WO1981001430A1 - Method of preventing erasure of an image and a booklet of security papers - Google Patents

Method of preventing erasure of an image and a booklet of security papers Download PDF

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Publication number
WO1981001430A1
WO1981001430A1 PCT/GB1980/000200 GB8000200W WO8101430A1 WO 1981001430 A1 WO1981001430 A1 WO 1981001430A1 GB 8000200 W GB8000200 W GB 8000200W WO 8101430 A1 WO8101430 A1 WO 8101430A1
Authority
WO
WIPO (PCT)
Prior art keywords
inorganic material
booklet
booklet according
image
clay
Prior art date
Application number
PCT/GB1980/000200
Other languages
French (fr)
Inventor
D Cole
Original Assignee
Wiggins Teape Group Ltd
D Cole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wiggins Teape Group Ltd, D Cole filed Critical Wiggins Teape Group Ltd
Publication of WO1981001430A1 publication Critical patent/WO1981001430A1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • D21H21/44Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
    • D21H21/46Elements suited for chemical verification or impeding chemical tampering, e.g. by use of eradicators

Definitions

  • This invention generally relates to the prevention of fraudulent alteration of documents.
  • it relates to a method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter, and also to a booklet of security papers.
  • ballpoint pens are now available, the ink from which is erasable for several hours after it has been applied to a writing surface.
  • Such ballpoint pens are described in US Patent 4 097 290 wherein it is stated that the ink properties of initial erasability and eventual permanence are due to certain rubber compounds and volatile solvents present in the ink. Whilst pens of this kind overcome the long-felt drawback of not permitting neat corrections, they also pose a serious problem in facilitating fraudulent alteration of security papers.
  • a ballpoint pen as just described will be referred to hereafter as an "erasable ballpoint pen".
  • a further example is provided by the kind of typewriter now marketed which enables corrections to be made by "lifting" typed indicia off the typing surface by means of the typewriter ribbon, and then typing other indicia in their place. Whilst such a facility is clearly advantageous for the typist, it again poses a problem in facilitating fraudulent alteration of security papers.
  • a typewriter as just described will be referred to hereafter as a "correctable typewriter”.
  • the present invention provides a method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter characterised in that the image is written or typed on a coated surface in which the coating contain an adsorbent inorganic material.
  • the surface may for example be the surface of a security paper, such as a bank cheque of the kind issued to the banks' customers in cheque books.
  • the present invention therefore also provides a booklet of security papers which are detachably secured together characterised in that the papers are provided with a coated typing or writing surface in which the coating contains an adsorbent inorganic material.
  • a particular advantage of the present invention is that a coated surface of the kind just described also affords good printability.
  • the adsorbent inorganic material is advantageously electron-accepting and may be silica gel although an acidic clay is preferred especially an acidic clay of the kind customarily used as a colour developer in pressuresensitive copying paper.
  • an acidic clay is preferred especially an acidic clay of the kind customarily used as a colour developer in pressuresensitive copying paper.
  • examples of such a clay include attapulgite and bentonite, for instance montmorillonite, clays.
  • the most preferred clay is an acid-washed dioctahedral montmorillonite clay such as that sold by Mizusawa Industrial Chemicals Ltd., Japan under the name "Silton M-AB.”
  • the minimum amount of inorganic material required to prevent erasure of the image varies in accordance with the particular material employed. Generally though, the minimum amount is about 1 gram per square metre of surface. The achievement of the invention is not of course dependent on any maximum amount of inorganic material but no additional benefit seems to be obtained over an amount of about 10 grams per square metre of surface.
  • the coating may also contain an extender, such as kaolin, and a binder, such as a butadiene latex.
  • an extender such as kaolin
  • a binder such as a butadiene latex.
  • Security paper having a coating of an adsorbent inorganic material is prepared in a conventional manner.
  • a coating mix containing the inorganic material and other components is prepared and coated on to security base paper sheet at, for example, the size press.
  • a coating mix was made by adding 23kg sodium hydroxide and 5kg Cellufix FF5 (a carboxymethyl cellulose water retention aid) to 180 gallons of water, and mixing for 10 minutes. 805kg “Silton M-AB” (acid-washed dioctahedral montmorillonite clay) and 200kg Dinkie A (kaolin) were then added with a further 110 gallons of water and mixed for 60 minutes. Finally 340kg Dow 86433 (butadiene latex binder) and 110 gallons of water were added and mixed to provide a coating mix with a solids content of 35.5%.
  • Dow 86433 butadiene latex binder
  • the coating mix containing "Silton M-AB” was then coated on to security base paper sheet (88 grams per square metre) to give a coated security paper (95 grams per square metre) in which the amount of "Silton M-AB” was 4.1 grams per square metre.

