US5024820A - Mechanism for charging and discharging a closed chamber utilizable as an extraction tank of a continuous vegetable material extraction unit and extraction process comprising an application thereof - Google Patents

Mechanism for charging and discharging a closed chamber utilizable as an extraction tank of a continuous vegetable material extraction unit and extraction process comprising an application thereof Download PDF

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Publication number
US5024820A
US5024820A US07/259,140 US25914088A US5024820A US 5024820 A US5024820 A US 5024820A US 25914088 A US25914088 A US 25914088A US 5024820 A US5024820 A US 5024820A
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Prior art keywords
charging
mechanism according
discharging mechanism
screw
screws
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Expired - Lifetime
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US07/259,140
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English (en)
Inventor
Dominique Coutiere
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BIOLANDES AGRO
SEVALANDES
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Biolandes
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Priority claimed from FR8714354A external-priority patent/FR2621829B1/fr
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Assigned to BIOLANDES reassignment BIOLANDES ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: COUTIERE, DOMINIQUE
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Publication of US5024820A publication Critical patent/US5024820A/en
Assigned to SEVALANDES reassignment SEVALANDES MERGER (SEE DOCUMENT FOR DETAILS). Assignors: BIOLANDES
Assigned to BIOLANDES AGRO reassignment BIOLANDES AGRO CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: SEVALANDES
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0215Solid material in other stationary receptacles
    • B01D11/0223Moving bed of solid material
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/10Production of fats or fatty oils from raw materials by extracting
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/02Recovery or refining of essential oils from raw materials
    • C11B9/025Recovery by solvent extraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D2011/002Counter-current extraction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention relates to continuous plant extraction units and concerns more precisely a mechanism for charging and discharging the closed chamber that constitutes the extraction tank, and the extraction process comprising an application thereof.
  • the applicant has also developed a process wherein the vegetable material is charged and discharged continuously, thus permitting its automation, hence substantial labour saving, as well as very good reproducibility.
  • the charging device comprises a complementary means designed to compress the product for processing to form a plug before it is introduced into the processing chamber, the plugs formed by the compressed product both at the point of charging and at the point of discharging being sufficiently tight to maintain inside the said chamber liquid or gaseous processing fluids.
  • a system for withdrawing the processed product located in the bottom of the chamber enables the said processed product to be compressed and the discharge device comprises at least one means for crumbling the compressed product.
  • the complementary means of the discharge device also enables the plug to be crumbled.
  • the charging device consists of an endless screw with which is associated a complementary means of compressing the product constituted by another endless screw the axis of which is normal to the first screw.
  • the complementary means for compressing the product to be processed upstream of the chamber is constituted by another endless screw mounted on a rotating shaft with a vertical axis, which screw passes through the orifice admitting the product into the tank and is accommodated in a box into which emerges the tube containing the endless supply screw.
  • the shaft projects inside the tank and carries horizontal blades on its end.
  • the screw extends from the inside of the tube to within a certain distance from the blade of the vertical screw, the plug of compressed product occupying the said tube over this distance.
  • the withdrawal system comprises a conveyor belt of parallel endless screws which recovers the product processed and supplies it to a collecting evacuation screw, the said screw conveyor belt being composed of screws having a slightly conical profile the flare of which opens out towards the collecting evacuation screw, the conical profile of the conveyor belt screws being obtained, for example, through the association of an cylindrical axial core and a wing or fin of increasing width.
  • the invention also provides for the screws of the conveyor belt to rotate above collecting troughs which form the bottom of the chamber and which are separated from one another by ridges that are triangular in cross-section and the axes of which are parallel to the axes of the screws of the conveyor belt and the points of which are orientated upwards, a set of screws located on one side of the median plane and a set of screws located on the other side being of inverted pitches and each driven in inverse directions and at the same speed.
  • the invention also provides for there to be an evacuation tube, below the collecting troughs, transverse to the screws, forming a gutter or channel open over the width of the base of the tank, which extends outside as far as a decompression chamber opening downwards, the said tube containing a mechanical means for displacing the processed products collected towards the chamber, advantageously constituted by an endless screw, mounted on a rotating shaft with a horizontal axis, and which is located in the horizontal tube.
