US4186095A - Oil collecting apparatus - Google Patents

Oil collecting apparatus Download PDF

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Publication number
US4186095A
US4186095A US05/898,079 US89807978A US4186095A US 4186095 A US4186095 A US 4186095A US 89807978 A US89807978 A US 89807978A US 4186095 A US4186095 A US 4186095A
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rotor
liquid
inlet
sidewall
stator
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Expired - Lifetime
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US05/898,079
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Gosta Walin
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    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B15/00Cleaning or keeping clear the surface of open water; Apparatus therefor
    • E02B15/04Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
    • E02B15/10Devices for removing the material from the surface
    • E02B15/107Whirling means forming a vortex in the water; cyclones
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/204Keeping clear the surface of open water from oil spills
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00Liquid purification or separation
    • Y10S210/918Miscellaneous specific techniques
    • Y10S210/922Oil spill cleanup, e.g. bacterial
    • Y10S210/923Oil spill cleanup, e.g. bacterial using mechanical means, e.g. skimmers, pump

Definitions

  • the present invention relates to apparatus for collecting pollution, especially oil, from a surface contaminated liquid.
  • An apparatus includes a submerged, roto-symmetrically shaped vortex chamber with inlet and outlet for the liquid, means for bringing liquid within the vortex chamber into a horizontally rotating vortex movement, and a pollution outlet tube arranged above the vortex chamber.
  • the efficiency is considerably improved in that a rotationally symmetrical stator is arranged at the level of the liquid surface, the stator having a collecting cavity which opens downwards in a central part of the stator, said pollution outlet tube being connected to the collecting cavity.
  • the stator has a lower end surface which slopes downwards and inwards through the liquid surface to the opening of the collecting cavity, the stator being arranged in a concentric manner with respect to the vortex chamber.
  • the vortex chamber may comprise the interior of a hollow rotor having an upper threshold inlet.
  • the invention also includes a method of separating oil from water.
  • FIG. 1 is a side view, partly in section, of an embodiment of the invention
  • FIG. 2 is a top view of the arrangement of FIG. 1 cooperating with floating oil barriers;
  • FIG. 3 is a schematical side view, in section, with reference to which the operative function of the stator is explained below.
  • FIG. 1 there is shown an apparatus for collecting oil from oil discharges at sea.
  • the apparatus includes a rotationally symmetrical stator 1 and a rotor 2.
  • the stator 1 is rigidly connected to a framework 3 which includes float bodies 4 being arranged in such a manner that the apparatus floats steadily in a correct floating position.
  • the rotor 2 is mounted on a shaft 5, which is driven by a motor 7 through a gear box 6.
  • the motor 7 and the gear box 6 are rigidly connected to the framework 3 through a shield 8.
  • a collecting cavity 9 which is open downwards and has an outlet tube 10 in its upper part.
  • the lower end surface 11 of the stator 1 slopes downwards and inwards through the water surface and partly into the interior of rotor 2 to the opening of the collecting cavity 9.
  • the rotor 2 confines a vortex chamber 12 and is open upwards. It has a cylindrical side wall 13 terminating somewhat below the water surface level CWL. Thus, the surface layer including the oil floating on the water is free to enter the vortex chamber 12 through the threshold inlet formed by the upper edge of cylindrical side wall 13.
  • a plurality of outlet openings 14 In a lower part of the cylindrical side wall 13 and around its periphery there are provided a plurality of outlet openings 14.
  • annular plates 15 and 16 are arranged around the periphery of the side wall 16. Between the plates 15 and 16 an inner plate 16a and a plurality of radial vanes 16b are provided whereby multi-chambered inner an inner radial pump is formed having inlets 17 and an outlets 18.
  • An outer multichambered radial pump radial turbine 19 with inlet 20 and outlet 21 is formed on the outside of the cylindrical side wall around its periphery. Outside the outlet 21 guide vanes 22 are mounted on the framework 3.
  • the operation of the apparatus is described below with reference also to the schematical view in FIG. 3 for explaining the operative function of the stator 1. It is presumed that the apparatus is operating in a water area which has been polluted by oil, which is prevented from spreading by means of floating oil barriers 23 (FIG. 2). The apparatus is floating is such a manner that the water surface level CWL is above the upper edge of the cylindrical side wall 13 permitting the surface layer to enter the vortex chamber 12.
  • the motor 7 brings the rotor 2 to rotate.
  • a vortex is established in the vortex chamber 12, i.e. liquid in the chamber is rotating around the shaft 5. It is essential that the liquid rotates properly in the volume below the lower end surface 11 of the stator 1.
  • rotation is not important.
  • boundary layer phenomenon due to the fact that the particles in this layer are retarded by friction against the stator 1, whereby their rotational velocity is reduced.
  • the horizontal pressure gradient force acting towards the centre of rotation is thus larger than the centrifugal force acting in the opposite direction. Due to this excess pressure force these particles move inwards along the lower end surface 11 of the stator in towards the collecting cavity 9.
  • boundary layer flux is well known in the art of hydrodynamics.
  • the purpose of the outer radial pump 19 is to provide a flow of water in towards the apparatus in a water layer adjacent to and below the polluted surface layer.
  • This water flow is comparatively strong and interacts with the polluted surface layer in such a manner that oil flows with increased velocity in towards the apparatus from a comparatively large area around the apparatus.
  • the inlet 20 of the pump 19 is situated on such a level below the water surface that oil from the surface layer will not be sucked into the pump.
  • the flow of water from the turbine outlet 21 is directed radially outwards and downwards below the float bodies 4 by means of the guide vanes 22.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Removal Of Floating Material (AREA)
  • Cleaning Or Clearing Of The Surface Of Open Water (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