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  • Color Printing (AREA)

Abstract

A method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter by writing or typing the image upon a surface coated with an adsorbent inorganic material, such as a montmorillonite acid clay. Such a method prevents fraudulent alteration of security papers.

Description

METHOD OF PREVENTING ERASURE OF AN IMAGE AND A BOOKLET OF SECURITY PAPERS
This invention generally relates to the prevention of fraudulent alteration of documents. In particular, it relates to a method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter, and also to a booklet of security papers.
It is conventional for security papers which are likely to be the subject of attempts at fraudulent alteration to contain reactive chemicals which produce colour changes if an attempt is made to erase or alter printed, typed or written indicia on the document. Whilst such chemicals are very useful, they do not serve as a safeguard against all possibilities for fraudulent alteration of security papers.
For example, ballpoint pens are now available, the ink from which is erasable for several hours after it has been applied to a writing surface. Such ballpoint pens are described in US Patent 4 097 290 wherein it is stated that the ink properties of initial erasability and eventual permanence are due to certain rubber compounds and volatile solvents present in the ink. Whilst pens of this kind overcome the long-felt drawback of not permitting neat corrections, they also pose a serious problem in facilitating fraudulent alteration of security papers. A ballpoint pen as just described will be referred to hereafter as an "erasable ballpoint pen". A further example is provided by the kind of typewriter now marketed which enables corrections to be made by "lifting" typed indicia off the typing surface by means of the typewriter ribbon, and then typing other indicia in their place. Whilst such a facility is clearly advantageous for the typist, it again poses a problem in facilitating fraudulent alteration of security papers. A typewriter as just described will be referred to hereafter as a "correctable typewriter".
It has now been found that attempts at fraudulent alteration of an image or indicia on a security paper, the image or indicia having been produced from an erasable ballpoint pen or a correctable typewriter, can be prevented by the provision of a coating of an adsorbent inorganic material on the writing or typing surface of the security paper. As the image or indicia produced on the coated surface is rendered substantially permanent from the time of writing or typing, it is much more difficult, if not impossible, to erase or alter it.
Accordingly, the present invention provides a method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter characterised in that the image is written or typed on a coated surface in which the coating contain an adsorbent inorganic material. The surface may for example be the surface of a security paper, such as a bank cheque of the kind issued to the banks' customers in cheque books. The present invention therefore also provides a booklet of security papers which are detachably secured together characterised in that the papers are provided with a coated typing or writing surface in which the coating contains an adsorbent inorganic material. A particular advantage of the present invention is that a coated surface of the kind just described also affords good printability.
The adsorbent inorganic material is advantageously electron-accepting and may be silica gel although an acidic clay is preferred especially an acidic clay of the kind customarily used as a colour developer in pressuresensitive copying paper. Examples of such a clay include attapulgite and bentonite, for instance montmorillonite, clays. The most preferred clay is an acid-washed dioctahedral montmorillonite clay such as that sold by Mizusawa Industrial Chemicals Ltd., Japan under the name "Silton M-AB."
The minimum amount of inorganic material required to prevent erasure of the image varies in accordance with the particular material employed. Generally though, the minimum amount is about 1 gram per square metre of surface. The achievement of the invention is not of course dependent on any maximum amount of inorganic material but no additional benefit seems to be obtained over an amount of about 10 grams per square metre of surface.
In addition to the inorganic material, the coating may also contain an extender, such as kaolin, and a binder, such as a butadiene latex.
Security paper having a coating of an adsorbent inorganic material is prepared in a conventional manner. Thus, a coating mix containing the inorganic material and other components is prepared and coated on to security base paper sheet at, for example, the size press.
The invention will now be illustrated by the following examples : -
Preparation of a Coated Security Paper
A coating mix was made by adding 23kg sodium hydroxide and 5kg Cellufix FF5 (a carboxymethyl cellulose water retention aid) to 180 gallons of water, and mixing for 10 minutes. 805kg "Silton M-AB" (acid-washed dioctahedral montmorillonite clay) and 200kg Dinkie A (kaolin) were then added with a further 110 gallons of water and mixed for 60 minutes. Finally 340kg Dow 86433 (butadiene latex binder) and 110 gallons of water were added and mixed to provide a coating mix with a solids content of 35.5%.
The coating mix containing "Silton M-AB" was then coated on to security base paper sheet (88 grams per square metre) to give a coated security paper (95 grams per square metre) in which the amount of "Silton M-AB" was 4.1 grams per square metre.
Paper coated thus was found to have good printability.
Comparative Example
The paper coated with "Silton M-AB" clay and a conventional china clay-coated printing paper were each written upon by an erasable ballpoint pen (sold under the trade name "Replay" by Papermate) and by a correctable typewriter (sold by IBM). Attempts at correction were then made by means of a rubber eraser and by suitable operation of the typewriter respectively. In both cases the original image remained substantially fast on the 'Silton M-AB' - coated paper but was easily removed' from the conventional printing paper.

