WO1987006104A1 - Ameliorations apportees a des produits du tabac - Google Patents
Ameliorations apportees a des produits du tabac Download PDFInfo
- Publication number
- WO1987006104A1 WO1987006104A1 PCT/GB1986/000749 GB8600749W WO8706104A1 WO 1987006104 A1 WO1987006104 A1 WO 1987006104A1 GB 8600749 W GB8600749 W GB 8600749W WO 8706104 A1 WO8706104 A1 WO 8706104A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tobacco
- zinc
- tobacco products
- iron
- ferric oxide
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
Definitions
- the present invention relates to tobacco products.
- the present invention seeks to provide an improved form of tobacco product.
- tobacco used herein includes not only tobacco but also other substances and tobacco-like substances which may be smoked.
- the present invention provides a mixture comprising tobacco and at least one substance selected from iron and zinc compounds of the type that are reduced to iron or zinc respectively on exposure to high temperatures.
- ferric oxide Under the conditions existing in the combustion area of a tobacco product which is being smoked, such as a cigarette, incorporating for example ferric oxide in particulate form, the ferric oxide is reduced to iron. In this state immediately after reduction the iron is pure and highly reactive, dissociating water vapour into hydrogen and oxygen and also causing the preferential combination of nitrogen with hydrogen, rather than with oxygen and carbon, to form ammonia in trace quantities which vapourise. Thus the combination of nitrogen and carbon to form, for example, pyridenes is reduced if not eliminated.
- the use alternatively or additionally of zinc oxide produces a similar effect and increases the nicotine yield in the resulting smoke.
- ferric oxide and/or zinc oxide also has the unexpected effect of removing the less desirable "taste” or "after taste” aspects of the tobacco products.
- ferric oxide and/or zince oxide are required and, since this compound is an inert, non-toxic, naturally occuring compound which is available in considerable quantities the addition of ferric oxide and/or zinc oxide does not in itself promote any harmful after effects.
- the most effective way of mixing the zinc oxide in ferric oxide with tobacco is to form the zinc oxide or ferric oxide in solution in e.g. water and spray the solution onto the tobacco. As the tobacco dries, the zinc oxide or ferric oxide is left as a deposit on the tobacco.
Abstract
La consommmation des produits du tabac, tels que les cigarettes, engendre des composés carcinogènes constitués d'azote et de carbone. L'addition de petites quantités d'oxyde de zinc et d'oxyde ferrique au tabac permet de réduire ou d'éliminer ces composés carcinogènes et présente aussi l'avantage d'éliminer "l'après-goût" vicié associé aux cigarettes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8609603 | 1986-04-19 | ||
GB868609603A GB8609603D0 (en) | 1986-04-19 | 1986-04-19 | Tobacco products |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1987006104A1 true WO1987006104A1 (fr) | 1987-10-22 |
Family
ID=10596494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1986/000749 WO1987006104A1 (fr) | 1986-04-19 | 1986-12-08 | Ameliorations apportees a des produits du tabac |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0265443A1 (fr) |
AU (1) | AU6771987A (fr) |
GB (1) | GB8609603D0 (fr) |
WO (1) | WO1987006104A1 (fr) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000040104A1 (fr) * | 1998-12-30 | 2000-07-13 | Choi Sang Gu | Loess ajoute au tabac et son procede de fabrication |
WO2003086112A1 (fr) * | 2002-04-08 | 2003-10-23 | Philip Morris Products S.A. | Utilisation de composes d'oxyhydroxyde pour la reduction du monoxyde de carbone dans la fumee principale d'une cigarette |
WO2003086115A1 (fr) * | 2002-04-12 | 2003-10-23 | Philip Morris Products S.A. | Additifs partiellement reduits sous forme de nanoparticules |
US6782892B2 (en) | 2002-08-30 | 2004-08-31 | Philip Morris Usa Inc. | Manganese oxide mixtures in nanoparticle form to lower the amount of carbon monoxide and/or nitric oxide in the mainstream smoke of a cigarette |
WO2004110189A2 (fr) | 2003-06-13 | 2004-12-23 | Philip Morris Products S.A. | Enveloppe de cigarette a matiere de remplissage catalytique et ses procedes de fabrication |
US7011096B2 (en) | 2001-08-31 | 2006-03-14 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7028694B2 (en) | 2003-08-22 | 2006-04-18 | Philip Morris Usa Inc. | Method for dispersing powder materials in a cigarette rod |
