US3881041A - Medium for heat bonding - Google Patents

Medium for heat bonding Download PDF

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Publication number
US3881041A
US3881041A US382875A US38287573A US3881041A US 3881041 A US3881041 A US 3881041A US 382875 A US382875 A US 382875A US 38287573 A US38287573 A US 38287573A US 3881041 A US3881041 A US 3881041A
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Prior art keywords
medium
heat bonding
carrier sheet
bonding substance
pressure sensitive
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US382875A
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English (en)
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Peter Otto Glienke
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Gutermann and Co AG
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Gutermann and Co AG
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/729Textile or other fibrous material made from plastics
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • A41D27/24Hems; Seams
    • A41D27/245Hems; Seams made by welding or gluing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4825Pressure sensitive adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/52Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive
    • B29C65/526Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive by printing or by transfer from the surfaces of elements carrying the adhesive, e.g. using brushes, pads, rollers, stencils or silk screens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/13Single flanged joints; Fin-type joints; Single hem joints; Edge joints; Interpenetrating fingered joints; Other specific particular designs of joint cross-sections not provided for in groups B29C66/11 - B29C66/12
    • B29C66/135Single hemmed joints, i.e. one of the parts to be joined being hemmed in the joint area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/431Joining the articles to themselves
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/04Dielectric heating, e.g. high-frequency welding, i.e. radio frequency welding of plastic materials having dielectric properties, e.g. PVC
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/08Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7316Surface properties
    • B29C66/73161Roughness or rugosity
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/906Roll or coil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1471Protective layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/16Two dimensionally sectional layer
    • Y10T428/163Next to unitary web or sheet of equal or greater extent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/16Two dimensionally sectional layer
    • Y10T428/163Next to unitary web or sheet of equal or greater extent
    • Y10T428/168Nonrectangular
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/22Nonparticulate element embedded or inlaid in substrate and visible
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24843Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer

Definitions

  • ABSTRACT A medium for effecting heat bonding between two surfaces of material comprising a carrier sheet one side of which carries layers of a heat bonding sub stance and of a pressure sensitive adhesive. such layers being arranged that the both present exposed surfaces.
  • FIG3 MEDIUM FOR HEAT BONDING This invention relates to a novel medium for effecting heat bonding, more particularly for joining together su perposed surfaces of textile or other sheet materials.
  • a prime difficulty has been to find a convenient, effective and economical medium and manner for performing this bonding method, which will ensure that the heat bonding substance will he firmly held in the required position against the material prior to heat bonding being effected; while at the same time allowing the operator to remove and re-apply the bonding substance prior to heat bonding if it has been incorrectly laid. It is also important to avoid stretching or tearing of the layer of heat bonding substance during these operzu tions.
  • a medium for effecting heat bonding between two surfaces of material comprises a carrier sheet one side of which carries lay ers ofa heat bonding substance and of a pressure sensitive adhesive, such layers being arranged that they both present exposed surfaces.
  • the user can press a strip ofthis medium against one portion of material, along the line of the proposed seam.
  • the adhesive will stick to the material and hold the strip in position.
  • the adhesive will also allow the user to remove and replace the strip if correct positioning is found not to have been achieved at the first or subsequent attempts.
  • Due to the carrier the layer or layers or the heat bonding substance will not be stretched or torn.
  • Heat is then applied to melt the heat bonding substance and bond it to the material.
  • the carrier sheet can then be removed (with or without the adhesive according to the two main embodiments of the invention to be described), leaving the heat bonding substance on the material.
  • the other portion of material is then applied over the heat bonding substance, and heat is again applied to melt the latter and achieve a firm bond between the superposed surfaces of material.
  • the arrangement is such that only the heat bonding substance is transferred to the first portion of material. and the adhesive is so preferentially adhered to the carrier sheet that it is pulled away from the material with the carrier sheet.
