WO1991006987A1 - Fuel cell power plant fuel control - Google Patents

Fuel cell power plant fuel control Download PDF

Info

Publication number
WO1991006987A1
WO1991006987A1 PCT/US1990/006097 US9006097W WO9106987A1 WO 1991006987 A1 WO1991006987 A1 WO 1991006987A1 US 9006097 W US9006097 W US 9006097W WO 9106987 A1 WO9106987 A1 WO 9106987A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
signal
temperature
fuel flow
reformer
Prior art date
Application number
PCT/US1990/006097
Other languages
French (fr)
Inventor
Glenn W. Scheffler
Original Assignee
International Fuel Cells Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Fuel Cells Corporation filed Critical International Fuel Cells Corporation
Priority to EP91900608A priority Critical patent/EP0508991B1/en
Priority to DE69011873T priority patent/DE69011873T2/en
Publication of WO1991006987A1 publication Critical patent/WO1991006987A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432Temperature; Ambient temperature
    • H01M8/04365Temperature; Ambient temperature of other components of a fuel cell or fuel cell stacks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0438Pressure; Ambient pressure; Flow
    • H01M8/04425Pressure; Ambient pressure; Flow at auxiliary devices, e.g. reformers, compressors, burners
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537Electric variables
    • H01M8/04574Current
    • H01M8/04589Current of fuel cell stacks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04746Pressure; Flow
    • H01M8/04776Pressure; Flow at auxiliary devices, e.g. reformer, compressor, burner
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the invention relates to the control of fuel for fuel cell power plants and in particular to the avoidance of fuel cell hydrogen starvation.
  • a fuel cell is a device which directly converts chemical energy into electrical energy.
  • fuel and oxygen are supplied to spaced electrodes where the release and acceptance of electrons occurs.
  • An ion transfer electrolyte capable of conducting an electrical charge separates the electrodes.
  • a fuel cell power plant uses a fuel cell stack comprised of a plurality of fuel cells electrically connected in series. They must use inexpensive fuel to produce economic power on a large scale. Accordingly, it is known to use natural gas which is steam reformed to produce increased molecular hydrogen in a reformer outside the fuel cells.
  • Incoming fuel will pass to this reformer with steam being added to provide additional hydrogen, and the incoming fuel heated in the presence of a catalyst to increase the molecular hydrogen.
  • the fuel is heated in the presence of a catalyst in the first portion of a bayonet tube reaching substantially peak temperature at the outlet of this catalytic bed.
  • the fuel then passes down through the bayonet tube in heat exchange relationship with the fuel being heated to recover a portion of the heat and to cool the outgoing fuel.
  • This is followed by a shift converter in which the CO is combined with the H_0 to produce CO- and additional H_.
  • This reformed fuel then passes to and through the fuel cell where the chemical reaction removes a portion of the hydrogen.
  • the effluent from the fuel cell containing the excess hydrogen is conducted to the reformer where it is burned forming combustion gases which pass in heat exchange relationship with the fuel being reformed.
  • a low fuel flow for the same current results in a high utilization factor within the fuel cell and a low amount of hydrogen leaving the fuel cell. This results in a low reformer temperature, producing a relatively low fuel conversion. More critically, however, this results in a hydrogen starvation condition within the electrodes of the fuel cell which cannot be tolerated because of the immediate and permanent damage caused.
  • a fuel utilization factor of 90-95 percent is the highest hydrogen utilization which can be tolerated even during transients. With the overall utilization at 95 percent, some portions of the fuel cell may well be approaching starvation.
  • An economical and acceptable safe operating condition is that of 80-85 percent utilization. Accordingly, it is desired to select the fuel flow for a steady state operation which results in approximately 80 percent fuel utilization.
  • a fuel cell power plant has a conventional fuel supply, reformer, and fuel cell stack with the exhaust from the fuel cell returning with its excess hydrogen to the reformer. It is then burnt as a heat source for the reformer. Current is sensed to determine the electrical load on the fuel cell and temperature of the reformer fuel is also sensed. The feed forward signal from the sensed current establishes a nominal desired fuel flow signal immediately with any change in the current.
  • a function generator establishes a nominal desired reformer temperature set point as a function of the sensed current.
