US6881301B2 - Method and arrangement for controlling moisture in a multiroll calender - Google Patents
Method and arrangement for controlling moisture in a multiroll calender Download PDFInfo
- Publication number
- US6881301B2 US6881301B2 US10/240,919 US24091903A US6881301B2 US 6881301 B2 US6881301 B2 US 6881301B2 US 24091903 A US24091903 A US 24091903A US 6881301 B2 US6881301 B2 US 6881301B2
- Authority
- US
- United States
- Prior art keywords
- web
- air
- float chamber
- calender
- calendering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related, expires
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
- D21G1/0073—Accessories for calenders
- D21G1/0093—Web conditioning devices
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G7/00—Damping devices
Definitions
- the present invention relates to paper and board machines. More specifically, the present invention relates to a method and an arrangement for controlling evaporation and moisture in a multinip calender when a continuous fibrous web is calendered in calendering nips placed one after the other before the fibrous web is wound on a reel-up/winder.
- Calendering is a method by means of which the properties, such as smoothness, of a web-like material, such as a paper or board web, are sought to be generally improved.
- the web is passed into a nip which is formed between rolls pressed against each other and in which the web is deformed by the action of temperature, moisture and nip load, in which connection the physical properties of the web can be affected by controlling the above-mentioned parameters and the time of action, and the obtained smoothness is a function of the work done to the web.
- the smoothness/impulse curve can be displaced, in particular in the temperature range of 100 EC-150 EC, typically by 0.2 ⁇ m in the smoothness scale in its direction.
- the web is usually passed from one nip to another by means of take-out or turning rolls, which are each situated at the take-out of the nip. It is also known that in connection with the take-out of the nip there are provided different steam boxes, spray devices and equivalent, by which attempts are made to control the change of the moisture content of the web.
- the primary object of the invention is not only to reduce the above-noted drawbacks and problems associated with calendering but also to generally improve control of evaporation and moisture in the calender in order to increase the quality potential at a given impulse level.
- an object of the invention is also to improve controllability in order that the moisture content of the web might be controlled in different situations of operation of the calender, for example, when there are changes in speed, roll temperatures and linear load.
- the invention is thus based on the new and inventive idea that by replacing one or more take-out rolls with an air-float chamber of the turning airborne type, the net evaporation from and the final moisture content of the web can be made constant in different running situations.
- the calender comprises an air-float chamber of the turning airborne type in connection with the outlet of at least one nip.
- connection moisture and evaporation can be made constant in the area of the entire calender, with the result that the web is not subject to large drying/moisturizing cycles, which is advantageous from the point of view of strength, dimensional stability, curling and after-roughening.
- glass transition temperatures are in the range of 120-90 EC, said glass transition temperature being the middle of the glass transition region characteristic of each fibre polymer pulp, such as mechanical and chemical fibre pulp, and the mouldability of pulp and thereby its capability of being calendered being at their best at said glass transition temperature.
- the temperature of the web can rise only to the level of 80-70 EC, which is substantially below optimal calendering temperature, but the moisture control according to the invention makes it possible to preserve the core moisture of the web and thus to use higher calendering temperatures, with the result that the temperature of the web can be raised to an optimal level of 120-90 EC corresponding to the glass transition temperature.
- the temperature of the web rises because of the longer dwell time to a clearly higher level than in calenders with 6 and 8 rolls.
- FIG. 1 which schematically shows a multinip calender in accordance with the invention.
- FIG. 2 is a graph showing the smoothness/work done on OptiLoadTM calenders.
- a multinip calender 10 is a calender of the supercalender type which comprises six rolls 11 , 12 , 13 , 14 , 15 and 16 and five nips 1 , 2 , 3 , 4 and 5 .
- one nip 3 of the supercalender 10 is a so-called reversing nip, in which there are two resilient-surface rolls 13 and 14 against each other.
- This reversing nip 3 is in the running direction of the web W after the two topmost nips 1 and 2 before the two lowermost nips 4 and 5 , in which connection substantially identical nip impulses can be applied to the web W before and after the reversing nip 3 .