  • This has the advantage of providing a ready means of removing the adhesive. if it is not desired to have the adhesive in the resultant ioint. ()n the other hand, there is then no pressure sensitive adhesive to assist in the holding of the other portion of material until the linal heat bonding is effected.
  • This first embodiment is suitably constructed by coating the said one side of the carrier sheet with a layer of pressure sensitive adhesive and applying the heat bonding substance over part of the layer of pres sure sensitive adhesive. It is ensured that the adhesive has such a strong affinity for the carrier sheet (cg. by giving the carrier sheet a roughened surface or preliminary coating of primer] that the adhesive will have a greater adherence to the carrier sheet than to the material. It is found that the heat bond to the heat bonding substance to the material will normally be sufficient to pull the heat bonding substance away from the carrier sheet upon removal of the latter from the material.
  • the arrangement is such that the adhesive is transferred to the material with the heat bonding substance.
  • the adhesive is then available on the material to assist in the holding of the other portion of material.
  • the adhesive on the one side of the carrier sheet is utilizable to serve a holding function against both portions of material, which is a substantial economy. If desired it may be contrived that the adhesive is dissolved out of the material after the joint has been formed.
  • This second embodiment requires that the surface of the carrier sheet has less affinity for the adhesive than the material, which can for example be ensured by coating the carrier sheet with a silicone or other release coat.
  • the area of the carrier sheet covered by the heat bonding substance will normally be distinct from that covered by the pressure sensitive adhesive, i.e., there will normally be no overlapping of the respective layers as may be provided in the first embodiment.
  • the purpose of this feature is to ensure that the full area of the heat bonding substance is available for contact with the said other portion of material, though this feature is not so important if the adhesive becomes miscible with the heat bonding substance during the heating.
  • the heat bonding substance be provided in discontinuous layers covering numerous substantially separate areas of the carrier sheet. c.g., in the form of dots. It is found that this, rather surprisingly, creates a stronger bond against forces tending to part the two portions of material which have been heat bonded together. If a continuous layer of heat bonding substance is used. one finds that, once such forces have started to lift a portion of such layer away from a portion of material, it can be somewhat easier to lift away the remainder ofthe layer. With discontinuous layers, this operation has to be individually started” for each dot or other portion of the heat bonding substance, and the bond becomes analogous to spot welding. Discontinuous layers of course also provide the advantage of economy in the quantity of substance used.
  • the layers of heat bonding substance and/or adhesive can be provided in the various other forms shown in the accompanying drawings. to be described hcreinbelow.
  • the adhesive can have a deleterious effect on the heat bonding substance if the two are permitted to have contact with each other.
  • the heat bonding sub stance be laterally separated from, and out of contact with, the pressure sensitive adhesive.
  • the exposed surface of the pressure sensitive adhesive is suitably covered by a readily removable protective sheet.
  • This may be provided by the reverse side of the carrier sheet, when such sheet is rolled up.
  • the reverse side of the carrier sheet may be coated with a silicone or other release material.
  • heat bonding substance is used herein to denote any substance, normally a polymer, which is capable of effecting the bonding of materials under the action of heat.
  • the bonding is normally effected by an actual melting of such substances, which may be any of the substances commonly known as hot melt adhesives.
  • Useful heat bonding substances include for example polyamides, polyamide copolymers, polyurethanes and polyacrylates.
  • the carrier sheet can be of any suitable material for the particular purpose, e.g., paper which can be impregnated, coated or otherwise treated to give it the required properties.
  • FIG. 1 is a cross-section of an example of the said first embodiment, in a first working stage
  • FIG. 2 illustrates the embodiment shown in FIG. 1, after the seam joint has been made
  • FIGS. 3 to 7 illustrate various constructions of the type of embodiment shown in FIG. 1, in elevation-and cross-section;
  • FIG. 8 illustrates an example of the said second embodiment, in a first working stage
  • FIG. 9 illustrates the embodiment shown in FIG. 8 after the joint seam has been formed
  • FIG. 10 illustrates a preferred example of the embodiment illustrated in FIG. 8.
