US493277A - Method of electro-depositing metals - Google Patents
Method of electro-depositing metals Download PDFInfo
- Publication number
- US493277A US493277A US493277DA US493277A US 493277 A US493277 A US 493277A US 493277D A US493277D A US 493277DA US 493277 A US493277 A US 493277A
- Authority
- US
- United States
- Prior art keywords
- metals
- electro
- metal
- depositing
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 60
- 239000002184 metal Substances 0.000 title description 60
- 150000002739 metals Chemical class 0.000 title description 34
- 238000000151 deposition Methods 0.000 title description 22
- 238000000034 method Methods 0.000 description 30
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
- 229910052802 copper Inorganic materials 0.000 description 18
- 239000010949 copper Substances 0.000 description 18
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 14
- 239000011780 sodium chloride Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 10
- 238000004070 electrodeposition Methods 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 230000005611 electricity Effects 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000011244 liquid electrolyte Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 229910001369 Brass Inorganic materials 0.000 description 4
- 241000304911 Crassula falcata Species 0.000 description 4
- 230000001464 adherent Effects 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 239000010951 brass Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010494 dissociation reaction Methods 0.000 description 4
- 230000005593 dissociations Effects 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 230000001376 precipitating Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 210000001736 Capillaries Anatomy 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 229910000754 Wrought iron Inorganic materials 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000001413 cellular Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001427 coherent Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000000615 nonconductor Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
Definitions
- My improvements relate, first, to the conro stitution of the liquid from which the metal is to be deposited, and the properties and conditions which such liquid must possess; and second, to the method or process of precipitating the metal from such liquid, and of [5 applying the electric current therein.
- a brush such for example as a common paint-brush, provided with a suitable insulating handle.
- This brush with its electrode may be dipped into a thin paste or liquid, composed of water into which has been stirred a sufficient quantity of carbonate of copper in the form of fine powder, and then repeatedly applied to the object, in the same manner that a paint-brush is used upon an object which is to be painted. If the distance between the movable anode and the cathode which is being operated upon is not too great, and the electromotive force of the current is suflicient the metallic constituent of the salt will be deposited upon the surface of the object, and will adhere firmly thereto.
- A represents a dynamo-electric machine or other suitable source of electricity.
- B is the object to be electroplated, here shown as a plate of metal.
- 0 is a brush, made of bristles, secured in the usual manner to a handle 0 of wood or other non-conducting material.
- D is the anode, formed of conducting material, preferably carbon, secured to the handle c and being in electrical contact with the surface of the mass of bristles forming the brush 0.
- the anode D and the cathode B are respectively connected with the positive and negative poles of the generator by flexible conductors w w.
- the cathode is, for example, of iron, and copper is deposited upon it by the above process from carbonate of copper, the coating is found to be so strongly adhesive at the surfaces of contact, that it virtually if not actually, effects a perfect union of the two dissimilar metals.
- the deposit of metal obtained by the process I have described is ceremoniesne in character, perfectly solid and coherent, and of uniform thickness, especially when applied by means of the mechanical device which I have hereinbefore described. In such case the deposit presents an appearance as if burnished, and is moreover fibrous and tough in structure.
- My process may also be employed for the deposition of alloys composed of two, three or more dilferent metals.
- I have used, with good results, a mixture of forty-five parts carbonate of zinc; forty-five parts carbonate of copper, and five to ten parts, either of cyanide of zinc or cyanide of copper.
Description
(No Model.)
0. LUGO. METHOD OF ELBOTRO DEPOSITING METALS.
No. 493,277. Patented Mar. 14, 1893.
25 basic and the deposited metal.
5 conductive surface).
UNTTED STATES PATENT Fries.
ORAZIO LUGO, OF NEW YORK, N. Y., ASSIGNOR TO THE COSMIC ALLOY AND METAL DEPOSITING COMPANY, OF NEW JERSEY.
METHOD OF ELECTRO-DEPOSITING METALS.
SPECIFICATION forming part of Letters Patent No. 493,277, dated March 14, 1893. 7 Application filed January 8, 1892. SerialNo. 417,400. (No specimens.)
To all whom it may concern.-
Be it known that I, ORAZIO LUGO, a citizen of the United States, and a resident of the city, county, and State of New York, have in- 5 vented or discovered certain new and useful Improvements in the Method of Electro-Depositing Metals, of whichthe following is a specification.
My improvements relate, first, to the conro stitution of the liquid from which the metal is to be deposited, and the properties and conditions which such liquid must possess; and second, to the method or process of precipitating the metal from such liquid, and of [5 applying the electric current therein.
The art of electro-platin g, which is the most useful application of the general process of electro-deposition, consists in precipitating a permanent coating of one or more metals upon a base or body of the same or of different metals. The complete success of this process requires, first, that the metal shall be deposited in a reguline state, and second, that a perfect union shall be effected between the The last named result, though heretofore possible to be accomplished in the case of certain metals, has been found to be difficult, and in some cases impossible, with other metals, when at- 0 tempted by any of the methods and processes heretofore known in the art. So far as I am aware, all these methods and processes contemplate the deposition of a given metal from an aqueous solution of some one of its 5 soluble salts, in which solution is immersed to be deposited. If for example, it be required to deposit an adherent coating of copper, the object which is to be coated is first cleaned in the usual manner (or if it be a nonconductor of electricity it is provided with a It is then connected with the negative terminal of a dynamo or other suitable generator of electricity. The positive terminal of the same generator may then be connected with a plate or electrode,
preferably of platinum or of platin'ized carbon,
and affixed to a brush, such for example asa common paint-brush, provided with a suitable insulating handle. This brush with its electrode, may be dipped into a thin paste or liquid, composed of water into which has been stirred a sufficient quantity of carbonate of copper in the form of fine powder, and then repeatedly applied to the object, in the same manner that a paint-brush is used upon an object which is to be painted. If the distance between the movable anode and the cathode which is being operated upon is not too great, and the electromotive force of the current is suflicient the metallic constituent of the salt will be deposited upon the surface of the object, and will adhere firmly thereto.