- Polymer is a general name of macromolecular compounds.
- partially crystalline polymers such as in mechanical pulps
- the composition of pulps corresponds to the original composition of wood, in which connection molecules are in the crystalline and amorphous regions.
- wood contains three different types of biopolymer: partially crystalline cellulose (crystallinity degree 45-90%), amorphous hemicelluloses and amorphous lignin.
- partially crystalline cellulose crystal cellulose
- amorphous hemicelluloses amorphous hemicelluloses
- lignin lignin
- the lignin content in chemical pulp is lower than in mechanical pulp.
- Pine sulphate pulp contains about 75% of cellulose, about 19% of hemicelluloses and about 6% of lignin.
- Deformations occurring in the fibre polymers of such mechanical and chemical pulps are dependent on time and partly irreversible, i.e. viscoelastic. Viscoelastic behaviour substantially depends on the shear rate, the structure of polymers, and temperature. Since the increase of temperature speeds up the movement of molecules and their segments, the increase of temperature causes the amorphous phase to react more quickly to an external force. In that connection, permanent deformations are brought about in the material by an external force of shorter duration.
- the amorphous phase is in the glass state, in which amorphous polymers and the amorphous parts of partially crystalline polymers have solidified so as to be hard and brittle.
- amorphous phase By the action of an external force, in the glass-state amorphous phase there may occur, in addition to reversible deformation (elastic component), permanent deformation (viscous component), which is called plastic deformation.
- An increase in the temperature of the amorphous phase occurring in the glass-state region does not affect its viscoelastic behaviour to any significant extent.
- glass transition temperature When the temperature of polymer rises to the glass transition region, all the physical and mechanical properties of the amorphous phase of the polymer change drastically and a considerable increase in the proportion of the viscous component is observed in the viscoelastic behaviour of the amorphous phase.
- the middle of the glass transition region is known as the so-called glass transition temperature. Below the glass transition temperature, large-scale fast segmental movements of amorphous polymers are totally inhibited, but by raising the temperature in the glass transition region a situation is reached in which polymer segments are capable of sliding past one another because of their thermal energy.
- glass transition temperatures it may be mentioned that in bone dry conditions, depending on the crystallinity degree, the glass transition temperatures vary as follows:
- the web W runs around a guide roll 6
- the web W passes further into a secondary moisturizing device 21 , 22 which is disposed in connection with the outlet of the first nip 1 and between the outlet of the roll pair 11 , 12 forming the topmost nip 1 and a take-out or turning roll 7 placed after the roll pair and referred to hereafter with the term “turning roll”.
- the secondary moisturizing device 21 , 22 the web W runs over the turning roll 7 into the second calendering nip 2 , which is formed, like the first nip 1 , advantageously between a smooth-surface press roll 12 , such as a metal roll, and a roll 13 covered with a resilient cover, such as a polymer roll.
- a smooth-surface press roll 12 such as a metal roll
- a resilient cover such as a polymer roll.
- the web W passes from the second nip 2 into an air-float chamber 20 of the turning airborne type of the invention disposed in connection with the outlet of the second nip 2 , which chamber also functions as a means for turning the running direction of the web W and for guiding it into the third nip, which is the reversing nip 3 of the calender, said nip being between two rolls 13 and 14 covered with a resilient cover, such as polymer rolls, in which connection work is done to both sides of the web W by means of a resilient-surface roll. In that connection, no turning roll is needed in the portion between the second nip 2 and the third nip 3 .
- the web W runs from the third nip 3 over a turning roll 7 into the fourth calendering nip 4 , which is formed, like the first nip 1 , advantageously between a smooth-surface press roll 15 , such as a metal roll, which is the lower roll of the fourth nip 4 , and a roll 14 covered with a resilient cover, such as a polymer roll, which is the upper roll of the fourth nip 4 .
- a smooth-surface press roll 15 such as a metal roll, which is the lower roll of the fourth nip 4
- a roll 14 covered with a resilient cover such as a polymer roll, which is the upper roll of the fourth nip 4 .