US7152609B2 (en) | 2003-06-13 | 2006-12-26 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette |
US7165553B2 (en) | 2003-06-13 | 2007-01-23 | Philip Morris Usa Inc. | Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette |
US20070113862A1 (en) * | 2001-08-31 | 2007-05-24 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce tobacco smoke constituents such as carbon monoxide |
US7243658B2 (en) | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7509961B2 (en) | 2003-10-27 | 2009-03-31 | Philip Morris Usa Inc. | Cigarettes and cigarette components containing nanostructured fibril materials |
US7640936B2 (en) | 2003-10-27 | 2010-01-05 | Philip Morris Usa Inc. | Preparation of mixed metal oxide catalysts from nanoscale particles |
US7677254B2 (en) | 2003-10-27 | 2010-03-16 | Philip Morris Usa Inc. | Reduction of carbon monoxide and nitric oxide in smoking articles using iron oxynitride |
US7712471B2 (en) | 2003-10-27 | 2010-05-11 | Philip Morris Usa Inc. | Methods for forming transition metal oxide clusters and smoking articles comprising transition metal oxide clusters |
US7878211B2 (en) | 2005-02-04 | 2011-02-01 | Philip Morris Usa Inc. | Tobacco powder supported catalyst particles |
US7934510B2 (en) | 2003-10-27 | 2011-05-03 | Philip Morris Usa Inc. | Cigarette wrapper with nanoparticle spinel ferrite catalyst and methods of making same |
US7950400B2 (en) | 2003-10-27 | 2011-05-31 | Philip Morris Usa Inc. | Tobacco cut filler including metal oxide supported particles |
US8006703B2 (en) | 2003-10-27 | 2011-08-30 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
US9107452B2 (en) | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE537734C (de) * | 1929-03-27 | 1931-11-06 | Wendt S Cigarrenfabriken Akt G | Verfahren zur Entfernung des Nikotins aus Tabakrauch |
FR2117355A5 (fr) * | 1970-12-03 | 1972-07-21 | Liggett & Myers Inc | |
DE2227832A1 (de) * | 1971-06-11 | 1973-01-11 | British American Tobacco Co | Rauchmaterial |
DE2525276A1 (de) * | 1975-06-06 | 1977-01-13 | Brasec Gmbh Chemisch Physikali | Verfahren zur entgiftung von tabak |
-
1986
- 1986-04-19 GB GB868609603A patent/GB8609603D0/en active Pending
- 1986-12-08 WO PCT/GB1986/000749 patent/WO1987006104A1/fr unknown
- 1986-12-08 AU AU67719/87A patent/AU6771987A/en not_active Abandoned
- 1986-12-08 EP EP19870900190 patent/EP0265443A1/fr not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE537734C (de) * | 1929-03-27 | 1931-11-06 | Wendt S Cigarrenfabriken Akt G | Verfahren zur Entfernung des Nikotins aus Tabakrauch |
FR2117355A5 (fr) * | 1970-12-03 | 1972-07-21 | Liggett & Myers Inc | |
DE2227832A1 (de) * | 1971-06-11 | 1973-01-11 | British American Tobacco Co | Rauchmaterial |
DE2525276A1 (de) * | 1975-06-06 | 1977-01-13 | Brasec Gmbh Chemisch Physikali | Verfahren zur entgiftung von tabak |
Cited By (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000040104A1 (fr) * | 1998-12-30 | 2000-07-13 | Choi Sang Gu | Loess ajoute au tabac et son procede de fabrication |
US7011096B2 (en) | 2001-08-31 | 2006-03-14 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette |
US20070113862A1 (en) * | 2001-08-31 | 2007-05-24 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce tobacco smoke constituents such as carbon monoxide |
US7017585B2 (en) | 2001-08-31 | 2006-03-28 | Philip Morris Usa Inc. | Oxidant/catalyst nanoparticles to reduce tobacco smoke constituents such as carbon monoxide |
AU2003208997B2 (en) * | 2002-04-08 | 2009-01-22 | Philip Morris Products, S.A. | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
WO2003086112A1 (fr) * | 2002-04-08 | 2003-10-23 | Philip Morris Products S.A. | Utilisation de composes d'oxyhydroxyde pour la reduction du monoxyde de carbone dans la fumee principale d'une cigarette |
EP1494549A1 (fr) * | 2002-04-08 | 2005-01-12 | Philip Morris Products S.A. | Utilisation de composes d'oxyhydroxyde pour la reduction du monoxyde de carbone dans la fumee principale d'une cigarette |
EP1494549A4 (fr) * | 2002-04-08 | 2011-01-05 | Philip Morris Prod | Utilisation de composes d'oxyhydroxyde pour la reduction du monoxyde de carbone dans la fumee principale d'une cigarette |
JP2005527205A (ja) * | 2002-04-08 | 2005-09-15 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | シガレットの主流煙における一酸化炭素を減少させるためのオキシヒドロキシド化合物の使用 |
CN100353875C (zh) * | 2002-04-08 | 2007-12-12 | 菲利普莫里斯生产公司 | 切割填充烟草组合物、香烟和制造香烟的方法 |
