WO1987003893A1 - Compositions a base d'ether de polyphenylene et de polyamide presentant une modification de leurs caracteristiques de resistance aux chocs - Google Patents

Compositions a base d'ether de polyphenylene et de polyamide presentant une modification de leurs caracteristiques de resistance aux chocs Download PDF

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Publication number
WO1987003893A1
WO1987003893A1 PCT/US1986/002725 US8602725W WO8703893A1 WO 1987003893 A1 WO1987003893 A1 WO 1987003893A1 US 8602725 W US8602725 W US 8602725W WO 8703893 A1 WO8703893 A1 WO 8703893A1
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WO
WIPO (PCT)
Prior art keywords
composition
crosslinked
shell
polyamide
resin
Prior art date
Application number
PCT/US1986/002725
Other languages
English (en)
Inventor
Gary Mell Bates
Gregory Robert Chambers
Sai-Pei Ting
Original Assignee
General Electric Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Company filed Critical General Electric Company
Publication of WO1987003893A1 publication Critical patent/WO1987003893A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M25/00—Catheters; Hollow probes
    • A61M25/01—Introducing, guiding, advancing, emplacing or holding catheters
    • A61M25/0105—Steering means as part of the catheter or advancing means; Markers for positioning
    • A61M25/0111—Aseptic insertion devices
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M25/00—Catheters; Hollow probes
    • A61M25/0043—Catheters; Hollow probes characterised by structural features
    • A61M2025/0062—Catheters; Hollow probes characterised by structural features having features to improve the sliding of one part within another by using lubricants or surfaces with low friction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/905—Polyphenylene oxide

