US6994891B2 - Method for producing an epoxy composition - Google Patents
Method for producing an epoxy composition Download PDFInfo
- Publication number
- US6994891B2 US6994891B2 US10/867,293 US86729304A US6994891B2 US 6994891 B2 US6994891 B2 US 6994891B2 US 86729304 A US86729304 A US 86729304A US 6994891 B2 US6994891 B2 US 6994891B2
- Authority
- US
- United States
- Prior art keywords
- mixture
- epoxy
- epoxy resin
- ceramic material
- polarized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 187
- 239000004593 Epoxy Substances 0.000 title claims abstract description 83
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 115
- 239000003822 epoxy resin Substances 0.000 claims abstract description 60
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 60
- 229910052742 iron Inorganic materials 0.000 claims abstract description 56
- 239000004848 polyfunctional curative Substances 0.000 claims abstract description 46
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 37
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 25
- 230000005672 electromagnetic field Effects 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 19
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract 18
- 238000002156 mixing Methods 0.000 claims description 28
- 229910000859 α-Fe Inorganic materials 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 6
- 229930185605 Bisphenol Natural products 0.000 claims description 4
- 230000003213 activating effect Effects 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 14
- -1 Cab-O-Sil® Chemical compound 0.000 abstract 1
- 241000238586 Cirripedia Species 0.000 description 7
- 238000000576 coating method Methods 0.000 description 4
- 239000013535 sea water Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 235000014653 Carica parviflora Nutrition 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 241000242757 Anthozoa Species 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 241000243321 Cnidaria Species 0.000 description 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Definitions
- the present invention is directed to an epoxy composition for marine applications and the method for producing the epoxy composition.
- an epoxy composition comprising a magnetized iron.
- Paint and other coatings for marine vessels and structures such as boat and ship bottoms, decks, hulls and off shore rigs are subjected to the corrosive effects of salt water and marine life, coral and barnacles for example, when immersed in sea water. Because of the negative effects of sea water, the marine vessels must be scraped and repainted or coated frequently, costing the loss of time and money as the vessels are pulled out of service for refurbishing.
- Burge et al. U.S. Pat. No. 4,686,252 disclose a process for preparing a building and/or construction material, a polymer modified aqueous dispersion, and its use thereof for the preparation of building materials.
- the process comprises admixing a stable aqueous dispersion containing a non-curing mixture of amorphous silicon dioxide and at least one polymer, with at least one inorganic binder.
- Ginsberg in U.S. Pat. No. 6,110,996, hereby incorporated as if reproduced in its entirety, discloses a building composition and method of preventing corrosion, the composition having ceramic-like qualities of durability and thermal insulation to be used as a coating over existing building materials using an epoxy composition.
- a primary object of the present invention is to provide a composition and method of producing the lightweight, high strength composition for use in the coating of marine vessels and structures, ships, smaller boats, and oil rigs for example, that are subjected to corrosion and barnacle build-up when immersed in sea water for a period of time.
- the present invention resides, in part, in the surprising realization that combining epoxy resin with ceramic materials and an iron particulate that is then magnetized, produces the ceramic-like qualities of strength, hardness, durability, waterproofing for marine surfaces as well as repelling sea life.
- One embodiment of the present invention comprises a first mixture having an epoxy resin, a ceramic material, a carbosil, a silicone, and an iron particulate, the iron particulate magnetized to create a polarized, electromagnetic field.
- the inventive composition also comprises a second mixture to be combined with the first mixture, the second mixture preferably comprising an epoxy hardener.
- the epoxy resin further comprises a color pigment.
- a preferred epoxy resin can comprise epichlordin bisphenol and a preferred epoxy hardener comprises jaffeine phenol.
- the iron particulate can comprise ferrite iron in the form of a powder.
- An alternative epoxy composition for marine applications comprises a first mixture comprising an epoxy resin, a ceramic material, a carbosil, a silicone, and iron particulate, the iron particulate magnetized to create a polarized, electromagnetic field, the first mixture in combination with a second mixture, the second mixture comprising an epoxy hardener, a ceramic material and a carbosil.
- the epoxy resin comprises from about 55% to 65% by weight of the composition.
- an epoxy resin is mixed with a ceramic material, a carbosil, and a silicone.
- Iron particulate such as ferrite iron is added to the mixture and an electro-magnetic coil is activated within the mixture resulting so that the ferrite iron particulate is magnetized to create a polarized, electro-magnetic field within the mixture.
- an epoxy hardener can be mixed with a ceramic material and a carbosil.
