US4494481A - Animal litter composition - Google Patents
Animal litter composition Download PDFInfo
- Publication number
- US4494481A US4494481A US06/441,318 US44131882A US4494481A US 4494481 A US4494481 A US 4494481A US 44131882 A US44131882 A US 44131882A US 4494481 A US4494481 A US 4494481A
- Authority
- US
- United States
- Prior art keywords
- ppm
- absorbent material
- salt
- solid absorbent
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241001465754 Metazoa Species 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 54
- 239000002250 absorbent Substances 0.000 claims abstract description 47
- 230000002745 absorbent Effects 0.000 claims abstract description 47
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 31
- 239000007787 solid Substances 0.000 claims abstract description 28
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 150000003624 transition metals Chemical class 0.000 claims abstract description 15
- 230000000737 periodic effect Effects 0.000 claims abstract description 7
- -1 transition metal salt Chemical class 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 239000004927 clay Substances 0.000 claims description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical group [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- 150000003751 zinc Chemical class 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical group [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical group [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 1
- 235000019645 odor Nutrition 0.000 abstract description 37
- 238000011161 development Methods 0.000 abstract description 15
- 210000002700 urine Anatomy 0.000 abstract description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- 229910021529 ammonia Inorganic materials 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 241000282326 Felis catus Species 0.000 description 8
- 239000008188 pellet Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 239000010881 fly ash Substances 0.000 description 4
- 101710134784 Agnoprotein Proteins 0.000 description 3
- 241000219823 Medicago Species 0.000 description 3
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 3
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000012216 bentonite Nutrition 0.000 description 3
- 229930002875 chlorophyll Natural products 0.000 description 3
- 235000019804 chlorophyll Nutrition 0.000 description 3
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 229910001428 transition metal ion Inorganic materials 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 241000588767 Proteus vulgaris Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 108010046334 Urease Proteins 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- KPWJBEFBFLRCLH-UHFFFAOYSA-L cadmium bromide Chemical compound Br[Cd]Br KPWJBEFBFLRCLH-UHFFFAOYSA-L 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- OKIIEJOIXGHUKX-UHFFFAOYSA-L cadmium iodide Chemical compound [Cd+2].[I-].[I-] OKIIEJOIXGHUKX-UHFFFAOYSA-L 0.000 description 2
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229910001987 mercury nitrate Inorganic materials 0.000 description 2
- DRXYRSRECMWYAV-UHFFFAOYSA-N nitrooxymercury Chemical compound [Hg+].[O-][N+]([O-])=O DRXYRSRECMWYAV-UHFFFAOYSA-N 0.000 description 2
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 229940007042 proteus vulgaris Drugs 0.000 description 2
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- GABQNAFEZZDSCM-RMKNXTFCSA-N Cinnamyl anthranilate Chemical compound NC1=CC=CC=C1C(=O)OC\C=C\C1=CC=CC=C1 GABQNAFEZZDSCM-RMKNXTFCSA-N 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- 229910017770 Cu—Ag Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- WRYNUJYAXVDTCB-UHFFFAOYSA-M acetyloxymercury Chemical compound CC(=O)O[Hg] WRYNUJYAXVDTCB-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010884 boiler slag Substances 0.000 description 1
- 239000010882 bottom ash Substances 0.000 description 1
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- LHQLJMJLROMYRN-UHFFFAOYSA-L cadmium acetate Chemical compound [Cd+2].CC([O-])=O.CC([O-])=O LHQLJMJLROMYRN-UHFFFAOYSA-L 0.000 description 1
- 229940075417 cadmium iodide Drugs 0.000 description 1