Definitions

  • compositions comprising a combination of polyphenylene ether resin and polyamide resin can be impact modified with a compound comprised of a crosslinked butylacrylate core/crosslinked styrenic shell which is particularly effective for thermoplastic applications requiring thermal stability.
  • Polyphenylene ether resins have been modified with polyamide resins to provide a wide variety of beneficial properties such as excellent heat resistance, chemical resistance, impact strength, hydrolytic stability and dimensional stability compared to either unmodified resin alone.
  • polyphenylene ether-polyamide compositions have found great utility in thermoplastic applications which take advantage of such properties. Exterior automotive applications such as body panels and wheel covers all benefit from the improved thermal properties of polyphenylene ether-polyamide compositions (PPE/PA compositions).
  • PPE/PA compositions polyphenylene ether-polyamide compositions
  • a satisfactory thermoplastic must be processed at elevated extrusion and molding temperatures. Such parts also experience high temperature finishing processes such as oven baking for paint and other finishes.
  • PPE/PA compositions also require that the resin be impact modified to provide adequate performance.
  • Impact modification of plastics by incorporation of rubber-like modifiers offers many advantages and disadvantages.
  • Conventional impact modifiers for PPE/PA compositions are either costly or ineffective compared to the impact modification system of the present invention.
  • Thermoplastic compositions of the present invention are comprised of: a. a base resin which is a compatible combination of a polyphenylene ether resin and a polyamide resin; and b. a property improving amount of an impact modifying agent having a core/shell structure wherein the core is a crosslinked acrylate such as butyl acrylate and the shell, which surrounds and interpenetrates the core, is a crosslinked styrenic shell.
  • the crosslinked styrenic shell will preferably be crosslinked polystyrene since this material is particularly useful in combination with PPE resins. It is expected that the crosslinked styrenic shell will typically be comprised of greater than 85 weight percent styrene although other monomer components (such as acrylonitrile) may be useful in s ⁇ sll amounts.
  • polystyrene resins and polyamide resins as well as means for providing compatible combinations thereof are described below.
  • the polyamide component comprise a continuous phase in the overall composition and, therefore, typically at least 35 percent by weight of the total PPE-polyamide-modifier composition will be comprised of the polyamide component.
  • the remainder of the composition will be comprised of the PPE and core-shell modifier, in typical weight ratios described below.
  • the preferred modifying component is itself comprised of 40 to 90 weight percent of a crosslinked acylate such as butyl acrylate, which is surrounded and interpenetrated by 60 to 10 weight percent of a crosslinked polystyrene.
  • a crosslinked acylate such as butyl acrylate
  • Polyphenylene ethers are a well known class of compounds sometimes referred to as polyphenylene oxides. Examples of suitable polyphenylene ethers and processes for preparation can be found in U.S Patent Nos. 3,306,874; 3,306,875; 3,257,357; and 3,257,358.
  • Compositions of the present invention will encompass homopolymers, copolymers and graft copolymers obtained by the oxidative coupling of phenolic compounds.
  • the preferred polyphenylene ethers used as base resins in compositions of the present invention will be comprised of units derived from 2,6-dimethyl phenol. Also contemplated are PPE copolymers comprised of units derived from 2,6-dimethyl phenol and 2,3,6-trimethyl phenol.
  • a particularly useful polyphenylene ether would be poly (2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity (I.V.) greater than, approximately 0.10 dl/g as measured in chloroform at 25°C.
  • the I.V. will typically be between 0.40 and 0.50 dl/g.
  • PPE having high glass transition temperatures will ordinarily improve the stiffness of the resin compositions.
  • polyamide resins useful in the practice of the present invention are a generic family of resins known as nylons, characterized by the presence of an amide group (-CONH-).
  • nylons characterized by the presence of an amide group (-CONH-).
  • Nylon-6 and nylon-6,6 are the generally preferred polyamides and are available from a variety of commercial sources.
  • Other polyamides,however, such as nylon-4, nylon-12, nylon-6,10, nylon-6,9 or others such as the amorphous nylons may be useful for particular polyphenylene ether-polyamide applications.
  • the polyamides can be provided by a number of well known processes.
  • Nylon-6 for example, is a polymerization product of caprolactam.
  • Nylon-6,6 is a condensation product of adipic acid and hexamethylenediamine.
  • a nylon-6,6 having an average molecular weight of approximately 10,000 is especially preferred for many useful polyphenylene ether-polyamide thermoplastic applications.
  • Preferred polyamides will typically have a relative viscosity of at least 35, in accordance with ASTM Test Method D789.
  • a corcpatibilizing agent will be employed in the preparation of the composition.
  • the expression "compatibilizing agent” refers to those polyfunctional, non-rubbery compounds which interact with either the polyphenylene ether, the polyamide or both. This interaction may be chemical (e.g. grafting) or physical (e.g. effecting the surface characteristics of the dispersed phases). In either instance the resulting polyphenylene ether-polyamide composition appears to exhibit improved compatibility, particularly as evidenced by enhanced impact strength, mold line strength and/or elongation.
  • compatibilizing agents are well known for polyphenylene ether-polyamide compositions.
  • these compatibilizing agents may be mentioned: liquid diene polymers, epoxy compounds, quinones, oxidized polyolefin waxes, organosilane compounds, and certain polyfunctional organic acids.
  • Suitable polyphenylene ether-polyamide compositions can be provided in the manner taught by U.S. Patent 4,315,086 which is hereby incorporated by reference. In particular, it has been found that a small amount of a material having in its molecule both an anhydride group and a carbon to carbon double bond (e.g. maleic anhydride) is a suitable compatibilizer of polyphenylene ether-polyamide blends. There are, however, many other effective compatibilizing agents.