Claims

What we claim is :-
1. A method of preventing erasure of an image produced from an erasable ballpoint pen or a correctable typewriter characterised in that the image is written or typed on a coated surface in which the coating contains an adsorbent inorganic material.
2. A booklet of security papers which are detachably secured together characterised in that the papers are provided with a coated typing or writing surface in which the coating contains an adsorbent inorganic material.
3. A method or booklet according to claim 1 or 2, characterised in that the adsorbent inorganic material is electron-accepting.
4. A method or booklet according to claim 3, characterised in that the electron-accepting adsorbent inorganic material is silica gel.
5. A method or booklet according to claim 3, characterised in that the electron-accepting adsorbent inorganic material is an acidic clay.
6. A method or booklet according to claim 5, characterised in that the acidic clay is selected from the group consisting of attapulgite and bentonite clays.
7. A method or booklet according to claim 6, characterised in that the bentonite clay is a montmorillonite clay.
8. A method or booklet according to claim 7, characterised in that the montmorillonite clay is an acid-washed di-octahedral montmorillonite clay.
9. A method or booklet according to any one of the preceding claims characterised in that the weight of the coating is from 1 to 10 grams per square metre of surface.
10. A method or booklet according to any one of the preceding claims, characterised in that the coating contains a binder.
PCT/GB1980/000200 1979-11-21 1980-11-20 Method of preventing erasure of an image and a booklet of security papers WO1981001430A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB7940210 1979-11-21
GB7940210 1979-11-21

Publications (1)

Publication Number Publication Date
WO1981001430A1 true WO1981001430A1 (en) 1981-05-28

Family

ID=10509331

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1980/000200 WO1981001430A1 (en) 1979-11-21 1980-11-20 Method of preventing erasure of an image and a booklet of security papers

Country Status (2)

Country Link
EP (1) EP0029714A1 (en)
WO (1) WO1981001430A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2574099B1 (en) * 1984-12-05 1987-02-27 Aussedat Rey INFALSIFIABLE PRINT-WRITE SUPPORT
FR2814476B1 (en) 2000-09-11 2003-04-11 Arjo Wiggins Sa SAFETY SHEET HAVING A TRANSPARENT OR TRANSLUCENT LAYER

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE523251A (en) *
US2213643A (en) * 1938-10-11 1940-09-03 Vanderbilt Co R T Coated fibrous sheet materials
US2333979A (en) * 1941-08-15 1943-11-09 Fox River Paper Corp Safety paper
US2641557A (en) * 1948-11-18 1953-06-09 Ncr Co Paper with improved printing characteristics
GB760080A (en) * 1953-09-15 1956-10-31 Ncr Co Process for producing pigment-containing paper-coating compositions
DE2036892A1 (en) * 1970-07-24 1972-02-03 Huber, Dr. Otto, 8022 Grunwald Lacquers - for surface finishing of paper

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE523251A (en) *
US2213643A (en) * 1938-10-11 1940-09-03 Vanderbilt Co R T Coated fibrous sheet materials
US2333979A (en) * 1941-08-15 1943-11-09 Fox River Paper Corp Safety paper
US2641557A (en) * 1948-11-18 1953-06-09 Ncr Co Paper with improved printing characteristics
GB760080A (en) * 1953-09-15 1956-10-31 Ncr Co Process for producing pigment-containing paper-coating compositions
DE2036892A1 (en) * 1970-07-24 1972-02-03 Huber, Dr. Otto, 8022 Grunwald Lacquers - for surface finishing of paper

Also Published As

Publication number Publication date
EP0029714A1 (en) 1981-06-03

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