An apparatus for collecting pollution, especially oil, from a surface contaminated liquid. The apparatus is adapted to float on the surface of the liquid. A surface layer of liquid with pollutant is drawn into a rotating hollow rotor by virtue of a liquid vortex established therein. The incoming liquid contacts the overlying surface of a concentrically arranged stator. This contact reduces the rotational velocity of the boundary layer of liquid containing the pollutant. The resultant force urges the pollutant toward the center of the vortex, whence it is drawn off through a collecting cavity located centrally of the stator.

Description

The present invention relates to apparatus for collecting pollution, especially oil, from a surface contaminated liquid.
There is an increasing demand for means capable of removing pollution from surface contaminated liquids. Particularly, oil discharges into seas, rivers and lakes are serious environmental problems. To prevent such oil from spreading over a vast area of the water surface it may be encircled by floating barriers defining an area in which there commonly is a relatively thin layer of oil floating on the water surface. It is difficult to remove this thin oil layer without simultaneously removing a considerable amount of water.
In the Swiss patent specification 510 792 there is suggested an arrangement in which a vortex is formed in surface contaminated water. Oil flows into the cavity formed in the centre of the vortex, where there is accumulated a volume of oil which is sufficiently large to be removed without simultaneously removing any substantial amount of water. However, this arrangement has certain drawbacks. Thus, for example, the shape and position of the accumulated oil volume varies with the heave of the sea, whereby the removing of oil is less efficient.
An apparatus according to the invention includes a submerged, roto-symmetrically shaped vortex chamber with inlet and outlet for the liquid, means for bringing liquid within the vortex chamber into a horizontally rotating vortex movement, and a pollution outlet tube arranged above the vortex chamber. According to the invention the efficiency is considerably improved in that a rotationally symmetrical stator is arranged at the level of the liquid surface, the stator having a collecting cavity which opens downwards in a central part of the stator, said pollution outlet tube being connected to the collecting cavity. The stator has a lower end surface which slopes downwards and inwards through the liquid surface to the opening of the collecting cavity, the stator being arranged in a concentric manner with respect to the vortex chamber. The vortex chamber may comprise the interior of a hollow rotor having an upper threshold inlet. The invention also includes a method of separating oil from water.
The invention is further described below with references to the drawings, in which:
FIG. 1 is a side view, partly in section, of an embodiment of the invention;
FIG. 2 is a top view of the arrangement of FIG. 1 cooperating with floating oil barriers; and
FIG. 3 is a schematical side view, in section, with reference to which the operative function of the stator is explained below.
In FIG. 1 there is shown an apparatus for collecting oil from oil discharges at sea. The apparatus includes a rotationally symmetrical stator 1 and a rotor 2. The stator 1 is rigidly connected to a framework 3 which includes float bodies 4 being arranged in such a manner that the apparatus floats steadily in a correct floating position. The rotor 2 is mounted on a shaft 5, which is driven by a motor 7 through a gear box 6. The motor 7 and the gear box 6 are rigidly connected to the framework 3 through a shield 8.
In the central part of the stator 1 there is provided a collecting cavity 9, which is open downwards and has an outlet tube 10 in its upper part. The lower end surface 11 of the stator 1 slopes downwards and inwards through the water surface and partly into the interior of rotor 2 to the opening of the collecting cavity 9.