  • FIG. 1 can be seen a layer of material, in this case a web of fabric 1, the cut edge of which is designated 2.
  • a layer of material in this case a web of fabric 1, the cut edge of which is designated 2.
  • the joining medium comprises a carrier sheet 3, for example a paper having a rough surface, a layer 4 of pressure sensitive adhesive applied thereto, and a film 5 of heat bonding substance which in turn is applied to the adhesive layer 4.
  • This joining medium is laid on the fabric web 1 at a distance from the cut edge 2 corresponding to the desired width of hem and, when subjected to slight pressure, adheres by means of the adhesive layer 4.
  • the adhesive itself has greater affinity for the carrier layer 3 than for the fabric web 1.
  • the joining medium applied and adhesively secured in this manner is then ironedv This causes the film 5 to melt and the film penetrates at least partly into the web 1, without however passing through the latter.
  • the carrier sheet 3 is then peeled off, together with the adhesive layer 4 adhering to it, from the fabric web 1.
  • the film 5 bonded in position remains adhering to the fabric web 1.
  • the latter is then turned over to the width of the hem and laid over the film 5, as can be seen in FIG. 2.
  • the film 5 is then re melted and bonds together the hem, which now comprises two layers, in the region indicated by crosses and designated 6.
  • FIG. 3 illustrates essentially the same example in which the carrier sheet 13 is in the form of a strip.
  • a layer of adhesive 14 is applied to this carrier sheet, and to the layer 14 a film 15 of heat bonding substance is applied.
  • the film 15 has a smaller width than the carrier sheet 13, so that the adhesive layer 14 projects at the edge and is exposed for the purpose of application.
  • FIG. 4 A similar example is illustrated in FIG. 4.
  • An adhe sive layer 24 is once again applied to a carrier sheet 23, which is in strip form.
  • the film 25 is in this case of zigzag shape, so that it imitates the conventional seam form.
  • the width of the carrier sheet 33 and that of the film 35 coincide with one another.
  • the film 35 however is provided with cut' outs 36.
  • the adhesive layer 34 lies under the film 35 and is exposed through the cutouts 36.
  • the heat bonding substance is of geometrically regular form
  • an irregular form is selected.
  • An adhesive layer 44 is once again applied to the carrier sheet 43.
  • the heat bonding substance in this case is in the form of a web of non-woven fibres 45 which are irregular and are disposed at irregular distances from one another.
  • the adhesive layer 44 is exposed between the fibres.
  • FIG. 7 on the other hand a regular shape is once again selected for the heat bonding substance, but this time in discontinuous layers applied to the adhesive layer 54 which is coated on the carrier sheet 53.
  • the example illustrated shows the heat bonding substance in rectangular portions, which are disposed in columns spaced a short distance apart.
  • the carrier sheet 53 may if desired be provided with perforations 56, by means of which it can be divided into narrow strips.
  • FIGS. 8 and 9 illustrate the said second embodiment of the invention and show a similar illustration to that in FIGS. 1 and 2.
  • a web of fabric 61 having a cut edge 62 is shown, and this web is once again to be hemmed.
  • a joining medium which consists of a carrier sheet 63, two strip layers 64 of a pressure sensitive adhesive, and a strip layer of hot melt adhesive spaced from the adhesive strips.
  • the carrier sheet 63 may be a coated or impregnated paper the affinity of which for the adhesive 64 is less than the affinity of the latter for the fabric web 61.
  • the layer 65 melts and partly penetrates into the fabric web 61.
  • the carrier sheet 63 is then lifted off in accordance with the dotand-dash lines shown while the transfer adhesive 64, which is for the most part transferred by the action of pressure, and also the layer 65 remain adhering to the fabric web 61. Consequently, only the carrier sheet 63 is removed.
  • the fabric web 61 is then folded over and ironed again, whereby the layer 65 is re-melted in the region 66 indicated by crosses, and thus the joining seam is produced.
