WO1992003219A1 - Aeration apparatus with diffuser - Google Patents

Aeration apparatus with diffuser Download PDF

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Publication number
WO1992003219A1
WO1992003219A1 PCT/AU1991/000398 AU9100398W WO9203219A1 WO 1992003219 A1 WO1992003219 A1 WO 1992003219A1 AU 9100398 W AU9100398 W AU 9100398W WO 9203219 A1 WO9203219 A1 WO 9203219A1
Authority
WO
WIPO (PCT)
Prior art keywords
conduit
plate
liquid
diffuser
bubbles
Prior art date
Application number
PCT/AU1991/000398
Other languages
English (en)
French (fr)
Inventor
Graeme John Jameson
Original Assignee
The University Of Newcastle Research Associates Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The University Of Newcastle Research Associates Limited filed Critical The University Of Newcastle Research Associates Limited
Publication of WO1992003219A1 publication Critical patent/WO1992003219A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/1431Dissolved air flotation machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • B01F23/23231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits being at least partially immersed in the liquid, e.g. in a closed circuit
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234Surface aerating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234Surface aerating
    • B01F23/2341Surface aerating by cascading, spraying or projecting a liquid into a gaseous atmosphere
    • B01F23/23413Surface aerating by cascading, spraying or projecting a liquid into a gaseous atmosphere using nozzles for projecting the liquid into the gas atmosphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/45Mixing liquids with liquids; Emulsifying using flow mixing
    • B01F23/454Mixing liquids with liquids; Emulsifying using flow mixing by injecting a mixture of liquid and gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/20Jet mixers, i.e. mixers using high-speed fluid streams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4335Mixers with a converging-diverging cross-section
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4337Mixers with a diverging-converging cross-section
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/305Treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids

