US6475891B2 - Method of forming a pattern for a semiconductor device - Google Patents
Method of forming a pattern for a semiconductor device Download PDFInfo
- Publication number
- US6475891B2 US6475891B2 US09/984,949 US98494901A US6475891B2 US 6475891 B2 US6475891 B2 US 6475891B2 US 98494901 A US98494901 A US 98494901A US 6475891 B2 US6475891 B2 US 6475891B2
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- United States
- Prior art keywords
- layer
- pattern
- forming
- sacrificial layer
- conformal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 76
- 239000004065 semiconductor Substances 0.000 title claims abstract description 53
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 238000005530 etching Methods 0.000 claims abstract description 21
- 238000000059 patterning Methods 0.000 claims abstract description 3
- 229920002120 photoresistant polymer Polymers 0.000 claims description 32
- 230000002093 peripheral effect Effects 0.000 claims description 23
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 10
- 229920005591 polysilicon Polymers 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910021332 silicide Inorganic materials 0.000 claims description 5
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 5
- 238000001039 wet etching Methods 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 3
- 238000000206 photolithography Methods 0.000 abstract description 16
- 239000010410 layer Substances 0.000 description 119
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 206010010144 Completed suicide Diseases 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000007261 regionalization Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/7684—Smoothing; Planarisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/528—Geometry or layout of the interconnection structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/09—Manufacture or treatment with simultaneous manufacture of the peripheral circuit region and memory cells
Definitions
- the present invention relates to a method of forming a pattern for a semiconductor device. More particularly, the present invention relates to a method of forming a fine pitch pattern having a feature width under several tens of nanometers for a semiconductor device using sacrificial layer patterns.
- a base layer 12 acting as an interlayer insulation film 12 is formed on a semiconductor substrate 10 .
- a layer 13 to be a predetermined pattern, is formed on the base layer 12 , and subsequently a photoresist film (not shown) is formed on the layer 13 .
- a photoresist film pattern 16 is formed by exposing and developing the photoresist film.
- the layer 13 is partially etched to expose the base layer 12 using the photoresist film pattern 16 as an etching mask, so that predetermined pattern layers 13 a , 13 b , such as metal wires or gate electrodes, are formed.
- the resolution capability of a photoresist film is usually improved by employing a light source having a short wavelength, or by incrementing a numerical aperture (NA) of a lens.
- a light source having a short wavelength or by incrementing a numerical aperture (NA) of a lens.
- NA numerical aperture
- a DUV (deep ultraviolet) light source such as KrF (248 nm) or ArF (193 nm) having a wavelength shorter than G-line (436 nm) or I-line (365 nm) has been used, and an X-ray light source is being developed.
- a method of forming a pattern for a semiconductor device comprising forming a sacrificial layer on a semiconductor substrate, forming a sacrificial layer pattern by patterning the sacrificial layer, forming a conformal layer on a resultant structure after forming the sacrificial layer pattern, and forming a layer pattern by anisotropically etching the conformal layer.
- a base layer may be formed between the semiconductor substrate and the sacrificial layer.
- the sacrificial layer is formed from a material having a high etching selectivity to the conformal layer and the semiconductor substrate, wherein the sacrificial layer is preferably formed of silicon nitride.
- the conformal layer is preferably a conductive layer formed of a material from the group consisting of aluminum, tungsten, cobalt, copper, titanium and polysilicon.
- the conformal layer may be a polycide double layer including a polysilicon layer and a silicide layer, or a multilayer, the multilayer being formed of films selected from the group consisting of a titanium film, an aluminum film, and a titanium nitride film.
- the method further includes planarizing an upper surface of the sacrificial layer pattern and the layer pattern after forming the layer pattern.
- the method further includes removing the sacrificial layer pattern by means of a wet etching process after forming the layer pattern.
- a method of forming patterns for semiconductor devices comprising forming a sacrificial layer on a semiconductor substrate having a cell region and a peripheral region; forming a sacrificial layer pattern on the semiconductor substrate of the cell region; forming a conformal layer on the entire surface of the semiconductor substrate including the sacrificial layer pattern; forming a photoresist pattern on the conformal layer formed at the peripheral region; and anisotropically etching the conformal layer to expose the semiconductor substrate, thereby forming a first pattern comprised of the conformal layer on the sidewalls of the sacrificial layer pattern at the cell region, and forming a second pattern beneath the photoresist patterns at the peripheral region, wherein the second pattern has a width relatively wider than that of the first patterns.
- a base layer may be formed between the semiconductor substrate and the sacrificial layer.
- the sacrificial layer is preferably formed of a material having a high etching selectivity to the semiconductor substrate, the base layer and the conformal layer.
- the sacrificial layer is preferably formed of silicon nitride.