  • the adhesive layers 64 which during the first ironing operation were likewise transferred to the bottom layer of fabric. remain adhering in the region of the seam.
  • the chemical or physical properties of the transfer adhesive 64 may be so selected that the adhesive is dissolved during the first washing or cleaning operation.
  • FIG. illustrates a preferred embodiment of the example illustrated in FIGS. 8 and 9.
  • Portions 74 of a transfer adhesive. in the form of adhesive dots. and also portions 75 of heat bonding substance in the form of welding dots are applied to a carrier sheet 73. for example of silicone paper.
  • a uniform grid pattern. which can be produced in a simple manner by the screen printing method or the like. is selected for this purpose.
  • This form of medium can naturally also be produced in larger webs and be separated into strips by means of suitable perforations.
  • the heat bonding substance can be applied in the form of layers of particles (bonded or sintered together) instead of in film form. and such is indeed preferred for the examples of FIGS. 8-10.
  • a medium for effecting heat bonding between two surfaces of textile fabric material comprising a carrier sheet one side only of which carries layers of a heat bonding substance and of a pressure sensitive adhesive, such layers being arranged that they both present exposed surfaces in a plane substantially parallel to the carrier sheet, the surface carrying the heat bonding substance being such that the heat bonding substance is readily transferable therefrom to the surface of the fabric material to be bonded.
  • a medium as claimed in claim 1 wherein the heat bonding substance is provided in discontinuous layers covering numerous substantially separate areas of the carrier sheet.
  • the pressure sensitive adhesive having such a strong affinity for the surface of the carrier sheet that it will remain adherent to the carrier sheet after transfer of the heat bonding substance to the surface of the material to be bonded.
  • thermoforming substance is a hot melt adhesive

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Decoration Of Textiles (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
US382875A 1972-08-02 1973-07-26 Medium for heat bonding Expired - Lifetime US3881041A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2237923A DE2237923A1 (de) 1972-08-02 1972-08-02 Mittel zum verbinden von insbesondere textilen stoffen mittels schweiss- oder heissiegelfaehigen polymeren

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US3881041A true US3881041A (en) 1975-04-29

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US (1) US3881041A (xx)
AR (1) AR208501A1 (xx)
AU (1) AU467637B2 (xx)
BE (1) BE802921A (xx)
BR (1) BR7305904D0 (xx)
CA (1) CA991922A (xx)
CH (1) CH583293A5 (xx)
DE (1) DE2237923A1 (xx)
FR (1) FR2195282A5 (xx)
GB (1) GB1371019A (xx)
IT (1) IT990090B (xx)
NL (1) NL7310442A (xx)
ZA (1) ZA735234B (xx)

Cited By (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042843A (en) * 1975-06-05 1977-08-16 Electronic Arrays, Inc. Voltage level adaption in MOSFET chips
US4079466A (en) * 1976-12-20 1978-03-21 William Rosenstein Synthetic resinous garment
US4101359A (en) * 1975-09-24 1978-07-18 Compagnie Des Etablissements De La Risle-Papeteries De Pont-Audemer Composite material for use in covering walls, and a method of manufacturing same
US4200938A (en) * 1977-10-25 1980-05-06 Letourneau Thomas R Adjustable pant leg system
