US6905725B2 - Method for creating and visualizing an optically invisible mark - Google Patents
Method for creating and visualizing an optically invisible mark Download PDFInfo
- Publication number
- US6905725B2 US6905725B2 US10/475,935 US47593503A US6905725B2 US 6905725 B2 US6905725 B2 US 6905725B2 US 47593503 A US47593503 A US 47593503A US 6905725 B2 US6905725 B2 US 6905725B2
- Authority
- US
- United States
- Prior art keywords
- question
- image
- meta
- optically invisible
- visualization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/003—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using security elements
- G07D7/0032—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using security elements using holograms
Definitions
- the invention relates to a method for writing and reading visually imperceptible information and can mainly be used for visualization of hidden images (marks) identifying objects, which provide protection against unauthorized reproduction (forgery), but also for purposes of scientific research, for providing visualization of optically invisible structures in the surface layer of an object by variation of surface energy.
- a disadvantage of the method for visualization of a hidden image known in the art is its limited applicability.
- the geometric parameters of the microstructures of the protective mark, which are subjected to visualization by means of optical means are such, that they are considered defects of the item of jewelry and greatly reduce its aesthetic qualities and its value.
- the method closest to the disclosed invention is the method of creation and visualization of an optically invisible mark, according to which in the area of the surface of the object in question an optically invisible marking image is formed by means of modification of at least one part of said surface, after which visualization of the microstructures of the marking image is established, by means of etching and subsequent observation of the mark by means of powerful optical or electronic microscopes (RU No. 2073270, C1).
- a disadvantage of said method of creation and visualization of an optically invisible mark known from the prior art is its limited range of application due to its applicability exclusively for special polymeric materials in the form of films, and to its inability to provide visualization of a marking image without using strong microscopes.
- the known method does not allow the mark to be kept optically invisible after its first visualization (i.e. reproduction by use of etching).
- the object of the disclosed invention is the creation on the surface of the object in question of a lasting optically invisible mark (i.e. invisible for use with any optical microscope) allowing the temporary, and, in addition, repeated visualization, including visualization without use of optical means.
- a lasting optically invisible mark i.e. invisible for use with any optical microscope
- This aim is achieved in that, in the method of creation and visualization of an optically invisible mark, according to which on the surface of the object in question an optically invisible marking image is formed by modification of, at least, one part of the surface, after which visualization of said image is established, according to the invention, said surface of the object in question is preliminarily brought to a mirror, the modification is made by changing the surface energy of the modified parts, and visualization of the optically invisible marking image is provided by means of creation, in the area of the surface of the object in question, of a meta-stable environment by means of which the visually perceived image of the optically invisible mark is obtained in the form of difference of the structures formed by particles of the stable phase of the meta-stable environment on parts of the surface with different surface energy.
- meta-stable environment super-cooled vapor may be used, an image of structures being obtained, which structures are formed by particles of the stable phase of the meta-stable environment, in the form of drops of liquid on the surface of the object in question.
- a meta-stable environment can conveniently be obtained from the water vapor in the surrounding air, for example by cooling the object in question.
- meta-stable environment super-heated liquid As a meta-stable environment super-heated liquid may be used, an image of structures being obtained, which structures are formed by particles of the stable phase of the meta-stable environment, in the form of gas bubbles on the surface of the object in question.
- the optically invisible marking image may be formed by a spatially modulated ion beam.
- FIG. 1 shows the object in question with an optically invisible marking image before its visualization.
- FIG. 2 shows the object in question after realization of visualization of the optically invisible marking image.
- an optically invisible (hidden) marking image is formed by means of modification of, at least, one part of said surface.
- the modification is brought about by changing the surface energy of the parts being modified.
- the modified parts can be obtained, for example, by means of subjecting the corresponding surface of the object in question to a spatially modulated ion beam (for example, by passing an ion beam through a stencil mask) or by means of laser ablation.
- Visualization of the optically invisible (hidden) image is achieved by establishing in the area of said surface (carrying the optically invisible marking image) of the object in question a meta-stable environment, by means of which a visually observed image of an optically invisible mark is obtained in the form of a difference in structures (formed by particles of the stable phase of the meta-stable environment) on parts of the surface of the object in question with a different surface energy (i.e. on the parts, that are functionally “nucleation centers” of the stabilization of the phase of said meta-stable environment).