- QCUOBSQYDGUHHT-UHFFFAOYSA-L cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 description 1
- 229910000331 cadmium sulfate Inorganic materials 0.000 description 1
- KTTSJTVLWUJJMN-UHFFFAOYSA-L cadmium(2+);dichlorate Chemical compound [Cd+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O KTTSJTVLWUJJMN-UHFFFAOYSA-L 0.000 description 1
- BAAYWLNVHTVAJJ-UHFFFAOYSA-L cadmium(2+);diformate Chemical compound [Cd+2].[O-]C=O.[O-]C=O BAAYWLNVHTVAJJ-UHFFFAOYSA-L 0.000 description 1
- BJHNOFIZTODKMI-UHFFFAOYSA-L cadmium(2+);diiodate Chemical compound [Cd+2].[O-]I(=O)=O.[O-]I(=O)=O BJHNOFIZTODKMI-UHFFFAOYSA-L 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- CMRVDFLZXRTMTH-UHFFFAOYSA-L copper;2-carboxyphenolate Chemical compound [Cu+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O CMRVDFLZXRTMTH-UHFFFAOYSA-L 0.000 description 1
- NSGLMHRMZITSKO-UHFFFAOYSA-L copper;dibromate Chemical compound [Cu+2].[O-]Br(=O)=O.[O-]Br(=O)=O NSGLMHRMZITSKO-UHFFFAOYSA-L 0.000 description 1
- IQKQUSLYXMWMQZ-UHFFFAOYSA-N copper;oxido-(oxido(dioxo)chromio)oxy-dioxochromium Chemical compound [Cu+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O IQKQUSLYXMWMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011981 development test Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002730 mercury Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000002601 urease inhibitor Substances 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- GTQFPPIXGLYKCZ-UHFFFAOYSA-L zinc chlorate Chemical compound [Zn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O GTQFPPIXGLYKCZ-UHFFFAOYSA-L 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- TUDPEWOTGHYZBQ-UHFFFAOYSA-L zinc;dibromate Chemical compound [Zn+2].[O-]Br(=O)=O.[O-]Br(=O)=O TUDPEWOTGHYZBQ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
- A01K1/0152—Litter
Definitions
- This invention relates to an inexpensive absorbent animal litter product which is capable of preventing the development of unpleasant urine odors over an extended period of time.
- Silver, copper, mercury, cadmium and zinc ions are known urease inhibitors; see, for example, Kaneshiro et al., Arch. Biochem. Biophys. 174 647-650 (1976) and Geike, Z. Anal. Chem. Band 258, Heft 4, 284-285 (1972). Practical applications disclosed include the quantitative analysis of these metals with urease (e.g. the Geike reference cited above), and the use of copper salts as additives to urea fertilizer to prevent its decomposition (U.S. Pat. No. 3,523,018, issued Aug. 4, 1970, to Geissler et al).
- Prior art attempts to deodorize cat litter include the addition of a perfume (see, e.g., U.S. Pat. No. 3,921,581, issued Nov. 25, 1975 to Brewer), and the addition of chlorophyll, mainly in the form of dried alfalfa to the litter, (see, e.g., U.S. Pat. No. 3,923,005, issued Dec. 2, 1975 to Fry et al., assigned to The Clorox Company).
- the composition of fly ash includes silicon dioxide, alumina, ferric oxide, calcium oxide, magnesium oxide, sodium oxide and potassium oxide. The material is not reported to contain any of the Group Ib or IIb transition metals.
- This invention relates to a solid absorbent material useful as an animal litter, having adsorbed thereto from about 50 ppm to about 3000 ppm of a soluble salt of a transition metal of Group Ib or group IIb of the periodic table of the elements.
- the transition metals may be used at such low levels that neither their cost nor their toxicity creates any problems.
- the animal litter material of this invention effectively prevents the development of unpleasant odors over an extended period of time.
- This invention further encompasses a method of making the subject animal litter product.
- gas concentrations are volume in volume, unless indicated otherwise.
- the amounts of transition metal are expressed in weight of the transition metal salt by weight of the absorbent material.
- the transition metal salt is adsorbed to the solid absorbent material by contacting the solid absorbent material with a solution, preferably an aqueous solution, of the transition metal salt.
- Contacting means wetting at least a significant portion of the surface area of the solid absorbent material with the transition metal solution, and thus includes impregnating, soaking, and spraying.
