US3921698A - Method for the production of metallic ingots - Google Patents

Method for the production of metallic ingots Download PDF

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Publication number
US3921698A
US3921698A US285315A US28531572A US3921698A US 3921698 A US3921698 A US 3921698A US 285315 A US285315 A US 285315A US 28531572 A US28531572 A US 28531572A US 3921698 A US3921698 A US 3921698A
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US
United States
Prior art keywords
ingot
mold
liquid
cooled
rod
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US285315A
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English (en)
Inventor
Helmut Theodor Grof
Heinrich Fritz Sonntag
Helmut Scheidig
Anton Wamser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leybold Heraeus Verwaltung GmbH
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Leybold Heraeus Verwaltung GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19712143445 external-priority patent/DE2143445C3/de
Application filed by Leybold Heraeus Verwaltung GmbH filed Critical Leybold Heraeus Verwaltung GmbH
Application granted granted Critical
Publication of US3921698A publication Critical patent/US3921698A/en
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16—Remelting metals
    • C22B9/18—Electroslag remelting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B4/00—Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys

Definitions

  • the present invention relates to a method and means for the formation or production of metallic blocks or ingots from sources of materials that are either in the liquid or solid state.
  • crystallization extends upwards from the bottom of a liquid-cooled chill mold or crucible equipped with a removable bottom.
  • Such methods are used when the metallic ingots have any desired cross-section and length which exceeds the length of the casting mold.
  • the ingot is moved with substantially uniform velocity out of the chill mold from the bottom, after the-upper surface of the ingot is substantially solidified.
  • the same object may be achieved by lifting the mold in the upward direction.
  • the freshlyformed surface of the ingot is still at substantially high temperature, and when exposed to the surrounding atmosphere or environment, an extensive amount of heat loss takes place due to radiation and convection.
  • the heat transfer or heat flow does not only take place from the cylindrical or rectangular surface of the ingot. Instead, the heat transfer also takes place over a considerable portion of the fluid-cooled bottom of the chill mold, upon which the ingot is supported as a result of its own weight.
  • the rate of heat flow or heat transfer depends upon the temperature difference and thereby upon the prevailing ingot length and space between the still liquid upper surface of the ingot and the bottom of the ingot.
  • the heat transfer from the bottom of the ingot does not occur uniformly during the formation of the ingot. Instead, a considerably larger portion of heat is conducted away through the bottom ofthe ingot during the initial period of ingot formation. Less heat is conducted in this manner, when the ingot is in the process of being completed.
  • the temperature gradient is, thereby, very steep at the beginning of the process, and becomes substantially flat near the end of the melting process.
  • the situation is such that the ingot material itself serves as a thermal insulator between the liquid melt and the bottom of the chill mold.
  • a varying heat transfer is, however, undesirable. particularly when ingots are to be formed with relatively limited lengths.
  • Such ingots are produced with substantially slow solidification rate.
  • Such a case is. for example, incurred when melting blocks or ingots through the use of the electroslag melting or remelting process.
  • the formation or production of ingots requires, thereby, a considerable amount of time.
  • substantially 200 melting hours are required.
  • the upper portion of the ingot is held at the melting temperature, the lower portion of the ingot becomes cooled.
  • ingots of such sizes are needed for the production of turbine rotors which are made of a specific alloy steel as, for example, 28 NiCrMo 74 (material number 1.6589).
  • a critical cooling rate prevails below a predetermined temperature limit which is not to be passed through. Otherwise, cracks or tears take place in the ingot which lead to the discarding of the ingot.
  • the initial phase of an electroslag remelting process requires a water cooled bottom for reasons that are well known in the art.
  • This water cooled bottom must connect with the cylindrical or rectangular wall of the chill mold. From the viewpoint of the water cooling requirement and material characteristics, this bottom of the chill mold is in the form of a hollow copper plate. After a series of melting hours when sufficient space exists between the liquid melt and the bottom edge of the ingot, it is possible to drop below the critical temperature limit in the region of the mold bottom, whereby the feared cracks or tears in the ingot may appear.
  • Another object of the present invention is to provide an arrangement for the production ofingots of the fore going character, which is simple in design and construction.