Definitions

  • the gas-liquid mixture which forms in the pipe can have a voidage of up to 60 percent by volume approximately, and behaves as a homogeneous fluid whose density is much less than the liquid in which the pipe is immersed. Accordingly, in the absence of any special
  • the present invention aims to prevent the formation of the plume, by mounting a shield or diffuser outside the vertical pipe, which has the effect of breaking up the dense foam which issues from the pipe exit, and allowing the gas bubbles to rise
  • the present invention provides apparatus , for aerating liquids wherein a dense dispersion of bubbles
  • a substantially vertical conduit adapted to be immersed in use in a body of liquid
  • a diffuser extending outwardly from the exterior of the conduit and positioned to be immersed in the body of liquid, the diffuser being arranged to disperse bubbles issuing from the lower end of the conduit outwardly away from the conduit as the bubbles rise in the body of liquid.
  • the diffuser comprises a plate surrounding the conduit and extending outwardly and upwardly from a predetermined position on the exterior of the conduit.
  • the plate is provided with a plurality of holes therethrough sized to allow a predetermined flow rate of bubbles through each hole.
  • a gap is provided between the inner periphery of the plate and the exterior of the conduit and a diverting ring is positioned on the exterior of the conduit below the gap, arranged to divert upwardly moving bubbles outwardly away from the conduit and away from the gap between the conduit and the plate.
  • Figure la is a diagrammatic cross-sectional elevation through a basic form of aeration apparatus with diffuser according to the invention
  • Figure lb is a view similar to Figure la showing the behaviour of a bouyant plume of dense foam in the absence of a- diffuser
  • Figure lc is a sectional plan view of the diffuser incorporated in the apparatus of Figure la;
  • Figure 2a is a cross-sectional elevation through the lower part of the conduit forming part of the apparatus of Figure la showing an alternative embodiment of the diffuser;
  • Figure 2b is a plan view of the diffuser shown in Figure 2a.
  • Figure 3a and Figure 3b are diagrammatic cross-sectional elevations of alternative forms of diffuser.
  • the invention relates to any form of aeration apparatus in which a dense dispersion of bubbles is emitted from the lower end (5) of a downwardly extending conduit or pipe (3) immersed in a body of water (4) , in the form of the invention shown in Figure la, liquid enters through an entry pipe (1) and a nozzle assembly (22) which terminates in an orifice (2) which faces essentially vertically downwards.
  • the nozzle is mounted in the top of a conduit or pipe (3) which is essentially vertical.
  • the liquid issues from the orifice (2) in the form of a high-speed jet (8) which can move downwardly through the pipe (3) .
  • the vertical pipe is mounted by way of support means (not shown) so that its lower end is submerged in a reservoir of liquid (4) having a surface (9) .
  • the liquid may or may not be identical in all respects to the liquid entering through the entry pipe (1) .
  • the liquid levels in the reservoir and inside the vertical pipe (3) are the same.
  • the high-speed liquid jet is first established by the orifice (2), it travels downwards through the pipe (3) and plunges into the liquid, entraining gas which is inside the pipe and carrying it out of the lower extremity (5) , to rise in the reservoir (4) in the form of fine bubbles.
  • the vertical pipe (3) fills rapidly with a dense foam of bubbles dispersed in the feed liquid, and the pressure in the head space of the pipe drops below the ambient pressure outside the pipe. Accordingly, new gas is drawn into the pipe through the air entry (6) and may be regulated by valve (7) .
  • the gas-liquid mixture which forms in the vertical pipe (3) has a voidage of up to 60 percent by volume approximately, and behaves as a homogeneous fluid whose density is much less than the liquid in the reservoir (4) . Accordingly, in the absence of any special precautions, it tends to rise as a buoyant plume, hugging the outer wall of the pipe (3) and rising rapidly to the surface (9) , as shown in Figure lb. Consequently, the bubbles in the plume do not mix with the liquid in the reservoir, and the possibility of contact with this liquid is lost.
  • the bubble diffuser can conveniently be made from a plate in the form of a frustum of a cone, inverted so that the open end is uppermost.
  • the cone is perforated with a multiplicity of holes (11) as shown in the alternative view, Figure lc.
  • the buoyant plume issuing from the exit (5) of the vertical pipe (3) ,rises and spreads over the underside of the diffuser (10) , to pass through the individual holes (11) in the diffuser (10) .
  • the bubbles of gas rise individually through the liquid in the reservoir (4) .
  • the diameter of the conical diffuser (10) shown in Figure lc should be in the range 1.5 to 10 times the outer diameter of the pipe (3) , with good practical results being found when the cone diameter is 2 to 3 times the pipe diameter.
  • the half-angle of the cone from which the frustum is formed is conveniently in the range 30 to 60 .
  • the diameter of the holes (11) can be in the range 1 to 30 mm, and the holes should be distributed evenly over the conical surface to give an open area in the range 1 to 15% of the area of the surface.
  • the diffuser it is not necessary for the diffuser to be in the shape of a cone. Other shapes will perform as well, providing the elevation of the underside of the diffuser above the exit (5) of the vertical pipe (3) , always increases as the radial distance from the axis of the pipe increases. If the underside of the diffuser surface is at any stage horizontal or tending to dip downwards as radial distance from the vertical pipe increases, there will be a tendency for the bubbles to collect in this area and coalesce, and thereby form less surface area per unit of gas volume, which will reduce the efficiency of any contacting operation between the gas and the liquid.
  • An alternative form of the diffuser is shown in
  • FIGs 2a and 2b where the diffuser (12) takes the shape of part of a circular dish, with holes (13) perforating the dish.
  • the radius of curvature of the dish can conveniently be in the range 2 to 20 times the diameter of the vertical pipe (3)
  • the diameter of the diffuser (12) shown in Figure 2b should be in the range 1.5 to 20 times the outer diameter of the pipe (3) , with good practical results being found when the diffuser diameter is 2 to 3 times the pipe diameter.
  • the diameter of the holes (13) can be in the range 1 to 30 mm, and the holes can conveniently be distributed evenly over the surface to give a total area of the perforations in the range 1 to 20% of the area of the diffuser surface.
  • a difficulty which can arise with the diffuser arrangements as shown in Figures la and 2a is that solid matter which may have been suspended in the liquid in the reservoir, may tend to settle on the upper face of the diffuser (10) or (12) and build up into a thick layer which may block the holes (11) or (13) .
  • This possibility can be avoided by mounting the diffuser (10) or (12) so that an annular gap (15) exists between the diffuser and the pipe wall (3) .
  • the conical diffuser is advantageous in this application because it will provide a surface of constant angle to the horizontal, down which any solids which may have deposited on the upper surface may slide toward the axis of the cone.
  • the half-angle of the cone, of which the diffuser is a frustum, should be such that the solids will slide toward the axis and hence fall through the annular gap (15) .
  • a diverting ring (14) or (16) in conjunction with the annular space (15) .
  • the purpose of the diverting ring is to prevent the dense foam rising from the open end (5) of the pipe (3) , from entering the annular gap (15) and thereby evading the diffuser (10) or (12) .
  • the ring is mounted on the outer wall of the vertical pipe (3) , and can conveniently be of triangular section (14) as shown in Figure 3a or of semi-circular section as in Figure 3b at (16) .
  • the invention has been described with reference to the aeration of wastewaters, it is also suitable for the flotation of mineral particles so as to remove the valuable minerals from unwanted waste matter, by contacting them with fine bubbles in a suspension of the mineral in water, so that the particles which it is desired to remove have been rendered non-wetting by the liquid while the particles which are to remain in the liquid are rendered wettable by the liquid.
  • the valuable particles then adhere to the surface of the fine bubbles and rise with them to the surface of the liquid, from which they may be removed as a froth.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
  • Physical Water Treatments (AREA)
PCT/AU1991/000398 1990-08-27 1991-08-27 Aeration apparatus with diffuser WO1992003219A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPK1974 1990-08-27
AUPK197490 1990-08-27