- the conformal layer is preferably a conductive layer.
- the conformal layer is preferably selected from the group consisting of aluminum, tungsten, cobalt, copper, titanium and polysilicon.
- the conductive layer may also be formed of a double layer comprised of a polysilicon layer and a suicide layer, or a multiplayer, the multilayer being formed of films selected from the group consisting of a titanium film, an aluminum film, and a titanium nitride film.
- the method further includes planarizing an upper surface of the sacrificial layer pattern and the first and second patterns after anisotropically etching the layer.
- the method further includes removing the sacrificial layer pattern by means of a wet etching process after anisotropically etching the layer.
- the sacrificial layer pattern is formed at the cell region and the peripheral region, respectively; during forming the sacrificial layer pattern, the photoresist film pattern is formed on the layer at the peripheral region, and while the second pattern is formed beneath the photoresist film pattern during anisotropic etching of the layer, a dummy pattern is formed on sidewalls of the sacrificial layer pattern at the peripheral region.
- FIGS. 1A through 1C illustrate cross-sectional views of a semiconductor device for sequentially showing a method of forming patterns for semiconductor devices in accordance with the prior art
- FIG. 2 illustrates a plan view of a semiconductor device showing patterns to be formed in accordance with an embodiment of the present invention
- FIGS. 3A through 3G illustrate cross-sectional views of a semiconductor device showing a method of forming patterns for a semiconductor device in accordance with an embodiment of the present invention.
- FIG. 2 shows patterns to be formed in accordance with an embodiment of the present invention
- FIGS. 3A through 3G illustrate cross-sectional views taken along line I—I in FIG. 2 for showing a method of forming patterns for semiconductor devices in accordance with an embodiment of the present invention.
- a semiconductor substrate is covered with a base layer 102 .
- First patterns 110 a , second patterns 110 b and dummy patterns 110 c are arranged on the base layer 102 .
- the first patterns 110 a are arranged across the cell region of the semiconductor substrate such that they are equally spaced apart.
- the second patterns 110 b are formed in the peripheral region.
- the second patterns 110 b have a line width greater than that of the first patterns 110 a and dummy patterns 110 c .
- Each of the second patterns 110 b is surrounded by a dummy pattern 110 c .
- Dummy patterns 110 c are formed to reduce the step height difference between the cell region and the peripheral region.
- the line width d 1 of first patterns 110 a formed in the cell region is the same width as the dummy patterns 110 c formed in the peripheral region.
- the second patterns 110 b formed in the peripheral region have line widths d 3 , d 4 , each of which is wider than the line width d 1 of the first patterns 110 a and the dummy patterns 110 c .
- Distances d 2 between each of patterns 110 a , 110 b , 110 c are equal.
- a base layer 102 acting as an interlayer insulation film is formed on a semiconductor substrate 100 .
- the base layer 102 is preferably formed of silicon oxide.
- a sacrificial layer 103 is formed on the base layer 102 .
- the sacrificial layer 103 is preferably formed of a material that has a high etching selectivity to the base layer 102 . For instance, if silicon oxide is used as a base layer 102 , a sacrificial layer 103 is formed from silicon nitride. A thickness of the sacrificial layer 103 is determined according to a thickness of a pattern layer to be formed in accordance with the present invention.
- a photoresist film (not shown) is formed on the sacrificial layer 103 and then patterned to be first photoresist film patterns 106 , which are used as a mask for etching the sacrificial layer 103 .
- the first photoresist film patterns 106 are formed by considering the line widths d 1 , d 3 , d 4 of the first, second and dummy patterns 110 a , 110 b , and 110 c , respectively, and the distance d 2 between each of the patterns shown in FIG. 2 .
- the sacrificial layer 103 is used to form the first patterns 110 a and the dummy patterns 110 c .
- the second patterns 110 b are formed by means of a photolithography technique.
- a shape and size of the first photoresist film patterns 106 are determined by considering the subsequent processes.
- a line width of the first photoresist film pattern 106 is the same as the distance d 2 between each of the patterns. Accordingly, the line width of the photoresist film patterns 106 is indicated by d 2 . Further, in the cell region, the first photoresist film patterns 106 having the line width d 2 are formed at intervals of the two first patterns 110 a . Thus, a distance between each of the first photoresist film patterns 106 in the cell region preferably corresponds to a value of (2 1 +d 2 ).
- the first photoresist film patterns 106 are not formed to cover areas in which the second patterns 110 b , the dummy patterns 110 c and the separating area between the second patterns 110 b and the dummy patterns 110 c would be formed. That is, the first photoresist film patterns 106 are formed between each of the dummy patterns 110 c in the peripheral region.