  • the preferred compositions of the present invention will be comprised of a polyamide resin in an amount equal to or greater than approximately 35 percent by weight of the total composition (i.e. the PPE, PA, and core-shell components taken together).
  • the remaining components will be comprised of the PPE and core-shell impact modifier, and may together account for up to approximately 65 percent by weight of the total composition.
  • the ratio of PPE to core shell modifier may range from approximately 99:1 to 50:50 and will typically range from approximately 75 to 80 parts PPE and 20 to 25 parts core-shell modifier.
  • weight ratios and percentages represent the compositional formulations of the present invention.
  • the order of combining the components to provide final products may be varied as will be described below.
  • the preferable core-shell interpolymer modifiers are those having a crosslinked acrylate rubber core, such as butyl acrylate. Surrounding this crosslinked core is a shell-like structure of crosslinked styrenic resin, preferably styrene, which surrounds and interpenetrates the crosslinked core. Incorporation of small amounts of other monomers such as acrylonitrile and/or methyl methacrylate with styrene in the shell can also provide useful products if the resulting copolymer shell does not cause significant incompatibility with the polyphenylene ether-polyamide matrix. The integrity of such preferable core-shell structures is maintained by the interpenetrating network of the several crosslinked moieties rather than by grafting the structures together.
  • the core-shell interpolymer compositions may be formed by the following type of two-step, sequential polymerization process:
  • acrylate for purposes of the present invention
  • acrylate emulsion polymerizing an acrylate monomer charge (herein designated "acrylate”, for purposes of the present invention), of at least one C 2 -C 10 alkyl acrylate, C 8 -C 22 alkyl (meth) acrylate, or compatible mixtures thereof, in an aqueous polymerization medium in the presence of an effective amount of a suitable di- or polyethyleneically unsaturated crosslinking agent for such type of monomer, with the C 4 -C 8 alkyl acrylates being the preferred acrylate monomers for use in this step;
  • This core-shell product which is used as the interpolymer impact modifier in the PPE-polyamide blends of the present invention generally comprises from about 40% to about 90%, by weight, of at least one of the above-identified crosslinked acrylates, and from about 10% to about 60%, by weight, of the crosslinked styrene component. It contains little graft polymerization between the crosslinked styrenic copolymer components and the crosslinked acrylate polymeric component.
  • the core will comprise 50 to 80 weight percent crosslinked acrylate, based on the weight of crosslinked core and crosslinked shell taken together. Further details regarding this type of polymer composition can be found in the aforementioned U.S. Pat. No. 3,044,731 to A.J.
  • the core-shell interpolymer provided by the foregoing process can be isolated and dried by conventional means and can be provided in powder or pellet form.
  • Typical PPE-polyamide polymer compositions of the present invention will be comprised of approximately 1 to 30 parts by weight of the core-shell interpolymer modifier based upon 100 parts of the polyphenylene ether-polyamide base resin. It is particularly preferred that about 10 to 20 parts by weight of the core-shell interpolymer additive will be used per 100 parts of the PPE-polyamide base resin. When less than about 2 parts additive are utilized, insufficient beneficial effect will be achieved for typical applications. When greater than approximately 20 parts of additives are utilized, little additional benefit is achieved while other advantageous properties may be diminished for certain applications.
  • each of the ingredients could be blended and extruded at once, thereby providing thermoplastic resin having a particular property profile.
  • the polyphenylene ether with or without a compatibilizing agent, could be pre-compounded with the core-shell interpolymer impact modifier. Thereafter, the polyamide resin could be charged to the extruder downstream, at a point sufficient to provide adequate mixing but with minimum risk of degradation due to excess heat.
  • thermoplastic compositions of the present invention thereby providing a variety of useful products.
  • additives such as fillers, pigments and flame retarding compounds
  • specific embodiments of the present invention are taught in the following examples which are not limiting in any way. All parts are by weight unless otherwise indicated. Synthesis of Core-Shell Additives
  • a crosslinked polybutylacrylate core having an interpenetrating, crosslinked polystyrene shell was prepared in a five liter, three-necked flask equipped with a heating/cooling jacket, a Teflon blade agitator, a thermometer and a nitrogen purge.
  • Solution B Sodium Metabisulfite 1.75 g deionized water 27.4 g
  • Solution C Ammonium Persulfate 4.84 g deionized water 76.1 g
  • Solution D styrene 250.6 g divinyl benzene 2.65 g (55% active solution from Dow Chemical)
  • the product latex was coagulated in a solution of 0.25 weight percent CaCl 2 in methanol at a rate of 1600 ml methanol per 800 ml latex.
  • the coagulum was filtered, rinsed with fresh methanol, and dried in a vacuum oven at 60°C.
  • the product had a number average latex particle diameter of 211 nanometers, a swell index in methyl ethyl ketone (MEK) of 8.1 and a percent Gel fraction from MEK extraction of 91.1%.
  • MEK methyl ethyl ketone
  • Preparation B Crosslinked Core/Uncrosslinked Styrene Shell A crosslinked polybutyl acrylate core with an interpenetrating but uncrosslinked styrene shell was provided in the same manner as for Preparation A, except that the divinyl benzene crosslinker in Solution D was eliminated. A product having a final conversion of approximately 97% was recovered as in Preparation A.
  • the product of preparation B had an average latex particle diameter of 203 nanometers, a swell index in MEK of 14.4 and a % Gel from MEK extraction of 63.4%.
  • thermoplastic blends were mixed by a Henschel mixer, extruded by a 28mm Werner & Pfleiderer twin screw extruder having a temperature profile (set) of 480, 520, 550, 550, 556°F, and injection molded into ASTM specimens by a 3 ounce Newbury injection molding machine at a melt temperature of 570°F and a mold temperature of 150°F.
  • the formulations had the compositions shown in Table 1, ports are by weight.
  • Blend 1 (b) 381 106% 96%

