UST961009I4 - Oriented polyolefin film treated with amine sulphates - Google Patents

Oriented polyolefin film treated with amine sulphates Download PDF

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Publication number
UST961009I4
UST961009I4 US05/762,166 US76216677A UST961009I4 US T961009 I4 UST961009 I4 US T961009I4 US 76216677 A US76216677 A US 76216677A US T961009 I4 UST961009 I4 US T961009I4
Authority
US
United States
Prior art keywords
amine
hydrogen atom
solution
dispersion
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US05/762,166
Inventor
Brian N. Hendy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB4769/76A external-priority patent/GB1558065A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of UST961009I4 publication Critical patent/UST961009I4/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/06—Coating with compositions not containing macromolecular substances
    • C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/91—Product with molecular orientation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

antistatic polyolefin films, particularly oriented polyolefin, are produced by extruding a polyolefin to form a cast extrudate, and applying to at least one surface of the cast extrudate a solution or dispersion in a volatile vehicle an amine sulfate or mixture of amine sulfates having the general formula ##STR1## where x is a positive integer, y is zero or a positive integer, the sum of x and y is from 2 to 5, A is a hydrogen atom and when y is zero A may also be a lower alkyl group, and R is a univalent aliphatic radical containing from 8 to 22 carbon atoms, and afterwards heating and stretching the extrudate to orient it. Preferred materials include amine sulphates in which the sum of x+ y is 2, A is hydrogen and R is a mixture of aliphatic hydrocarbon radicals having 8 to 18, preferably 12 to 18, carbon atoms particularly those derived from tallow or soya oil or derived from coconut oil. Examples of suitable amines from which amine sulfates may be prepared are the Endomeen's T/12, S/12 and C/12. It has been found that the corresponding hydrochloride does not provide the oriented film with satisfactory properties. The amine sulfate is conveniently employed at a concentration of up to about 60% by weight of the solution or dispersion and preferably from 10 to 50%.
Preferably the solution or dispersion also contains as a supplementary additive a quaternary ammonium compound of the general formula: ##STR2## where each of R1, R2, and R3, which may be the same or different, is a hydrogen atom or a lower alkyl radical, or R1 and R2 are each methylene groupings within a common five- or six-membered saturated heterocyclic ring, Z is a methylene group when R4 is a hydrogen atom or an acyl radical containing up to 15 carbon atoms, or Z is a carbonyl group when R4 is a hydrogen atom, and X is a univalent anion or an equivalent of a multivalent anion. The preferred quaternary ammonium compound is choline chloride. The presence of the quaternary ammonium compound in the solution or dispersions reduces the amount of amine sulfate to about 0.25 to 2.5% required to achieve the desired film properties, the total concentration of the amine sulfate and additional additive within the range of up to 60%.
US05/762,166 1976-02-06 1977-01-24 Oriented polyolefin film treated with amine sulphates Pending UST961009I4 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB4769/76A GB1558065A (en) 1976-02-06 1976-02-06 Oriented polyolefin film
UK4769/76 1976-02-06
UK14547/76 1976-04-09
GB1454776 1976-04-09

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US06/025,600 Continuation US4241144A (en) 1976-02-06 1979-03-30 Antistatic polyolefin films

Publications (1)

Publication Number Publication Date
UST961009I4 true UST961009I4 (en) 1977-08-02

Family

ID=26239354

Family Applications (2)

Application Number Title Priority Date Filing Date
US05/762,166 Pending UST961009I4 (en) 1976-02-06 1977-01-24 Oriented polyolefin film treated with amine sulphates
US06/025,600 Expired - Lifetime US4241144A (en) 1976-02-06 1979-03-30 Antistatic polyolefin films

Family Applications After (1)

Application Number Title Priority Date Filing Date
US06/025,600 Expired - Lifetime US4241144A (en) 1976-02-06 1979-03-30 Antistatic polyolefin films

Country Status (8)

Country Link
US (2) UST961009I4 (en)
JP (1) JPS5295775A (en)
CA (1) CA1090084A (en)
DE (1) DE2704078C3 (en)
FR (1) FR2340341A1 (en)
IT (1) IT1079107B (en)
LU (1) LU76709A1 (en)
NL (1) NL7701132A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316070A (en) 1979-08-21 1982-02-16 Prosise Robert L Cookware with liquid microwave energy moderator
US4999252A (en) * 1988-01-14 1991-03-12 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine mixtures films
US5096761A (en) * 1988-03-15 1992-03-17 W. R. Grace & Co.-Conn. Antistatically conductive masking film for electrostatic spray painting
US5153075A (en) * 1988-01-14 1992-10-06 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine polymeric films
US5171641A (en) * 1988-01-14 1992-12-15 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine polymeric films

