US97566A - Improved explosive compound for use in fire-arms, blasting - Google Patents
Improved explosive compound for use in fire-arms, blasting Download PDFInfo
- Publication number
- US97566A US97566A US97566DA US97566A US 97566 A US97566 A US 97566A US 97566D A US97566D A US 97566DA US 97566 A US97566 A US 97566A
- Authority
- US
- United States
- Prior art keywords
- arms
- blasting
- fire
- explosive compound
- potash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 22
- 238000005422 blasting Methods 0.000 title description 12
- 150000001875 compounds Chemical class 0.000 title description 6
- 239000000203 mixture Substances 0.000 description 18
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 229940072033 potash Drugs 0.000 description 6
- 235000015320 potassium carbonate Nutrition 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000011435 rock Substances 0.000 description 6
- UTYXJYFJPBYDKY-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide;trihydrate Chemical compound O.O.O.[K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UTYXJYFJPBYDKY-UHFFFAOYSA-N 0.000 description 6
- 206010010254 Concussion Diseases 0.000 description 4
- 241000251729 Elasmobranchii Species 0.000 description 4
- 238000004880 explosion Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 239000003721 gunpowder Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000002269 spontaneous Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2S,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2R,3R,4S,5R,6S)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- ORXDSIPBTFAEKJ-UHFFFAOYSA-N ferrocyanide Chemical compound N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N ORXDSIPBTFAEKJ-UHFFFAOYSA-N 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 2
- 239000011872 intimate mixture Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000004642 transportation engineering Methods 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
- C06B29/04—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with an inorganic non-explosive or an inorganic non-thermic component
Definitions
- This new composition of my invention possesses several new and important features. It may be combined with sand and subjected to great friction without igniting, while it ignites with heavy concussion. It contains in its composition paraffiue, being a new application of this hydrocarbon as an explosive. Paraffine is composed of carbon 24, hydrogen 25. It burns without residue; it, therefore, increases at once the volume of gases and the explosive force, while, from its greasy character, it holds the particles of the mass together, thus preventing mechanical decomposition, which makes it useful in the formation of cartridges for small-arms.
- This new explosive does not require to be combined with water. Granulation decreases its explosive properties, which is not desirable for blasting very hard rocks; but granulation may be employed for small-arms to advantage. Nitrates should never be combined with chlorate of potash, or any of its combinations, as such combinations lead frequently to spontaneous combustion, and are .easily exploded by friction, and sometimes by compression. 1
- ingredients herein set forth may be all combined with water and granulated, I prefer, for the blasting of rocks, bursting of rifle and smooth-bore shells, as used in ordnance. and for the explosion of torpedoes, a mixture formed by mechanical means, and in the following manner:
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
Description
nron THOMAS TAYLOR, OF WASHINGTON, DISTRICT OF COLUMBIA.
IMPROVED EXPLOSIVE COMPOUND FOR USE IN FIRE-ARMS, BLASTING, &c.
Specification forming part of Letters Patent No. 97,566, dated December 19, 1869.
To all whom it may concern:
Be it known that I, THOMAS TAYLOR, of Washington city, in the District of Columbia, have invented a new and useful Composition of Matter, which I propose as a substitute for gunpowder, gun-cotton, glycerine, and other explosives used in the blasting of rocks, and
,for general mining purposes, and for use in small arms, for the explosion of torpedoes and ordnance projectiles.
This new composition of my invention possesses several new and important features. It may be combined with sand and subjected to great friction without igniting, while it ignites with heavy concussion. It contains in its composition paraffiue, being a new application of this hydrocarbon as an explosive. Paraffine is composed of carbon 24, hydrogen 25. It burns without residue; it, therefore, increases at once the volume of gases and the explosive force, while, from its greasy character, it holds the particles of the mass together, thus preventing mechanical decomposition, which makes it useful in the formation of cartridges for small-arms. When about equal parts of chlorate of potash and the yellow prussiate of potash are combined with about one thirty-second part by weight of parafline, the mass being intimately mixed by mechanical means and reduced to an exceedingly fine powder, a highly-explosive compound is formed. A spark, or match, or flame instantly ignites the powder. The whole mass explodes almost instantaneously, and, therefore, for blasting purposes is much superior to gunpowder. For small-arms it can be used with safety by simply increasing the proportion of par-afline. The time of combustion may be lengthened to any degree necessary.
This new explosive does not require to be combined with water. Granulation decreases its explosive properties, which is not desirable for blasting very hard rocks; but granulation may be employed for small-arms to advantage. Nitrates should never be combined with chlorate of potash, or any of its combinations, as such combinations lead frequently to spontaneous combustion, and are .easily exploded by friction, and sometimes by compression. 1
Although the ingredients herein set forth may be all combined with water and granulated, I prefer, for the blasting of rocks, bursting of rifle and smooth-bore shells, as used in ordnance. and for the explosion of torpedoes, a mixture formed by mechanical means, and in the following manner:
First. I take, say, one pound of ferro-cyanide of potassium-yellow prussiate of potash-and reduce it by mechanical means to a very fine powder.
Second. I then combine with the yellow prussiate of potash about one thirty-second part of paraffine, forming a very intimate mixture.
Third. I take one pound of the chlorate of potash and reduce it by mechanical means to an impalpable powder, the finer the better.
I next combine these ingredients intimately in the dry state by passing them through a sieve several times, or by any other mechanical device.
When properly combined this mixture is highly explosive and is ready for use, but for transportation purposes I prefer to pack the mealed yellow prussiate of potash and parai fine mixture and the mealed chlorate of potash by themselves, in which condition no ac cident could take place. In this way large quantities may be stored or transported in perfect safety. The ingredients in their separate condition would not explode were a hot iron placed in either.
I When I desire to make the combustion slow,
to render it fit for small-arms, I increase the proportion of paraffine. Paraffine, when combined with explosives, tends to prevent their spontaneous combustion. It also lessens their tendency to explode by concussion or friction. I sometimes add paraffine to ordinary grinpowder to make it burn more slowly. Having described the nature of my invention and its mode of manufacture I shall now set forth my claim.
What I claim as new, and desire to secure by Letters Patent, is-
The new combination of ingredients forming a new explosive, for the purposes set forth and described, substantially.
THOMAS TAYLOR.
Witnesses:
S. H. SWETLAND, A. MoGALLUM.
Publications (1)
Publication Number | Publication Date |
---|---|
US97566A true US97566A (en) | 1869-12-07 |
Family
ID=2167027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US97566D Expired - Lifetime US97566A (en) | Improved explosive compound for use in fire-arms, blasting |
Country Status (1)
Country | Link |
---|---|
US (1) | US97566A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3793100A (en) * | 1972-11-24 | 1974-02-19 | Unidynamics Phoenix | Igniter composition comprising a perchlorate and potassium hexacyano cobaltate iii |
US20060025631A1 (en) * | 2004-07-30 | 2006-02-02 | Bender Timothy P | Arylamine processes |
-
0
- US US97566D patent/US97566A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3793100A (en) * | 1972-11-24 | 1974-02-19 | Unidynamics Phoenix | Igniter composition comprising a perchlorate and potassium hexacyano cobaltate iii |
US20060025631A1 (en) * | 2004-07-30 | 2006-02-02 | Bender Timothy P | Arylamine processes |
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