- the unpleasant odors associated with the urine of household pets is perceived as an important problem by the owners of such pets. It is therefore not surprising that the literature is replete with reports of attempts to alleviate this problem.
- animal litter products to which perfume or chlorophyll has been added are animal litter products to which perfume or chlorophyll has been added.
- the former may be in the form of encapsulated particles, the latter e.g. in the form of alfalfa pellets.
- an animal litter material In order to effectively prevent the development of malodors, an animal litter material must therefore be capable of eliminating sulfide and mercaptan odors.
- the capability of eliminating ammonia odor is of only secondary importance and may not be important at all, as it is unlikely that the amount of ammonia generated will exceed the ODT under normal conditions in the typical home.
- transition metal salt The low levels of transition metal salt are effective only if they are adsorbed to the absorbent material. If the salt is added as a pulverized or crystalline material in a dry form to the litter material no appreciable prevention of odor development is obtained, even if substantially higher levels of transition metal salt are used.
- any absorbent solid material suitable for use as an animal litter is suitable for use in the present invention.
- Suitable examples include minerals, typically clay such as kaolinites, montmorillonites, or bentonites; fly ash as obtained from the burning of coal; but also absorbent fibrous webs like cellulosic webs or polymeric fibrous webs; pelletized absorbent materials (e.g. sawdust or polyurethane foam); and the like.
- pellets of a cation exchange resin can be loaded with transition metal ions by cation exchange; these pellets, when mixed with a conventional animal litter product, will effectively prevent the development of malodors.
- Particle sizes typically range from about 0.1 inch to about 0.5 inch (from about 0.25 cm to about 1.3 cm).
- Other examples of suitable solid absorbent materials are disclosed in U.S. Pat. No. 3,921,581, issued Nov. 25, 1975 to Brewer, incorporated herein by reference.
- suitable sources of the transition metal ion are its soluble salts.
- suitable examples are silver chlorate, silver nitrate, mercury acetate, mercury chloride, mercury nitrate, copper metaborate, copper bromate, copper bromide, copper chloride, copper dichromate, copper nitrate, copper salicylate, copper sulfate, zinc acetate, zinc borate, zinc bromate, zinc bromide, zinc chlorate, zinc chloride, zinc sulfate, cadmium acetate, cadmium borate, cadmium bromide, cadmium chlorate, cadmium chloride, cadmium formate, cadmium iodate, cadmium iodide, cadmium permanganate, cadmium nitrate, cadmium sulfate, and gold chloride
- Animal litter products according to the present invention can be prepared as follows.
- the calculated amount of transition metal salt is dissolved in an amount of water which is sufficient to completely saturate the solid absorbent material.
- the amount of water necessary will vary with the kind of absorbent material used and typically is in the range of from about 1 liter to about 5 liters per kg of solid absorbent material.
- the solid absorbent material is slurried with the transition metal salt solution.
- the slurry is then allowed to equilibrate for about 10 minutes.
- the slurry may be agitated by stirring or by vibrating which reduces the amount of time needed for equilibration.
- the water is drained off and the wet solid material is collected on e.g., a screen.
- the solid material is then dried at ambient conditions, or in an oven at a temperature of from about 50° C. to about 95° C.
- This procedure lends itself extremely well to a continuous process, whereby metered flows of solid absorbent material and transition metal solution are contacted with each other, the material is subsequently drained on a perforated conveyor belt and dried in an air-dry tunnel.
- the amount of transition metal salt on the absorbent material may be determined by direct analysis, or by analyzing the drained-off solution and calculating the mass balance.
- the amount of solution may be such that it is just sufficient to saturate the absorbent material so that no draining step will be necessary. This insures quantitative deposition of the transition metal salt and eliminates the necessity of handling excess water.
- transition metal salt need not be fixed to the absorbent material by calcination, or be converted to its oxide. This is important because it eliminates an energy intensive, and therefore costly, process step and it also makes the process of this invention suitable for absorbent materials which are not heat resistant like cellulose fibers, polymeric fibers and polyurethane foam pellets.