- the surface energy determines the work of forming the “nucleation centers” of a new phase and the energy of the phase transformation activation process.
- the existence of surface energy and surface tension lies at the root of meta-stable states (i.e. states of supercooling, superheating).
- the surface energy depends only minimally on the temperature.
- supercooled vapor for example, obtained from water vapor from the surrounding air by contacting it with the cooled object in question
- superheated liquid for example, water vapor from the surrounding air by contacting it with the cooled object in question
- the surface of the object in question is made into a mirror in order to increase the contrast of the visualized marking image.
- a visualization mode can be used, in which the condition of “meta-stability” of the surrounding environment is fulfilled exclusively for the parts of the surface of the object in question that are being modified.
- the preparation requirements in particular, regarding the processing purity class
- the visualization mode of the image of the optically invisible mark moves from a dynamic process to a more static one, for which it is necessary to provide thermal and/or baric stabilization of said process.
- the disclosed method is essentially based on the strong dependence of the formation dynamics at the surface of the object of the stable phase from the meta-stable environment from the value of the free surface energy.
- the formation of the stable phase from the meta-stable environment takes place differently.
- a different formation dynamic of the stable phase leads to visualization of the structure of the surface parts, that form the optically invisible marking image.
- the mark is permanent, because the modification of the parts of the surface object by changing the surface energy, e.g. obtained by means of spatially modulated ion beams, leads to a stable (including under ambient conditions) change of the state and structure of the surface with a changed surface energy.
- a hidden (optically invisible) marking image was formed in the shape of a snow-flake with a diameter of 6 mm, by modification of surface parts of the object by means of an ion beam passed through a stencil mask.
- the substrate was placed in the cooling chamber of a household refrigerator. Then the substrate was placed in the surrounding environment (corresponding with room conditions).
- the optically invisible (hidden) marking image was visualized in the shape of drop of condensed water, distributed in a determined fashion on the surface of the object in question, as shown in FIG. 2 of the drawings, where the visually observed image of the snow-flake mark (formed form drop of condensed water) is shown at 7 ⁇ magnification.
- Tests carded out in the course of one year with the initial mark (shown in FIG. 2 ), did not reveal any decrease in contrast of the mark after multiple visualizations in the course of the testing period. From the moment of creation of said mark the repeated application of the visualization process by means of the meta-stable environment does not transform the optically invisible marking image into a permanently visible one, as is the case, for example, in the prototype, following visualization of the optically invisible mark in a polymeric film by means of alkali etching.
- the disclosed invention may be applied widely in various technical and scientific areas for writing and reading information is hidden from visual perception. It may in particular be used for repeated visualization of hidden images (marks) identifying an object, which images provide protection from unauthorized reproduction (forgery), as well as for purposes of scientific research in order to provide the visualization of optically invisible structures that differ only by the magnitude of the surface energy.
Abstract
This invention relates to methods of writing and reading information hidden from visual observation and may be used for visualizing hidden images (marks) identifying an object, which provide protection from unauthorized reproduction (forgery). The method of creation and visualization of an optically invisible mark consists in the following. On the surface of the object in question an optically invisible marking image is formed by means of modification of, at least one part of said surface, after which visualization of said image is established. Prior to formation of the optically invisible marking image the surface of the object in question (carrying the applied image) is made into a mirror. Modification is achieved by changing the surface energy of the parts being modified. In addition the visualization of the optically invisible marking image is achieved by means of establishing in the area of said surface of the object in question a meta-stable environment, by means of which the visually observed image of the optically invisible mark is obtained as differences of the structures, which are formed by particles of the stable phase of the meta-stable environment, on parts of the surface (of the object in question) with different surface energy. Different variants regarding the use of meta-stable environments, as well as methods of formation, on the surface of a object in question, of an optically invisible marking image are provided.
Description
The invention relates to a method for writing and reading visually imperceptible information and can mainly be used for visualization of hidden images (marks) identifying objects, which provide protection against unauthorized reproduction (forgery), but also for purposes of scientific research, for providing visualization of optically invisible structures in the surface layer of an object by variation of surface energy.