Publications (1)

Publication Number Publication Date
WO1992003219A1 true WO1992003219A1 (en) 1992-03-05

Family

ID=3774921

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/AU1991/000398 WO1992003219A1 (en) 1990-08-27 1991-08-27 Aeration apparatus with diffuser
PCT/AU1991/000399 WO1992003220A1 (en) 1990-08-27 1991-08-27 Aeration apparatus with draft tube
PCT/AU1991/000397 WO1992003218A1 (en) 1990-08-27 1991-08-27 Aeration of liquids

Family Applications After (2)

Application Number Title Priority Date Filing Date
PCT/AU1991/000399 WO1992003220A1 (en) 1990-08-27 1991-08-27 Aeration apparatus with draft tube
PCT/AU1991/000397 WO1992003218A1 (en) 1990-08-27 1991-08-27 Aeration of liquids

Country Status (8)

Country Link
EP (1) EP0546033A1 (enrdf_load_stackoverflow)
JP (1) JPH06500260A (enrdf_load_stackoverflow)
KR (1) KR930702065A (enrdf_load_stackoverflow)
CN (1) CN1060453A (enrdf_load_stackoverflow)
CA (1) CA2090619A1 (enrdf_load_stackoverflow)
MX (2) MX9100830A (enrdf_load_stackoverflow)
WO (3) WO1992003219A1 (enrdf_load_stackoverflow)
ZA (2) ZA916775B (enrdf_load_stackoverflow)

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US6092667A (en) * 1997-12-09 2000-07-25 Multotec Process Equipment Limited Method and apparatus for aeration of liquids or slurries
US8196750B2 (en) * 2007-06-19 2012-06-12 Renewable Algal Energy, Llc Process and apparatus for adsorptive bubble separation using a dense foam
GB2582980A (en) * 2019-04-12 2020-10-14 Colin Howard Stanwell Smith Improvements to sewage treatment plants

