WO1989006681A1 - Lubrifiant et procede de compoundage dudit lubrifiant - Google Patents
Lubrifiant et procede de compoundage dudit lubrifiant Download PDFInfo
- Publication number
- WO1989006681A1 WO1989006681A1 PCT/US1988/000076 US8800076W WO8906681A1 WO 1989006681 A1 WO1989006681 A1 WO 1989006681A1 US 8800076 W US8800076 W US 8800076W WO 8906681 A1 WO8906681 A1 WO 8906681A1
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- WO
- WIPO (PCT)
- Prior art keywords
- amount
- present
- composition
- less
- molybdenum disulfide
- Prior art date
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/72—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
- F42B12/76—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the casing
- F42B12/80—Coatings
- F42B12/82—Coatings reducing friction
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
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- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
- C10M101/025—Petroleum fractions waxes
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- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
- C10M103/02—Carbon; Graphite
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- C10M103/06—Metal compounds
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- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/22—Carboxylic acids or their salts
- C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
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- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10N2040/32—Wires, ropes or cables lubricants
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/34—Lubricating-sealants
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/36—Release agents or mold release agents
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/40—Generators or electric motors in oil or gas winning field
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- C10N2040/42—Flashing oils or marking oils
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/50—Medical uses
Definitions
- This invention relates to lubricants and, more particularly, to lubricating compositions especially adapted for use in conjunction with grease and oil as additives and with firearm projectiles as coatings, and methods of compounding such lubricants.
- leading is the phenomenon of lead from the bullet being deposited, by melting or otherwise, on the interior surfaces of the gun barrel. When this occurs, it is difficult to fire the bullets accurately and consistently even with exactly matched loads in a firearm even from a fixed position.
- commercial ammunition manufacturers and individual hand loaders have adopted various expedients.
- One of these consists of jacketing the lead bullet with gilding metal, a copper base alloy nominally containing 5 percent zinc.
- jacketed bullet is a significant advance in the art, it too has disadvantages, the more important of which includes the expensiveness and "copper fouling", i.e., the transference of copper from the bullet to the inner surface of the barrel.
- copper fouling i.e., the transference of copper from the bullet to the inner surface of the barrel.
- Aluminum jacketed bullets have been introduced for pistol and revolvers to solve the leading problem at reduced cost and yet allow suitable upset upon impact. Yet, this round is not suitable for rifles where bullet velocities are high enough to cause aluminum fouling.
- the lubricant of the present invention is a modified wax lubricant comprising a combination of petroleum and silicone oil metallic soap greases, beeswax and graphite and molybdenum disulfide.
- the greases and molybdenum disulfide are mixed and heated at an elevated temperature for a period of time. Then, the temperature is lowered and beeswax and graphite are added and blended at the lower temperature for a period of time.
- the resulting lubricant composition yields superior results. Firing bullets coated with this composition results in lowered gun barrel temperatures, tighter and consistent target patterns, and litte or no gun barrel fouling. Moreover, the antifouling characteristics of the composition result in the cleaning of the gun firing mechanism. Also, when coating bullets with the composition in automatic or semi-automatic bullet lubrication - application machinery, the machinery is cleaned and kept clean during operation. No other beeswax-containing bullet lubricant is known to be so characterized.
- the composition may be formulated from basic ingredients such as molybdenum disulfide powder, mineral oil, silicone oil such as phenyl-methyl-silicone oil, and metallic soap grease such as lithium soap grease. Alternately, it may be formulated from commercially-avaliable blended grease and paste lubricating products. In the latter category, MOLYKOTE BR-2 PLUS (a molybdenum disulfide-containing mineral oil-lithium soap base grease), MOLYKOTE 44 (a silicone oil thickened with lithium soap), and MOLYKOTE G-n (a molybdenum disulfide-containing mineral oil base paste) manufactured by Dow Corning of Midland, Michigan, U.S.A. are suitable.