The rotor 2 confines a vortex chamber 12 and is open upwards. It has a cylindrical side wall 13 terminating somewhat below the water surface level CWL. Thus, the surface layer including the oil floating on the water is free to enter the vortex chamber 12 through the threshold inlet formed by the upper edge of cylindrical side wall 13. In a lower part of the cylindrical side wall 13 and around its periphery there are provided a plurality of outlet openings 14. Above the outlet openings 14 annular plates 15 and 16 are arranged around the periphery of the side wall 16. Between the plates 15 and 16 an inner plate 16a and a plurality of radial vanes 16b are provided whereby multi-chambered inner an inner radial pump is formed having inlets 17 and an outlets 18. An outer multichambered radial pump radial turbine 19 with inlet 20 and outlet 21 is formed on the outside of the cylindrical side wall around its periphery. Outside the outlet 21 guide vanes 22 are mounted on the framework 3.
The operation of the apparatus is described below with reference also to the schematical view in FIG. 3 for explaining the operative function of the stator 1. It is presumed that the apparatus is operating in a water area which has been polluted by oil, which is prevented from spreading by means of floating oil barriers 23 (FIG. 2). The apparatus is floating is such a manner that the water surface level CWL is above the upper edge of the cylindrical side wall 13 permitting the surface layer to enter the vortex chamber 12.
The motor 7 brings the rotor 2 to rotate. Thus, a vortex is established in the vortex chamber 12, i.e. liquid in the chamber is rotating around the shaft 5. It is essential that the liquid rotates properly in the volume below the lower end surface 11 of the stator 1. In a cylindrical liquid volume below the collecting chamber 9 rotation is not important. In the layer immediately adjacent to the lower end surface 11 of the stator 1 there occurs a so-called boundary layer phenomenon due to the fact that the particles in this layer are retarded by friction against the stator 1, whereby their rotational velocity is reduced. For particles in the boundary layer the horizontal pressure gradient force acting towards the centre of rotation is thus larger than the centrifugal force acting in the opposite direction. Due to this excess pressure force these particles move inwards along the lower end surface 11 of the stator in towards the collecting cavity 9. Such boundary layer flux is well known in the art of hydrodynamics.
As oil is floating on the water surface, oil will be present in the boundary layer adjacent to the stator 1. Thus, oil is transported within this boundary layer into the collecting chamber 9, wherefrom it is pumped away through the outlet tube 10 by a pump (not shown) to suitable subsequent treatment. The water floating out through the pump outlet 18 has a rotary movement around the shaft 5. The object of that water flow is to support the rotation motion of the liquid in the vortex chamber 12. Excess water leaves the vortex chamber through the outlet openings 14.
The purpose of the outer radial pump 19 is to provide a flow of water in towards the apparatus in a water layer adjacent to and below the polluted surface layer. This water flow is comparatively strong and interacts with the polluted surface layer in such a manner that oil flows with increased velocity in towards the apparatus from a comparatively large area around the apparatus. Thus, the inlet 20 of the pump 19 is situated on such a level below the water surface that oil from the surface layer will not be sucked into the pump. The flow of water from the turbine outlet 21 is directed radially outwards and downwards below the float bodies 4 by means of the guide vanes 22.