  • the complementary means provided for in the discharge device to compress the processed product downstream of the tank is constituted by a shutter or flap biased against the horizontal evacuation tube at its outlet into the decompression chamber, the endless screw extending into the tube to within a certain distance of the shutter so that the plug of product occupies the said tube over this distance.
  • the invention also relates to the equipment suitable for its implementation and constituted by a hydrodistillation unit and a device for recovering the latent heat of distillation.
  • the vegetable material Before it enters the tank, the vegetable material is broken up, if necessary, into fragments of between 2 and 5 cm by crushing.
  • one of the objects of the invention is also to ensure that the process is self-sufficient in terms of energy.
  • the mixture of steam+essential oil is condensed in coils cooled by substantial quantities of cold water, obviously with a loss of the latent heat.
  • the process according to the invention recovers this latent heat with the help of a gas, preferably air, which is then used to dry the spent vegetable material, permitting its satisfactory combustion.
  • a gas preferably air
  • This condensation system has the advantage of eliminating the substantial cold water requirements of the prior art and of permitting total self-sufficiency of hydrodistillation in terms of energy. It even makes it possible to enhance the value of the residue, which can be used as a fuel outside this process. This additional profitability can prove important in cases in which the processed vegetable material gives rise to large excess volumes of residue not used for the energy of the process, which is the case of ligneous vegetable materials with a high proportion of wood, such as conifers, in particular maritime pine, and eucalyptus.
  • the dried spent vegetable material can be used in animal foods as a cellulose supplement, particularly for ruminants.
  • FIG. 1 represents a cross-sectional diagrammatic view of an extraction tank fitted with the charging and discharging mechanism
  • FIG. 2 an elevation of the base of the tank
  • FIG. 3 a top view of the base
  • FIG. 4 a cross-sectional view along IV--IV of FIG. 2
  • FIG. 5 an elevation, on a larger scale, of a screw of the discharge conveyor belt
  • FIG. 6 the overall view of the process.
  • FIG. 1 we see still tank, 1, which takes the form of a cylindrical reservoir resting on a base, 2, forming a square housing itself supported by feet, 3.
  • the closed tank On the upper portion, the closed tank is fitted with a central orifice, 4, and with outlet orifices, 5, for the oil-laden vapour, evacuated via conduits 6.
  • Orifice 4, which is used to charge the tank with raw material, is traversed by an endless screw 7 mounted on a rotating shaft, 8, with a vertical shaft that projects inside the tank, which screw extends over the entire height of a rectangular admission box a little wider than the width of the screw.
  • a motor, 10, mounted on the shaft end outside box 9 drives shaft 8 in rotation, as well as horizontal blades, 11, fixed to its lower end.
  • the end of horizontal tube 12 has an admission opening, 19, for the raw material arriving from a crushing unit.
  • Screw 13 extends from the end of tube 12, towards opening 19, to within a certain distance of the blade of vertical screw 7.
  • the box constituting the base, 2 is provided with a bottom formed by a series of collecting troughs, 15, separated from one another by ridges, 16, of triangular cross-section the points of which are orientated upwards.
  • the troughs and ridges are parallel and extend over almost the entire width of the base.
  • the screws are arranged so as to occupy each of the collecting troughs 15, the ridges 16 being located between each screw, thus restricting the possible points at which the material might accumulate on the bottom.
  • the embodiment of the withdrawal device according to FIG. 1 shows eight screws; the four screws on one side of a median plane and the four screws on the other are of inverse pitch and rotate in opposite directions. Each set of four is driven at the same speed by a motor and via suitable pulleys and chains, not represented.
  • Tube 35 serves to house another endless screw, 21, mounted on a shaft, 25, which thus extends transversely to screws 17 of the conveyor belt, and which extends over the entire width of the base and beyond, to within a distance D of chamber 20.
  • the screw is driven by an appropriate motor, not represented, in the desired direction to displace the collected products out of the tank, towards chamber 20.
  • Shaft 25 of the screw carries blades, 26, on its end in chamber 20.
  • FIG. 5 shows in greater detail the profile of one of these screws 17.
  • shaft 18 of screw 17 there is provided a cylindrical core, 27, and screw wing or thread, 28, the profile of which is slightly tapered, the thickness of the wing or thread being small on one side and greater on the other, towards evacuation tube 35.
  • shaft 18 passes over tube 35, is supported on the edge of the base and ends in a key, 29, serving to drive it via a pulley, not represented. Close to the edge of the base, shaft 18 carries two crumbling blades 30.
  • the steam injected at the base of the reservoir is admitted through a manifold pipe, 32, placed on one side of base 2 and is distributed inside the said reservoir by tubes, 33, located at the apex of each triangular cross-section ridge 16 and provided with a plurality of upwardly orientated orifices, 34.