  • a dynamic compensator modifies this desired temperature set point to obtain a transient temperature set point.
  • This compensator includes two lead/lag compensators, one of which is set to generate a predominant lead characteristic and the other to establish a predominant lag characteristic. These lead/lag compensators are arranged in parallel with their signal passing to a high select component. This selects the higher of the two lead/lag signals as a modified temperature set point.
  • Figure 1 is a schematic of a fuel cell power plant and the control arrangement
  • Figure 2 is a curve showing the system characteristics
  • Figure 3 is a plot versus time of the nominal temperature set point and the modifications made by each lead/lag compensator.
  • Figure 4 is a plot versus time of the nominal temperature set point and the selected control signal.
  • Incoming fuel 10 passes through fuel control valve 12 to reformer 14.
  • Steam mixer 16 adds a proportional amount of steam to the steam entering the reformer.
  • fuel is heated in the presence of catalyst within reformer tubes 18 to a midpoint temperature approximating its peak which is measured by temperature sensor 20. It thereafter passes through regeneration tubes 22, usually concentrically within tubes 18 to aid in heating of the incoming fuel and cooling the exiting fuel.
  • Figure 2 illustrates the characteristics of this system to be controlled.
  • a point such as 36, represents a particular current flow and fuel flow.
  • the constant temperature lines 38 show a temperature of 650*C for this condition. Basically with the indicated fuel flow and the removal of a certain amount of hydrogen by the designated current flow, sufficient hydrogen results which when burned in a reformer produce a temperature of 650"C at the temperature sensing point. This represents a hydrogen utilization of about 80 percent as indicated by hydrogen utilization curves 40. Point 42 represents a higher load and a higher fuel flow, but again operation on the 80 percent utilization curve. This yields reformer temperature of 800*C.
  • a decrease in fuel flow at a given current results in a decreasing reformer temperature. This results in a decreased conversion of fuel in the reformer, but this is not particularly serious. What is serious, however, is the increased fuel utilization occurring and the concomitant tendency toward starvation of the fuel cell electrodes. It is extremely important therefore to avoid flow deficiencies for a particular load, particularly any below the 95% utilization curve.
  • the selected and desirable line of operation is that along the line connecting the points 36 and 42.
  • the current sensed signal from current sensor 30 also passes to a first function generator 60.
  • This function generator establishes the nominal temperature set point which would ultimately be desired for operation at the sensed current load.
  • This nominal desired temperature set point passes through line 62 to dynamic compensators 64.
  • the signal passes in parallel through a first lead/lag compensator 66 and a second lead/lag compensator 68.
  • the first lead/lag compensator is set to have substantial lead action while the second lead/lag compensator is set to have substantial lag action.
  • the output from the two compensators is passed to high select component 70 which passes the higher of the two signals through line 72 to temperature error means 74.
  • the modified set point temperature here is compared to the actual sensed temperature signal through line 76 resulting in an error signal passing through line 78.
  • Proportional and integral action is applied to this error signal by signal conditioner 79.
  • This error signal is modified by conversion apparatus 80 to provide a signal of unity with a zero error. It is accordingly applied in multiplier 82 as a modifier for the feed forward signal to the flow control. This supplies the correction to return the reformer temperature to the desired design value.
  • Multiplier 84 in the feed forward line will be used for appropriate conversion of the current sensed signal to the level desired for the fuel control. Also in the event of a consistent error in the fuel flow measurement or a consistent variation in the estimation of heating value, the temperature conversion loop would continue to maintain an offset that is other than unity. At such steady state operation multiplier 84 may be modified to remove such offset.
  • the high select apparatus 70 operating on these two signals produces the curve of Figure 4 where the output through line 72 is initially that indicated by 86, thereafter the line 90, 88 and 98.
  • the enhanced utilization of the temperature measurement as described above reduces reliance on the actual flow measurement. Transient errors induced by flow meter error or variations in fuel heating value are reduced, since the control has increased forces on the result of the inputs.