Claims (7)

What I claim is:
1. Apparatus for separating and collecting floating pollution from a surface-contaminated liquid comprising:
a buoyant framework including a plurality of floats;
a hollow rotor having a generally upstanding sidewall, an open upper end defining an inlet to the interior of said rotor, outlets in a lower portion of said sidewall, and a closed bottom supporting said rotor in said framework for rotation about a substantially vertical axis with said inlet submerged in the liquid near the surface thereof;
drive means carried by said framework for rotating said rotor to establish a vortex of liquid in said rotor interior to draw contaminated liquid thereinto through said inlet and to expel liquid therefrom through said outlets;
a stator carried by said framework directly above said rotor, said stator being substantially symmetrical about said vertical axis and having a central pollution-collecting cavity which opens downwardly with the opening of said cavity located below said rotor inlet and within said rotor interior so as to be submerged in the liquid, and a lower pollution-contacting and diverting surface which slopes downwardly and inwardly from above said rotor inlet at the periphery of said stator, through said rotor inlet and through the surface of the liquid into said rotor interior, to the submerged opening of said cavity to slow the movement of the floating pollution and divert it toward said collecting chamber; and
vaned inner pump means in said rotor interior for recirculating a portion of the liquid near the bottom of said rotor back toward the top of said rotor to support the liquid vortex, said inner pump means comprising a plurality of annularly arranged pumping chambers defined by spaced annular upper and lower plates attached to said sidewall above said outlets, an inner plate joined to the inner edges of said upper and lower plates, and a plurality of upstanding annularly spaced radial vanes dividing the annular space between said sidewall and said plates into chambers having an outlet in said upper plate adjacent to said sidewall and an inlet in said lower plate adjacent to said inner plate.
2. An apparatus according to claim 1 further comprising vaned outer pump means attached to the exterior of said rotor sidewall for drawing liquid toward the apparatus to augment to flow of pollution into said rotor inlet.
3. An apparatus according to claim 2 wherein said outer pump means comprises a plurality of annularly arranged pumping chambers having an axially directed inlet located below said rotor inlet and an outwardly directed outlet located below said axially directed inlet.
4. An apparatus according to claim 3 further comprising a plurality of spaced stationary guide vanes carried by said support means and surrounding said rotor in alignment with said outwardly directed outlet to guide the flow of liquid emerging from said outer pump means.
5. An apparatus according to claim 4 wherein said drive means comprises a motor mounted above said stator, and a drive shaft extending from said motor through said stator and the interior of said rotor into engagement with the bottom of said rotor.
6. Apparatus for separating and collecting floating pollution from a surface-contaminated liquid comprising:
a hollow rotor having a sidewall, an open upper end defining an inlet to the interior of said rotor, lower outlet means, vaned inner pump means in said rotor interior attached to said sidewall for recirculating a portion of the liquid near the bottom of said rotor back toward the top of said rotor to support the liquid vortex, said inner pump means comprising a plurality of annularly arranged pumping chambers defined by spaced annular upper and lower plates attached to said sidewall, an annular inner plate joined to the inner edges of said upper and lower plates, and a plurality of upstanding annularly spaced radial vanes dividing the annular space between said sidewall and said plates into chambers having an outlet in said upper plate adjacent to said sidewall and an inlet in said lower plate adjacent to said inner plate;
support means for supporting said rotor for rotation about a substantially vertical axis with said inlet submerged in the liquid near the surface thereof;
drive means carried by said support means for rotating said rotor to establish a vortex of liquid in said rotor interior to draw contaminated liquid thereinto through said inlet and to expel liquid therefrom through said outlet means; and
a stator carried by said support means directly above said rotor, said stator being substantially symmetrical about said vertical axis and having a central pollution-collecting cavity which opens downwardly with the opening of said cavity located below said rotor inlet and within said rotor interior so as to be submerged in the liquid, and a lower pollution-contacting and diverting surface which slopes downwardly and inwardly from above said rotor inlet at the periphery of said stator, through said rotor inlet and through the surface of the liquid into said rotor interior, to the submerged opening of said cavity to slow the movement of the floating pollution and divert it toward said collecting chamber.
US05/898,079 1977-04-27 1978-04-20 Oil collecting apparatus Expired - Lifetime US4186095A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE7704814A SE416220B (en) 1977-04-27 1977-04-27 oil recovery PUMP
SE7704814 1977-04-27