  • a further object of the present invention is to provide an arrangement, as set forth, which may be economically fabricated and readily maintained.
  • the objects of the present invention are achieved by providing that the heat flow or heat transfer from the ingot to the bottom or base of the chill mold is decreased or reduced in a stepwise manner after the bottom portion of the ingot has become solidified.
  • This aim of the present invention can be carried out in various ways.
  • the bottom of the mold can be dropped from the lower side of the ingot at least for a period of time, whereby a rod-shaped member provides for maintaining the current and provides for mechanical support.
  • This rod-shaped member becomes integral with the lower side ofthe ingot at the beginning of the remelting process.
  • the cooled bottom of the mold can be removed or lowered from the bottom side of the ingot for a substantially short period of time. After introducing an insulating intermediate layer in the form of, for example.
  • the bottom can be again laid against the undersurface of the ingot.
  • it is possible to avoid particular means for supporting the ingot since the ingot is held for a short period of time by the chill mold as a result of unavoidable frictional effects.
  • the temporary interruption of current for several seconds. can be considered to have negligible effects.
  • a gas-heated ring burner is particularly well adapted for this purpose. This burner surrounds substantially the ingot in the vicinity of the bottom of the mold.
  • the heat flow or heat transfer from the ingot to the bottom of the chill mold is reduced immediately upon dropping or lowering of the cooled chill mold bottom.
  • the heat transfer from the liquid melt zone of the ingot to the bottom zone is such, that the lower portion of the ingot retains for a substantially very long time, a temperature which is above the critical limit temperature. This is due to the conductivity of the metal.
  • a rod-shaped member which is made integral with the ingot in the initial phase. an unallowable high temperature gradient occurs only at this rod-shaped member. This is, however, unobjectionable since the rod- 3 shapctl member has a substantially smaller cross-section than the ingot. so that the heat flow becomes thereby restricted.
  • the rod-shaped mem her is not a part of the ingot. this member is usually sev ered from the ingot after the latter has been completed.
  • the arrangement for carrying out the method in accordance with the present invention has, moreover. a driven platform on which is mounted the bottom of the chill mold for taking into account the downward mo tion of the ingot. Means are also provided for varying the space a. between the platform and the bottom of the chill mold.
  • the present in vention provides that the bottom of the chill mold has at least one opening for admitting a rod-shaped member to become integral with the ingot.
  • This rod-shaped member is. for example. inserted at the beginning of the remelting process. and abuts against the platform on one end. This member projects with the other end through the bottom of the chill mold and into the interior space of the mold. Besides serving as a pure me chanical support. this rod-shaped member also serves to apply the melting current to the ingot.
  • the present invention provides for a further arrangement which may be introduced into the space between the wall ofthe chill mold and the bottom of the mold.
  • This auxiliary arrangement provides for external heating of the ingot from the lower edge or surface. The reduced heat flow between the lower end of the ingot and the lowered bottom of the chill mold. prevents thereby also that the additional heating be transmitted directly again through the bottom of the chill mold.
  • the bottom of the chill mold is again raised. and assumes again the support of the ingot. In this manner. the mold can be raised over the upper edge or end of the ingot for the purpose of removing the completed ingot. In this case, a thermal insulating intermediate layer is also desirable.
  • FIG. I is an elevational sectional view of an electroslag remelting arrangement. shortly after the formation of a solid portion at the bottom of the ingot. in accor dance with the present invention
  • FIG. 2 is an elevational view of the arrangement of FIG. I after melting has taken place over a substantially longer period of time and the bottom of the chill mold has been lowered, in accordance with the present in vention.
  • an electrode 1 to be melted is made of an alloy adapted to turbine rotors.
  • the electrode l is secured to an elec trode holding arrangement through a rod 2 and a feeder 3.
  • the feeder 3 is movable longitudinally along a vertical column 4. Vertical motion of the feeder 3 is accomplished through a threaded rod 5 which engages a threaded nut 6 within the feeder 3.
  • the column 4 serves as a support for this feeder 3.
  • the upper end of the threaded rod 5 is retained by a bearing 7 which is secured to the guide column 4 by means ofa transverse member 8.
  • the lower bearing 9 of the threaded rod is on a speed reducer unit 10 which reduces the speed of a driving motor 1] to the desired speed of the spindle.
  • Parts 2ll represent the transport or moving arrange ment for the electrode.