Abstract

Fuel cell current is sensed (30) and during a transient, a feed forward demand signal (50) sent to the fuel flow regulator (58). A nominal desired reformer temperature is established for the new fuel cell current. This desired temperature signal (62) is dynamically compensated (64) to establish the operating temperature set point (72). A predominantly lead compensation (66) is achieved for a desired temperature increase and a predominantly lag compensation (68) for a desired temperature decrease. Increased reliance on the temperature as a result of the system input reduces reliance on the accuracy of fuel flow measurement and on the consistency of fuel heating value.

Description

Description
Fuel Cell Power Plant Fuel Control
Technical Field
The invention relates to the control of fuel for fuel cell power plants and in particular to the avoidance of fuel cell hydrogen starvation.
Background of the Invention
A fuel cell is a device which directly converts chemical energy into electrical energy. In a fuel cell fuel and oxygen are supplied to spaced electrodes where the release and acceptance of electrons occurs. An ion transfer electrolyte capable of conducting an electrical charge separates the electrodes.
With an open external circuit the charges accumulate within the fuel cell. When the circuit is closed, the reaction occurs at a rate sufficient to supply whatever current is drawn from the external circuit. It is evident that fuel and oxidant must be supplied to the respective electrodes so that current can be continually supplied to the load in the external circuit. In fact it is essential that fuel be immediately supplied commensurate with any current flow since depletion of hydrogen would otherwise occur at the electrode resulting in serious and permanent damage to the electrode. A fuel cell power plant uses a fuel cell stack comprised of a plurality of fuel cells electrically connected in series. They must use inexpensive fuel to produce economic power on a large scale. Accordingly, it is known to use natural gas which is steam reformed to produce increased molecular hydrogen in a reformer outside the fuel cells.
Incoming fuel will pass to this reformer with steam being added to provide additional hydrogen, and the incoming fuel heated in the presence of a catalyst to increase the molecular hydrogen. Usually the fuel is heated in the presence of a catalyst in the first portion of a bayonet tube reaching substantially peak temperature at the outlet of this catalytic bed. The fuel then passes down through the bayonet tube in heat exchange relationship with the fuel being heated to recover a portion of the heat and to cool the outgoing fuel. This is followed by a shift converter in which the CO is combined with the H_0 to produce CO- and additional H_.
This reformed fuel then passes to and through the fuel cell where the chemical reaction removes a portion of the hydrogen. The effluent from the fuel cell containing the excess hydrogen is conducted to the reformer where it is burned forming combustion gases which pass in heat exchange relationship with the fuel being reformed.
With a given load or current draw on the fuel cell it can be appreciated that a range of fuel flows may be passed through the system. A relatively high fuel flow results in a substantial surplus of hydrogen leaving the fuel cell (or a low hydrogen utilization factor) with this large amount of hydrogen passing to the burner firing the reformer. This results in a relatively high reformer temperature with high conversion efficiency, but with a low overall plant efficiency because of the excess amounts of hydrogen being burned rather than being used for the direct conversion to electricity.
A low fuel flow for the same current results in a high utilization factor within the fuel cell and a low amount of hydrogen leaving the fuel cell. This results in a low reformer temperature, producing a relatively low fuel conversion. More critically, however, this results in a hydrogen starvation condition within the electrodes of the fuel cell which cannot be tolerated because of the immediate and permanent damage caused. in selecting the particular operating condition it is usually taken that a fuel utilization factor of 90-95 percent is the highest hydrogen utilization which can be tolerated even during transients. With the overall utilization at 95 percent, some portions of the fuel cell may well be approaching starvation. An economical and acceptable safe operating condition is that of 80-85 percent utilization. Accordingly, it is desired to select the fuel flow for a steady state operation which results in approximately 80 percent fuel utilization.
As a power plant traverses its operating range the reformer temperature which is correlated to this desirable utilization factor varies. Accordingly, the control system as it operates through a transient must deal not only with the change in load, but the change in heat storage required to achieve the new operating condition. - A -
It is known to use an immediate feed forward signal for controlling the amount of fuel in response to a sensed current signal which is a measurement of the load on the fuel cell. In addition to this immediate fuel flow change signals are sent to adjust the fuel flow to achieve the new desired operating temperature. It has been found that the fuel control system itself in attempting to achieve this temperature modification will result in starvation of the fuel cell during transients. Prior art systems in order to guard against such situation have required maximum/minimum limit schedules interposed in the control systems.
Summary of the Invention
A fuel cell power plant has a conventional fuel supply, reformer, and fuel cell stack with the exhaust from the fuel cell returning with its excess hydrogen to the reformer. It is then burnt as a heat source for the reformer. Current is sensed to determine the electrical load on the fuel cell and temperature of the reformer fuel is also sensed. The feed forward signal from the sensed current establishes a nominal desired fuel flow signal immediately with any change in the current.
A function generator establishes a nominal desired reformer temperature set point as a function of the sensed current. A dynamic compensator modifies this desired temperature set point to obtain a transient temperature set point. This compensator includes two lead/lag compensators, one of which is set to generate a predominant lead characteristic and the other to establish a predominant lag characteristic. These lead/lag compensators are arranged in parallel with their signal passing to a high select component. This selects the higher of the two lead/lag signals as a modified temperature set point.
This is compared to the actual sensed temperature and an error signal is established which is unity with no error. The feed forward signal to the fuel flow from the current sensor is modified by multiplication with the temperature error signal to establish a transient desired flow set point. A conventional tight control loop measures and modulates the fuel flow to establish the desired set point flow. Excessive decreases in fuel flow are thereby avoided.
