-04-15

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Cited By (5)

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US6452126B1 (en) * 1999-03-12 2002-09-17 Mba Polymers, Inc. Electrostatic separation enhanced by media addition
WO2006011018A1 (fr) * 2004-07-21 2006-02-02 Anglo Operations Limited Dispositif et procede de separation de particules
US7063213B2 (en) 2002-07-22 2006-06-20 Mba Polymers, Inc. Mediating electrostatic separation
ITRE20100045A1 (it) * 2010-05-31 2011-12-01 Stefano Cassani Metodo e dispositivo per separare particelle di un determinato materiale sintetico da particelle di diversi materiali sintetici
CN103537379A (zh) * 2013-10-30 2014-01-29 上海大学 渣金间外加电场的渣金分离装置

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Publication number Priority date Publication date Assignee Title
US6452126B1 (en) * 1999-03-12 2002-09-17 Mba Polymers, Inc. Electrostatic separation enhanced by media addition
US7063213B2 (en) 2002-07-22 2006-06-20 Mba Polymers, Inc. Mediating electrostatic separation
WO2006011018A1 (fr) * 2004-07-21 2006-02-02 Anglo Operations Limited Dispositif et procede de separation de particules
AU2005266117B2 (en) * 2004-07-21 2010-01-07 Anglo Operations Limited Device for and method of separating particles
ITRE20100045A1 (it) * 2010-05-31 2011-12-01 Stefano Cassani Metodo e dispositivo per separare particelle di un determinato materiale sintetico da particelle di diversi materiali sintetici
WO2011151690A1 (fr) * 2010-05-31 2011-12-08 Stefano Cassani Procédé et dispositif de séparation de particules d'un matériau synthétique déterminé à partir de particules de différents matériaux synthétiques
US8853583B2 (en) 2010-05-31 2014-10-07 Stefano CASSANI Method and a device for separating particles of a determined synthetic material from particles of different synthetic materials
CN103537379A (zh) * 2013-10-30 2014-01-29 上海大学 渣金间外加电场的渣金分离装置
CN103537379B (zh) * 2013-10-30 2016-03-30 上海大学 渣金间外加电场的渣金分离装置

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