EP0014040A1 (en) * 1979-01-09 1980-08-06 Albany International Corp. Tennis balls and methods of covering tennis balls
US4316756A (en) * 1980-08-15 1982-02-23 Gff, Inc. Method for bonding a pocket blank to a garment portion
US4321710A (en) * 1979-05-25 1982-03-30 Haggar Company Pocket construction
US4349920A (en) * 1978-10-02 1982-09-21 Haggar Company Pocket construction
US4365355A (en) * 1978-10-05 1982-12-28 Haggar Company Patch pocket and flap constructions
US4420518A (en) * 1982-03-24 1983-12-13 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Hot melt recharge system
US4440821A (en) * 1979-04-20 1984-04-03 Nitto Electric Industrial Co., Ltd. Heat shrinkable material
US4460426A (en) * 1980-06-06 1984-07-17 Showa Seitai Kogyo Kaisha Ltd. Composite paper sheets adapted to manufacture bags and process
US4465717A (en) * 1979-10-01 1984-08-14 Raychem Limited Assembly for marking elongate objects
US4549916A (en) * 1978-10-05 1985-10-29 Haggar Company Patch pocket and flap constructions
US5716687A (en) * 1994-07-20 1998-02-10 Chumbley; James F. Fusible bonding sheet and methods of fabrication thereof
US5806281A (en) * 1996-05-31 1998-09-15 Kt Industries Inc. Tear tape adapted for complete sealing of package overwrap
US5901706A (en) * 1997-06-09 1999-05-11 Kimberly-Clark Worldwide, Inc. Absorbent surgical drape
US5981012A (en) * 1997-11-25 1999-11-09 Kimberly-Clark Worldwide, Inc. Flushable release liner comprising a release coating on a water-sensitive film
US5985396A (en) * 1997-11-25 1999-11-16 Kimberly-Clark Worldwide, Inc. Flushable release liners and methods of making the same
FR2817563A1 (fr) * 2000-12-04 2002-06-07 Protechnic Sa Produit thermoadhesif sur support transfert, notamment pour l'industrie textile
US6530910B1 (en) 1997-12-31 2003-03-11 Kimberly-Clark Worldwide, Inc. Flushable release film with combination wiper
US6565969B1 (en) 1999-10-21 2003-05-20 3M Innovative Properties Company Adhesive article
US20030116284A1 (en) * 1997-02-06 2003-06-26 Downs John P. Handheld mechanical adhesive segment applicator apparatus and method
US20030118771A1 (en) * 1997-02-06 2003-06-26 Downs John P. Roll of adhesive segments for use in an adhesive segment applicator apparatus and method of making the same
US20030164220A1 (en) * 1997-02-06 2003-09-04 Downs John P. Stand and pneumatic actuator for adhesive segment applicator apparatus
US6638603B1 (en) 1997-08-15 2003-10-28 Kimberly-Clark Worldwide, Inc. Screen printed coating on water-sensitive film for water protection
US6640864B2 (en) 1997-02-06 2003-11-04 Glue Dots International, Llc Dispensing apparatus for a thermoplastic adhesive tape
US20040106354A1 (en) * 2001-02-06 2004-06-03 Sara Lee Corporation Methods of making cotton blend glue brassieres
US6837771B2 (en) 2001-02-06 2005-01-04 Playtex Apparel, Inc. Undergarments made from multi-layered fabric laminate material
US20050126692A1 (en) * 2003-12-09 2005-06-16 Hajny Roger V. System and method for advancing thermoplastic adhesive segment dispensing tape and applying adhesive segments thereby
US20050178507A1 (en) * 2003-12-09 2005-08-18 Hajny Roger V. System and method for advancing thermoplastic adhesive segment dispensing tape and applying adhesive segments thereby
US20050255275A1 (en) * 2004-05-14 2005-11-17 Downs John P Adhesive dispensing tape including a transparent carrier material
US20050266198A1 (en) * 1997-02-06 2005-12-01 Downs John P Adhesive segment indexing method and apparatus and roll of adhesive segments for use therewith