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DE4309918C2 (de) * 1993-03-26 1994-09-15 Voith Gmbh J M Flotationszelle mit einem Injektor
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JP2007111573A (ja) * 2004-06-08 2007-05-10 Tetsuhiko Fujisato 曝気方法とその装置とそのシステム
US7476320B1 (en) 2004-11-12 2009-01-13 Leggette Brashears & Graham, Inc. Process for groundwater remediation
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JP2008200604A (ja) * 2007-02-20 2008-09-04 Fuji Clean Kogyo Kk 気泡処理装置、水処理装置
US8544827B1 (en) 2009-04-28 2013-10-01 Nested Nozzle Mixers, Inc. Nested nozzle mixer
AT509812B1 (de) * 2010-05-10 2013-06-15 Ac2T Res Gmbh Vorrichtung und verfahren zur künstlichen alterung eines fluids
JP5535861B2 (ja) * 2010-10-08 2014-07-02 三菱重工業株式会社 エアレーション装置及びこれを備えた海水排煙脱硫装置
CN102351267B (zh) * 2011-06-28 2013-05-08 福州威龙环保技术有限公司 微气泡及微纳米气泡扩散装置
JP6042061B2 (ja) * 2011-10-12 2016-12-14 Jfeエンジニアリング株式会社 噴霧ノズル、該噴霧ノズルを用いた流体微粒化装置
JP5912393B2 (ja) * 2011-10-12 2016-04-27 Jfeエンジニアリング株式会社 噴霧ノズル及び気体と液体との混合方法
CN102491510B (zh) * 2011-12-06 2013-06-12 江南大学 一种上流式好氧生物反应器
US20160089679A1 (en) * 2013-05-23 2016-03-31 Dpsms Tecnologia E Inovacao Em Mineracao Ltda Automated system of froth flotation columns with aerators injection nozzles and process thereof
FR3018206A1 (fr) 2014-03-07 2015-09-11 Degremont Procede et dispositif de dispersion de gaz dans un liquide
CN104291428A (zh) * 2014-10-22 2015-01-21 无锡市通用机械厂有限公司 Pam加药设备预湿润装置
WO2016169493A1 (zh) * 2015-04-22 2016-10-27 关广联 一种水增氧装置
WO2017193156A1 (en) * 2016-05-09 2017-11-16 Aerofloat (Holdings) Pty Ltd Aerating lance assembly and aeration tank incorporating same
CN106745864A (zh) * 2016-12-23 2017-05-31 重庆科创水处理设备有限公司 水处理曝气分散装置
CN108339673B (zh) * 2018-02-10 2023-11-21 内蒙古科灵时代矿业技术有限公司 一种空化射流浮选气泡发生器及浮选装置
CN110479127B (zh) * 2019-07-18 2020-09-29 中国矿业大学 一种微纳米泡发生装置及生成微纳米泡的方法
CN110296319B (zh) * 2019-07-24 2025-03-21 中国海洋石油集团有限公司 一种lng接收站bog发电系统
CN112340823B (zh) * 2020-10-27 2021-08-24 四川轻化工大学 一种废水处理装置及其处理方法
CN114772773B (zh) * 2022-06-23 2022-09-02 福建省粤华环保科技有限公司 一种自适应油水分离设备

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US6092667A (en) * 1997-12-09 2000-07-25 Multotec Process Equipment Limited Method and apparatus for aeration of liquids or slurries
US8196750B2 (en) * 2007-06-19 2012-06-12 Renewable Algal Energy, Llc Process and apparatus for adsorptive bubble separation using a dense foam
GB2582980A (en) * 2019-04-12 2020-10-14 Colin Howard Stanwell Smith Improvements to sewage treatment plants

Also Published As

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JPH06500260A (ja) 1994-01-13
ZA916774B (en) 1992-05-27
WO1992003220A1 (en) 1992-03-05
EP0546033A1 (en) 1993-06-16
WO1992003218A1 (en) 1992-03-05
MX9100830A (es) 1992-04-01
MX9100829A (es) 1992-04-01
EP0546033A4 (enrdf_load_stackoverflow) 1994-02-02
KR930702065A (ko) 1993-09-08
CN1060453A (zh) 1992-04-22
ZA916775B (en) 1992-05-27
CA2090619A1 (en) 1992-02-28

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