US6769437B2 (en) | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
US7228862B2 (en) | 2002-04-08 | 2007-06-12 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
KR100961605B1 (ko) * | 2002-04-12 | 2010-06-07 | 필립모리스 프로덕츠 에스.에이. | 부분적으로 환원된 나노입자 첨가제를 포함하는 절단 충전재 조성물 및 궐련 |
US7168431B2 (en) | 2002-04-12 | 2007-01-30 | Philip Morris Usa Inc. | Partially reduced nanoparticle additives to lower the amount of carbon monoxide and/or nitric oxide in the mainstream smoke of a cigarette |
WO2003086115A1 (fr) * | 2002-04-12 | 2003-10-23 | Philip Morris Products S.A. | Additifs partiellement reduits sous forme de nanoparticules |
EP1494551A4 (fr) * | 2002-04-12 | 2011-01-19 | Philip Morris Prod | Additifs partiellement reduits sous forme de nanoparticules |
CN1324999C (zh) * | 2002-04-12 | 2007-07-11 | 菲利普莫里斯生产公司 | 降低香烟烟雾中一氧化碳和一氧化氮数量的纳米颗粒添加剂 |
EP1494551A1 (fr) * | 2002-04-12 | 2005-01-12 | Philip Morris Products S.A. | Additifs partiellement reduits sous forme de nanoparticules |
US6782892B2 (en) | 2002-08-30 | 2004-08-31 | Philip Morris Usa Inc. | Manganese oxide mixtures in nanoparticle form to lower the amount of carbon monoxide and/or nitric oxide in the mainstream smoke of a cigarette |
US7243658B2 (en) | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7152609B2 (en) | 2003-06-13 | 2006-12-26 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette |
US9119421B2 (en) | 2003-06-13 | 2015-09-01 | Philip Morris Usa Inc. | Cigarette wrapper with printed catalyst |
US9107452B2 (en) | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
WO2004110189A2 (fr) | 2003-06-13 | 2004-12-23 | Philip Morris Products S.A. | Enveloppe de cigarette a matiere de remplissage catalytique et ses procedes de fabrication |
US7165553B2 (en) | 2003-06-13 | 2007-01-23 | Philip Morris Usa Inc. | Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7568485B2 (en) | 2003-08-22 | 2009-08-04 | Philip Morris Usa Inc. | System for dispersing powder materials in a cigarette rod |
US7028694B2 (en) | 2003-08-22 | 2006-04-18 | Philip Morris Usa Inc. | Method for dispersing powder materials in a cigarette rod |
US7997281B2 (en) | 2003-10-27 | 2011-08-16 | Philip Morris Usa Inc. | Reduction of carbon monoxide and nitric oxide in smoking articles using nanoscale particles and/or clusters of nitrided transition metal oxides |
US8011374B2 (en) | 2003-10-27 | 2011-09-06 | Philip Morris Usa, Inc. | Preparation of mixed metal oxide catalysts from nanoscale particles |
US10743579B2 (en) | 2003-10-27 | 2020-08-18 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
US7934510B2 (en) | 2003-10-27 | 2011-05-03 | Philip Morris Usa Inc. | Cigarette wrapper with nanoparticle spinel ferrite catalyst and methods of making same |
US7950400B2 (en) | 2003-10-27 | 2011-05-31 | Philip Morris Usa Inc. | Tobacco cut filler including metal oxide supported particles |
US7677254B2 (en) | 2003-10-27 | 2010-03-16 | Philip Morris Usa Inc. | Reduction of carbon monoxide and nitric oxide in smoking articles using iron oxynitride |
US8006703B2 (en) | 2003-10-27 | 2011-08-30 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
US7712471B2 (en) | 2003-10-27 | 2010-05-11 | Philip Morris Usa Inc. | Methods for forming transition metal oxide clusters and smoking articles comprising transition metal oxide clusters |
US8434495B2 (en) | 2003-10-27 | 2013-05-07 | Philip Morris Usa Inc. | Tobacco cut filler including metal oxide supported particles |
US8496012B2 (en) | 2003-10-27 | 2013-07-30 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
US7640936B2 (en) | 2003-10-27 | 2010-01-05 | Philip Morris Usa Inc. | Preparation of mixed metal oxide catalysts from nanoscale particles |
US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
US9351520B2 (en) | 2003-10-27 | 2016-05-31 | Philip Morris Usa Inc. | Cigarettes and cigarette components containing nanostructured fibril materials |
US7509961B2 (en) | 2003-10-27 | 2009-03-31 | Philip Morris Usa Inc. | Cigarettes and cigarette components containing nanostructured fibril materials |
US8631803B2 (en) | 2005-02-04 | 2014-01-21 | Philip Morris Usa Inc. | Tobacco powder supported catalyst particles |
US7878211B2 (en) | 2005-02-04 | 2011-02-01 | Philip Morris Usa Inc. | Tobacco powder supported catalyst particles |
Also Published As
Publication number | Publication date |
---|---|
EP0265443A1 (fr) | 1988-05-04 |
GB8609603D0 (en) | 1986-05-21 |
AU6771987A (en) | 1987-11-09 |
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