- a distance between each of the first photoresist film patterns 106 in the peripheral region corresponds to a total value of (2 1 + 2 d 2 +d 3 ), or (2 1 + 2 d 2 +d 4 ).
- the sacrificial layer 103 is dry etched using the first photoresist film pattern 106 as a mask, so that a sacrificial layer pattern 103 a is formed.
- a conformal layer 110 to be used for predetermined layer patterns in accordance with an embodiment the present invention, is formed on the entire upper surface of the resultant structure shown in FIG. 3 C. That is, the conformal layer 110 covers all of the sacrificial layer pattern 103 a and the base layer 102 .
- the conformal layer 110 may be formed of a conductive material such as aluminum (Al), tungsten (W), copper (Cu), cobalt (Co), titanium (Ti), other metal compounds, or polysilicon.
- the conformal layer 110 may also be formed of a double layer called a polycide comprised of a polysilicon layer and a silicide layer.
- the conformal layer 110 may be formed of a multilayer comprised of titanium film, titanium nitride film, aluminum film and titanium nitride film.
- the material for the conformal layer 110 is determined according to a function of the layer patterns. For instance, when using the layer patterns as a metal wire, aluminum or tungsten is a proper material for the conformal layer 110 . On the other hand, when using the layer patterns as a gate electrode, a silicide is proper.
- a width d 1 ′ of the conformal layer 110 formed on sidewalls of the sacrificial layer patterns 103 a is preferably the same as the width d 1 of the first patterns 110 a . Accordingly, the thickness d 1 ′ of the conformal layer 110 is formed to equal the width d 1 of the first patterns 110 a .
- second photoresist film patterns 112 are formed on the conformal layer 110 at the peripheral of the semiconductor substrate.
- the second photoresist film pattern 112 is a mask for forming the second patterns in the peripheral region. Accordingly, a width of each of the second photoresist film patterns 112 is preferably d 3 or d 4 .
- the conformal layer 110 is anisotropically etched, using the second photoresist film patterns 112 as an etching mask, to expose the base layer 102 .
- the second photoresist film patterns 112 are removed by means of an oxygen plasma ashing process after which the resultant structure is rinsed.
- layer patterns 110 a formed from the conformal layer 110 remain on the sidewalls of the sacrificial layer pattern 103 a because the conformal layer 110 is etched without an etching mask.
- the layer patterns 110 a in the cell region correspond to the first patterns 110 a shown in FIG. 2 .
- layer patterns 110 c remain on the sidewalls of the sacrificial layer pattern 103 a , to be used as dummy patterns 110 c , and at the same time layer patterns 110 b are formed on the base layer 102 .
- the layer patterns 110 b correspond to the second patterns 110 b shown in FIG. 2 .
- an upper surface of the semiconductor substrate is uneven due to a different step height of the layer patterns 110 a , 110 b and 110 c , so that a planarization process is needed.
- the surface of the semiconductor substrate is planarized by means of a CMP (chemical mechanical polishing) technique.
- CMP chemical mechanical polishing
- planarnzation process may be omitted.
- the sacrificial layer pattern 103 a are selectively removed by a wet etching process. As a result, only the layer patterns 110 a , 110 b , and 110 c that correspond to the first and second patterns 110 a , 110 b and dummy patterns 110 c remain on the base layer 102 .
- the sacrificial layer pattern 103 a when forming an insulation layer on the patterns 110 a , 110 b and 110 c after the planarization process, it is preferable to retain the sacrificial layer pattern 103 a .
- the sacrificial layer pattern 103 a must be removed when using the first and the second patterns 110 a and 110 b as a gate electrode.
- the present invention provides a method of forming fine pitch patterns by using sacrificial layer patterns.
- the cost of manufacturing highly integrated semiconductor devices can be reduced over the manufacturing cost when using short wavelength photolithography because the expensive equipment necessary for the short wavelength photolithography process is unwarranted in the present invention, and further, the process of manufacturing semiconductor devices is simplified by use of the present invention.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
Abstract
Description
Claims (16)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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KR2000-73011 | 2000-12-04 | ||
KR1020000073011A KR100354440B1 (en) | 2000-12-04 | 2000-12-04 | Method for forming patterns of semiconductor device |
KR00-73011 | 2000-12-04 |
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US20020068447A1 US20020068447A1 (en) | 2002-06-06 |
US6475891B2 true US6475891B2 (en) | 2002-11-05 |
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US09/984,949 Expired - Lifetime US6475891B2 (en) | 2000-12-04 | 2001-10-31 | Method of forming a pattern for a semiconductor device |
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KR (1) | KR100354440B1 (en) |
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US20020068447A1 (en) | 2002-06-06 |
KR20020043862A (en) | 2002-06-12 |
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