US20060150302A1 (en) * 2005-01-10 2006-07-13 Sara Lee Corporation Garments having seamless edge bands and processes for making
US20060162050A1 (en) * 2005-01-26 2006-07-27 Nike, Inc. Article of apparel incorporating a pleated structure
US20070083969A1 (en) * 2005-09-27 2007-04-19 Elena Brusilovsky Garment alteration
US20080017323A1 (en) * 2003-12-09 2008-01-24 Peterson Burton J Handheld adhesive applicator
US20100122835A1 (en) * 2008-11-19 2010-05-20 Sumitomo Wiring Systems, Ltd. wire protective member
US8113908B1 (en) 2000-07-20 2012-02-14 Dba Lux 1 Sarl Stiffened brassiere
EP2483070A1 (en) * 2009-09-29 2012-08-08 Under Armour, Inc. Method for bonding supplemental material to textiles
US8336474B2 (en) 2001-10-18 2012-12-25 Yugao Zhang Wrinkle free garment and method of manufacture
US20130212767A1 (en) * 2009-06-24 2013-08-22 Nike, Inc. Aerodynamic Garment With Applied Edge Treatments
USD708666S1 (en) 2011-11-18 2014-07-08 Glue Dots International, Llc Dispenser
WO2020243923A1 (en) * 2019-06-05 2020-12-10 Regina Miracle International (Group) Limited Method of manufacturing an article of clothing
US10918141B2 (en) 2009-06-24 2021-02-16 Nike, Inc. Drag-reducing exercise equipment

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114643716B (zh) * 2022-03-16 2024-03-19 福建华峰运动用品科技有限公司 一种多色包边制作工艺、包边产品及其应用

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US2191704A (en) * 1935-03-26 1940-02-27 Bennett Arthur Transfer adhesive process and product
US2411328A (en) * 1942-05-13 1946-11-19 Marian W Macnab Dressmaker's pattern
US2657159A (en) * 1945-07-14 1953-10-27 Harry Ernest Rubens Method of making clothing from component parts of sheet material
US3095649A (en) * 1958-04-17 1963-07-02 Wightwick Audrey Patterns for the manufacture of garments
US3097364A (en) * 1963-07-16 Device for forming cuffs on trousers
US3127303A (en) * 1964-03-31 wilson
US3168749A (en) * 1963-02-15 1965-02-09 Cala Abram Fabric hem
US3283345A (en) * 1964-01-30 1966-11-08 Duracraft Products Inc Upholstery cushion construction
US3328809A (en) * 1965-02-05 1967-07-04 Rosida Corp Trouser leg length adjuster
US3383263A (en) * 1966-04-26 1968-05-14 Rohm & Haas Method for preparing fabric laminate
US3741786A (en) * 1971-05-28 1973-06-26 Avery Products Corp Transfer tape having non-contiguous pressure sensitive adhesive patterns
US3785014A (en) * 1971-12-27 1974-01-15 Kay Cee Ind Prod Inc Adhesive slide fastener product

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3097364A (en) * 1963-07-16 Device for forming cuffs on trousers
US3127303A (en) * 1964-03-31 wilson
US2191704A (en) * 1935-03-26 1940-02-27 Bennett Arthur Transfer adhesive process and product
US2411328A (en) * 1942-05-13 1946-11-19 Marian W Macnab Dressmaker's pattern
US2657159A (en) * 1945-07-14 1953-10-27 Harry Ernest Rubens Method of making clothing from component parts of sheet material
US3095649A (en) * 1958-04-17 1963-07-02 Wightwick Audrey Patterns for the manufacture of garments
US3168749A (en) * 1963-02-15 1965-02-09 Cala Abram Fabric hem
US3283345A (en) * 1964-01-30 1966-11-08 Duracraft Products Inc Upholstery cushion construction
US3328809A (en) * 1965-02-05 1967-07-04 Rosida Corp Trouser leg length adjuster
US3383263A (en) * 1966-04-26 1968-05-14 Rohm & Haas Method for preparing fabric laminate
US3741786A (en) * 1971-05-28 1973-06-26 Avery Products Corp Transfer tape having non-contiguous pressure sensitive adhesive patterns
US3785014A (en) * 1971-12-27 1974-01-15 Kay Cee Ind Prod Inc Adhesive slide fastener product