- the epoxy resin, ceramic material, carbosil, and silicone are mixed in a first mixing tank and then added to a second mixing tank, the second mixing tank comprising a color pigment and the iron particulate, the second tank further comprising means for polarizing the iron particulate.
- the polarized epoxy resin mixture is combined with the epoxy hardener mixture and applied to a marine vessel.
- the mixing of the polarized epoxy resin mixture with the epoxy hardener mixture can be performed within a polarized spray system.
- the combined mixture of the polarized epoxy resin mixture and the epoxy hardener mixture can be cured by heating to at least 150° F. before applying to the marine vessel.
- the FIGURE is a schematic of the method of the present invention.
- the present invention is directed to a composition and method of producing the lightweight, high strength composition for use in the coating of marine vessels and structures, ships, smaller boats, and oil rigs for example, that are subjected to corrosion and barnacle build-up when immersed in sea water for a period of time.
- the lightweight, high strength epoxy composition produces an electromagnetic field to reduce the build-up of marine life onto the surface of the vessel.
- the mixture of two unique epoxy materials, magnetized to produce a polarized, electromagnetic field results in a composition that exhibits the physical properties of corrosion-resistance, durability and anti-fouling (from barnacles and corals) when applied to marine surfaces.
- an epoxy resin preferably in liquid form, 20
- a mixer 22 to be combined with one or more materials, preferably dry materials 40 , which are piped into a feeder 42 and then into the mixer 22 .
- the dry materials may be selected from a group of one or more additives selected from a group of additives, the group comprising a ceramic material, a carbosil, a silicone, a color pigment and ferrite iron particulate.
- the combined mixture is then submitted to a polarizing process, preferably in a second tank 24 so that the ferrite iron particulate is magnetized to create a polarized, electromagnetic field.
- the color pigment may be added to this second tank 24 during the polarizing process.
- the epoxy resin comprises epichlordin bisphenol.
- the ferrite iron particulate can comprise ferrite iron powder, preferably, strantium ferrite.
- a second mixture is produced for ultimately combining with the first mixture at the point of application to the marine vessel.
- the second mixture comprises an epoxy hardener 30 .
- the epoxy hardener comprises jaffeine phenol.
- the epoxy hardener 30 can be combined with one or more additives 50 selected from a group of additives, the group comprising a ceramic material, a carbosil, a silicone, a color pigment and iron particulate, the iron particulate magnetized to create a polarized, electromagnetic field.
- Another preferred epoxy composition for marine applications comprises a first mixture comprising an epoxy resin, a ceramic material, a carbosil, a silicone, and ferrite iron particulate, the ferrite iron particulate magnetized to create a polarized, electro-magnetic field.
- the first mixture is combined on site of application with a second mixture, the second mixture comprising an epoxy hardener, a ceramic material and a carbosil.
- the epoxy resin comprises from about 55% to about 65% by weight of the composition
- the ceramic material in the first mixture comprises from about 15% to about 25% by weight
- the silicone comprises from about 10% to about 20% by weight
- the carbosil in the first mixture comprises about 10% to about 20% by weight
- the ferrite iron particulate comprises from about 2% to about 8% by weight
- a color pigment comprising from about 1% to about 5% by weight
- the epoxy hardener comprises from about 40% to about 60% by weight
- the ceramic material in the second mixture comprises from about 25% to about 35% by weight
- the carbosil in the second mixture comprises about 15% to about 25% by weight.
- a preferred ratio of the first mixture to the second mixture is 2:1.
- the combination of the first mixture and the second mixture when applied to a marine surface is a cured combination, the curing resulting from heating the combination of the epoxy resin mixture and the epoxy hardener mixture to at least 150° F.
- one preferred method for producing an epoxy composition comprises mixing a first mixture comprising an epoxy resin from tank A, 20 , with dry materials 40 .
- the dry materials 40 can be selected from a ceramic material, a carbosil, and a silicone.
- Iron particulate, such as ferrite iron is preferably included with the dry materials 40 and passed through a feeder 42 to a mixing tank 22 to be mixed with the epoxy resin.
- the resulting mixture is sent to another tank 24 and submitted to a polarizing process by activating an electromagnetic coil within the epoxy resin mixture so that the ferrite iron particulate is magnetized to create a polarized, electro-magnetic field within the mixture.
- the polarized epoxy resin mixture is then sent to a storage tank 26 and then poured into drums 28 for transport to sites for marine application.
- the epoxy resin, ceramic material, carbosil, and silicone are mixed in a first mixing tank 22 , preferably a centrifugal mixing tank, and than added to a second mixing tank 24 , the second mixing tank comprising a color pigment and the ferrite iron particulate, the second tank further comprises means for polarizing the ferrite iron particulate, an electromagnetic coil for example.