From the prior art a method is known for creating and visualizing an optically invisible mark, according to which in the near-surface area of the object (in particular, diamond jewelry) an image (protective mark), hidden from perception by the unaided eye is made by means of a laser beam, the further visualization of which may be established by means of corresponding optical means (U.S. Pat. No. 4,467,172).
A disadvantage of the method for visualization of a hidden image known in the art is its limited applicability. For example, when marking jewelry, in particular diamonds, the geometric parameters of the microstructures of the protective mark, which are subjected to visualization by means of optical means, are such, that they are considered defects of the item of jewelry and greatly reduce its aesthetic qualities and its value.
The method closest to the disclosed invention is the method of creation and visualization of an optically invisible mark, according to which in the area of the surface of the object in question an optically invisible marking image is formed by means of modification of at least one part of said surface, after which visualization of the microstructures of the marking image is established, by means of etching and subsequent observation of the mark by means of powerful optical or electronic microscopes (RU No. 2073270, C1).
A disadvantage of said method of creation and visualization of an optically invisible mark known from the prior art, is its limited range of application due to its applicability exclusively for special polymeric materials in the form of films, and to its inability to provide visualization of a marking image without using strong microscopes.
Apart from that, the known method does not allow the mark to be kept optically invisible after its first visualization (i.e. reproduction by use of etching).
The object of the disclosed invention is the creation on the surface of the object in question of a lasting optically invisible mark (i.e. invisible for use with any optical microscope) allowing the temporary, and, in addition, repeated visualization, including visualization without use of optical means.
This aim is achieved in that, in the method of creation and visualization of an optically invisible mark, according to which on the surface of the object in question an optically invisible marking image is formed by modification of, at least, one part of the surface, after which visualization of said image is established, according to the invention, said surface of the object in question is preliminarily brought to a mirror, the modification is made by changing the surface energy of the modified parts, and visualization of the optically invisible marking image is provided by means of creation, in the area of the surface of the object in question, of a meta-stable environment by means of which the visually perceived image of the optically invisible mark is obtained in the form of difference of the structures formed by particles of the stable phase of the meta-stable environment on parts of the surface with different surface energy.
As a meta-stable environment super-cooled vapor may be used, an image of structures being obtained, which structures are formed by particles of the stable phase of the meta-stable environment, in the form of drops of liquid on the surface of the object in question.
A meta-stable environment can conveniently be obtained from the water vapor in the surrounding air, for example by cooling the object in question.
As a meta-stable environment super-heated liquid may be used, an image of structures being obtained, which structures are formed by particles of the stable phase of the meta-stable environment, in the form of gas bubbles on the surface of the object in question.
It would be useful to make the surface of the object in question into a mirror by polishing.
The optically invisible marking image may be formed by a spatially modulated ion beam.
The invention is further elucidated in the drawings.
From a physical point of view the disclosed method of creation and visualization of an optically invisible mark (of a hidden image) is essentially based on similar principles regarding visualization of the tracks of charged particles during study thereof by means of a Wilson chamber or a bubble chamber, namely:
-
- condensation of supersaturated vapor on “nucleation centers” (ions) of the stabilized phase state, which (in a Wilson chamber) are ions, that are formed along the path of motion of a charged particle;
- boiling up of superheated liquid near “nucleation centers” of boiling (in a bubble chamber), which are formed as a result of heating a small area of liquid due to absorption therein of δ-electrons, which are emitted/released by the charged particle in the course of its movement.
However, the disclosed method is realized by the following, practically different, method.
On the surface of the object in question (preliminarily made into a mirror, for example, by polishing) an optically invisible (hidden) marking image is formed by means of modification of, at least, one part of said surface. The modification is brought about by changing the surface energy of the parts being modified. The modified parts can be obtained, for example, by means of subjecting the corresponding surface of the object in question to a spatially modulated ion beam (for example, by passing an ion beam through a stencil mask) or by means of laser ablation. Visualization of the optically invisible (hidden) image is achieved by establishing in the area of said surface (carrying the optically invisible marking image) of the object in question a meta-stable environment, by means of which a visually observed image of an optically invisible mark is obtained in the form of a difference in structures (formed by particles of the stable phase of the meta-stable environment) on parts of the surface of the object in question with a different surface energy (i.e. on the parts, that are functionally “nucleation centers” of the stabilization of the phase of said meta-stable environment).
