US418646A - Philip w - Google Patents
Philip w Download PDFInfo
- Publication number
- US418646A US418646A US418646DA US418646A US 418646 A US418646 A US 418646A US 418646D A US418646D A US 418646DA US 418646 A US418646 A US 418646A
- Authority
- US
- United States
- Prior art keywords
- gas
- chamber
- air
- hydrocarbon
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007789 gas Substances 0.000 description 24
- 239000004215 Carbon black (E152) Substances 0.000 description 16
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 14
- 239000011819 refractory material Substances 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000011449 brick Substances 0.000 description 4
- 239000002737 fuel gas Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- -1 superheated steam Substances 0.000 description 4
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2S)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 235000002912 Salvia officinalis Nutrition 0.000 description 2
- 125000004429 atoms Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 235000002020 sage Nutrition 0.000 description 2
- 239000001296 salvia officinalis l. Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
Definitions
- My invention relates to the production of gas to be used for fuel, which gas may have various heating qualities and is made from liquid hydrocarbon and water in the form of steam.
- Figure 1 is a vertical section of such an apparatus.
- Fig.2 is a horizontal section taken on the line 00 as, Fig. 1.
- A designates the shell or body of the appa ratus, which may be made of metal.
- A designates a lining for the shell A,which lining may be of any desired thickness and made of fire-brick or other suitable refractory material.
- the lower portion of the shell or body comprises a chamber A extending from which is an outlet a, provided with a valve a. Extending also from the pipe a is a stack 0 in which is arranged a valve. or damper a
- a grating B Above the chamber A is ar- -ranged a grating B, which grating, as here shown, comprises a series of bars secured in the refractory material A at their ends. Upon the grating B, I place broken fragments of fire-brick or other suitable refractory material C to any desired depth. Above the.
- broken refractory material C is a chamberD.
- the top of this chamber is of sufficientthickness to prevent loss of heat from the chamber D by radiation. In this chamber combustion takes place. Opening through the top of the chamber is a passage (1, normally closed at its outer end by a cover (1;
- Liquid hydrocarbon in the form of a spray is mixed with steam, preferablysuperheated, and air or oxygen, and the thoroughly-mixed product is delivered into the chamber D.
- This superheated steam is delivered through apipe F, provided with a sage G, which passage is, as here shown,
- hydrocarbon will be delivered tangentially into said chamber and will be given a circular or whirling motion about the same.
- a definite quantity of mixed hydrocarbon, superheated steam, and air or oxygen is delivered into the combustion chamber D.
- the cover d is raised and the gas ignited.
- the cover is closed, andcombustion is then continued in the chamber D.
- the valve a in the outlet-pipe a is closed and the Valve a in the stack a is opened.
- the products of. combustioncarbonic acid and hydrogen h then pass downwardly through the fragments C into the chamber A and are thence carried away through the stack a This is continued until the mass of fragmentary material C is brought to a high state of heat. WVhen this is accomplished, the supply of air or oxygen is shut off; but the supply of steam and hydrocarbon is continued in some what increased quantities.
- valve a is open and the valve a? closed.
- the circular or whirling motion given to the elements about the chamber D causes a thorough decomposition of all the atoms.
- the products of combuspoint where it will cease to be effective, and the operation of reheating is then repeated, as previously described, omitting the opening of the cover (1, which is only necessary when igniting the gas for preliminary heating.
- the process of making fuel-gas consisting in first converting hydrocarbon, steam, and air or oxygen by combustion into carbonic acid and hydrogen, next passing the product over refractory material to heat the latter to a high temperature, then discontinuing the air or oxygen and increasing the quantity of hydrocarbon, next burning this mixture and passing the products of combustion over the incandescent mass to convert them into a permanent gas by contact with the heated material, substantially as specified.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
Description
(N0 Model.)
- P. W. MACKENZIE.
PROCESS OF MAKING GAS.
Pa iented Dec. 31, 1889.
y n/M1903,
UNITED STATES PATENT OFFICE.
PH I LIP W. MACKENZIE, OF NEW YORK, N. Y., ASSIGNOR TO THE FUEL GAS AND LIGHT IMPROVEMENT COMPANY OF AMERICA, OF SAME PLACE.
PROCESS OF MAKING GAS.
I SPECIFICATION forming part of Letters Patent No. 418,646, dated December 31, 1889.
Application filed June 4, 1889. Serial No. 313,079- (No model.)