Cited By (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042843A (en) * 1975-06-05 1977-08-16 Electronic Arrays, Inc. Voltage level adaption in MOSFET chips
US4101359A (en) * 1975-09-24 1978-07-18 Compagnie Des Etablissements De La Risle-Papeteries De Pont-Audemer Composite material for use in covering walls, and a method of manufacturing same
US4079466A (en) * 1976-12-20 1978-03-21 William Rosenstein Synthetic resinous garment
US4200938A (en) * 1977-10-25 1980-05-06 Letourneau Thomas R Adjustable pant leg system
US4349920A (en) * 1978-10-02 1982-09-21 Haggar Company Pocket construction
US4549916A (en) * 1978-10-05 1985-10-29 Haggar Company Patch pocket and flap constructions
US4365355A (en) * 1978-10-05 1982-12-28 Haggar Company Patch pocket and flap constructions
EP0014040A1 (en) * 1979-01-09 1980-08-06 Albany International Corp. Tennis balls and methods of covering tennis balls
US4440821A (en) * 1979-04-20 1984-04-03 Nitto Electric Industrial Co., Ltd. Heat shrinkable material
US4321710A (en) * 1979-05-25 1982-03-30 Haggar Company Pocket construction
US4465717A (en) * 1979-10-01 1984-08-14 Raychem Limited Assembly for marking elongate objects
US4460426A (en) * 1980-06-06 1984-07-17 Showa Seitai Kogyo Kaisha Ltd. Composite paper sheets adapted to manufacture bags and process
US4316756A (en) * 1980-08-15 1982-02-23 Gff, Inc. Method for bonding a pocket blank to a garment portion
US4420518A (en) * 1982-03-24 1983-12-13 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Hot melt recharge system
US5716687A (en) * 1994-07-20 1998-02-10 Chumbley; James F. Fusible bonding sheet and methods of fabrication thereof
US5806281A (en) * 1996-05-31 1998-09-15 Kt Industries Inc. Tear tape adapted for complete sealing of package overwrap
US20050118378A1 (en) * 1997-02-06 2005-06-02 Glue Dots International, Llc Thermoplastic adhesive dispensing method and apparatus
US20040151861A1 (en) * 1997-02-06 2004-08-05 Downs John P. Thermoplastic adhesive dispensing method and apparatus
US7837815B2 (en) 1997-02-06 2010-11-23 Glue Dots International Llc Adhesive segment indexing method and apparatus and roll of adhesive segments for use therewith
US20110059282A1 (en) * 1997-02-06 2011-03-10 Downs John P Adhesive Segment Indexing Method and Apparatus and Roll of Adhesive Segments for Use Therewith
US7195049B2 (en) 1997-02-06 2007-03-27 Glue Dots International, Llc Handheld mechanical adhesive segment applicator apparatus and method
US20050266198A1 (en) * 1997-02-06 2005-12-01 Downs John P Adhesive segment indexing method and apparatus and roll of adhesive segments for use therewith
US6686016B2 (en) 1997-02-06 2004-02-03 Glue Dots International, Llc Thermoplastic adhesive dispensing method and apparatus
US6640864B2 (en) 1997-02-06 2003-11-04 Glue Dots International, Llc Dispensing apparatus for a thermoplastic adhesive tape
US20030116284A1 (en) * 1997-02-06 2003-06-26 Downs John P. Handheld mechanical adhesive segment applicator apparatus and method
US20030118771A1 (en) * 1997-02-06 2003-06-26 Downs John P. Roll of adhesive segments for use in an adhesive segment applicator apparatus and method of making the same
US20030164220A1 (en) * 1997-02-06 2003-09-04 Downs John P. Stand and pneumatic actuator for adhesive segment applicator apparatus
US5901706A (en) * 1997-06-09 1999-05-11 Kimberly-Clark Worldwide, Inc. Absorbent surgical drape
US6638603B1 (en) 1997-08-15 2003-10-28 Kimberly-Clark Worldwide, Inc. Screen printed coating on water-sensitive film for water protection