It should be noted, that the surface energy determines the work of forming the “nucleation centers” of a new phase and the energy of the phase transformation activation process. The existence of surface energy and surface tension lies at the root of meta-stable states (i.e. states of supercooling, superheating). Moreover, unlike the surface tension, the surface energy depends only minimally on the temperature.
As a meta-stable environment, usually supercooled vapor is used (for example, obtained from water vapor from the surrounding air by contacting it with the cooled object in question) or superheated liquid.
In case supercooled vapor is used as a meta-stable environment, an image of structures, which are formed by particles of a stable phase of the meta-stable environment, is obtained as drops of liquid on the surface of the object in question.
In case superheated liquid is used as a meta-stable environment, the image of the structures, formed by particles of the stable phase of the meta-stable environment, is obtained in the form of gas bubbles on the surface of the object in question.
The surface of the object in question is made into a mirror in order to increase the contrast of the visualized marking image.
It should also be noted, that for increasing the contrast of the visually observed mage of the optically invisible mark a visualization mode can be used, in which the condition of “meta-stability” of the surrounding environment is fulfilled exclusively for the parts of the surface of the object in question that are being modified. As a consequence, the preparation requirements (in particular, regarding the processing purity class) of the surface of the object in question, where the optically invisible marking image is established. However, it should be noted, that for the last of the discussed cases, the visualization mode of the image of the optically invisible mark moves from a dynamic process to a more static one, for which it is necessary to provide thermal and/or baric stabilization of said process.
In that manner, the disclosed method is essentially based on the strong dependence of the formation dynamics at the surface of the object of the stable phase from the meta-stable environment from the value of the free surface energy. On parts of the surface with different surface energy the formation of the stable phase from the meta-stable environment takes place differently. In the method according to the invention on the parts that are modified by changing the surface energy a different formation dynamic of the stable phase leads to visualization of the structure of the surface parts, that form the optically invisible marking image. The mark is permanent, because the modification of the parts of the surface object by changing the surface energy, e.g. obtained by means of spatially modulated ion beams, leads to a stable (including under ambient conditions) change of the state and structure of the surface with a changed surface energy.
On the surface, polished to a class 13 purity, of a substrate (object in question) made of K-8 glass a hidden (optically invisible) marking image was formed in the shape of a snow-flake with a diameter of 6 mm, by modification of surface parts of the object by means of an ion beam passed through a stencil mask. For visualization of the optically invisible marking image the substrate was placed in the cooling chamber of a household refrigerator. Then the substrate was placed in the surrounding environment (corresponding with room conditions). As a result, the optically invisible (hidden) marking image (snow-flake) was visualized in the shape of drop of condensed water, distributed in a determined fashion on the surface of the object in question, as shown in FIG. 2 of the drawings, where the visually observed image of the snow-flake mark (formed form drop of condensed water) is shown at 7× magnification.
Tests, carded out in the course of one year with the initial mark (shown in FIG. 2), did not reveal any decrease in contrast of the mark after multiple visualizations in the course of the testing period. From the moment of creation of said mark the repeated application of the visualization process by means of the meta-stable environment does not transform the optically invisible marking image into a permanently visible one, as is the case, for example, in the prototype, following visualization of the optically invisible mark in a polymeric film by means of alkali etching.
Thus, the disclosed invention may be applied widely in various technical and scientific areas for writing and reading information is hidden from visual perception. It may in particular be used for repeated visualization of hidden images (marks) identifying an object, which images provide protection from unauthorized reproduction (forgery), as well as for purposes of scientific research in order to provide the visualization of optically invisible structures that differ only by the magnitude of the surface energy.