- FIG. 1 does not illustrate the possibility that an air-float chamber 20 of the web W according to the invention can also be disposed in connection with the outlet of the first nip 1 , the third nip 3 and/or the fourth nip 4 .
- the web W runs again over a turning roll 7 into the fifth calendering nip 5 , which is formed, like the second calendering nip 2 , advantageously between a smooth-surface press roll 15 , such as a metal roll, which is the upper roll of the fifth nip 5 , and a roll 16 covered with a resilient cover, such as a polymer roll, which is the lower roll of the fifth nip 5 .
- a smooth-surface press roll 15 such as a metal roll, which is the upper roll of the fifth nip 5
- a roll 16 covered with a resilient cover such as a polymer roll
- the web W is arranged to run via a closed draw instead of a free draw in order that the temperature and moisture content of the web might be regulated by means of a temperature and moisture regulation unit 8 , which is, for example, an infrared airborne web-dryer, even still after the fifth nip 5 before the last turning roll 7 , from which the web W runs to a reel-up/winder 9 .
- a temperature and moisture regulation unit 8 which is, for example, an infrared airborne web-dryer, even still after the fifth nip 5 before the last turning roll 7 , from which the web W runs to a reel-up/winder 9 .
- an air-float chamber of the turning airborne type or an equivalent in connection with the take-out of at least one nip 1 , 2 , 3 , 4 , 5 of the calender 10 for the purpose of controlling the moisture content of the web W, which chamber is closed and extends across the entire width of the web W.
- an air-float chamber 20 is placed in connection with the take-out of each nip 1 , 2 , 3 , 4 and 5 of the calender 10 , in which connection the compensation of evaporation and moisture is distributed and equalized uniformly over the entire area of the calender 10 .
- the secondary web moisturizing means 21 , 22 is disposed in connection with the lake-out of the first nip 1 .
- the secondary moisturizing means 21 , 22 situated between the outlet of the nip 1 and the turning roll 7 situated after the roll pair 11 , 12 forming the nip 1 , is a closed steam or air blow box, spray device, atomizing device or device which operates according to a given control to control evaporation and comprising an upper hood part 21 defining inside it an upper pocket that affects the web W from above and a lower hood part 22 defining inside it a lower pocket affecting the web W from below, said box/device/means extending across the entire width of the web W.
- the web W runs between the hood parts 21 and 22 and it uses steam, water or moist air for moisturizing the web W.
- a moisturizing medium in particular its feed pressure and feed temperature as well as feed amount, into the upper or the lower hood part 21 or 22 is independent of the feed of a moisturizing medium into the other hood part 22 or 21 , respectively, in which connection regulation of the temperature of and evaporation from one side of the web W is independent of the temperature of and evaporation from the other side of the web W.
- the moisturizing of the web W might also be regulated in the CD direction transverse to the machine direction of the paper machine, it is advantageous that the hood parts 21 and 22 are divided into compartments by means of partition walls in this cross machine direction, in which connection, for example, the edge parts of the web W can be moisturized differently from the middle parts of the web.
- the air-float chamber 20 of the turning airborne type for the web is disposed in connection with the take-out of the second nip 2 .
- the air-float chamber 20 in accordance with this embodiment is closed and extends across the entire width of the web W.
- the run of the web W passes in the air-conditioned passage of the air-float chamber, in which the web W is not in contact with the walls defining the passage and which is defined by an outer blow box 23 and an inner blow box 24 , which both blow air or steam to the web, the temperatures, moisture contents and flow quantities of said air or steam being adjustable independently of one another in order to moisturize the web W.
- the feed of a medium, in particular its feed pressure, feed temperature and feed quantity, into the outer blow box 23 is independent of the feed of a medium fed into the inner blow box 24 and vice versa, in which connection regulation of the temperature of and evaporation from one side of the web W is independent of regulation of the temperature of and evaporation from the other side of the web W.
- the blow boxes 23 and 24 are compartmentalized or divided in this cross direction, in which connection, for example, the edge parts of the web W can be treated differently from the middle parts of the web.