Brief Description of the Drawings
Figure 1 is a schematic of a fuel cell power plant and the control arrangement;
Figure 2 is a curve showing the system characteristics;
Figure 3 is a plot versus time of the nominal temperature set point and the modifications made by each lead/lag compensator; and
Figure 4 is a plot versus time of the nominal temperature set point and the selected control signal.
Description of the Preferred Embodiment
Incoming fuel 10 passes through fuel control valve 12 to reformer 14. Steam mixer 16 adds a proportional amount of steam to the steam entering the reformer.
Within the reformer 14 fuel is heated in the presence of catalyst within reformer tubes 18 to a midpoint temperature approximating its peak which is measured by temperature sensor 20. It thereafter passes through regeneration tubes 22, usually concentrically within tubes 18 to aid in heating of the incoming fuel and cooling the exiting fuel.
From the reformer the fuel passes through a shift convertor, not shown, and then to fuel cell stack 24 where the chemical energy is directly converted to electricity. The electricity passes through external circuit 26 including load 28 with this load being measured by current sensor 30.
The effluent from the fuel cell containing the excess hydrogen passes through conduit 32 to reformer 14. Here in burner 34 hot gas is formed passing in heat exchange relationship with the tubes 18.
Figure 2 illustrates the characteristics of this system to be controlled. A point, such as 36, represents a particular current flow and fuel flow.
The constant temperature lines 38 show a temperature of 650*C for this condition. Basically with the indicated fuel flow and the removal of a certain amount of hydrogen by the designated current flow, sufficient hydrogen results which when burned in a reformer produce a temperature of 650"C at the temperature sensing point. This represents a hydrogen utilization of about 80 percent as indicated by hydrogen utilization curves 40. Point 42 represents a higher load and a higher fuel flow, but again operation on the 80 percent utilization curve. This yields reformer temperature of 800*C.
At either of these points increasing the fuel flow for the same current withdrawal results in an increasing reformer temperature and a decreasing fuel utilization. Such overflow therefore uses more fuel than is necessary and represents a decrease in overall plant efficiency. While this is not desirable for the long term it is quite acceptable during transients.
A decrease in fuel flow at a given current results in a decreasing reformer temperature. This results in a decreased conversion of fuel in the reformer, but this is not particularly serious. What is serious, however, is the increased fuel utilization occurring and the concomitant tendency toward starvation of the fuel cell electrodes. It is extremely important therefore to avoid flow deficiencies for a particular load, particularly any below the 95% utilization curve.
While the system is capable of operating throughout a wide range on the illustrated curve, the selected and desirable line of operation is that along the line connecting the points 36 and 42.
It should be noted that in passing from point 36 to point 42 the fuel is to be increased as shown on the curve. Since the reformer temperature must also increase from 650 to 800*C, some over firing is required to supply the heat storage.
On the other hand in passing from point 42 to point 36 a decrease in fuel flow as illustrated on the curve is required. Since the reformer temperature is to be decreased, it is required that there be a further deficiency in flow to permit the decrease in temperature of the reformer. It is this further decrease in flow that has been found to be dangerous in the potential production of hydrogen starvation within the cell. Referring to Figure 1 the current sensed signal is passed through line 50 to a fuel flow summation point 52. This provides an immediate feed forward flow demand which is compared at set point 52 with the sensed flow 54. An error signal passing through line 56 operates actuator 58 to modulate the valve or fuel flow control means 12. Accordingly a tight control loop is supplied which rapidly brings a fuel flow to the fuel flow set point position.
The current sensed signal from current sensor 30 also passes to a first function generator 60. This function generator establishes the nominal temperature set point which would ultimately be desired for operation at the sensed current load. This nominal desired temperature set point passes through line 62 to dynamic compensators 64.
The signal passes in parallel through a first lead/lag compensator 66 and a second lead/lag compensator 68. The first lead/lag compensator is set to have substantial lead action while the second lead/lag compensator is set to have substantial lag action. The output from the two compensators is passed to high select component 70 which passes the higher of the two signals through line 72 to temperature error means 74. The modified set point temperature here is compared to the actual sensed temperature signal through line 76 resulting in an error signal passing through line 78. Proportional and integral action is applied to this error signal by signal conditioner 79. This error signal is modified by conversion apparatus 80 to provide a signal of unity with a zero error. It is accordingly applied in multiplier 82 as a modifier for the feed forward signal to the flow control. This supplies the correction to return the reformer temperature to the desired design value.
Multiplier 84 in the feed forward line will be used for appropriate conversion of the current sensed signal to the level desired for the fuel control. Also in the event of a consistent error in the fuel flow measurement or a consistent variation in the estimation of heating value, the temperature conversion loop would continue to maintain an offset that is other than unity. At such steady state operation multiplier 84 may be modified to remove such offset.
Referring to Figures 3 and 4 the operation of the dynamic compensator 64 is illustrated. An initial nominal temperature set point 86 is indicated. As current suddenly increases, there is a step change to temperature 88 as the new nominal set point temperature. Lead/lag compensator 66 set for substantial lead action produces an output modified signal 90 while lead/lag compensation 68 produces an output signal indicated by line 92. During a later downward transient the nominal temperature set point changes from the value at 88 to that of 94. The output of lead/lag compensator 66 produces the signal indicated by 96 while lead/lag compensator 68 produces the signal indicated by line 98.
The high select apparatus 70 operating on these two signals produces the curve of Figure 4 where the output through line 72 is initially that indicated by 86, thereafter the line 90, 88 and 98.
The enhanced utilization of the temperature measurement as described above reduces reliance on the actual flow measurement. Transient errors induced by flow meter error or variations in fuel heating value are reduced, since the control has increased forces on the result of the inputs.

