US7374818B2 - Coating system for silicon based substrates - Google Patents

Coating system for silicon based substrates Download PDF

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US7374818B2
US7374818B2 US11/135,857 US13585705A US7374818B2 US 7374818 B2 US7374818 B2 US 7374818B2 US 13585705 A US13585705 A US 13585705A US 7374818 B2 US7374818 B2 US 7374818B2
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silicon
layer
article according
oxide
yttrium
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US20070014996A1 (en
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Tania Bhatia
Wayde R. Schmidt
William K. Tredway
Venkata R. Vedula
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RTX Corp
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United Technologies Corp
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Priority to US11/135,857 priority Critical patent/US7374818B2/en
Priority to JP2006075908A priority patent/JP2006327923A/ja
Priority to DE602006014058T priority patent/DE602006014058D1/de
Priority to EP06251493A priority patent/EP1726681B1/fr
Priority to CNB2006100682523A priority patent/CN100415693C/zh
Publication of US20070014996A1 publication Critical patent/US20070014996A1/en
Publication of US7374818B2 publication Critical patent/US7374818B2/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/341—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one carbide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer

Definitions

  • the present invention drawn to a bond coat system to be applied to a silicon containing substrate.
  • Silicon-based monolithic ceramics such as, silicon carbide and silicon nitride, and composites such as, silicon carbide fiber reinforced silicon carbide matrix are attractive materials for use in gas turbine engine hot sections due to their high temperature mechanical and physical properties as well as lower density than metals.
  • these materials exhibit accelerated oxidation and recession in high temperature, aqueous environments such as, for example, the combustor and turbine sections of gas turbine engines.
  • significant effort has been given to providing barrier layers for the protection of the silicon based substrates so as to increase the service life of such components.
  • FIG. 1 a One variant of a protected coated ceramic article that constitutes prior art is shown in FIG. 1 a .
  • a composite article 10 comprises a silicon based substrate 12 , a bond coat or layer 14 which comprises a dense continuous layer of silicon metal, and an environmental barrier coating comprising a barrier layer 16 which comprises either an alkaline earth aluminosilicate based on barium and/or strontium; or yttrium silicate.
  • Another refractory top layer 18 such as, for example, aluminum oxide; or zirconium oxide; or yttrium oxide; or combinations thereof may be used on top of the barrier layer 16 .
  • FIG. 1 b Another embodiment of the prior art is shown in FIG. 1 b where intermediate layers 20 and 22 are included for lending compliance and/or chemical compatibility to the coating system.
  • the intermediate layer comprises, for example, a mixture of the barrier layer material with an additional oxide such as mullite.
  • These prior art coating systems have proved to be quite adherent and protective and have been used to prevent recession and oxidation of the silicon based substrate 12 .
  • the bond coat system of the invention incorporates the advantages offered by a silicon metal containing bond coat and barrier coating applied thereto while at the same time overcoming the disadvantages noted above.
  • a compliant layer having an elastic modulus of between 30 and 130 GPa is provided between a silicon based substrate and an oxygen gettering layer.
  • reduction in substrate strength is mitigated by making the coating system more flaw tolerant by supplying a compliant layer between the oxygen gettering layer and the substrate.
  • the coating system thus retains the advantages of the prior art systems without debiting the strength of the substrate.
  • the mitigation of the strength debit is brought about by the coating design of the present invention, which comprises a compliant layer, oxygen gettering layer, and additional barrier layer(s), which drives down the residual tensile stresses in the layers adjacent to the substrate and/or reduces the stored elastic strain energy of the coated system.
  • the compliant layer acts to buffer the stress concentration in the substrate thereby helping to retain the strength of the substrate.
  • the bond coat system of the present invention is a significant improvement over prior art systems known to date.
  • FIGS. 1 a and 1 b are schematic illustrations of composite articles in accordance with the prior art
  • FIG. 2 is a schematic illustration of the composite article in accordance with one embodiment of the present invention.
  • FIG. 3 is a graph showing the advantages of the present invention with respect to retained strength of the coated article.
  • the composite article 100 of the present invention is illustrated and comprises a silicon based substrate 120 , an oxygen gettering layer 140 and a compliant layer 30 between the silicon based substrate and the silicon metal containing oxygen gettering layer.