Claims (6)
1. A method of creation and visualization of an optically invisible mark, according to which on the surface of a object in question an optically invisible image of a mark is formed by modifying at least one part of the surface, after which the visualization of that image is achieved, characterized in that the surface of the object in question is preliminarily made into a mirror, a modification is made by changing the surface energy of the modified parts, and visualization of optically invisible marking image is provided by means of creation, in the area of said surface of the object in question, of a meta-stable environment, by means of which a visually observed image of the optically invisible mark is achieved as difference in structures, formed by particles of the stable phase of the meta-stable environment, on the parts of the surface with different surface energy.
2. The method according to claim 1 , characterized in that as a meta-stable environment supercooled vapor is used, and a structure image is obtained, which structures are formed by particles of stable phase of the meta-stable environment, in the form of drops of liquid on the surface of the object in question.
3. The method according to claim 1 or 2 , characterized in that the meta-stable environment is obtained from water vapor of the surrounding air by cooling the object in question.
4. The method according to claim 1 , characterized in that as a meta-stable environment superheated liquid is used and an image of structures is obtained, which are made of particles of the stable phase of the meta-stable environment in the form of gas bubbles on the surface of the object in question.
5. Method according to claim 1 , characterized in that the surface of the object in question is made into a mirror by means of polishing.
6. Method according to claim 1 , characterized in that the optically invisible marking image is obtained by means of a spatially modulated ion beam.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/RU2001/000177 WO2002089041A1 (en) | 2001-04-26 | 2001-04-26 | Method for producing and visualising an optically invisible mark |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20040126703A1 US20040126703A1 (en) | 2004-07-01 |
| US6905725B2 true US6905725B2 (en) | 2005-06-14 |
Family
ID=20129617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/475,935 Expired - Fee Related US6905725B2 (en) | 2001-04-26 | 2001-04-26 | Method for creating and visualizing an optically invisible mark |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6905725B2 (en) |
| EP (1) | EP1391841A4 (en) |
| CN (1) | CN1258734C (en) |
| CA (1) | CA2445443C (en) |
| HK (1) | HK1068435A1 (en) |
| WO (1) | WO2002089041A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050084701A1 (en) * | 2003-10-20 | 2005-04-21 | The Boeing Company | Sprayed preforms for forming structural members |
| US20060225637A1 (en) * | 2005-04-07 | 2006-10-12 | The Coppola Companies | Tasting glasses having revealable indicators there on and method of conducting blind taste test |
| US20070228026A1 (en) * | 2006-03-31 | 2007-10-04 | S. Will International Co., Ltd | Method for printing laser mark on an inner peripheral surface of a ring |
| US20100054528A1 (en) * | 2006-08-04 | 2010-03-04 | Yuri Konstantinovich Nizienko | Method for Producing and Visualizing an Optically Hidden Mark |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7544390B2 (en) * | 2004-06-04 | 2009-06-09 | Visual Ice, Inc. | System and method for creating graphics on glass surfaces |
| EP1833635B1 (en) * | 2004-12-08 | 2012-06-06 | Laserop Ltd. | System and methods for producing tinted and non-tinted materials with non-discernable laser inscriptions |
| WO2006073325A1 (en) * | 2004-12-30 | 2006-07-13 | Yuri Konstantinovich Nizienko | Method for visualising an optically invisible mark image and device for carrying out said method |
| US20160167164A9 (en) * | 2006-07-10 | 2016-06-16 | Lazare Kaplan International, Inc. | System and method for gemstone microinscription |
| US8319145B2 (en) * | 2006-07-10 | 2012-11-27 | Lazare Kaplan International, Inc. | System and method for gemstone micro-inscription |
| CA2912955C (en) | 2013-05-30 | 2019-12-31 | Goldway Technology Limited | Method of marking material and system therefore, and material marked according to same method |