  • orifices 34 are staggered, from one tube to the next, and the spaces between them are greater or smaller according to whether the pipe is at the edge of the tank or towards its centre.
  • the vegetable material for processing is received continuously through opening 19 at the entry to tube 12, where it is displaced by screw 13 driven by motor 14.
  • the other motor, 10 being at a standstill, vertical screw 7 is immobilized and then prevents the material from passing through central orifice 4.
  • feed screw 13 continues its rotational movement, material becomes packed, at its output, against screw 7, finally forming a plug, 36, in space d, said plug being compressed and steam-tight.
  • blades 11 is to even out the apex of the pile that would form beneath central orifice 4.
  • tank 1 The material thus contained by tank 1 is traversed in counterflow by the steam emitted by orifices 34 of tubes 33.
  • the screws 17 rotate in the opposite direction on either half of the conveyor belt.
  • the spent vegetable material is removed from the pile very regularly over the entire surface of the tank.
  • the profiled shape of each screw ensures the continuous, homogeneous transfer of spent vegetable material, discharging the material, with the pile descending gradually onto the conveyor belt without the occurrence of any gaps or discontinuities in evacuation, hence without the creation of any preferential paths for the steam, which thus uniformly and regularly passes through all the material in the pile. Thanks to the special profile of the tank bottom formed by an alternation of troughs 15 and ridges 16, all the spent material is taken up by the screws which are well integrated with this profile, no permanent accumulation on this bottom being possible.
  • the spent material already somewhat compacted during the said transfer thanks to the conical profile of screws 17, then drops into the channel, after which it is moved by screw 21 through tube 35 in the direction of decompression chamber 20. Should the spent material thus displaced in slabs fail to fall of its own accord, it would be subjected to the action of crumbling blades 30, which would facilitate its fall. Should congestion occur for any reason whatsoever, contact 31 could then act as a safety contact and momentarily halt the screw conveyor belt. The spent vegetable material then accumulates in tube 35 over the distance D, where it is compressed against shutter 22 which forms a stop, and forms a plug, 37, which is also steam tight.
  • the fresh vegetable material passes firstly, if necessary, through a crusher, 38, which reduced it to an appropriate fragment size. It is then supplied to the tank, 1, by the continuous, automated charging and discharging system ensuring a suitable dwell time in the tank, this dwell time clearly being variable as a function of the type of vegetable material processed.
  • the steam is introduced into the tank in controlled quantities and in counterflow to the vegetable material, which is continuously evacuated by the device for discharging the bottom of the tank, and delivered to the drying installation 39.
  • the steam+oil mixture is discharged at the head of tank 1 and passes through a condenser, 40, then through a separator, 41, in which the oil phase is separated from the aqueous phase.
  • the condenser, 40 is cooled by a heat carrier, for example water, which circulates in an endless loop between the said condenser 40 and a space heater, 42.
  • Space heater 42 is swept by a air stream that is adjusted in such a way that the calories supplied by the heat carrier to the said air stream correspond to a temperature of the hot air obtained of approximately 40° to 60° C.
  • the heat carrier thus cooled down in the space heater 42 is returned to condenser 40.
  • the hot air thus obtained passes through the damp spent vegetable material arranged in a bed on the conveyor, 39, which spent vegetable material has been brought to the desired degree of dryness by the time it has reached the end of conveyor 39.
  • Part, or possibly all of the dried, spent vegetable material is burned in a furnace, for example a screw stoker boiler.
  • the surplus fraction is available for use, as indicated above, as a fuel or as an animal food complement.
  • the process according to the invention makes it possible to process in a very short space of time a large quantity of vegetable material, practically without using any labour, in a very regular manner, supplying essential oils of uniform quality, thanks to the homogeneity of the processing conditions.
  • the process can be used for all ligneous and non-ligneous vegetable materials serving as raw materials for the production of essential oils. It applies in particular to conifers, such as maritime pine, to eucalyptus, to shrubs and herbaceous plants, particularly tarragon, basil, rosemary, juniper, thyme, mint and mosses, as well as to barks and sawdusts. Material yield can attain and even exceed 80%, whereas, in the processes traditionally employed, yield is in the order of 20%.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Feed For Specific Animals (AREA)
  • Fodder In General (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
US07/259,140 1987-10-19 1988-10-18 Mechanism for charging and discharging a closed chamber utilizable as an extraction tank of a continuous vegetable material extraction unit and extraction process comprising an application thereof Expired - Lifetime US5024820A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR8714353 1987-10-19
FR8714354A FR2621829B1 (fr) 1987-10-19 1987-10-19 Mecanisme de chargement-dechargement d'une cuve fermee constituant l'alambic ou l'extracteur d'une unite de distillation en continu
FR8714353 1987-10-19
FR8714354 1987-10-19