- the air-float chamber 20 includes, enclosed in a common housing:
- the curved surface of the outer blow box 23 substantially corresponds in shape to the curved surface of the inner blow box 24 , but its radius of curvature is larger than the radius of curvature of the inner blow box 24 for forming for the web W a passage that extends through the air-float chamber 20 and which is not in contact with the web W.
- the hood parts 21 and 22 as well as the blow boxes 23 and 24 blow a feed pressure, feed temperature and feed quantity, into the outer blow box 23 is independent of the feed of a medium fed into the inner blow box 24 and vice versa, in which connection regulation of the temperature of and evaporation from one side of the web W is independent of regulation of the temperature of and evaporation from the other side of the web W.
- blow boxes 23 and 24 are compartmentalized or divided in this cross direction, in which connection, for example, the edge parts of the web W can be treated differently from the middle parts of the web.
- the air-float chamber 20 includes, enclosed in a common housing:
- the curved surface of the outer blow box 23 substantially corresponds in shape to the curved surface of the inner blow box 24 , but its radius of curvature is larger than the radius of curvature of the inner blow box 24 for forming for the web W a passage that extends through the air-float chamber 20 and which is not in contact with the web W.
- the blow flows act as blow flows that reduce the medium flow through the web W, which, on the one hand, assures contactless running of the web W through the secondary moisturizing device 21 , 22 and through the air-float chamber 20 and, on the other hand, facilitates the forming of a medium bed, causing the web W to float, between the web W and the lower hood part 22 or the inner blow box 24 .
- An advantage of the medium flows supplied to both sides of the web W is also that the different sides of the web can be treated independently of each other in different ways.
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- Paper (AREA)
- Treatment Of Fiber Materials (AREA)
- Drying Of Solid Materials (AREA)
- Rolls And Other Rotary Bodies (AREA)
Abstract
Description
-
- Supercalendering is calendering in a calender unit in which nips are formed between a smooth-surface press roll, such as a metal roll, and a roll covered with a resilient cover, such as a polymer roll. The resilient-surface roll adapts itself to the contours of the surface of paper and presses the opposite side of paper evenly against the smooth-surface press roll. Today, the supercalender typically comprises 10-12 nips and for the purpose of treating the sides of the web, the supercalender comprises a so-called reversing nip in which there are two resilient-surface rolls against each other. Supercalendering is an off-line calendering method, and at the moment it provides the best paper qualities having a PPS surface smoothness <1.5 μm, such as, for example, WFC, LWC-roto and. SC-A.
- Multinip on-line calendering is calendering in a calender unit in which nips are formed between a smooth-surface press roll, such as a metal roll, and a roll covered with a resilient cover, such as a polymer roll, which rolls are placed alternately one after the other. The resilient-surface roll conforms to the contours of the surface of paper and presses the opposite side of paper evenly against the smooth-surface press roll. A multinip on-line calender unit typically comprises 8 rolls and 7 nips. Linear load increases in the multinip on-line calender, in the same manner as in the supercalender, from the top nip to the bottom nip because of the force of gravity. Multinip on-line calendering is a calendering method by means of which it is possible to produce grades having a PPS surface smoothness >1.0 μm, such as, for example, film coated LWC and SC-C as well as lower-quality offset LWC and SC-B.
- Soft calendering is calendering in a calender unit in which nips are formed between a smooth-surface press roll, such as a metal roll, and a roll covered with a resilient cover, such as a polymer roll. In a soft calender, the nips are formed between separate roll pairs. In order to treat both sides of the web in the soft calender, the order of the roll pairs forming the successive nips is inverted with respect to the web so that the resilient-surface roll may be caused to work on both surfaces of the web. Soft calendering is an on-line calendering method by means of which it is possible to produce grades having a PPS surface smoothness >1.5 μm, such as, for example, MFC and lower-quality film coated LWC as well as SC-C.
