US4242211A - Lubricant for metal working - Google Patents
Lubricant for metal working Download PDFInfo
- Publication number
- US4242211A US4242211A US06/010,168 US1016879A US4242211A US 4242211 A US4242211 A US 4242211A US 1016879 A US1016879 A US 1016879A US 4242211 A US4242211 A US 4242211A
- Authority
- US
- United States
- Prior art keywords
- lubricant
- paste
- paste according
- glycol
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 46
- 238000005555 metalworking Methods 0.000 title claims abstract description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 15
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- 229940051250 hexylene glycol Drugs 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 239000010730 cutting oil Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Definitions
- This invention relates to a novel lubricant for metal working which is positively free of oily matter and is soluble in water.
- a lubricant such as a mineral oil, animal or vegetable oil, grease or the like is employed for the expansion of boiler tubes.
- Oily matter must be thoroughly removed before the start of boiler operation. This has usually been accomplished by a degreasing and cleaning operation that relies on so-called soda cooking, in which the oily matter is emulsified for subsequent removal by the addition of a large quantity of sodium hydroxide, sodium carbonate, sodium phosphate, sodium sulfite or the like and by boiling together up to a predetermined pressure.
- the ordinary degreasing method however, has shortcomings of high cost and labor requirements.
- the resulting waste liquid that contains oily matter cannot be discharged after a mere neutralizing treatment, but must be cleaned to the local effluent standard value for environmental protection (an oil content of not more than 5 ppm or, in some districts, not more than 1 ppm).
- the treatment of waste liquid to reach this degree of cleanliness involves enormous cost.
- a more recent trend in the art is to use a water-soluble cutting oil as the lubricant in order to simplify the process of degreasing and cleaning.
- the used cutting oil is thoroughly washed away by hot water or hydrazine but, because the waste liquid still contains oily matter, the problem of disposal of the waste remains.
- an object of this invention is to provide a novel lubricant for metal working which does not require no degreasing or cleaning and therefore no waste liquid treatment.
- the lubricant of the invention for pipe expanding is a completely oil-free, neutral, and water-soluble lubricant prepared by forming a paste from a mixture of a polyethylene oxide with water and/or a polyhydric alcohol, with or without the addition of a solid powder lubricant to the resulting paste.
- the polyethylene oxide--CH 2 CH 2 O-- n is used as the base for imparting lubricity to the lubricant.
- Polyethylene oxides ranging in molecular weight from 300 to 10,000 may be employed.
- a polyethylene oxide with a molecular weight from 1,000 and 4,000 or 600 and 4,000, respectively, is advantageously used because such alcohols are easily formed into pastes.
- the amount of water added to the polyethylene oxide varies with the molecular weight of the oxide used, but by rule of thumb it need only be sufficient for forming the oxide into paste which is not readily flowable.
- Polyethylene oxides with molecular weight ranges from 300 to 10,000 are viscous and waxy, and in order to form a non-flowing paste, the amount of water may be small for an oxide with a molecular weight of about 300 but will be large for an oxide with a molecular weight of about 10,000.
- water is added to account for from 5 to 60% by weight of the total amount of the lubricant of the invention for metal working.
- the polyhydric alcohol added to the polyethylene oxide not only imparts added lubricity to the resulting lubricant but also serves to convert polyethylene oxides with a relatively high molecular weights from the waxy to a pasty state. Therefore, a highly viscous alcohol, such as glycerol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, butylene glycol, or hexylene glycol, gives good result.
- a polyhydric alcohol is desirably used in a proportion ranging from 5 to 65% by weight of the total amount of the lubricant for metal working according to the invention, although the actual proportion may vary with the kind of the polyethylene oxide employed.
- the solid powder lubricant used in accordance with the invention will improve the workability as well as the lubricity of the resulting lubricant.
- additives are talc, molybdenum disulfide, and graphite. Desirably the additive accounts for from 0.5 to 20% by weight of the total amount of the lubricant working.
- the solid powder lubricant may be any of those which are normally commercially available.
- the lubricant of the invention is prepared simply by mixing water and/or a polyhydric alcohol with polyethylene oxide at ordinary temperature or at between about 40° and 70° C.
- the lubricant prepared by heating to about 40°-70° C. will become pasty on cooling to ordinary temperature.
- the addition of the solid powder lubricant may be effected at ordinary temperature or at the higher temperature of about 40°-70° C.
- the lubricant according to the invention is applied in advance on the sliding surfaces (i.e., on the pipe expanding parts) of the expander.
- the lubricant is in the form of a paste to act effectively on those surfaces without loss due to flow from the surfaces to be lubricated.