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

La résistance aux chocs de compositions thermoplastiques comprenant des combinaisons compatibles d'une résine d'éther de polyphénylène et d'une résine de polyamide, dont on désire améliorer les propriétés de résistance au vieillissement produit par la chaleur, peut être modifiée à l'aide d'un agent modificateur possédant une structure noyau-enveloppe comprenant un noyau en acrylate réticulé et une enveloppe en styrène réticulé.
PCT/US1986/002725 1985-12-20 1986-12-19 Compositions a base d'ether de polyphenylene et de polyamide presentant une modification de leurs caracteristiques de resistance aux chocs WO1987003893A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/811,808 US4681915A (en) 1985-12-20 1985-12-20 Impact modified polyphenylene ether-polyamide compositions
US811,808 1985-12-20

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WO1987003893A1 true WO1987003893A1 (fr) 1987-07-02

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EP (1) EP0252944A1 (fr)
JP (1) JPS63501961A (fr)
WO (1) WO1987003893A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0299619A2 (fr) * 1987-06-12 1989-01-18 Sumitomo Chemical Company, Limited Composition de résine thermoplastique
EP0322560A2 (fr) * 1987-12-30 1989-07-05 General Electric Company Compositions comprenant un élastomère thermoplastique, copolymère réticulé à partir d'acrylates et de composés vinylaromatiques et des polyamides
EP0529378A1 (fr) * 1991-08-24 1993-03-03 BASF Aktiengesellschaft Masse à mouler thermoplastique à base de polyamide et de polyphénylène ether
US5516855A (en) * 1987-11-04 1996-05-14 General Electric Company Amide-ester copolymers and process for the preparation thereof