- molybdenum disulfide powder such as MOLYKOTE Z powder from Dow Corning
- the preferred combination of the above ingredients is (by weight percent): 9-16X molybdenum disulfide; 13-20X mineral oil; 17-25X silicone oil; and 39-52X metallic soap grease.
- This initial composition is then preferably blended with 5-28X beeswax and 7-42X microfine graphite.
- the total amount of molybdenum disulfide present in the initial composition should be greater than about 5X and less than about 24X.
- the total amount of mineral oil present in the initial composition should be greater than about 10X and less than about 32X.
- the total amount of silicone oil present in the initial composition should be greater than about 13X and less than about 31%.
- the total amount of metallic soap grease present in the initial composition should be greater than about 34X and less than about 61X.
- Example E is particulary outstanding and far superior to any bullet lubricant known to the inventor. These examples were formulated using the MOLYKOTE brand products previously identified.
- Table II lists examples of final composition variations, in weight per cent, that are satisfactory. These examples include, as representative, Example E from Table I as the "Lubricating Composition".
- Table III converts the Table II data to volume per cent to illustrate the substantial portion of beeswax in the final composition. That such a high-proportioned beeswax- containing lubricant possesses such outstanding antifouling characteristics is in marked contrast to the general trend in thinking concerning bullet lubricants. This general trend identifies beeswax as an undesirable ingredient because of residue build-up.
- Use of bullets coated with the final composition herein cleans residue-fouled coating machinery, firing mechanisms and gun barrels, and results in reducing gun barrel temperatures in barrels over-heated by firing uncoated bullets.
- the ingredients making up the initial composition (such as those identified in Table I) are heated to 350-400 degrees F. for several minutes while being stirred continuously. A preferred heating period is about 5 minutes. The temperature is then reduced to 150-350 degrees F. and beeswax and microfine graphite are added. This final composition is blended for a short period, preferably about 2 minutes and then allowed to cool. The initial composition must be cooled as specified above before addition of the beeswax to yield a satisfactory final composition having the desired characteristics described.
- carnuba wax may be added, along with beeswax, in compounding the final composition.
- the addition of carnuba wax will harden a bullet coating and may be desirable for some applications.
- On a volume basis up to 25X carnuba wax may be added to the final composition. More than 25X volume addition results in cracking of the applied bullet coating.
- a preferred range would be 10-20 volume per cent.
- the lubricant of this invention is effective at concentrations of 1 X by volume up to 50X by volume. At the higher concentrations, its addition renders the resulting combination more and more pasty.
- a preferred concentration in lubricating oils is between about two oz. per quart of oil to two oz. per six quarts of oil.
- the addition of the lubricant as an additive to greases and oils is accomplished at an elevated temperature, preferably 150- 200 degrees F.
- the lubricant and the grease or oil to which it is to be added are separately pre-heated, and then the two constituents are blended and then allowed to cool to room temperature. The blend remains admixed thereafter.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Lubricants (AREA)
Abstract
La présente invention se rapporte à un lubrifiant à base de cire ayant subi un compoundage pour être utilisé comme lubrifiant pour balles d'armes à feu mais également comme additif pour des graisses et des huiles lubrifiantes d'usage général. Ledit lubrifiant comprend une combinaison de graisses de savon métallique à base d'huile de silicone et de pétrole, de cire d'abeilles, de graphite et de bisulfure de molybdène.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1988/000076 WO1989006681A1 (fr) | 1986-09-29 | 1988-01-15 | Lubrifiant et procede de compoundage dudit lubrifiant |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/912,413 US4731189A (en) | 1986-09-29 | 1986-09-29 | Bullet lubricant and method of compounding said lubricant |