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2960381D1 (en) 1978-03-15 1981-09-03 Ici Plc Antistatic films
US4310588A (en) * 1979-04-03 1982-01-12 Bareel Jean Michel Sliding element intended for use in skating
JPS59146848A (en) * 1983-02-14 1984-08-22 富士写真フイルム株式会社 Packing material for collecting and packing small box
US4785032A (en) * 1986-09-08 1988-11-15 Mobil Oil Corporation Water based coating composition and polymer film coated therewith
JPH02225536A (en) * 1989-02-27 1990-09-07 Mitsubishi Rayon Co Ltd Synthetic resin molding of excellent antistatic property and its production
US5175059A (en) * 1990-09-05 1992-12-29 Mitsubishi Rayon Company Ltd. Synthetic resin molded article having good antistatic property and process for preparation thereof
US5837343A (en) * 1996-09-11 1998-11-17 Park; Henry H. Reduced-friction composite structural element
US6872458B1 (en) 2001-02-16 2005-03-29 Applied Extrusion Technologies, Inc. Biaxally-oriented polypropylene films containing a non-crystallizable, amorphous polyester layer, and method of making the same
US7378155B2 (en) * 2003-03-25 2008-05-27 Applied Extrusion Technologies, Inc. Urethane based coating applied in-line for improved ink adhesion
EP1739119A1 (en) * 2005-06-29 2007-01-03 Bayer MaterialScience AG Process for the treatment of plastic profiles
JP2009507977A (en) * 2005-09-15 2009-02-26 チバ ホールディング インコーポレーテッド Coating composition for substrate marking containing latent activator
CN101755019A (en) * 2007-07-18 2010-06-23 巴斯夫欧洲公司 coating compositions
US9333786B2 (en) 2007-07-18 2016-05-10 Datalase, Ltd. Laser-sensitive coating formulations
RU2011120235A (en) 2008-10-23 2012-11-27 Дейталейз Лимитед HEAT-ABSORBING ADDITIVES
US9267042B2 (en) 2008-10-27 2016-02-23 Datalase Ltd. Coating composition for marking substrates

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2897170A (en) * 1954-04-09 1959-07-28 American Cyanamid Co Antistatic treatment with a quaternary ammonium compound containing a polyetheneoxy grouping and products thereof
US2832697A (en) * 1956-04-30 1958-04-29 Dow Chemical Co Method for applying antistatic agents to polymeric substances and destaticized articles thereby obtained
GB828012A (en) * 1957-04-29 1960-02-10 Dexter Chemical Corp A composition for application to textile material to impart antistatic and rewetting properties thereto
FR1386900A (en) * 1964-03-27 1965-01-22 Ici Ltd Antistatic polyvinyl chloride compositions and process for their preparation
DE1247010B (en) * 1965-10-08 1967-08-10 Huels Chemische Werke Ag Thermoplastic masses for the production of anti-static moldings made of highly crystalline polyethylene
GB1211736A (en) * 1967-12-07 1970-11-11 Geigy Uk Ltd Quaternised amino-chlorohydrins and their use in the treatment of shaped articles
US3975325A (en) * 1973-08-27 1976-08-17 Ici United States Inc. Antistatic agent composition
JPS5312971A (en) * 1976-07-22 1978-02-06 Honshu Paper Co Ltd Polypropylene composite film having antistatic and low temperature heat seal property and its production

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4316070A (en) 1979-08-21 1982-02-16 Prosise Robert L Cookware with liquid microwave energy moderator
US4999252A (en) * 1988-01-14 1991-03-12 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine mixtures films
US5153075A (en) * 1988-01-14 1992-10-06 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine polymeric films
US5171641A (en) * 1988-01-14 1992-12-15 W. R. Grace & Co.-Conn. Permanent antistatic acid copolymer/quaternary amine polymeric films
US5096761A (en) * 1988-03-15 1992-03-17 W. R. Grace & Co.-Conn. Antistatically conductive masking film for electrostatic spray painting

Also Published As

Publication number Publication date
JPS5295775A (en) 1977-08-11
FR2340341B1 (en) 1981-02-06
DE2704078C3 (en) 1993-05-27
US4241144A (en) 1980-12-23
DE2704078A1 (en) 1977-08-11
CA1090084A (en) 1980-11-25
LU76709A1 (en) 1978-04-13
DE2704078C2 (en) 1987-03-26
IT1079107B (en) 1985-05-08
FR2340341A1 (en) 1977-09-02
NL7701132A (en) 1977-08-09

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