- One preferred method of producing an epoxy hardener comprises mixing, within a separate tank 32 , an epoxy hardener from a storage tank 30 with one or more additives from a second tank 50 containing dry materials, the additives selected from a group of additives comprising a ceramic material, a carbosil, a silicone, a color pigment and ferrite iron particulate, the ferrite iron particulate magnetized to create a polarized, electromagnetic field.
- the dry materials from tank 50 are passed through a feeder 52 and fed into the mixer 32 , preferably a centrifugal mixer and then piped into a storage tank 34 for filling into storage drums 38 .
- the drums 28 , 38 can then be transported to the application sites for applying to marine surfaces.
- an epoxy hardener from a first tank 30 is mixed with a ceramic material and carbosil from a second tank 50 in a centrifugal mixer 32 .
- the epoxy resin mixture Upon application to a surface of a marine vessel, the epoxy resin mixture is combined with the epoxy hardener mixture, mixing the combined epoxy resin mixture and the epoxy hardener mixture and the resulting mixed combination is applied to a marine vessel.
- the epoxy resin mixture is a magnetically polarized mixture.
- the epoxy hardener mixture is magnetically polarized.
- the mixture of the polarized epoxy resin mixture from drums 28 is combined with the epoxy hardener from drums 38 within a polarized spray system 60 as known in the art.
- the combined mixture of the epoxy resin mixture and the epoxy hardener mixture can be cured, preferably within a spray system 60 comprising a heating coil, by heating to at least 150° F.
- the method comprises mixing an epoxy resin, a ceramic material, a carbosil, and a silicone in a mixing tank 22 using a centrifugal mixer, transferring the resulting mixture to a second tank, mixing the epoxy resin mixture with ferrite iron particulate within the second tank and continuing to mix with a centrifugal mixture.
- an electro-magnetic coil is activated within the second tank 24 so that the ferrite iron particulate is magnetized to create a polarized, electromagnetic field within the mixture.
- an epoxy hardener is mixed with a ceramic material and carbosil within a third mixer 32 .
- the epoxy resin mixture and epoxy hardener mixture are stored in separate drums until ready for application onto a surface of a marine vessel.
- the magnetically polarized epoxy resin mixture is combined with the epoxy hardener mixture and mixed thoroughly before applying the resulting mixed combination to the surface of a marine vessel.
- the ratio of the epoxy resin mixture to the epoxy hardener mixture is 2:1.
- One preferred method further comprises the step of curing the combined epoxy resin mixture and epoxy hardener mixture by heating before application to a marine surface.
- the epoxy resin mixture and the epoxy hardener mixture can be combined, mixed, cured and applied by a spray system.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/867,293 US6994891B2 (en) | 2004-06-14 | 2004-06-14 | Method for producing an epoxy composition |
EP05769091A EP1765518A4 (fr) | 2004-06-14 | 2005-06-14 | Procede permettant de produire une composition d'epoxy |
CA002570359A CA2570359A1 (fr) | 2004-06-14 | 2005-06-14 | Procede permettant de produire une composition d'epoxy |
PCT/US2005/020728 WO2005123271A2 (fr) | 2004-06-14 | 2005-06-14 | Procede permettant de produire une composition d'epoxy |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/867,293 US6994891B2 (en) | 2004-06-14 | 2004-06-14 | Method for producing an epoxy composition |
Publications (2)
Publication Number | Publication Date |
---|---|
US20050276926A1 US20050276926A1 (en) | 2005-12-15 |
US6994891B2 true US6994891B2 (en) | 2006-02-07 |
Family
ID=35460872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/867,293 Expired - Lifetime US6994891B2 (en) | 2004-06-14 | 2004-06-14 | Method for producing an epoxy composition |
Country Status (4)
Country | Link |
---|---|
US (1) | US6994891B2 (fr) |
EP (1) | EP1765518A4 (fr) |
CA (1) | CA2570359A1 (fr) |