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4923924A (en) * 1985-12-06 1990-05-08 Borg-Warner Chemicals, Inc. Thermoplastic impact modified polyamide-polyphenylene ether composition
DE3614899A1 (de) * 1986-05-02 1987-11-05 Bayer Ag Flammfeste polyamide
US4746708A (en) * 1986-05-27 1988-05-24 General Electric Company Hydroxyalkyl- and aminoalkyl-functionalized polyphenylene ethers
US5015698A (en) * 1986-05-27 1991-05-14 General Electric Company Polyphenylene ether-polyester copolymers, precursors therefor, compositions containing said copolymers, and methods for their preparation
EP0524705B1 (fr) * 1986-09-30 1998-07-22 Sumitomo Chemical Company, Limited Composition de résine thermoplastique
US5288786A (en) * 1986-09-30 1994-02-22 Sumitomo Chemical Co., Ltd. Thermoplastic resin composition
JPH0776301B2 (ja) * 1986-11-19 1995-08-16 三菱化学株式会社 熱可塑性樹脂組成物
US5284914A (en) * 1986-12-08 1994-02-08 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin compound
US5244699A (en) * 1987-03-27 1993-09-14 North Dakota State University Polymeric vehicle for coatings
US5235006A (en) * 1987-03-27 1993-08-10 North Dakota State University Mesogens and polymers with mesogens
CA1334702C (fr) * 1989-05-11 1995-03-07 Warren Joseph Peascoe Compositions elastomeriques d'ester de polyetherimide
JPH03159511A (ja) * 1989-08-24 1991-07-09 Furukawa Electric Co Ltd:The 自動車用電気接続箱及びその製造方法
DE19527586C2 (de) * 1994-08-10 2003-07-10 Gen Electric Polyarylensulfid-Harzmischungen mit hoher Fließeigenschaft und Duktilität
KR0150765B1 (ko) * 1995-04-25 1998-10-15 유현식 자연색상이 우수한 폴리페닐렌 에테르계 열가소성 수지 조성물
WO1997049387A1 (fr) 1996-06-27 1997-12-31 G.D. Searle And Co. Particules comprenant des copolymeres amphiphiles, possedant un domaine d'enveloppe reticulee et un domaine de noyau utiles et autres dans des applications pharmaceutiques
CN1063190C (zh) * 1997-04-03 2001-03-14 中国石油化工总公司 交联硬核核壳共聚微粒
CN1063192C (zh) * 1997-04-03 2001-03-14 中国石油化工总公司 核壳微粒增韧聚苯乙烯材料
CN1063187C (zh) * 1997-04-03 2001-03-14 中国石油化工总公司 核壳微粒增韧聚苯乙烯材料制备工艺
US7022776B2 (en) * 2001-11-07 2006-04-04 General Electric Conductive polyphenylene ether-polyamide composition, method of manufacture thereof, and article derived therefrom

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1985005372A1 (fr) * 1984-05-21 1985-12-05 General Electric Company Compositions a base de polyamide - ether de polyphenylene modifies et procede
WO1987000540A1 (fr) * 1985-07-24 1987-01-29 General Electric Company Ethers de polyphenylene fonctionnalises et leurs procedes de preparation et d'utilisation

Family Cites Families (2)

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Publication number Priority date Publication date Assignee Title
US4315086A (en) * 1979-08-08 1982-02-09 Sumitomo Chemical Company, Limited Resin compositions
DE3102251A1 (de) * 1981-01-24 1982-09-02 Basf Ag, 6700 Ludwigshafen Thermoplastische formmassen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1985005372A1 (fr) * 1984-05-21 1985-12-05 General Electric Company Compositions a base de polyamide - ether de polyphenylene modifies et procede
WO1987000540A1 (fr) * 1985-07-24 1987-01-29 General Electric Company Ethers de polyphenylene fonctionnalises et leurs procedes de preparation et d'utilisation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0299619A2 (fr) * 1987-06-12 1989-01-18 Sumitomo Chemical Company, Limited Composition de résine thermoplastique
EP0299619B1 (fr) * 1987-06-12 1995-05-17 Sumitomo Chemical Company, Limited Composition de résine thermoplastique
US5516855A (en) * 1987-11-04 1996-05-14 General Electric Company Amide-ester copolymers and process for the preparation thereof
EP0322560A2 (fr) * 1987-12-30 1989-07-05 General Electric Company Compositions comprenant un élastomère thermoplastique, copolymère réticulé à partir d'acrylates et de composés vinylaromatiques et des polyamides
EP0322560A3 (fr) * 1987-12-30 1990-11-07 General Electric Company Compositions comprenant un élastomère thermoplastique, copolymère réticulé à partir d'acrylates et de composés vinylaromatiques et des polyamides
EP0529378A1 (fr) * 1991-08-24 1993-03-03 BASF Aktiengesellschaft Masse à mouler thermoplastique à base de polyamide et de polyphénylène ether

Also Published As

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JPH0560835B2 (fr) 1993-09-03
US4681915A (en) 1987-07-21
JPS63501961A (ja) 1988-08-04
EP0252944A1 (fr) 1988-01-20

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