- a. Initial moisture content, the number of steam treatments and calendering temperature are mainly determined on the basis of the final moisture content after calendering such that
- i. when the final moisture content is too low, the web absorbs moisture, which results in deterioration of the achieved gloss in the form of after-roughening, and
- ii. when the final moisture content is too high, the drying of the web effectively destroys the obtained quality values.
- b. On the other hand, determination of the initial moisture content in calendering is affected by the desired optical properties and the level of blackening. When the final moisture content becomes too high, the opacity, or translucence, of the web deteriorates, which appears in finished paper product as an increase in print-through values, and the level of blackening rises, which diminishes the selling value of paper in the form of reduced brightness and poor visual impression.
- for cellulose, in the range of 200. EC-250 EC,
- for hemicellulose, in the range of 150 EC-220 EC, and
- for lignin, in the range of 130 EC-205 EC.
-
- either, as shown in
FIG. 1 , via aninitial moisturizing device 17, - or directly from the
guide roll 6, which is enabled by the present invention, into the first, topmost nip 1 of thecalender 10, which nip is between the topmost rolls 11 and 12 of the calender. The lower roll of the 11, 12 is in the example illustrated inroll pair FIG. 1 advantageously a smooth-surface press roll 12, such as a metal roll, and the upper roll of the 11, 12 is advantageously aroll pair roll 11 covered with a resilient cover, such as a polymer roll.
- either, as shown in
- a turning device whose surface facing the web W is curved outwards and which is not in contact with the web, the turning device serving as an
inner blow box 24 and its curved surface facing the web W being perforated, and - an
outer blow box 23 whose surface facing the web W is curved inwards and which is not in contact with the web and whose curved surface facing the web W is perforated.
-
- a turning device whose surface facing the web W is curved outwards and which is not in contact with the web, the turning device serving as an
inner blow box 24 and its curved surface facing the web W being perforated, and - an
outer blow box 23 whose surface facing the web W is curved inwards and which is not in contact with the web and whose curved surface facing the web W is perforated.
- a turning device whose surface facing the web W is curved outwards and which is not in contact with the web, the turning device serving as an
Claims (20)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20000788 | 2000-04-04 | ||
| FI20000788A FI20000788A0 (en) | 2000-04-04 | 2000-04-04 | Procedure and arrangement for controlling moisture in multiple calendars |
| PCT/FI2001/000319 WO2001075224A1 (en) | 2000-04-04 | 2001-04-03 | Method and arrangement for controlling moisture in a multiroll calender |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20040025720A1 US20040025720A1 (en) | 2004-02-12 |
| US6881301B2 true US6881301B2 (en) | 2005-04-19 |
Family
ID=8558113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/240,919 Expired - Fee Related US6881301B2 (en) | 2000-04-04 | 2001-04-03 | Method and arrangement for controlling moisture in a multiroll calender |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6881301B2 (en) |
| EP (1) | EP1268926B1 (en) |
| JP (1) | JP2003529683A (en) |
| AT (1) | ATE271157T1 (en) |
| AU (1) | AU2001252294A1 (en) |
| CA (1) | CA2405137C (en) |
| DE (1) | DE60104295T2 (en) |
| FI (1) | FI20000788A0 (en) |
| WO (1) | WO2001075224A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120111516A1 (en) * | 2010-04-29 | 2012-05-10 | Metso Paper, Inc. | Method and Apparatus for Treating a Fibrous Web |
| US20160017543A1 (en) * | 2012-12-12 | 2016-01-21 | Munksjö Oyj | Method of Manufacturing Glassine Paper |