WO (1) | WO2005123271A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080286579A1 (en) * | 2007-05-16 | 2008-11-20 | Boulder Based Designs Inc. | Method for identification of equipment |
US20090145047A1 (en) * | 2007-10-15 | 2009-06-11 | Hurricanefabric.Com, Llc | Weather protection system |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009061308A1 (fr) * | 2007-11-05 | 2009-05-14 | Warren Environmental, Inc. | Procédé et système permettant de préchauffer des revêtements époxy destinés à une application par pulvérisation |
US9085710B2 (en) * | 2011-08-30 | 2015-07-21 | Illinois Tool Works Inc. | Toughened epoxy system for abrasion resistant coatings |
CN105694632B (zh) * | 2016-04-11 | 2017-10-13 | 浙江新乐造船有限公司 | 一种用于船舶舱壁的防火涂层及其制备方法和应用 |
CN113403011A (zh) * | 2021-05-28 | 2021-09-17 | 长江航道工程局有限责任公司 | 一种挖泥船泥泵修补剂及其制备方法和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5874773A (ja) * | 1981-10-28 | 1983-05-06 | Aisin Chem Co Ltd | 溶接継手の耐食層形成方法 |
US4558077A (en) * | 1984-03-08 | 1985-12-10 | General Motors Corporation | Epoxy bonded rare earth-iron magnets |
US4762864A (en) * | 1986-06-19 | 1988-08-09 | Ashland Oil Inc. | High performance induction curable two-component structural adhesive with nonsagging behavior |
US4874548A (en) * | 1988-03-14 | 1989-10-17 | Ameron, Inc. | Conductive adhesive |
US20020177027A1 (en) * | 2001-01-18 | 2002-11-28 | Yeager Gary William | Electrically conductive thermoset composition, method for the preparation thereof, and articles derived therefrom |
US20040144960A1 (en) * | 2001-09-11 | 2004-07-29 | Toshiaki Arai | Resin-magnet composition |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717606A (en) * | 1971-04-05 | 1973-02-20 | H Lomasney | Solventless coal tar extended antifouling coating |
JPS61216935A (ja) * | 1985-03-22 | 1986-09-26 | B O Chem Kk | 鉄鋼構造物の保護法 |
JPH06116515A (ja) * | 1992-10-02 | 1994-04-26 | Asahi Denka Kogyo Kk | 防汚塗料組成物 |
GB9310873D0 (en) * | 1993-05-26 | 1993-07-14 | Waterline Paints Limited | An anti-fouling paint |
-
2004
- 2004-06-14 US US10/867,293 patent/US6994891B2/en not_active Expired - Lifetime
-
2005
- 2005-06-14 WO PCT/US2005/020728 patent/WO2005123271A2/fr active Application Filing
- 2005-06-14 EP EP05769091A patent/EP1765518A4/fr not_active Withdrawn
- 2005-06-14 CA CA002570359A patent/CA2570359A1/fr not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5874773A (ja) * | 1981-10-28 | 1983-05-06 | Aisin Chem Co Ltd | 溶接継手の耐食層形成方法 |
US4558077A (en) * | 1984-03-08 | 1985-12-10 | General Motors Corporation | Epoxy bonded rare earth-iron magnets |
US4762864A (en) * | 1986-06-19 | 1988-08-09 | Ashland Oil Inc. | High performance induction curable two-component structural adhesive with nonsagging behavior |
US4874548A (en) * | 1988-03-14 | 1989-10-17 | Ameron, Inc. | Conductive adhesive |
US20020177027A1 (en) * | 2001-01-18 | 2002-11-28 | Yeager Gary William | Electrically conductive thermoset composition, method for the preparation thereof, and articles derived therefrom |
US20040144960A1 (en) * | 2001-09-11 | 2004-07-29 | Toshiaki Arai | Resin-magnet composition |
Non-Patent Citations (1)
Title |
---|
English Abstract of JP 58-074773, Osamu et al., May 6, 1983. * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080286579A1 (en) * | 2007-05-16 | 2008-11-20 | Boulder Based Designs Inc. | Method for identification of equipment |
US20090145047A1 (en) * | 2007-10-15 | 2009-06-11 | Hurricanefabric.Com, Llc | Weather protection system |
US20090145048A1 (en) * | 2007-10-15 | 2009-06-11 | Hurricanefabric.Com, Llc | Weather protection system |
US8215073B2 (en) * | 2007-10-15 | 2012-07-10 | Hurricane Fabric, Llc | Weather protection system |
US8215072B2 (en) * | 2007-10-15 | 2012-07-10 | Hurricane Fabric, Llc | Weather protection system |
US8833034B2 (en) | 2007-10-15 | 2014-09-16 | Hurricane Fabric, Llc | Clip for weather protection system |
Also Published As
Publication number | Publication date |
---|---|
EP1765518A2 (fr) | 2007-03-28 |
WO2005123271A2 (fr) | 2005-12-29 |
US20050276926A1 (en) | 2005-12-15 |
CA2570359A1 (fr) | 2005-12-29 |
EP1765518A4 (fr) | 2007-11-14 |
WO2005123271A3 (fr) | 2006-03-16 |
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