The accompanying drawing shows a simple form of apparatus by which my invention may conveniently be carried into effect.
A represents a dynamo-electric machine or other suitable source of electricity.
B is the object to be electroplated, here shown as a plate of metal.
0 is a brush, made of bristles, secured in the usual manner to a handle 0 of wood or other non-conducting material.
D is the anode, formed of conducting material, preferably carbon, secured to the handle c and being in electrical contact with the surface of the mass of bristles forming the brush 0.
The anode D and the cathode B (the latter through the base plate E), are respectively connected with the positive and negative poles of the generator by flexible conductors w w.
Vhen the cathode is, for example, of iron, and copper is deposited upon it by the above process from carbonate of copper, the coating is found to be so strongly adhesive at the surfaces of contact, that it virtually if not actually, effects a perfect union of the two dissimilar metals.
The deposit of metal obtained by the process I have described is reguline in character, perfectly solid and coherent, and of uniform thickness, especially when applied by means of the mechanical device which I have hereinbefore described. In such case the deposit presents an appearance as if burnished, and is moreover fibrous and tough in structure.
I sometimes prefer to employ the cyanides of certain metals, either alone or in conjunction with the carbonates.
In the deposition of copper according to my improved process, I have obtained good results with a mixture of five to ten parts cyanide of copper with ninety to ninety-five parts carbonate of copper, using an electromotive force of fifty to one hundred volts or even ess.
My process may also be employed for the deposition of alloys composed of two, three or more dilferent metals. In depositing brass, for example, I have used, with good results, a mixture of forty-five parts carbonate of zinc; forty-five parts carbonate of copper, and five to ten parts, either of cyanide of zinc or cyanide of copper.
In case it is required to deposit metals of which the carbonates are not obtainable, as for example gold, tin, &c., I make use of the oxides, and employ in conjunction with said oxides the carbonates of the alkalies, or preferably of the alkaline earth, as forv example, the carbonate of lime or carbonate of magnesia.
I have also discovered that in certain cases, in which the carbonate of a metal is of such character as to strongly resist dissociation,or requires for such dissociation an inconveniently high electromotive force, the presence of one of the earth-carbonates materially facilitates the conduction and rapid decomposition of the metallic salt. The processes of depositing metals from their carbonates, in the presence of the carbonates of the alkalies or of the alkaline earth, or from their oxides,
under similar conditions, are not herein specifically claimed.
I have succeeded in depositing an adherent metallic coating by the hereinbefore described process, upon cast and wrought iron, steel, zinc,alnminium, lead,tin,brass, graphite and many other conducting substances.
Instead of the brush hereinbefore described, otherinsolublenon-conducting cellular or capillary substances, may be employed to hold the electrolyte in place while it is being applied to the body to be coated.
The specific form of brush hereinbeforede- 5o scribed is claimed in another application for Letters-Patent of the United States (Serial No. 4l7,751) filed January 11, 1892.
I claim as my invention 1'. The hereinbefore described process of electro-deposition, which consists in depositing a metal from a liquid electrolyte or paste composed of a mixture of one or more insoluble salts of such metal with water, by passing an electric current through the same in connection with a suitable anode, as set forth.
'2. The hereinbefore described process of electro deposition, which consists in the repeated application to the surface of the object which is to receive the deposit, of a liquid electrolyte orpaste, composed of a mixture of water with one or more insoluble salts of the metal to be deposited, and in causing the same to be traversed by an electric current, as set forth.
3. The hereinbefore described process of electro-deposition, which consists in simultaneously depositing two or-more metals from a liquid electrolyte or paste, composed of a mixture of water with one or more insoluble salts of each of said metals, by causing an electric current to traverse said electrolyte, as set forth.
4. The hereinbefore described process of electro-deposition, which consists in depositing a metal or metals from a liquid or paste, consisting of a mixture of water with one or more insoluble salts of such metal or metals, by spreading or painting the same upon the cathode while subjected to the decomposing effect of a current of electricity, as set forth.
In testimony whereof I have hereunto subscribed my name this 7th day of January, A. D. 1892.
ORAZIO LUGO.
Witnesses:
SAML. M. HITCHCOCK, CORTLANDT PARKER, J r.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US493277A true US493277A (en) | 1893-03-14 |
Family
ID=2562120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US493277D Expired - Lifetime US493277A (en) | Method of electro-depositing metals |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US493277A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3259556A (en) * | 1964-09-28 | 1966-07-05 | Gen Dynamics Corp | Ribbon electroplating method |
| US3324015A (en) * | 1963-12-03 | 1967-06-06 | Hughes Aircraft Co | Electroplating process for semiconductor devices |
-
0
- US US493277D patent/US493277A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3324015A (en) * | 1963-12-03 | 1967-06-06 | Hughes Aircraft Co | Electroplating process for semiconductor devices |
| US3259556A (en) * | 1964-09-28 | 1966-07-05 | Gen Dynamics Corp | Ribbon electroplating method |
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