- lubricant according to the invention has been described as used in the expanding of tubing for boilers, it should be obvious to those skilled in the art that the lubricant may be applied to the expanding for the manufacture of heat exchangers and other apparatus and also to working of metals in general.
- the lubricant of the invention for metal working is:
- the lubricant eliminates the necessity of degreasing and washing before the initiation of boiler operation. Hence there is no problem of water liquid disposal and therefore, remarkable reductions in labor and chemical costs, and total working time required for the manufacture.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1195378A JPS54105650A (en) | 1978-02-07 | 1978-02-07 | Pipe expanding lubricant |
JP53/11952 | 1978-02-07 | ||
JP1195278A JPS54105649A (en) | 1978-02-07 | 1978-02-07 | Pipe expanding lubricant |
JP53/11953 | 1978-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
US4242211A true US4242211A (en) | 1980-12-30 |
Family
ID=26347476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/010,168 Expired - Lifetime US4242211A (en) | 1978-02-07 | 1979-02-07 | Lubricant for metal working |
Country Status (5)
Country | Link |
---|---|
US (1) | US4242211A (enrdf_load_stackoverflow) |
CA (1) | CA1126718A (enrdf_load_stackoverflow) |
DE (1) | DE2905045A1 (enrdf_load_stackoverflow) |
FR (1) | FR2416260A1 (enrdf_load_stackoverflow) |
GB (1) | GB2016040B (enrdf_load_stackoverflow) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996005275A1 (en) * | 1994-08-12 | 1996-02-22 | Hoeganaes Corporation | Powder metallurgy lubricant composition and methods for using same |
US5549836A (en) * | 1995-06-27 | 1996-08-27 | Moses; David L. | Versatile mineral oil-free aqueous lubricant compositions |
RU2137817C1 (ru) * | 1998-07-20 | 1999-09-20 | Расим Фарман оглы Мустафаев | Смазочно-охлаждающая жидкость для механической обработки металлов |
RU2168539C1 (ru) * | 2000-10-23 | 2001-06-10 | Леонид Петрович Ануфриев | Смазочно-охлаждающая жидкость для механической обработки материалов |
US20070105727A1 (en) * | 2003-11-26 | 2007-05-10 | Honda Motor Co., Ltd. | Water-base lubricant for plastic forming |
RU2303628C2 (ru) * | 2004-04-05 | 2007-07-27 | ООО "Научно-техническая фирма "ТЕХМА" | Концентрат смазочно-охлаждающей жидкости для механической обработки металлов |
RU2303627C2 (ru) * | 2004-04-05 | 2007-07-27 | ООО "Научно-техническая фирма "ТЕХМА" | Концентрат смазочно-охлаждающей жидкости для механической обработки металлов |
RU2329296C1 (ru) * | 2007-03-07 | 2008-07-20 | ООО Научно-производственное предприятие "Производство наноматериалов" | Технологическая смазка для пластической обработки металлов и сплавов |
RU2341642C2 (ru) * | 2002-09-13 | 2008-12-20 | Констракшн Рисерч Энд Текнолоджи Гмбх | Способ бурения твердой породы при помощи буровой туннелепроходческой машины |
US20100048759A1 (en) * | 2008-08-22 | 2010-02-25 | Ecolab Inc. | Method for lubricating surgical instruments |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3224784C2 (de) * | 1982-07-01 | 1984-04-26 | Siemens AG, 1000 Berlin und 8000 München | Kabelgleitmittel |
JPH0517795A (ja) * | 1991-07-17 | 1993-01-26 | Hanano Shoji Kk | アルミニウム合金鍛造用粉末潤滑剤 |
DE10343441B3 (de) * | 2003-09-19 | 2005-05-04 | Angelika Riepe | Verwendung eines flüssigen Gleitmittels |
DE102008006614A1 (de) * | 2008-01-29 | 2009-07-30 | Riepe, Angelika | Trennmittel |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2704744A (en) * | 1951-07-30 | 1955-03-22 | Inst Francais Du Petrole | Wire drawing composition |
CA524879A (en) * | 1956-05-08 | Shell Development Company | Metal working lubricant | |
US2820764A (en) * | 1951-11-02 | 1958-01-21 | Standard Oil Co | Thickened lubricants |
US2952335A (en) * | 1958-02-18 | 1960-09-13 | Shell Oil Co | Method of lubricating metal surfaces with a vaporous lubricant |
US3071543A (en) * | 1960-07-12 | 1963-01-01 | Mcgee Chemical Company Inc | Solid lubricant containing compositions |
US3124531A (en) * | 1964-03-10 | Metal working lubricant | ||