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US5024820A true US5024820A (en) 1991-06-18

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US07/259,140 Expired - Lifetime US5024820A (en) 1987-10-19 1988-10-18 Mechanism for charging and discharging a closed chamber utilizable as an extraction tank of a continuous vegetable material extraction unit and extraction process comprising an application thereof

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Country Link
US (1) US5024820A (fr)
EP (1) EP0313441B1 (fr)
JP (1) JP2592112B2 (fr)
CN (1) CN1032018C (fr)
AU (1) AU614778B2 (fr)
BR (1) BR8805665A (fr)
CA (1) CA1333520C (fr)
DE (1) DE3881330T2 (fr)
DZ (1) DZ1260A1 (fr)
ES (1) ES2040367T3 (fr)
IL (1) IL88074A (fr)
PT (1) PT88787B (fr)
TN (1) TNSN88108A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5582694A (en) * 1994-09-21 1996-12-10 Idaho Mint Distiller, Inc. Hydrodistillation process for essential mint oils
US5891501A (en) * 1997-11-25 1999-04-06 Mckellip; Lewis L. Method for extraction of essential oils from plant material
WO2000054599A1 (fr) * 1999-03-15 2000-09-21 Konstantinos Zikas Unite de deshydratation de produits en vrac
CN102908803A (zh) * 2012-11-09 2013-02-06 青岛中科华联新材料有限公司 一种薄膜萃取槽传动装置
CN104016150A (zh) * 2013-12-15 2014-09-03 广西鱼峰水泥股份有限公司 斜槽进给装置
US20140332363A1 (en) * 2012-02-06 2014-11-13 Michael McGolden Method and system for gasification of biomass
US20190030100A1 (en) * 2012-10-18 2019-01-31 Robert J Rapp Essential Element Management
US11505764B2 (en) * 2017-09-29 2022-11-22 Chenguang Biotech Group Co., Ltd Continuous distillation process

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2040367T3 (es) * 1987-10-19 1993-10-16 Biolandes Agro Mecanismo de carga-descarga de un recinto cerrado utilizable como cuba de extraccion de una unidad de extraccion en continuo de vegetales, y procedimiento de extraccion que comprende la aplicacion.
KR101172244B1 (ko) * 2012-02-29 2012-08-07 형 복 이 슬러지 배출장치를 갖는 액기스 추출기
CN102921187B (zh) * 2012-11-07 2015-03-11 无锡市新耀生物工程技术有限公司 一种动植物高粉末度高蛋白料连续萃取装置
CN103599646B (zh) * 2013-12-10 2016-06-08 苏州鼎机新能源材料科技有限公司 防轴辊卡死的萃取槽
CN104818118A (zh) * 2015-04-21 2015-08-05 绍兴文理学院 一种花梨木木屑萃取花梨木精油的生产工艺及其设备
CN108264964B (zh) * 2018-02-05 2021-08-06 广州四季风食品科技有限公司 一种茉莉花浸膏香精生产用自动上料机构
CN110917654A (zh) * 2019-12-27 2020-03-27 昆明弘承商贸有限公司 一种溶液低温萃取装置及其高效萃取工艺

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB176104A (en) * 1920-11-26 1922-02-27 Francis Lawry Usher An improved process of and apparatus for extracting essential oils and other volatile substances
US2203666A (en) * 1938-07-19 1940-06-11 Extractol Process Ltd Method and mechanism for continuously forming liquid-impervious plugs in extraction units
US2752377A (en) * 1950-12-04 1956-06-26 Barber Greene Co Solvent extraction process
US2990255A (en) * 1955-04-22 1961-06-27 Rice Growers Ass Of California Oil extraction apparatus
US3005398A (en) * 1958-12-01 1961-10-24 Continental Copper & Steel Ind Extraction apparatus
US3467576A (en) * 1967-12-18 1969-09-16 James D A Clark Continuous treatment of fibrous material and apparatus
US3565634A (en) * 1966-08-25 1971-02-23 Astra Nutrition Ab Apparatus and method for continuous extraction of fats from organic matter
SU825610A1 (ru) * 1979-05-18 1981-04-30 Zaguta Nikolaj F Сепаратор' для отделения твердых частиц от паров к устройствам для паровой ' отгонки эфирных масел 1