Claims

Claims
1. In a fuel cell power plant having, fuel supply means for supplying a flow of fuel, a reformer receiving and reforming said flow of fuel, a fuel stack receiving fuel from said reformer, a conduit for conveying fuel cell exhaust containing excess hydrogen to said reformer, a burner for burning said exhaust and said reformer in heat exchange relationship with the fuel supply passing through said reformer; a control system comprising: a current sensor for sensing the electrical load on said fuel cell stack and establishing a current sensed signal; a fuel flow summation point; means for conducting said current sensed signal to said fuel flow summation point as a nominal desired fuel flow signal; a temperature sensor for sensing the temperature of the reformed fuel at said reformer and establishing a temperature sensed signal; a first function generator for setting a nominal desired reformer fuel temperature set point representing the steady state desired temperature as a function of the sensed current; a dynamic compensator for modifying said desired reformer fuel temperature set point to obtain a transient temperature set point comprising, a first lead/lag compensator, a second lead/lag, compensator, one of said lead/lag compensators generating a predominantly lead characteristic signal and the other generating a predominantly lag characteristic signal, and a high select component for selecting and passing - li ¬
the higher signal of said lead characteristic signal and said lag characteristic signal; error means for comparing said higher signal with said sensed temperature signal and establishing a temperature error signal; means for modifying said nominal desired fuel flow signal as a function of by said temperature error signal and establishing a transient desired fuel flow set point signal to said fuel flow summation point; fuel flow sensing means for establishing a fuel flow sensed signal; means for conveying said fuel flow sensed signal to said fuel flow summation point and establishing a fuel flow error signal; and fuel flow control means responsive to said fuel flow error signal for controlling said fuel flow.
2. A control system as in claim 1: conversion means for providing a converted signal of unity for a temperature error of zero; and said means for modifying said nominal desired fuel flow signal comprising multiplication means for multiplying said nominal desired fuel flow signal by said converted signal.
3. A control system as in claim 2: said means for conducting said current sensed signal to said fuel flow summation point being free of proportional or integral action.
4. A control system as in claim 3: a signal conditioner for applying proportional and integral action to said temperature error signal.
PCT/US1990/006097 1989-10-24 1990-10-24 Fuel cell power plant fuel control WO1991006987A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP91900608A EP0508991B1 (en) 1989-10-24 1990-10-24 Fuel cell power plant fuel control
DE69011873T DE69011873T2 (en) 1989-10-24 1990-10-24 FUEL CONTROL OF A FUEL CELL POWER PLANT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/427,223 US5009967A (en) 1989-10-24 1989-10-24 Fuel cell power plant fuel control
US427,223 1989-10-24