- transition metal salt The amount of transition metal salt to be used depends on its effectiveness, its cost and its toxicity.
- Silver salts and mercury salts are very effective but are also toxic and expensive and are therefore used at levels ranging from about 50 ppm to about 500 ppm, preferably from about 100 ppm to about 300 ppm.
- Copper salts, zinc salts and cadmium salts are most effectively used at levels ranging from about 1500 ppm to about 3000 ppm, preferably at levels from about 1800 ppm to about 2500 ppm.
- Gold salts are effective and substantially less toxic than silver or mercury. However, under prevailing economic circumstances it is doubtful that the use of gold salts would ever be economically feasible.
- Samples of a commercial clay cat litter product (Cat's Pride, from Oil-Dri Corporation of America, Chicago, Ill.) were treated with solutions of transition metal salts by the batch method described above at the rate of 1 liter solution per 1135 g of clay. The samples were stirred until the litter was thoroughly saturated with the entire solution. The wet material was then dried in an oven at 93° C. 15 g of the litter product were weighed into a container and treated with 15 ml of cat urine. (If catheterized cat urine was used Proteus vulgaris was added, as Proteus vulgaris is present in normal cat urine and not in catheterized cat urine).
- the container was closed and the head space above the litter material was analyzed for ammonia and sniffed for odor development by two independent panelists once every weekday after start of the test. The results are summarized in the table below. The controls were run with untreated samples of Cat's Pride clay litter.
- absorbent solid materials having soluble transition metal salts adsorbed thereto, are prepared: bentonite clay+500 ppm silver chlorate; fly ash pellets (ca 1 cm particle size)+300 ppm mercury nitrate; cellulose fiber web+2000 ppm copper (II) chloride; sawdust pellets (ca 0.5 cm particle size)+2500 ppm zinc sulfate; and polyurethane foam pellets (ca 0.8 cm particle size)+1800 ppm cadmium nitrate.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Epidemiology (AREA)
- Housing For Livestock And Birds (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Test 1 ______________________________________ 50 ppm 200 ppm 500 ppm Control AgNO.sub.3 AgNO.sub.3 AgNO.sub.3 NH.sub.3 NH.sub.3 NH.sub.3 NH.sub.3 o- Day (ppm) odor (ppm) odor (ppm) odor (ppm) dor ______________________________________ 7 3 - 0 - 0 - 0 - 8 3 - 0 - 0 - 0 - 9 5 - 0 - 0 - 0 - 13 35 + 10 - 0 - 0 - 14 50 ++ 10 - 0 - 0 - 15 60 +++ 20 - 0 - 5 - 16 80 +++ .sup.a + .sup.a - .sup.a - 21 150 +++ 100 + 0 - 2.5 ______________________________________ - no odor detectable + detectable odor ++ strong odor +++ very strong odor .sup.a not measured
Test 2 __________________________________________________________________________ 200 ppm 2000 ppm 200 ppm 2000 ppm Control CuSO.sub.4 CuSO.sub.4 HgCl.sub.2 HgCl.sub.2 NH.sub.3 NH.sub.3 NH.sub.3 NH.sub.3 NH.sub.3 Day (ppm) odor (ppm) odor (ppm) odor (ppm) odor (ppm) odor __________________________________________________________________________ 6 2 - 5 - 0 - 0 - 0 - 7 50 ++ 5 - 10 - 0 - 0 - 8 210 +++ 5 - 10 - 2.5 - 2.5 - 9 600 +++ .sup.a - .sup.a - .sup.a - .sup.a - 14 520 +++ 10 - 40 - 0 - 10 - 15 520 +++ 38 + 60 + 0 - 25 - 16 600 +++ 40 + 70 + 0 - 30 - __________________________________________________________________________ - no odor detectable + detectable odor ++ strong odor +++ very strong odor .sup.a not measured