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US06/116,647 Division US4295975A (en) 1977-04-27 1980-01-29 Oil collecting method
US06/116,648 Division US4332519A (en) 1977-04-27 1980-01-29 Oil collecting apparatus

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US06/116,648 Expired - Lifetime US4332519A (en) 1977-04-27 1980-01-29 Oil collecting apparatus
US06/116,647 Expired - Lifetime US4295975A (en) 1977-04-27 1980-01-29 Oil collecting method

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US06/116,647 Expired - Lifetime US4295975A (en) 1977-04-27 1980-01-29 Oil collecting method

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JP (1) JPS6038993B2 (en)
AU (2) AU3544878A (en)
BR (1) BR7802585A (en)
CA (1) CA1114306A (en)
DE (1) DE2818609A1 (en)
DK (1) DK146616C (en)
ES (1) ES469245A1 (en)
FI (1) FI62162C (en)
FR (1) FR2388948A1 (en)
GB (1) GB1602343A (en)
IT (1) IT7867944A0 (en)
NL (1) NL7804282A (en)
NO (1) NO147959C (en)
PT (1) PT67928B (en)
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Cited By (7)

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Publication number Priority date Publication date Assignee Title
US4295975A (en) * 1977-04-27 1981-10-20 Walin Goesta Oil collecting method
US4610788A (en) * 1985-05-06 1986-09-09 Ward Jay A Oil/water separating system
US5292433A (en) * 1992-08-04 1994-03-08 Fletcher Gerald L Method and apparatus for recovering oil spill
US5527461A (en) * 1994-06-02 1996-06-18 Hill; Gordon A. Airlift oil scavenger
WO2000062887A1 (en) * 1999-04-21 2000-10-26 Koblizek Jan Equipment for liquid separation
CN112878290A (en) * 2020-01-07 2021-06-01 马俊 Small trough body and water surface garbage cleaning device with small trough body
CN112878289A (en) * 2020-01-07 2021-06-01 马俊 Gate stay wire and direction controller with same for water surface garbage cleaning device

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SE418629B (en) * 1979-09-11 1981-06-15 Sanera Projekting Ab DEVICE FOR THE COLLECTION OF OIL OR SIMILAR FLOWING A WATER SHOOT LIKE THE WATER
FR2540904A1 (en) * 1983-02-11 1984-08-17 Elf France Method for the selective pumping of hydrocarbons contained in water, and apparatus for the implementation of this method
US4527633A (en) * 1983-07-13 1985-07-09 Pump Engineer Associates, Inc. Methods and apparatus for recovery of hydrocarbons from underground water tables
US4625801A (en) * 1983-07-13 1986-12-02 Pump Engineer Associates, Inc. Methods and apparatus for recovery of hydrocarbons from underground water tables
US4546830A (en) * 1983-07-13 1985-10-15 Pump Engineer Associates, Inc. Methods and apparatus for recovery of hydrocarbons from underground water tables
US4549810A (en) * 1984-12-20 1985-10-29 Usm Corporation Phase separating rotary processor and method
US4826406A (en) * 1987-10-08 1989-05-02 S&Me, Incorporated Pressure extraction pump system for recovering liquid hydrocarbons from ground water
US4844797A (en) * 1988-03-22 1989-07-04 S&Me, Incorporated Vacuum extraction system
JP2529889B2 (en) * 1989-12-22 1996-09-04 光弘 関野 Floating liquid separation and collection device
US5135666A (en) * 1991-05-23 1992-08-04 Lucas James E Marine oil spill clean-up method using a motion compensator means
JP2598864B2 (en) * 1993-01-14 1997-04-09 株式会社ワールドケミカル Liquid recovery device
AU669774B2 (en) * 1993-01-26 1996-06-20 Walter Pollution Control System B.V. Oil sucking-off station
US5554279A (en) * 1994-09-26 1996-09-10 Rdp Company Apparatus for treatment of sewage sludge