Publications (1)

Publication Number Publication Date
WO1991006987A1 true WO1991006987A1 (en) 1991-05-16

Family

ID=23693974

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1990/006097 WO1991006987A1 (en) 1989-10-24 1990-10-24 Fuel cell power plant fuel control

Country Status (8)

Country Link
US (1) US5009967A (en)
EP (1) EP0508991B1 (en)
JP (1) JP2793365B2 (en)
AT (1) ATE110496T1 (en)
DE (1) DE69011873T2 (en)
DK (1) DK0508991T3 (en)
ES (1) ES2064984T3 (en)
WO (1) WO1991006987A1 (en)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4322765C1 (en) * 1993-07-08 1994-06-16 Daimler Benz Ag Dynamic power regulation system for vehicle electric drive unit - regulates power output delivered by fuel cell using correction of oxidant mass flow rate
US5360679A (en) * 1993-08-20 1994-11-01 Ballard Power Systems Inc. Hydrocarbon fueled solid polymer fuel cell electric power generation system
JP3384059B2 (en) * 1993-11-12 2003-03-10 富士電機株式会社 Fuel cell generator
US6186254B1 (en) * 1996-05-29 2001-02-13 Xcelliss Fuel Cell Engines Inc. Temperature regulating system for a fuel cell powered vehicle
JP4000607B2 (en) * 1996-09-06 2007-10-31 トヨタ自動車株式会社 Fuel cell power generation apparatus and method
DE69736245T2 (en) * 1996-11-13 2007-06-14 Minnesota Mining And Manufacturing Company, St. Paul STORAGE AND DISTRIBUTION OF UNDER PRESSURE GASES IN MICROBUBBLES
US6821660B2 (en) * 1998-09-08 2004-11-23 Fideris, Inc. Gas humidification device for operation, testing, and evaluation of fuel cells
US6383671B1 (en) * 1998-09-08 2002-05-07 Lynntech, Inc. Gas humidification device for operation testing and evaluation of fuel cells
US6638652B1 (en) * 1998-10-02 2003-10-28 Toyota Jidosha Kabushiki Kaisha Fuel cell control apparatus
US6641625B1 (en) 1999-05-03 2003-11-04 Nuvera Fuel Cells, Inc. Integrated hydrocarbon reforming system and controls
JP4100533B2 (en) * 1999-05-06 2008-06-11 日産自動車株式会社 Temperature controller for exhaust hydrogen combustor in fuel cell vehicle
JP3532458B2 (en) * 1999-05-24 2004-05-31 本田技研工業株式会社 Fuel reformer for solid oxide fuel cell
US6393354B1 (en) 2000-12-13 2002-05-21 Utc Fuel Cells, Llc Predictive control arrangement for load-following fuel cell-powered applications
JP4753506B2 (en) * 2001-09-28 2011-08-24 大阪瓦斯株式会社 Hydrogen-containing gas generator and method for operating the same
US6989208B2 (en) * 2002-01-28 2006-01-24 Utc Fuel Cells, Llc Fuel cell power plant used as reformate generator
JP4140253B2 (en) * 2002-03-15 2008-08-27 日産自動車株式会社 Fuel reforming system
DE10216691A1 (en) * 2002-04-16 2003-11-06 Ballard Power Systems Long term control of fuel cell installation, takes into account operational parameters, external conditions and results from experience
US6890671B2 (en) * 2002-12-19 2005-05-10 Utc Fuel Cells, Llc Fuel mixing control for fuel cell power plants operating on multiple fuels
US20060134480A1 (en) * 2004-10-07 2006-06-22 Ford Motor Company A sensor assembly for measuring humidity, pressure and temperature
US20070196704A1 (en) * 2006-01-23 2007-08-23 Bloom Energy Corporation Intergrated solid oxide fuel cell and fuel processor
US9190693B2 (en) 2006-01-23 2015-11-17 Bloom Energy Corporation Modular fuel cell system
US7659022B2 (en) * 2006-08-14 2010-02-09 Modine Manufacturing Company Integrated solid oxide fuel cell and fuel processor
US8241801B2 (en) 2006-08-14 2012-08-14 Modine Manufacturing Company Integrated solid oxide fuel cell and fuel processor
US8920997B2 (en) 2007-07-26 2014-12-30 Bloom Energy Corporation Hybrid fuel heat exchanger—pre-reformer in SOFC systems
US8852820B2 (en) 2007-08-15 2014-10-07 Bloom Energy Corporation Fuel cell stack module shell with integrated heat exchanger