Claims (18)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/441,318 US4494481A (en) | 1982-11-12 | 1982-11-12 | Animal litter composition |
CA000440964A CA1216739A (en) | 1982-11-12 | 1983-11-10 | Animal litter composition |
EP83306886A EP0109276A3 (en) | 1982-11-12 | 1983-11-11 | Animal litter composition and method for preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/441,318 US4494481A (en) | 1982-11-12 | 1982-11-12 | Animal litter composition |
Publications (1)
Publication Number | Publication Date |
---|---|
US4494481A true US4494481A (en) | 1985-01-22 |
Family
ID=23752420
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/441,318 Expired - Lifetime US4494481A (en) | 1982-11-12 | 1982-11-12 | Animal litter composition |
Country Status (3)
Country | Link |
---|---|
US (1) | US4494481A (en) |
EP (1) | EP0109276A3 (en) |
CA (1) | CA1216739A (en) |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3520384A1 (en) * | 1985-06-07 | 1986-12-11 | Effem Gmbh, 2810 Verden | LIVESTOCK AND METHOD FOR THE PRODUCTION THEREOF |
WO1987003169A1 (en) * | 1985-11-29 | 1987-06-04 | Kal Kan Foods, Inc. | Animal litter and method of preparation |
US4685420A (en) * | 1985-12-11 | 1987-08-11 | The Dow Chemical Company | Animal litter and related processes |
DE3708556A1 (en) * | 1986-03-21 | 1987-10-01 | Colgate Palmolive Co | ABSORBING INSERT FOR ANIMAL TUBS AND THE LIKE |
US4949672A (en) * | 1988-06-17 | 1990-08-21 | The Clorox Company | Boron-based odor control animal litter |
WO1991005464A1 (en) * | 1989-10-13 | 1991-05-02 | Nelson Thomas E | An animal litter containing zeolite |
US5016568A (en) * | 1989-06-23 | 1991-05-21 | The Clorox Company | Odor controlling animal litter with pine oil |
US5018482A (en) * | 1988-06-17 | 1991-05-28 | The Clorox Company | Combined odor controlling animal litter |
US5031578A (en) * | 1990-04-10 | 1991-07-16 | The Procter & Gamble Company | Pet litter box system which prevents the development of unpleasant odors |
US5038721A (en) * | 1990-04-10 | 1991-08-13 | The Procter & Gamble Company | Animal waste collection system comprising nonsorbent, nonclumping litter, liquid sorbent means and filter |
US5062392A (en) * | 1990-04-10 | 1991-11-05 | The Procter & Gamble Company | Filtering and disposal system for pet litter |
US5094190A (en) * | 1988-06-17 | 1992-03-10 | The Clorox Company | Boron-based odor control animal litter |
US5135743A (en) * | 1989-06-23 | 1992-08-04 | The Clorox Company | Combined odor controlling animal litter |
US5176108A (en) * | 1988-06-17 | 1993-01-05 | The Clorox Company | Boron-based odor control animal litter |
US5183655A (en) * | 1988-06-17 | 1993-02-02 | The Clorox Company | Combined odor controlling animal litter |
US5189987A (en) * | 1989-06-23 | 1993-03-02 | The Clorox Company | Odor controlling animal litter with pine oil |
US5295456A (en) * | 1993-05-03 | 1994-03-22 | Church & Dwight Co., Inc. | Deodorizing additives for animal litters |
US5303676A (en) * | 1993-05-03 | 1994-04-19 | Church & Dwight Co., Inc. | Animal litters containing a deodorizing additive |
US5317990A (en) * | 1989-01-13 | 1994-06-07 | American Colloid Company | Animal dross absorbent and method |
US5386803A (en) * | 1989-01-13 | 1995-02-07 | American Colloid Company | Animal dross absorbent and method |