PCT/US1988/000076 WO1989006681A1 (fr) | 1986-09-29 | 1988-01-15 | Lubrifiant et procede de compoundage dudit lubrifiant |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1989006681A1 true WO1989006681A1 (fr) | 1989-07-27 |
Family
ID=26777607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1988/000076 WO1989006681A1 (fr) | 1986-09-29 | 1988-01-15 | Lubrifiant et procede de compoundage dudit lubrifiant |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO1989006681A1 (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000025084A1 (fr) * | 1998-10-26 | 2000-05-04 | Lambeth Properties Limited | Projectiles non mortels |
WO2001029158A1 (fr) * | 1999-10-22 | 2001-04-26 | Sergei Nikolaevich Alexandrov | Composition lubrifiante |
CH700584B1 (de) * | 2006-12-11 | 2010-09-30 | Saltech Ag | Schusswaffengeschoss. |
EP2285941A1 (fr) * | 2008-04-09 | 2011-02-23 | Saint-gobain Performance Plastics Corporation | Composition de graisse de palier |
GB2553340A (en) * | 2016-09-02 | 2018-03-07 | Illinois Tool Works | Wire Rope lubricant |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2560051A (en) * | 1942-10-14 | 1951-07-10 | Firestone Tire & Rubber Co | Friction material lubricant |
US3015623A (en) * | 1960-06-24 | 1962-01-02 | Sinclair Refining Co | Lithium base grease containing lead oleate, sulfurized lard oil and molybdenum disulfide |
US3097169A (en) * | 1960-05-27 | 1963-07-09 | Leslie B Hall | Solid bullet lubricant |
US3170878A (en) * | 1961-03-03 | 1965-02-23 | Socony Mobil Oil Co Inc | Grease composition |
US3933657A (en) * | 1974-09-12 | 1976-01-20 | Texaco Inc. | Lubricant with synergistic extreme pressure additives |
US4363737A (en) * | 1981-06-15 | 1982-12-14 | Alvaro Rodriguez | Lubrication pastes |
-
1988
- 1988-01-15 WO PCT/US1988/000076 patent/WO1989006681A1/fr unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2560051A (en) * | 1942-10-14 | 1951-07-10 | Firestone Tire & Rubber Co | Friction material lubricant |
US3097169A (en) * | 1960-05-27 | 1963-07-09 | Leslie B Hall | Solid bullet lubricant |
US3015623A (en) * | 1960-06-24 | 1962-01-02 | Sinclair Refining Co | Lithium base grease containing lead oleate, sulfurized lard oil and molybdenum disulfide |
US3170878A (en) * | 1961-03-03 | 1965-02-23 | Socony Mobil Oil Co Inc | Grease composition |
US3933657A (en) * | 1974-09-12 | 1976-01-20 | Texaco Inc. | Lubricant with synergistic extreme pressure additives |
US4363737A (en) * | 1981-06-15 | 1982-12-14 | Alvaro Rodriguez | Lubrication pastes |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000025084A1 (fr) * | 1998-10-26 | 2000-05-04 | Lambeth Properties Limited | Projectiles non mortels |
US6371028B2 (en) | 1998-10-26 | 2002-04-16 | Michael Ernest Saxby | Projectiles |
WO2001029158A1 (fr) * | 1999-10-22 | 2001-04-26 | Sergei Nikolaevich Alexandrov | Composition lubrifiante |
CH700584B1 (de) * | 2006-12-11 | 2010-09-30 | Saltech Ag | Schusswaffengeschoss. |
EP2285941A1 (fr) * | 2008-04-09 | 2011-02-23 | Saint-gobain Performance Plastics Corporation | Composition de graisse de palier |
EP2285941A4 (fr) * | 2008-04-09 | 2011-12-07 | Saint Gobain Performance Plast | Composition de graisse de palier |
US8496381B2 (en) | 2008-04-09 | 2013-07-30 | Saint-Gobain Performance Plastics Corporation | Bearings |
US8703675B2 (en) | 2008-04-09 | 2014-04-22 | Saint-Gobain Performance Plastics Corporation | Bearing grease composition |
US9657776B2 (en) | 2008-04-09 | 2017-05-23 | Saint-Gobain Performance Plastics Corporation | Bearings |
GB2553340A (en) * | 2016-09-02 | 2018-03-07 | Illinois Tool Works | Wire Rope lubricant |
WO2018045337A1 (fr) * | 2016-09-02 | 2018-03-08 | Illinois Tool Works Inc. | Lubrifiant pour câble métallique |
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