US3249538A (en) * | 1958-10-14 | 1966-05-03 | Kloeckner Werke Ag | Lubricating method and composition |
US3256186A (en) * | 1963-02-12 | 1966-06-14 | Lubrizol Corp | Process for producing carbonated basic metal compositions |
US3995465A (en) * | 1975-03-21 | 1976-12-07 | Sun Oil Company Of Pennsylvania | Method of coldworking metal pieces |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB603320A (en) * | 1945-10-22 | 1948-06-14 | Du Pont | Fluid compositions for use in devices operated by fluid pressure |
-
1979
- 1979-02-06 CA CA320,914A patent/CA1126718A/en not_active Expired
- 1979-02-07 FR FR7903077A patent/FR2416260A1/fr active Granted
- 1979-02-07 DE DE19792905045 patent/DE2905045A1/de not_active Withdrawn
- 1979-02-07 GB GB7904214A patent/GB2016040B/en not_active Expired
- 1979-02-07 US US06/010,168 patent/US4242211A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA524879A (en) * | 1956-05-08 | Shell Development Company | Metal working lubricant | |
US3124531A (en) * | 1964-03-10 | Metal working lubricant | ||
US2704744A (en) * | 1951-07-30 | 1955-03-22 | Inst Francais Du Petrole | Wire drawing composition |
US2820764A (en) * | 1951-11-02 | 1958-01-21 | Standard Oil Co | Thickened lubricants |
US2952335A (en) * | 1958-02-18 | 1960-09-13 | Shell Oil Co | Method of lubricating metal surfaces with a vaporous lubricant |
US3249538A (en) * | 1958-10-14 | 1966-05-03 | Kloeckner Werke Ag | Lubricating method and composition |
US3071543A (en) * | 1960-07-12 | 1963-01-01 | Mcgee Chemical Company Inc | Solid lubricant containing compositions |
US3256186A (en) * | 1963-02-12 | 1966-06-14 | Lubrizol Corp | Process for producing carbonated basic metal compositions |
US3995465A (en) * | 1975-03-21 | 1976-12-07 | Sun Oil Company Of Pennsylvania | Method of coldworking metal pieces |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996005275A1 (en) * | 1994-08-12 | 1996-02-22 | Hoeganaes Corporation | Powder metallurgy lubricant composition and methods for using same |
US5518639A (en) * | 1994-08-12 | 1996-05-21 | Hoeganaes Corp. | Powder metallurgy lubricant composition and methods for using same |
US5538684A (en) * | 1994-08-12 | 1996-07-23 | Hoeganaes Corporation | Powder metallurgy lubricant composition and methods for using same |
JP2948322B2 (ja) | 1994-08-12 | 1999-09-13 | ヘガネス・コーポレーシヨン | 粉末冶金滑剤組成物及びその使用法 |
US5549836A (en) * | 1995-06-27 | 1996-08-27 | Moses; David L. | Versatile mineral oil-free aqueous lubricant compositions |
RU2137817C1 (ru) * | 1998-07-20 | 1999-09-20 | Расим Фарман оглы Мустафаев | Смазочно-охлаждающая жидкость для механической обработки металлов |
RU2168539C1 (ru) * | 2000-10-23 | 2001-06-10 | Леонид Петрович Ануфриев | Смазочно-охлаждающая жидкость для механической обработки материалов |
RU2341642C2 (ru) * | 2002-09-13 | 2008-12-20 | Констракшн Рисерч Энд Текнолоджи Гмбх | Способ бурения твердой породы при помощи буровой туннелепроходческой машины |
US20070105727A1 (en) * | 2003-11-26 | 2007-05-10 | Honda Motor Co., Ltd. | Water-base lubricant for plastic forming |
RU2303628C2 (ru) * | 2004-04-05 | 2007-07-27 | ООО "Научно-техническая фирма "ТЕХМА" | Концентрат смазочно-охлаждающей жидкости для механической обработки металлов |
RU2303627C2 (ru) * | 2004-04-05 | 2007-07-27 | ООО "Научно-техническая фирма "ТЕХМА" | Концентрат смазочно-охлаждающей жидкости для механической обработки металлов |
RU2329296C1 (ru) * | 2007-03-07 | 2008-07-20 | ООО Научно-производственное предприятие "Производство наноматериалов" | Технологическая смазка для пластической обработки металлов и сплавов |
US20100048759A1 (en) * | 2008-08-22 | 2010-02-25 | Ecolab Inc. | Method for lubricating surgical instruments |
Also Published As
Publication number | Publication date |
---|---|
GB2016040B (en) | 1982-10-27 |
CA1126718A (en) | 1982-06-29 |
GB2016040A (en) | 1979-09-19 |
FR2416260B1 (enrdf_load_stackoverflow) | 1984-01-20 |
DE2905045A1 (de) | 1979-08-16 |
FR2416260A1 (fr) | 1979-08-31 |
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