  • the bond coat materials in the prior art are mostly oxygen gettering agents such as Silicon (Si) and refractory metal suicides and combinations thereof.
  • Si Silicon
  • refractory metal suicides and combinations thereof While a Silicon containing oxygen gettering layer 140 , is a preferred embodiment of this invention, alternatively, layer 140 could also be high temperature metallic alloys that are alumina or chromia formers as known in the art.
  • the compliant layer 30 is selected from the group consisting of alkaline earth alumino silicates, yttrium monosilicate, yttrium disilicate, rare earth mono and disilicates, hafnium silicate, zirconium silicate; oxides of hafnium, zirconium, yttrium, rare earth metals, niobium, titanium, tantalum, silicon, aluminum; silicon nitride; silicon carbide; silicon oxynitrides; silicon oxy carbides; silicon oxycarbonitrides; silicon refractory metal oxides; alumina forming refractory metal alloys; chromia forming refractory metal alloys, and mixtures thereof.
  • the composition of the compliant layer be selected from the group consisting of yttrium oxide, hafnium oxide, rare earth metal oxides, yttrium monosilicate, yttrium disilicate, rare earth mono and disilicates, hafnium silicate, and mixtures thereof.
  • the preferred elastic modulus of the compliant layer is 30-130 GPa.
  • the porosity of the compliant layer must be controlled in order to ensure the desired behavior characteristics noted above. It is preferred that the compliant layer have a porosity of about 2 to 50%, and more preferably about 5 to 25%. Porosity refers to the fraction of voids in the compliant layer 30 .
  • the thickness of the compliant layer is preferred to be between 20 and 250 microns and more preferably between 40 and 125 microns.
  • the ratio of thickness of the compliant layer to the oxygen gettering layer is preferred to be between 0.1:1 and 10:1.
  • the compliant layer 30 may comprise a plurality of layers having the composition of the materials set forth above.
  • the compliant layer 30 and gettering layer 140 may be repeated one or more times in the environmental barrier coating system if desired.
  • the silicon based substrate 120 includes materials selected from the group consisting of monolithic silicon nitride, monolithic silicon carbide, silicon nitride containing composites, silicon carbide containing composites, silicon oxynitrides, silicon oxycarbides, silicon carbonitrides, molybdenum alloys containing silicon, niobium alloys containing silicon.
  • the article of the present invention includes further environmental barrier layers 160 and 180 applied on to the bond coat system.
  • the barrier layers provide protection against high velocity steam at high temperatures and high pressure.
  • the barrier layers may comprise mullite, alkaline earth aluminosilicates including barium strontium aluminosilicate (BSAS) and strontium aluminosilicate (SAS), yttrium silicates, rare earth silicates, hafnium or zirconium silicate, oxides of hafnium, zirconium, titanium, silicon, yttrium, rare earth metals, tantalum, niobium, aluminum and mixtures thereof.
  • BSAS barium strontium aluminosilicate
  • SAS strontium aluminosilicate
  • the layers described above may be applied by any processing methods known in prior art which include, thermal spraying, chemical vapor deposition, physical vapor deposition, electrophoretic deposition, electrostatic deposition, preceramic polymer pyrolysis, sol-gel, slurry coating, dipping, air-brushing, sputtering, slurry painting or any combination thereof.
  • sacrificial pore formers can be used to introduce the porosity into the compliant layer. Sacrificial pore formers are well known in the art and include materials such as polyesters, polystyrene, etc.
  • FIG. 3 shows four-point bending strength of SN282 silicon nitride with the new environmental barrier coating (EBC) bond coat architecture, shown as a fraction of the strength retained compared to the baseline SN282 material (without an EBC). Two different variations of the new bond coat architecture are shown. The range of baseline strength for uncoated SN282 is indicated by the shading. The dashed line shows the typical fraction of retained strength using the prior art EBC architecture, where silicon was applied directly to the silicon nitride substrate. Description of the examples below further demonstrates the advantages of the new EBC architecture.
  • EBC environmental barrier coating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
US11/135,857 2005-05-23 2005-05-23 Coating system for silicon based substrates Active US7374818B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US11/135,857 US7374818B2 (en) 2005-05-23 2005-05-23 Coating system for silicon based substrates
JP2006075908A JP2006327923A (ja) 2005-05-23 2006-03-20 ケイ素ベースの基体のためのコーティング系
DE602006014058T DE602006014058D1 (de) 2005-05-23 2006-03-21 Schichtsystem für siliziumhaltige Substrats
EP06251493A EP1726681B1 (fr) 2005-05-23 2006-03-21 Systéme de couches pour substrats à base de silicium
CNB2006100682523A CN100415693C (zh) 2005-05-23 2006-03-22 硅基衬底的涂层系统

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Application Number Priority Date Filing Date Title
US11/135,857 US7374818B2 (en) 2005-05-23 2005-05-23 Coating system for silicon based substrates

