USRE4819E - Improvement in nitroglycerine compounds - Google Patents
Improvement in nitroglycerine compounds Download PDFInfo
- Publication number
- USRE4819E USRE4819E US RE4819 E USRE4819 E US RE4819E
- Authority
- US
- United States
- Prior art keywords
- nitro
- glycerine
- nitroglycerine
- improvement
- compounds
- Prior art date
Links
- 229960003711 glyceryl trinitrate Drugs 0.000 title description 30
- -1 nitroglycerine compounds Chemical class 0.000 title 2
- SNIOPGDIGTZGOP-UHFFFAOYSA-N 1,2,3-propanetrioltrinitrate Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 28
- 239000002360 explosive Substances 0.000 description 14
- 238000004880 explosion Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003721 gunpowder Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000020 Nitrocellulose Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N Sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2S,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2R,3R,4S,5R,6S)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000320 mechanical mixture Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 230000001737 promoting Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
Definitions
- ALFRED NOBEL of the city (if-Hamburg, Germany, has invented certain new and useful Improvements in the Manufacture ot' Nitro-Glycerine, and certain compounds thereof, and in the utilization of nitroglycerine as an explosive.
- Nitro-glycerinc belongs to aclass of explosives long known, but notat the date of N0- BELs invention applied to technical purposes, in consequence of practical difficulties in procuring their explosion. Nitro glycerine is liquid at ordinary temperatures, and by that characteristic is distinguishable from solid explosives, such as gunpowder, gun-cotton, &c., and has also the property that fire may be applied to it without its exploding.
- Nitro-glycerine for example, if ignited in an open space, is slowly decomposed and takes fire; but the flameis apt to die out when the match is with drawn, hence it cannot, under ordinary circumstances, be looked upon as a ready explosive agent; for, while gunpowder and other substances used as explosivesprior to N0- BELs invention always explode when fire is set to them, nitro-glycerine will not explode from the mere contact of flame. So, also, if a drop of nitro-glycerine be poured on an anvil, the blow of a hammer causes it to explode; but only that part is involved which has received the blow, so that in this case the explosion is merely a local one.
- a principal object of NOBELS invention consists in the removal of this obstacle to the use of nitro-glycerine as an explosive.
- two dilferent methods have been invented by NOBEL for promoting the explosion of nitro-glycerine: one method, which forms the subject of this patent, consists in a compound with nitro-glycerine of a readily-ignitible substance; and the other method, which is described in a separate specification, relates to the means of effecting the explosion.
- NOBEL discovered that, by mixing nitroglycerine with rocket-powder, which is amere loose mechanical mixture of niter, charcoal,
- Rocket-powder is almost non-explosive, but readily burns and deflagrates on contact with a spark of fire, while nitro-glycerinc, on the other hand, as before stated, is hard to explode; but when the explosion is obtained is extremely violent in its efl'ects.
Description
UNITED STATES ALFRED NOBEL, OF HAMBURG, GERMANY, ASSIGNOR TO THE UNITED STATES BLASTING-OIL COMPANY, OF NEWV YORK, N. Y.
IMPROVEMENT IN NlTRO-GLYCERINE COMPOUNDS.
Specification forming part of Letters Patent No. 50,617, dated October 24, 1865; reissue No. 3,380, dated April 13, 1869; reissue No. 4,819, dated March 19, 1872.
DIVIsION E.
SPECIFICATION.
To all whom it may concern:
Be it known that ALFRED NOBEL, of the city (if-Hamburg, Germany, has invented certain new and useful Improvements in the Manufacture ot' Nitro-Glycerine, and certain compounds thereof, and in the utilization of nitroglycerine as an explosive.
The improvement; in the manufacture of nitro-glycerine is the subject of a separate specification; this specification having reference to the utilization of nitro-glycerine as an ex plosive.
Nitro-glycerinc belongs to aclass of explosives long known, but notat the date of N0- BELs invention applied to technical purposes, in consequence of practical difficulties in procuring their explosion. Nitro glycerine is liquid at ordinary temperatures, and by that characteristic is distinguishable from solid explosives, such as gunpowder, gun-cotton, &c., and has also the property that fire may be applied to it without its exploding. Nitro-glycerine, for example, if ignited in an open space, is slowly decomposed and takes fire; but the flameis apt to die out when the match is with drawn, hence it cannot, under ordinary circumstances, be looked upon as a ready explosive agent; for, while gunpowder and other substances used as explosivesprior to N0- BELs invention always explode when fire is set to them, nitro-glycerine will not explode from the mere contact of flame. So, also, if a drop of nitro-glycerine be poured on an anvil, the blow of a hammer causes it to explode; but only that part is involved which has received the blow, so that in this case the explosion is merely a local one.
A principal object of NOBELS invention consists in the removal of this obstacle to the use of nitro-glycerine as an explosive. For this end two dilferent methods have been invented by NOBEL for promoting the explosion of nitro-glycerine: one method, which forms the subject of this patent, consists in a compound with nitro-glycerine of a readily-ignitible substance; and the other method, which is described in a separate specification, relates to the means of effecting the explosion.
NOBEL discovered that, by mixing nitroglycerine with rocket-powder, which is amere loose mechanical mixture of niter, charcoal,
and sulphur, the difiiculty in effecting the ex plosionot nitro-glycerine was ei'i'ectually overcome. Rocket-powder is almost non-explosive, but readily burns and deflagrates on contact with a spark of fire, while nitro-glycerinc, on the other hand, as before stated, is hard to explode; but when the explosion is obtained is extremely violent in its efl'ects.
By the mixing of these substances a compound is produced which is a very powerful explosive, and is easily exploded by means of the simple contact with fire. The mixing may be effected in any convenient manner, and the proportions in which they are combined may be varied to suit the pleasure or convenience of the user or manufacturer.
.What, therefore, we claim as the invention of ALFRED NOBEL, and desire to secure by Letters Patent, is-- The mixture of nitro-glycerine and rocketpowder, substantially as and for the purposes hereinbefore described.
In witness whereof the said THE UNITED STATES BLASTING-OIL COMPANY, by TAL. P. SHAFFNER, President, have hereunto set their hand.
THE UNITED STATES BLASTING-OiL 00., By TAL. P. SHAFFNER, President.
Witnesses:
OCTAVIUS KNIGHT, EDM. F. BROWN.
Family
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