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Publication number Priority date Publication date Assignee Title
DE1805426A1 (de) * 1968-10-26 1970-05-14 Jacobs Joh & Co Verfahren und Vorrichtung zur Gewinnung von Kaffeeinhaltsstoffen,insbesondere Aromastoffen,aus Roestkaffee durch Wasserdampfdestillation
FR2101966A5 (en) * 1970-08-20 1972-03-31 Up Right Inc Squashing and handling appts - for fruits such as grapes
AU451824B2 (en) * 1970-08-25 1974-08-02 JOHN MACKENZIE, WINIFRED MACKENZIE, IAN BRUCE MACKENZIE, NEIL SCORGIE MACKENZIE and TREVORS TREUDING Juice extracting device and process
FR2435521A1 (fr) * 1978-09-11 1980-04-04 Tournaire Sa Dispositif pour extraire les huiles essentielles par hydrodistillation.
ES2040367T3 (es) * 1987-10-19 1993-10-16 Biolandes Agro Mecanismo de carga-descarga de un recinto cerrado utilizable como cuba de extraccion de una unidad de extraccion en continuo de vegetales, y procedimiento de extraccion que comprende la aplicacion.

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB176104A (en) * 1920-11-26 1922-02-27 Francis Lawry Usher An improved process of and apparatus for extracting essential oils and other volatile substances
US2203666A (en) * 1938-07-19 1940-06-11 Extractol Process Ltd Method and mechanism for continuously forming liquid-impervious plugs in extraction units
US2752377A (en) * 1950-12-04 1956-06-26 Barber Greene Co Solvent extraction process
US2990255A (en) * 1955-04-22 1961-06-27 Rice Growers Ass Of California Oil extraction apparatus
US3005398A (en) * 1958-12-01 1961-10-24 Continental Copper & Steel Ind Extraction apparatus
US3565634A (en) * 1966-08-25 1971-02-23 Astra Nutrition Ab Apparatus and method for continuous extraction of fats from organic matter
US3467576A (en) * 1967-12-18 1969-09-16 James D A Clark Continuous treatment of fibrous material and apparatus
SU825610A1 (ru) * 1979-05-18 1981-04-30 Zaguta Nikolaj F Сепаратор' для отделения твердых частиц от паров к устройствам для паровой ' отгонки эфирных масел 1

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5582694A (en) * 1994-09-21 1996-12-10 Idaho Mint Distiller, Inc. Hydrodistillation process for essential mint oils
US5891501A (en) * 1997-11-25 1999-04-06 Mckellip; Lewis L. Method for extraction of essential oils from plant material
WO2000054599A1 (fr) * 1999-03-15 2000-09-21 Konstantinos Zikas Unite de deshydratation de produits en vrac
US20140332363A1 (en) * 2012-02-06 2014-11-13 Michael McGolden Method and system for gasification of biomass
US11613705B2 (en) * 2012-02-06 2023-03-28 Mcgolden, Llc Method and system for gasification of biomass
US20190030100A1 (en) * 2012-10-18 2019-01-31 Robert J Rapp Essential Element Management
US10849949B2 (en) * 2012-10-18 2020-12-01 Robert J Rapp Essential element management
CN102908803A (zh) * 2012-11-09 2013-02-06 青岛中科华联新材料有限公司 一种薄膜萃取槽传动装置
CN102908803B (zh) * 2012-11-09 2015-04-01 青岛中科华联新材料有限公司 一种薄膜萃取槽传动装置
CN104016150A (zh) * 2013-12-15 2014-09-03 广西鱼峰水泥股份有限公司 斜槽进给装置
US11505764B2 (en) * 2017-09-29 2022-11-22 Chenguang Biotech Group Co., Ltd Continuous distillation process

Also Published As

Publication number Publication date
IL88074A0 (en) 1989-06-30
JPH01146992A (ja) 1989-06-08
AU614778B2 (en) 1991-09-12
PT88787B (pt) 1994-06-30
ES2040367T3 (es) 1993-10-16
PT88787A (pt) 1989-07-31
IL88074A (en) 1992-05-25
DE3881330D1 (de) 1993-07-01
TNSN88108A1 (fr) 1990-07-10
JP2592112B2 (ja) 1997-03-19
CN1032018C (zh) 1996-06-12
AU2391788A (en) 1989-04-20
DE3881330T2 (de) 1993-09-09
DZ1260A1 (fr) 2004-09-13
BR8805665A (pt) 1989-07-18
EP0313441A1 (fr) 1989-04-26
CN1032672A (zh) 1989-05-03
EP0313441B1 (fr) 1993-05-26
CA1333520C (fr) 1994-12-20

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