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US20070014996A1 US20070014996A1 (en) 2007-01-18
US7374818B2 true US7374818B2 (en) 2008-05-20

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US (1) US7374818B2 (fr)
EP (1) EP1726681B1 (fr)
JP (1) JP2006327923A (fr)
CN (1) CN100415693C (fr)
DE (1) DE602006014058D1 (fr)

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US20090186237A1 (en) * 2008-01-18 2009-07-23 Rolls-Royce Corp. CMAS-Resistant Thermal Barrier Coatings
US20090184280A1 (en) * 2008-01-18 2009-07-23 Rolls-Royce Corp. Low Thermal Conductivity, CMAS-Resistant Thermal Barrier Coatings
US20090274850A1 (en) * 2008-05-01 2009-11-05 United Technologies Corporation Low cost non-line-of -sight protective coatings
US20100080984A1 (en) * 2008-09-30 2010-04-01 Rolls-Royce Corp. Coating including a rare earth silicate-based layer including a second phase
US20100129636A1 (en) * 2008-11-25 2010-05-27 Rolls-Royce Corporation Abradable layer including a rare earth silicate
US20100136349A1 (en) * 2008-11-25 2010-06-03 Rolls-Royce Corporation Multilayer thermal barrier coatings
US20100158680A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Cmas mitigation compositions, environmental barrier coatings comprising the same, and ceramic components comprising the same
US20100159253A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Environmental barrier coatings providing cmas mitigation capability for ceramic substrate components
US20100154422A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Cmas mitigation compositions, environmental barrier coatings comprising the same, and ceramic components comprising the same
US20100159151A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Methods for making environmental barrier coatings and ceramic components having cmas mitigation capability
US20100159261A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Environmental barrier coatings providing cmas mitigation capability for ceramic substrate components
US20100159150A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Methods for making environmental barrier coatings and ceramic components having cmas mitigation capability
US20100159252A1 (en) * 2008-12-19 2010-06-24 Glen Harold Kirby Environmental barrier coatings providing cmas mitigation capability for ceramic substrate components
US20110033630A1 (en) * 2009-08-05 2011-02-10 Rolls-Royce Corporation Techniques for depositing coating on ceramic substrate
US20110206937A1 (en) * 2010-02-25 2011-08-25 Schmidt Wayde R Composite article having a ceramic nanocomposite layer
US20110236695A1 (en) * 2010-03-29 2011-09-29 Schmidt Wayde R Composite article having a solid solution protective layer
US8475945B2 (en) * 2011-06-23 2013-07-02 United Technologies Corporation Composite article including silicon oxycarbide layer
US9177828B2 (en) 2011-02-10 2015-11-03 Micron Technology, Inc. External gettering method and device
US9194242B2 (en) 2010-07-23 2015-11-24 Rolls-Royce Corporation Thermal barrier coatings including CMAS-resistant thermal barrier coating layers
US9938839B2 (en) 2014-03-14 2018-04-10 General Electric Company Articles having reduced expansion and hermetic environmental barrier coatings and methods for their manufacture
US10125618B2 (en) 2010-08-27 2018-11-13 Rolls-Royce Corporation Vapor deposition of rare earth silicate environmental barrier coatings
US10329205B2 (en) 2014-11-24 2019-06-25 Rolls-Royce Corporation Bond layer for silicon-containing substrates
US10851656B2 (en) 2017-09-27 2020-12-01 Rolls-Royce Corporation Multilayer environmental barrier coating
US10941079B2 (en) * 2015-09-10 2021-03-09 Rolls-Royce High Temperature Composites, Inc. Applying silicon metal-containing bond layer to ceramic or ceramic matrix composite substrates
US11274562B2 (en) 2017-04-25 2022-03-15 General Electric Company Gas turbine components and methods of assembling the same
US11655543B2 (en) 2017-08-08 2023-05-23 Rolls-Royce Corporation CMAS-resistant barrier coatings
US11851770B2 (en) 2017-07-17 2023-12-26 Rolls-Royce Corporation Thermal barrier coatings for components in high-temperature mechanical systems

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EP1996341B1 (fr) * 2006-02-20 2018-09-26 Kang N. Lee Article comprenant un systeme de revetement formant une barriere environnementale
DE102006050789A1 (de) * 2006-10-27 2008-04-30 Mtu Aero Engines Gmbh Aufgedampfte Beschichtung und thermisch belastbares Bauteil mit einer solchen Beschichtung, sowie Verfahren und Vorrichtung zur Herstellung einer solchen Beschichtung
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EP1726681B1 (fr) 2010-05-05
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