| SG11201602743TA (en) | 2013-10-11 | 2016-05-30 | Chow Tai Fook Jewellery Co Ltd | Method of providing markings to precious stones including gemstones and diamonds, and markings and marked precious stones marked according to such a method |
| CN106556608B (en) * | 2016-07-14 | 2019-05-28 | 苏州新材料研究所有限公司 | A kind of method and system of testing product surface defect |
| CN110998427A (en) * | 2017-08-10 | 2020-04-10 | 金泰克斯公司 | Laser ablated surface with indicia |
| EP4028226A4 (en) * | 2019-07-02 | 2023-06-07 | Master Dynamic Limited | Method of marking a solid-state material, markings formed from such methods and solid-state materials marked according to such a method |
| EP3994614A4 (en) * | 2019-07-02 | 2023-04-05 | Master Dynamic Limited | Method of marking a diamond, markings formed from such methods and diamonds marked according to such a method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0271245A2 (en) | 1986-12-04 | 1988-06-15 | Isomed, Inc. | Method and apparatus for detecting counterfeit articles |
| US5206496A (en) * | 1990-08-15 | 1993-04-27 | United Distillers, Plc | Sub-surface marking |
| WO1994006102A1 (en) | 1992-08-27 | 1994-03-17 | Thomas De La Rue & Company Limited | Security document inspection |
| RU2073270C1 (en) | 1995-10-31 | 1997-02-10 | Борис Ильич Белоусов | Method of information medium and protecting film fabrication for documents and working piece crasher and imitating staving off |
| US5767483A (en) * | 1993-08-19 | 1998-06-16 | United Distillers Plc | Method of laser marking a body of material having a thermal conductivity approximately equal to that of glass |
| WO1999034315A2 (en) | 1997-12-29 | 1999-07-08 | Sicpa Holding S.A. | Use of inorganic particles and method for marking and identifying a substrate or an article |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4467172A (en) * | 1983-01-03 | 1984-08-21 | Jerry Ehrenwald | Method and apparatus for laser engraving diamonds with permanent identification markings |
| US5410125A (en) * | 1990-10-11 | 1995-04-25 | Harry Winston, S.A. | Methods for producing indicia on diamonds |
| US5753887A (en) * | 1995-05-16 | 1998-05-19 | Engraving Technologies, Inc. | Apparatus for laser engraving indicia on gemstones |
| GB9710738D0 (en) * | 1997-05-23 | 1997-07-16 | Gersan Ets | Diamond marking |
| GB9727364D0 (en) * | 1997-12-24 | 1998-02-25 | Gersan Ets | Watermark |
-
2001
- 2001-04-26 EP EP01954549A patent/EP1391841A4/en not_active Withdrawn
- 2001-04-26 US US10/475,935 patent/US6905725B2/en not_active Expired - Fee Related
- 2001-04-26 WO PCT/RU2001/000177 patent/WO2002089041A1/en active Application Filing
- 2001-04-26 CN CNB018234194A patent/CN1258734C/en not_active Expired - Fee Related
- 2001-04-26 CA CA2445443A patent/CA2445443C/en not_active Expired - Fee Related
-
2005
- 2005-01-13 HK HK05100351A patent/HK1068435A1/en not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0271245A2 (en) | 1986-12-04 | 1988-06-15 | Isomed, Inc. | Method and apparatus for detecting counterfeit articles |
| US5206496A (en) * | 1990-08-15 | 1993-04-27 | United Distillers, Plc | Sub-surface marking |
| WO1994006102A1 (en) | 1992-08-27 | 1994-03-17 | Thomas De La Rue & Company Limited | Security document inspection |
| US5767483A (en) * | 1993-08-19 | 1998-06-16 | United Distillers Plc | Method of laser marking a body of material having a thermal conductivity approximately equal to that of glass |
| RU2073270C1 (en) | 1995-10-31 | 1997-02-10 | Борис Ильич Белоусов | Method of information medium and protecting film fabrication for documents and working piece crasher and imitating staving off |
| WO1999034315A2 (en) | 1997-12-29 | 1999-07-08 | Sicpa Holding S.A. | Use of inorganic particles and method for marking and identifying a substrate or an article |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050084701A1 (en) * | 2003-10-20 | 2005-04-21 | The Boeing Company | Sprayed preforms for forming structural members |
| US7128948B2 (en) * | 2003-10-20 | 2006-10-31 | The Boeing Company | Sprayed preforms for forming structural members |
| US20070014983A1 (en) * | 2003-10-20 | 2007-01-18 | The Boeing Company | Sprayed Preforms for Forming Structural Members |
| US7381446B2 (en) | 2003-10-20 | 2008-06-03 | The Boeing Company | Sprayed preforms to forming structural members |