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US3810546A (en) * 1971-09-15 1974-05-14 Shell Oil Co Apparatus for controlling a polluting liquid
US3831756A (en) * 1970-06-29 1974-08-27 Trw Inc Surface tension method of and apparatus for separating immiscible liquids
US3853767A (en) * 1971-04-23 1974-12-10 Patents & Dev As Pumping apparatus for skimming and recovering an oil layer from a body of water
US3880758A (en) * 1973-04-18 1975-04-29 Frank Galicia Oil collection device
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US2422464A (en) * 1942-09-01 1947-06-17 Bartholomew Tracy Method and apparatus for separating liquid from solids by rotatably mounted means
US3800951A (en) * 1968-12-23 1974-04-02 Bertin & Cie Apparatus for removing a substance floating as a layer on the surface of a body of liquid
US3615017A (en) * 1969-12-15 1971-10-26 Joe M Valdespino Oil entrapment and containment watercraft
US3664505A (en) * 1970-02-18 1972-05-23 Charles J Brittingham Oil collection device
US3715034A (en) * 1970-05-06 1973-02-06 A Ivanoff Device for removing oil slicks
US3753492A (en) * 1970-06-19 1973-08-21 V Aiello Separating apparatus
US3831756A (en) * 1970-06-29 1974-08-27 Trw Inc Surface tension method of and apparatus for separating immiscible liquids
US3656619A (en) * 1970-08-03 1972-04-18 Donald J Ryan Apparatus and method for removing floating pollutants from a body of water
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US3810546A (en) * 1971-09-15 1974-05-14 Shell Oil Co Apparatus for controlling a polluting liquid
US3753496A (en) * 1971-12-20 1973-08-21 E Boyd Converging vortex apparatus for separating oil from water
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US3890234A (en) * 1973-04-18 1975-06-17 Frank Galicia Oil separation and recovery device

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4295975A (en) * 1977-04-27 1981-10-20 Walin Goesta Oil collecting method
US4610788A (en) * 1985-05-06 1986-09-09 Ward Jay A Oil/water separating system
US5292433A (en) * 1992-08-04 1994-03-08 Fletcher Gerald L Method and apparatus for recovering oil spill
US5527461A (en) * 1994-06-02 1996-06-18 Hill; Gordon A. Airlift oil scavenger
WO2000062887A1 (en) * 1999-04-21 2000-10-26 Koblizek Jan Equipment for liquid separation
CN112878290A (en) * 2020-01-07 2021-06-01 马俊 Small trough body and water surface garbage cleaning device with small trough body
CN112878289A (en) * 2020-01-07 2021-06-01 马俊 Gate stay wire and direction controller with same for water surface garbage cleaning device
CN112878291A (en) * 2020-01-07 2021-06-01 马俊 Floating body and water surface garbage cleaning device with same

Also Published As

Publication number Publication date
ZA782319B (en) 1979-04-25
FI62162C (en) 1982-11-10
DE2818609A1 (en) 1978-11-02
FI62162B (en) 1982-07-30
PT67928A (en) 1978-05-01
AU559025B2 (en) 1987-02-19
DK146616B (en) 1983-11-21
US4295975A (en) 1981-10-20
PT67928B (en) 1979-10-15
NL7804282A (en) 1978-10-31
NO147959C (en) 1983-07-20
SE7704814L (en) 1978-10-28
AU8894482A (en) 1983-01-13
AU3544878A (en) 1979-11-01
JPS6038993B2 (en) 1985-09-04
FI781205A (en) 1978-10-28
FR2388948A1 (en) 1978-11-24
JPS5416842A (en) 1979-02-07
NO781452L (en) 1978-10-30
NO147959B (en) 1983-04-05
DK181678A (en) 1978-10-28
DE2818609C2 (en) 1989-02-23
SU709003A3 (en) 1980-01-05
IT7867944A0 (en) 1978-04-26
US4332519A (en) 1982-06-01
BR7802585A (en) 1978-11-14
CA1114306A (en) 1981-12-15
GB1602343A (en) 1981-11-11
ES469245A1 (en) 1979-01-16
SE416220B (en) 1980-12-08
FR2388948B1 (en) 1983-05-13
DK146616C (en) 1984-04-30

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