WO2009105191A2 (en) 2008-02-19 2009-08-27 Bloom Energy Corporation Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer
US8968958B2 (en) * 2008-07-08 2015-03-03 Bloom Energy Corporation Voltage lead jumper connected fuel cell columns
US8802266B2 (en) * 2009-05-26 2014-08-12 The Invention Science Fund I, Llc System for operating an electrical energy storage device or an electrochemical energy generation device using microchannels based on mobile device states and vehicle states
US20100304259A1 (en) * 2009-05-26 2010-12-02 Searete Llc. A Limited Liability Corporation Of The State Of Delaware Method of operating an electrical energy storage device or an electrochemical energy generation device using high thermal conductivity materials during charge and discharge
US8715875B2 (en) * 2009-05-26 2014-05-06 The Invention Science Fund I, Llc System and method of operating an electrical energy storage device or an electrochemical energy generation device using thermal conductivity materials based on mobile device states and vehicle states
US9433128B2 (en) * 2009-05-26 2016-08-30 Deep Science, Llc System and method of operating an electrical energy storage device or an electrochemical energy generation device, during charge or discharge using microchannels and high thermal conductivity materials
US8440362B2 (en) 2010-09-24 2013-05-14 Bloom Energy Corporation Fuel cell mechanical components
EP2661782B1 (en) 2011-01-06 2018-10-03 Bloom Energy Corporation Sofc hot box components
US9755263B2 (en) 2013-03-15 2017-09-05 Bloom Energy Corporation Fuel cell mechanical components
EP3061146B1 (en) 2013-10-23 2018-03-07 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
KR20150072665A (en) * 2013-12-20 2015-06-30 현대자동차주식회사 Apparatus for detecting opening and closing of pilot operated solenoid valve for hydrogen tank and method for the same
JP6566425B2 (en) 2014-02-12 2019-08-28 ブルーム エネルギー コーポレイション STRUCTURE AND METHOD FOR FUEL CELL SYSTEM WITH MULTIPLE FUEL CELLS AND POWER ELECTRONICS POWERING A LOAD IN PARALLEL CONSIDERING INTEGRATED ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY
US10651496B2 (en) 2015-03-06 2020-05-12 Bloom Energy Corporation Modular pad for a fuel cell system
US11398634B2 (en) 2018-03-27 2022-07-26 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2119949A1 (en) * 1970-12-31 1972-08-11 United Aircraft Corp
JPS58133782A (en) * 1982-02-01 1983-08-09 Hitachi Ltd Control system of fuel cell power generating plant
JPS60107268A (en) * 1983-11-15 1985-06-12 Toshiba Corp Control system for fuel cell power generation plant
JPS61101970A (en) * 1984-10-25 1986-05-20 Toshiba Corp Fuel flow rate control device for fuel cell generation plant
JPS61233979A (en) * 1985-04-10 1986-10-18 Toshiba Corp Controller of fuel cell power generating plant
JPS634565A (en) * 1986-06-24 1988-01-09 Toshiba Corp Fuel cell power generating system
JPS63292575A (en) * 1987-05-26 1988-11-29 Toshiba Corp Fuel cell power generating system
JPS6448380A (en) * 1987-08-19 1989-02-22 Toshiba Corp Fuel cell power generating plant

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3343991A (en) * 1966-02-16 1967-09-26 Allis Chalmers Mfg Co Control for a system with a parabolic relationship between a parameter and an output
US3585077A (en) * 1968-11-19 1971-06-15 United Aircraft Corp Reformer fuel flow control
US4046956A (en) * 1976-05-27 1977-09-06 United Technologies Corporation Process for controlling the output of a selective oxidizer
DE3438780A1 (en) * 1984-10-23 1986-04-24 Hüls AG, 4370 Marl METHOD FOR THE PRODUCTION OF CABLE COMPOUNDS