| US20060225637A1 (en) * | 2005-04-07 | 2006-10-12 | The Coppola Companies | Tasting glasses having revealable indicators there on and method of conducting blind taste test |
| US7610872B2 (en) * | 2005-04-07 | 2009-11-03 | Roman Coppola | Tasting glasses having revealable indicators there on and method of conducting blind taste test |
| US20070228026A1 (en) * | 2006-03-31 | 2007-10-04 | S. Will International Co., Ltd | Method for printing laser mark on an inner peripheral surface of a ring |
| US20100054528A1 (en) * | 2006-08-04 | 2010-03-04 | Yuri Konstantinovich Nizienko | Method for Producing and Visualizing an Optically Hidden Mark |
| US8313793B2 (en) | 2006-08-04 | 2012-11-20 | Valinmark Inc. | Method for producing and visualizing an optically hidden mark |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2445443C (en) | 2013-01-08 |
| CN1522422A (en) | 2004-08-18 |
| WO2002089041A1 (en) | 2002-11-07 |
| HK1068435A1 (en) | 2005-04-29 |
| CA2445443A1 (en) | 2002-11-07 |
| EP1391841A4 (en) | 2004-07-28 |
| US20040126703A1 (en) | 2004-07-01 |
| EP1391841A1 (en) | 2004-02-25 |
| CN1258734C (en) | 2006-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6905725B2 (en) | Method for creating and visualizing an optically invisible mark | |
| US10475355B2 (en) | Method of providing markings to precious stones including gemstones and diamonds, and markings and marked precious stones marked according to such a method | |
| US5149938A (en) | Methods for producing indicia on diamonds | |
| CN107087404A (en) | Optically-variable transparent counterfeiting element | |
| US20040008888A1 (en) | Method for marking gemstones with a unique micro discrete indicia | |
| CN112739492B (en) | Method for generating and detecting light-permeable image in diamond and detection system | |
| AU2014334373A1 (en) | Method of providing markings to precious stones including gemstones and diamonds, and markings and marked precious stones marked according to such a method | |
| Allen et al. | Craters on silicon surfaces created by gas cluster ion impacts | |
| US20180193814A1 (en) | Method of marking material and system therefore, and material marked according to same method | |
| EP2053537B1 (en) | Method for producing and visualising an optically hidden mark | |
| CN106132723B (en) | Security element with lenticular image | |
| JPH11316308A (en) | Diffraction grating pattern | |
| CN101827713B (en) | Method for marking valuable articles | |
| JP2000121815A (en) | Diffraction grating pattern and article applied with same diffraction grating pattern | |
| RU2426487C2 (en) | Identification mark to mark valuable items and valuable item with its application | |
| TWI253406B (en) | Method for engraving irreproducible pattern on the surface of a diamond | |
| Hans et al. | Dynamics of nanoscale triangular features on Ge surfaces | |
| Kothes et al. | Expanding shells of shocked neutral hydrogen around compact HII regions | |
| WO2003099707A3 (en) | Method of altering the properties of a thin film and substrate implementing said method | |
| Kim et al. | Nanopatterning by ion beam sputtering in unconventional formats | |
| KR20020008283A (en) | Method of hologram design using hot stamping and water decal, sticker and designed nail manufactured using the same method | |
| Suzuki et al. | Direct formation of arrays of prolate Ag nanoparticles by dynamic oblique deposition | |
| WO2006073325A1 (en) | Method for visualising an optically invisible mark image and device for carrying out said method | |
| RU2427041C2 (en) | Method of making identification mark for marking valuable articles and valuable article with said mark | |
| RU2107629C1 (en) | Information card |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: VALINMARK INC., CANADA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:DYKHNE, ALEXANDER MIKHAILOVICH;NIZIENKO, YURI KONSTANTINOVICH;REEL/FRAME:015073/0916 Effective date: 20031024 |
|
| FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY |
|
| FPAY | Fee payment |
Year of fee payment: 4 |
|
| FPAY | Fee payment |
Year of fee payment: 8 |
|
| SULP | Surcharge for late payment |
Year of fee payment: 7 |
|
| REMI | Maintenance fee reminder mailed | ||
| LAPS | Lapse for failure to pay maintenance fees | ||
| STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
| FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20170614 |