| US20220081838A1 (en) * | 2020-09-11 | 2022-03-17 | Chan Li Machinery Co., Ltd. | Liquid applying apparatus for fiber products |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI20000788A0 (en) | 2000-04-04 | 2000-04-04 | Valmet Corp | Procedure and arrangement for controlling moisture in multiple calendars |
| FI115981B (en) * | 2002-06-19 | 2005-08-31 | Metso Paper Inc | Procedure, system and calender for checking the moisture profile and / or gradient of a paper web and web |
| DE10255716B4 (en) * | 2002-11-29 | 2006-08-31 | Voith Paper Patent Gmbh | Web treatment device, in particular calender |
| FI114994B (en) * | 2003-11-20 | 2005-02-15 | Metso Paper Inc | Treating fibrous web in paper machine involves arranging web to travel between dryer section and finishing device under controlled temperature and moisture conditions to regulate evaporation of water and heat from web, and drying web |
| DE10357938A1 (en) * | 2003-12-11 | 2005-07-07 | Voith Paper Patent Gmbh | Method for satinizing a web of paper or cardboard and calender |
| DE102004010894A1 (en) | 2004-03-06 | 2005-09-22 | Voith Paper Patent Gmbh | Method and device for treating a web of paper or cardboard |
| US7387064B2 (en) | 2004-03-12 | 2008-06-17 | Metso Paper, Inc. | Method and apparatus for producing calendered paper |
| DE102004062563A1 (en) * | 2004-12-24 | 2006-07-06 | Voith Paper Patent Gmbh | Apparatus and method for treating a web of material |
| FI120368B (en) | 2007-10-25 | 2009-09-30 | Metso Paper Inc | Method and arrangement for controlling the properties of a fiber web |
| CN102414459B (en) * | 2009-04-21 | 2015-07-15 | 维美德技术有限公司 | A roll for a fibre web machine |
| EP3012371A1 (en) * | 2014-10-21 | 2016-04-27 | Valmet Technologies, Inc. | Method of treating a fiber web and a calender for treating a fiber web |
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-
2000
- 2000-04-04 FI FI20000788A patent/FI20000788A0/en not_active IP Right Cessation
-
2001
- 2001-04-03 AU AU2001252294A patent/AU2001252294A1/en not_active Abandoned
- 2001-04-03 CA CA002405137A patent/CA2405137C/en not_active Expired - Fee Related
- 2001-04-03 AT AT01925594T patent/ATE271157T1/en active
- 2001-04-03 DE DE60104295T patent/DE60104295T2/en not_active Expired - Lifetime
- 2001-04-03 US US10/240,919 patent/US6881301B2/en not_active Expired - Fee Related
- 2001-04-03 WO PCT/FI2001/000319 patent/WO2001075224A1/en not_active Ceased
- 2001-04-03 JP JP2001572693A patent/JP2003529683A/en not_active Withdrawn
- 2001-04-03 EP EP01925594A patent/EP1268926B1/en not_active Expired - Lifetime
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120111516A1 (en) * | 2010-04-29 | 2012-05-10 | Metso Paper, Inc. | Method and Apparatus for Treating a Fibrous Web |
| US8425721B2 (en) * | 2010-04-29 | 2013-04-23 | Metso Paper, Inc. | Method and apparatus for treating a fibrous web |
| US20160017543A1 (en) * | 2012-12-12 | 2016-01-21 | Munksjö Oyj | Method of Manufacturing Glassine Paper |
| US9587355B2 (en) * | 2012-12-12 | 2017-03-07 | Munksjö Oyj | Method of manufacturing glassine paper |
| US20220081838A1 (en) * | 2020-09-11 | 2022-03-17 | Chan Li Machinery Co., Ltd. | Liquid applying apparatus for fiber products |
| US11655592B2 (en) * | 2020-09-11 | 2023-05-23 | Chan Li Machinery Co., Ltd. | Liquid applying apparatus for fiber products |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003529683A (en) | 2003-10-07 |
| DE60104295D1 (en) | 2004-08-19 |
| WO2001075224A1 (en) | 2001-10-11 |
| EP1268926B1 (en) | 2004-07-14 |
| ATE271157T1 (en) | 2004-07-15 |
| EP1268926A1 (en) | 2003-01-02 |
| CA2405137A1 (en) | 2001-10-11 |
| AU2001252294A1 (en) | 2001-10-15 |
| DE60104295T2 (en) | 2005-07-21 |
| WO2001075224B1 (en) | 2002-02-14 |
| FI20000788A0 (en) | 2000-04-04 |
| CA2405137C (en) | 2008-06-17 |
| US20040025720A1 (en) | 2004-02-12 |
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