US5421291A (en) * | 1994-03-28 | 1995-06-06 | Church & Dwight Co., Inc. | Animal litter containing a water-swellable clay, carboxymethylcellulose, and siliceous coated bicarbonate particles |
EP0719496A3 (en) * | 1994-12-28 | 1996-09-11 | Bis Corp | Pet toilet and toilet sand used therefor |
US5634431A (en) * | 1994-10-18 | 1997-06-03 | Malireddy S. Reddy | Odor inhibiting pet litter |
WO1997025076A1 (en) * | 1996-01-11 | 1997-07-17 | Isk Biosciences Corporation | Odor control for compositions containing organic sulfur compounds |
WO1998027261A3 (en) * | 1996-12-17 | 1998-09-03 | Procter & Gamble | Animal care system and litter with reduced malodor impression |
WO2000029039A1 (en) * | 1998-11-14 | 2000-05-25 | Sanodor As | Spray containing amphoteric material to reduce malodors |
US6287550B1 (en) * | 1996-12-17 | 2001-09-11 | The Procter & Gamble Company | Animal care system and litter with reduced malodor impression |
US6962129B1 (en) | 2004-07-16 | 2005-11-08 | Church & Dwight Co., Inc. | Clumping compacted bicarb litter |
WO2008131120A1 (en) * | 2007-04-18 | 2008-10-30 | Church & Dwight Co., Inc. | Puffed bentonite litter |
US20110061598A1 (en) * | 2009-09-15 | 2011-03-17 | Chett Boxley | Environmentally-Friendly Animal Litter |
US8522720B2 (en) | 2009-09-15 | 2013-09-03 | Ceramatec, Inc. | Environmentally-friendly animal litter |
US10440934B2 (en) | 2014-08-26 | 2019-10-15 | Ep Minerals, Llc | Low density compositions with synergistic absorbance properties |
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DE3506070A1 (en) * | 1985-02-21 | 1986-08-21 | Ytong AG, 8000 München | Animal litter |
US5429073A (en) * | 1993-10-26 | 1995-07-04 | Shakespeare Company | Bedding materials for animals |
JP4649707B2 (en) * | 2000-06-12 | 2011-03-16 | 黒崎白土工業株式会社 | Method for producing metal compound-supported granular material |
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US20160219829A1 (en) * | 2013-09-06 | 2016-08-04 | 7905122 Canada Inc. | Anti-odor material for animal litters using phosphorotriamides in powder form |
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Cited By (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3520384A1 (en) * | 1985-06-07 | 1986-12-11 | Effem Gmbh, 2810 Verden | LIVESTOCK AND METHOD FOR THE PRODUCTION THEREOF |
US4736706A (en) * | 1985-06-07 | 1988-04-12 | Mars, Inc. | Animal litter and process for the production thereof |
WO1987003169A1 (en) * | 1985-11-29 | 1987-06-04 | Kal Kan Foods, Inc. | Animal litter and method of preparation |
US4685420A (en) * | 1985-12-11 | 1987-08-11 | The Dow Chemical Company | Animal litter and related processes |
DE3708556A1 (en) * | 1986-03-21 | 1987-10-01 | Colgate Palmolive Co | ABSORBING INSERT FOR ANIMAL TUBS AND THE LIKE |
US5183655A (en) * | 1988-06-17 | 1993-02-02 | The Clorox Company | Combined odor controlling animal litter |
US5094190A (en) * | 1988-06-17 | 1992-03-10 | The Clorox Company | Boron-based odor control animal litter |
US4949672A (en) * | 1988-06-17 | 1990-08-21 | The Clorox Company | Boron-based odor control animal litter |
US5018482A (en) * | 1988-06-17 | 1991-05-28 | The Clorox Company | Combined odor controlling animal litter |
US5176108A (en) * | 1988-06-17 | 1993-01-05 | The Clorox Company | Boron-based odor control animal litter |
US5386803A (en) * | 1989-01-13 | 1995-02-07 | American Colloid Company | Animal dross absorbent and method |