To all whom it may concern.-
'Be it known that I, PHILIP WV. MACKENZIE, of New York, in the county and State of New York,"have invented a certain new and useful Improvement in Processes of Making Gas, of which the following is a specification.
My invention relates to the production of gas to be used for fuel, which gas may have various heating qualities and is made from liquid hydrocarbon and water in the form of steam.
I will describe in detail a process embodying my improvement, and then point out the novel features in the claim.
The accompanying drawings illustrate apparatus by which my process may be conveniently carried out.
' Figure 1 is a vertical section of such an apparatus. Fig.2 is a horizontal section taken on the line 00 as, Fig. 1.
Similar letters of reference designate correponding parts in both figures.
A designates the shell or body of the appa ratus, which may be made of metal.
A designates a lining for the shell A,which lining may be of any desired thickness and made of fire-brick or other suitable refractory material. The lower portion of the shell or body comprises a chamber A extending from which is an outlet a, provided with a valve a. Extending also from the pipe a is a stack 0 in which is arranged a valve. or damper a Above the chamber A is ar- -ranged a grating B, which grating, as here shown, comprises a series of bars secured in the refractory material A at their ends. Upon the grating B, I place broken fragments of fire-brick or other suitable refractory material C to any desired depth. Above the.
broken refractory material C is a chamberD. The top of this chamber is of sufficientthickness to prevent loss of heat from the chamber D by radiation. In this chamber combustion takes place. Opening through the top of the chamber is a passage (1, normally closed at its outer end by a cover (1;
Liquid hydrocarbon in the form of a spray is mixed with steam, preferablysuperheated, and air or oxygen, and the thoroughly-mixed product is delivered into the chamber D. I
prefer to employ superheated steam to act as an injector. This superheated steam is delivered through apipe F, provided with a sage G, which passage is, as here shown,
curved, so that mixed air or oxygen, steam,
and hydrocarbon will be delivered tangentially into said chamber and will be given a circular or whirling motion about the same.
The operation is as follows: A definite quantity of mixed hydrocarbon, superheated steam, and air or oxygen is delivered into the combustion chamber D. The cover d is raised and the gas ignited. When sufficiently burning, the cover is closed, andcombustion is then continued in the chamber D. The valve a in the outlet-pipe a, is closed and the Valve a in the stack a is opened. The products of. combustioncarbonic acid and hydrogen h then pass downwardly through the fragments C into the chamber A and are thence carried away through the stack a This is continued until the mass of fragmentary material C is brought to a high state of heat. WVhen this is accomplished, the supply of air or oxygen is shut off; but the supply of steam and hydrocarbon is continued in some what increased quantities. The valve a is open and the valve a? closed. The circular or whirling motion given to the elements about the chamber D causes a thorough decomposition of all the atoms. The products of combuspoint where it will cease to be effective, and the operation of reheating is then repeated, as previously described, omitting the opening of the cover (1, which is only necessary when igniting the gas for preliminary heating.
If richer gas is required, or when it might be used for illuminating purposes, a greater quantity of hydrocarbon is used, and when a continuous flow of gas is required two or more apparatuses havinga common deliverypipe may be used, which may be alternately heated.
Although I prefer to shut off the air or oxygen during the making of the permanent gas, I may employ it, and when air is used the nitrogen Will be neutralized by the addition of a very limited quantity of carbon. By the use of separate superheating devices the different elements might be raised to a temperature such that a very limited quantity of air would be required for the maintenance of the heat, and consequently very little nitrogen would be produced.
Ihave filed an application for United States Letters Patent, Serial No. 313,078, June 14, 1889, for an improvement in gas apparatus adapted to carry out the process herein described and claimed. I do not herein lay claim to anything claimed therein.
W hat I claim as my invention, and desire to secure by Letters Patent, is-
The process of making fuel-gas, consisting in first converting hydrocarbon, steam, and air or oxygen by combustion into carbonic acid and hydrogen, next passing the product over refractory material to heat the latter to a high temperature, then discontinuing the air or oxygen and increasing the quantity of hydrocarbon, next burning this mixture and passing the products of combustion over the incandescent mass to convert them into a permanent gas by contact with the heated material, substantially as specified.
PHILIP V. MACKENZIE.
\Vitnesses:
ALBT. VAN DYKE, GEORGE A. BAKER.
Publications (1)
Publication Number | Publication Date |
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US418646A true US418646A (en) | 1889-12-31 |
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US418646D Expired - Lifetime US418646A (en) | Philip w |
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- US US418646D patent/US418646A/en not_active Expired - Lifetime
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