  • At least a part of the length of the electrode 1 to be melted. is within a chill mold [2.
  • the latter has a mold wall 13 in the form of a cylindrical hollow wall provided with connections 14 for the entrance and exit of cooling fluid 15.
  • a liquid slag layer 16 is present within the chill mold 12.
  • the electrode 1 dips into this slag layer 16, to a small extent.
  • the electrode melts in a drop wise manner through the slag layer I6, and collects in a liquid puddle l7 beneath the layer 16.
  • the puddle 17 becomes part of the ingot 18, after solidification resulting from heat removal.
  • a mold bottom 19 is provided for closing the lower end of the mold wall.
  • This bottom or base 19 is liquid cooled.
  • the bottom or base 19, furthermore. is carried on a platform 22 made movable through a hydraulic cylinder 20 and piston rod 21.
  • the expression plat form" here is to be considered as not limited only to a planar construction. Instead this expression is also applicable to any reference plane type of arrangement which provides for relative motion with respect to the wall 13 of the mold.
  • the bottom 19 of the chill mold is at the distance a from the platform 22.
  • the platform has a series of threaded nuts 23 which cooperate with threaded rods 24. These threaded rods or spindles 24 are driven through a drive 25 which is connected to a shaft 26 passing through the device 25. The shaft 26 is. in turn. driven or set into motion through a driving motor 27. The parts 23 to 27 form the drive for the platform 22.
  • the bottom 19 of the chill mold is provided with a circular-shaped opening at its center which coincides with the axis of the electrode 1 and wall 13 ofthe mold.
  • a cylindrical rod-shaped member 28 is present within this opening. after being inserted at the start of the pro cess. The lower end of the rod 28 abuts against the platform 22.
  • an internal melting of the upper side of the rod 28 takes place with the lower side of the block or ingot 18 within the portion outlined by the broken line 29.
  • the ingot l8 and rod 28 become integral.
  • the application of the melting current results. on the one hand. through a line 30 to the platform 22.
  • FIG. 2 shows an arrangement after the elapse of a considerable amount oftime.
  • FIG. 2 corresponds to an instant of time at which a larger portion of the ingot has already been formed.
  • Elements which are the same in both FIGS. 1 and 2 are denoted by the same reference numerals.
  • a lowering of the mold bottom 19 has taken place relative to the platform, so that now the distance a prevails between the platform and the bottom 19.
  • a ringshaped air gap 33 is present between the lower end of the ingot l8 and the mold bottom 19. This air gap serves to improve the thermal insulation between the ingot and the mold bottom. Further dropping or lowering of the platform 22 results now with equal distance between the bottom 19 and platform 22.
  • the ingot l8 abuts the platform 22 through the rod 28 which also retains the application of the melting current.
  • a heat source 34 in the form of a ring gas burner for the purpose of heating the ingot.
  • This heat source is advantageously in the form of two parts, so that it can be placed in the position shown.
  • This heat source can be lowered together with the platform 22, and to introduce additional heat sources in the continuously increasing space between the wall 13 and the bottom 19.
  • the position of the heat source or sources can also be made variable within this space.
  • the application of the present invention is not to be limited to electroslag remelting processes.
  • the present invention is equally applicable in an advantageous 6 manner to electric arc furnaces. particularly the vacuum electric arc type of furnace.
  • a method for producing a metallic ingot comprising the steps of: passing melted material into a liquidcooled chill mold. said mold having a liquid-cooled bottom movable from the walls of said mold; solidifying said material through crystallization directed upward from the bottom to produce an ingot; and separating the bottom of said mold from the bottom of said ingot over at least a period of time. so that heat flow from said ingot is substantially reduced after solidification of a lower portion of said ingot.
  • a method for producing a metallic ingot comprising the steps of: passing melted material into a liquidcooled chill mold. said mold having a liquid-cooled bottom movable from the walls of said mold; solidifying said material through crystallization directed upward from the bottom to produce an ingot; positioning said liquid-cooled bottom of said mold relative to said walls so that heat flow from said ingot is substantially reduced after solidification of a lower portion of said in got; and separating the bottom of said mold from the bottom of said ingot over at least a period of time.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Furnace Details (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
US285315A 1971-08-31 1972-08-31 Method for the production of metallic ingots Expired - Lifetime US3921698A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712143445 DE2143445C3 (de) 1971-08-31 Verfahren und Vorrichtung zum Herstellen von metallischen Blöcken