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2119949A1 (en) * 1970-12-31 1972-08-11 United Aircraft Corp
JPS58133782A (en) * 1982-02-01 1983-08-09 Hitachi Ltd Control system of fuel cell power generating plant
JPS60107268A (en) * 1983-11-15 1985-06-12 Toshiba Corp Control system for fuel cell power generation plant
JPS61101970A (en) * 1984-10-25 1986-05-20 Toshiba Corp Fuel flow rate control device for fuel cell generation plant
JPS61233979A (en) * 1985-04-10 1986-10-18 Toshiba Corp Controller of fuel cell power generating plant
JPS634565A (en) * 1986-06-24 1988-01-09 Toshiba Corp Fuel cell power generating system
JPS63292575A (en) * 1987-05-26 1988-11-29 Toshiba Corp Fuel cell power generating system
JPS6448380A (en) * 1987-08-19 1989-02-22 Toshiba Corp Fuel cell power generating plant

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 003, no. 246 (E - 769)<5394> 8 June 1989 (1989-06-08) *
PATENT ABSTRACTS OF JAPAN vol. 007, no. 247 (E - 208)<1392> 2 November 1983 (1983-11-02) *
PATENT ABSTRACTS OF JAPAN vol. 009, no. 258 (E - 350)<1981> 16 October 1985 (1985-10-16) *
PATENT ABSTRACTS OF JAPAN vol. 010, no. 283 (E - 620)<3051> 26 September 1986 (1986-09-26) *
PATENT ABSTRACTS OF JAPAN vol. 011, no. 077 (E - 487)<2524> 7 March 1987 (1987-03-07) *
PATENT ABSTRACTS OF JAPAN vol. 012, no. 204 (E - 620)<3051> 11 June 1988 (1988-06-11) *
PATENT ABSTRACTS OF JAPAN vol. 013, no. 123 (E - 733)<3471> 27 March 1989 (1989-03-27) *

Also Published As

Publication number Publication date
ES2064984T3 (en) 1995-02-01
US5009967A (en) 1991-04-23
ATE110496T1 (en) 1994-09-15
DE69011873T2 (en) 1995-04-13
EP0508991B1 (en) 1994-08-24
DK0508991T3 (en) 1995-02-13
JPH05504436A (en) 1993-07-08
EP0508991A1 (en) 1992-10-21
DE69011873D1 (en) 1994-09-29
JP2793365B2 (en) 1998-09-03

Similar Documents

Publication Publication Date Title
US5009967A (en) Fuel cell power plant fuel control
US6585785B1 (en) Fuel processor apparatus and control system
KR20190112092A (en) Methods and systems for providing hydrogen, electricity, and coproduction
JPS59213601A (en) Control device of reforming reaction
JPS5923066B2 (en) Fuel cell power generator equipped with fuel processing means
US6818336B2 (en) Fuel control for fuel-processor steam generation in low temperature fuel cell power plant
JP2009081052A (en) Solid oxide fuel cell power generation system and operation control method of solid oxide fuel cell power generation system
JP2001165431A (en) Apparatus for controlling air-fuel ratio of reformer for fuel cell
JPS6056374A (en) Fuel flow controlling device for fuel cell
JP2533616B2 (en) Combustion control device for catalytic combustor for fuel cell
JPS6229868B2 (en)
JPS6318307B2 (en)
JPS6345763A (en) Operation controller of fuel cell power generating plant
JPH03167759A (en) Catalyst temperature controller of fuel reformer for use in fuel cell
JPH04284365A (en) Fuel cell power generating device
JPH079813B2 (en) Fuel cell power plant
JPS63254675A (en) Fuel cell power generating system
JPS62119869A (en) Control system for fuel cell power generation plant
JPS6345764A (en) Operating controller of fuel cell power generating plant
JP2009238622A (en) Solid oxide fuel cell power generation system and its operation control method
JPH0556628B2 (en)
JPS62285369A (en) Fuel cell power generation plant
JP6492873B2 (en) Fuel cell system
JPH02213056A (en) Fuel cell power generating plant
JPS63119164A (en) Fuel cell generating system

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA DK JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE

WWE Wipo information: entry into national phase

Ref document number: 1991900608

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: CA

WWP Wipo information: published in national office

Ref document number: 1991900608

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1991900608

Country of ref document: EP