US5503111A (en) * | 1989-01-13 | 1996-04-02 | American Colloid Company | Animal dross absorbent and method |
US5317990A (en) * | 1989-01-13 | 1994-06-07 | American Colloid Company | Animal dross absorbent and method |
US5135743A (en) * | 1989-06-23 | 1992-08-04 | The Clorox Company | Combined odor controlling animal litter |
US5189987A (en) * | 1989-06-23 | 1993-03-02 | The Clorox Company | Odor controlling animal litter with pine oil |
US5016568A (en) * | 1989-06-23 | 1991-05-21 | The Clorox Company | Odor controlling animal litter with pine oil |
WO1991005464A1 (en) * | 1989-10-13 | 1991-05-02 | Nelson Thomas E | An animal litter containing zeolite |
US5062392A (en) * | 1990-04-10 | 1991-11-05 | The Procter & Gamble Company | Filtering and disposal system for pet litter |
US5038721A (en) * | 1990-04-10 | 1991-08-13 | The Procter & Gamble Company | Animal waste collection system comprising nonsorbent, nonclumping litter, liquid sorbent means and filter |
US5031578A (en) * | 1990-04-10 | 1991-07-16 | The Procter & Gamble Company | Pet litter box system which prevents the development of unpleasant odors |
US5303676A (en) * | 1993-05-03 | 1994-04-19 | Church & Dwight Co., Inc. | Animal litters containing a deodorizing additive |
US5295456A (en) * | 1993-05-03 | 1994-03-22 | Church & Dwight Co., Inc. | Deodorizing additives for animal litters |
US5421291A (en) * | 1994-03-28 | 1995-06-06 | Church & Dwight Co., Inc. | Animal litter containing a water-swellable clay, carboxymethylcellulose, and siliceous coated bicarbonate particles |
US5634431A (en) * | 1994-10-18 | 1997-06-03 | Malireddy S. Reddy | Odor inhibiting pet litter |
EP0719496A3 (en) * | 1994-12-28 | 1996-09-11 | Bis Corp | Pet toilet and toilet sand used therefor |
WO1997025076A1 (en) * | 1996-01-11 | 1997-07-17 | Isk Biosciences Corporation | Odor control for compositions containing organic sulfur compounds |
WO1998027261A3 (en) * | 1996-12-17 | 1998-09-03 | Procter & Gamble | Animal care system and litter with reduced malodor impression |
US6287550B1 (en) * | 1996-12-17 | 2001-09-11 | The Procter & Gamble Company | Animal care system and litter with reduced malodor impression |
WO2000029039A1 (en) * | 1998-11-14 | 2000-05-25 | Sanodor As | Spray containing amphoteric material to reduce malodors |
US6962129B1 (en) | 2004-07-16 | 2005-11-08 | Church & Dwight Co., Inc. | Clumping compacted bicarb litter |
WO2006019999A1 (en) | 2004-07-16 | 2006-02-23 | Church & Dwight Co., Inc. | Clumping compacted bicarb litter |
WO2008131120A1 (en) * | 2007-04-18 | 2008-10-30 | Church & Dwight Co., Inc. | Puffed bentonite litter |
US20110061598A1 (en) * | 2009-09-15 | 2011-03-17 | Chett Boxley | Environmentally-Friendly Animal Litter |
US8251016B2 (en) | 2009-09-15 | 2012-08-28 | Ceramatec, Inc. | Environmentally-friendly animal litter |
US8511254B2 (en) | 2009-09-15 | 2013-08-20 | Ceramatec, Inc. | Environmentally friendly animal litter |
US8522720B2 (en) | 2009-09-15 | 2013-09-03 | Ceramatec, Inc. | Environmentally-friendly animal litter |
US10440934B2 (en) | 2014-08-26 | 2019-10-15 | Ep Minerals, Llc | Low density compositions with synergistic absorbance properties |
Also Published As
Publication number | Publication date |
---|---|
EP0109276A2 (en) | 1984-05-23 |
CA1216739A (en) | 1987-01-20 |
EP0109276A3 (en) | 1985-05-15 |
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