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US3921698A true US3921698A (en) 1975-11-25

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US (1) US3921698A (ja)
JP (1) JPS518853B2 (ja)
FR (1) FR2151066B1 (ja)
IT (1) IT964021B (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978907A (en) * 1975-03-24 1976-09-07 Volf Iudovich Rabinovich Method of electroslag remelting by melting main and additional electrodes and machine for effecting said method
US4008752A (en) * 1975-04-18 1977-02-22 Volf Iudovich Rabinovich Plant for the electroslag melting of shaped castings
WO2008061453A1 (fr) * 2006-11-21 2008-05-29 Nanyang Hanye Special Steel Co., Ltd Lingot de fonderie ayant une fine structure granuleuse équiaxe

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3564872D1 (en) * 1984-11-07 1988-10-13 Ciba Geigy Ag Process for stabilizing a photographic material containing a magenta coupler
GB8808694D0 (en) * 1988-04-13 1988-05-18 Kodak Ltd Stabilization of dye images produced in photographic materials
JP2592677B2 (ja) * 1989-06-22 1997-03-19 富士写真フイルム株式会社 ハロゲン化銀カラー写真感光材料

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3683997A (en) * 1971-06-09 1972-08-15 Metsubishi Jukogyo Kk Electroslag remelting process
US3713476A (en) * 1969-05-08 1973-01-30 B Paton Installation for making ingots and method therefor
US3802481A (en) * 1969-09-18 1974-04-09 Boehler & Co Ag Geb Process for electroslag-remelting of metals, in particular, steel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3713476A (en) * 1969-05-08 1973-01-30 B Paton Installation for making ingots and method therefor
US3802481A (en) * 1969-09-18 1974-04-09 Boehler & Co Ag Geb Process for electroslag-remelting of metals, in particular, steel
US3683997A (en) * 1971-06-09 1972-08-15 Metsubishi Jukogyo Kk Electroslag remelting process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978907A (en) * 1975-03-24 1976-09-07 Volf Iudovich Rabinovich Method of electroslag remelting by melting main and additional electrodes and machine for effecting said method
US4008752A (en) * 1975-04-18 1977-02-22 Volf Iudovich Rabinovich Plant for the electroslag melting of shaped castings
WO2008061453A1 (fr) * 2006-11-21 2008-05-29 Nanyang Hanye Special Steel Co., Ltd Lingot de fonderie ayant une fine structure granuleuse équiaxe

Also Published As

Publication number Publication date
DE2143445A1 (de) 1973-03-08
JPS518853B2 (ja) 1976-03-22
FR2151066A1 (ja) 1973-04-13
IT964021B (it) 1974-01-21
FR2151066B1 (ja) 1976-08-13
JPS4832728A (ja) 1973-05-02
DE2143445B2 (de) 1974-12-12

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