US5985396A (en) * 1997-11-25 1999-11-16 Kimberly-Clark Worldwide, Inc. Flushable release liners and methods of making the same
US5981012A (en) * 1997-11-25 1999-11-09 Kimberly-Clark Worldwide, Inc. Flushable release liner comprising a release coating on a water-sensitive film
US6294238B1 (en) 1997-11-25 2001-09-25 Kimberly-Clark Corporation Flushable release liner comprising a release coating on a water-sensitive film
US6296914B1 (en) 1997-11-25 2001-10-02 Kimberly-Clark Corporation Flushable release liners and methods of making the same
US6530910B1 (en) 1997-12-31 2003-03-11 Kimberly-Clark Worldwide, Inc. Flushable release film with combination wiper
US6565969B1 (en) 1999-10-21 2003-05-20 3M Innovative Properties Company Adhesive article
US8113908B1 (en) 2000-07-20 2012-02-14 Dba Lux 1 Sarl Stiffened brassiere
FR2817563A1 (fr) * 2000-12-04 2002-06-07 Protechnic Sa Produit thermoadhesif sur support transfert, notamment pour l'industrie textile
US8235765B2 (en) 2001-02-06 2012-08-07 Hbi Branded Apparel Enterprises, Llc Composite fabric laminate for making an undergarment
US20060099884A1 (en) * 2001-02-06 2006-05-11 Playtex Apparel, Inc. Undergarments made from multi-layered fabric laminate material
US8176572B2 (en) 2001-02-06 2012-05-15 Hbi Branded Apparel Enterprises, Llc Method of forming a laminated fabric panty
US20100288434A1 (en) * 2001-02-06 2010-11-18 Gloria Falla Method of Forming a Laminated Fabric Panty
US6837771B2 (en) 2001-02-06 2005-01-04 Playtex Apparel, Inc. Undergarments made from multi-layered fabric laminate material
US20100297912A1 (en) * 2001-02-06 2010-11-25 Gloria Falla Composite fabric laminate for making an undergarment
US7682219B2 (en) 2001-02-06 2010-03-23 Hbi Branded Apparel Enterprises, Llc Undergarments made from multi-layered fabric laminate material
US7690965B2 (en) 2001-02-06 2010-04-06 Hbi Branded Apparel Enterprises, Llc Methods of making cotton blend glue brassieres
US20040106354A1 (en) * 2001-02-06 2004-06-03 Sara Lee Corporation Methods of making cotton blend glue brassieres
US8336474B2 (en) 2001-10-18 2012-12-25 Yugao Zhang Wrinkle free garment and method of manufacture
US20050126692A1 (en) * 2003-12-09 2005-06-16 Hajny Roger V. System and method for advancing thermoplastic adhesive segment dispensing tape and applying adhesive segments thereby
US8006734B2 (en) 2003-12-09 2011-08-30 Glue Dots International Llc System and method for advancing thermoplastic adhesive segment dispensing tape and applying adhesive segments thereby
US20080017323A1 (en) * 2003-12-09 2008-01-24 Peterson Burton J Handheld adhesive applicator
US20050178507A1 (en) * 2003-12-09 2005-08-18 Hajny Roger V. System and method for advancing thermoplastic adhesive segment dispensing tape and applying adhesive segments thereby
US20050255275A1 (en) * 2004-05-14 2005-11-17 Downs John P Adhesive dispensing tape including a transparent carrier material
US20110048077A1 (en) * 2005-01-10 2011-03-03 Warren Roger D Method of Forming Garments Having Seamless Edge Bands
US8117674B2 (en) 2005-01-10 2012-02-21 Hbi Branded Apparel Enterprises, Llc Method of forming garments having seamless edge bands
US20060150302A1 (en) * 2005-01-10 2006-07-13 Sara Lee Corporation Garments having seamless edge bands and processes for making
US7854022B2 (en) * 2005-01-10 2010-12-21 Hbi Branded Apparel Enterprises, Llc Garments having seamless edge bands and processes for making same
US20060162050A1 (en) * 2005-01-26 2006-07-27 Nike, Inc. Article of apparel incorporating a pleated structure
US20070083969A1 (en) * 2005-09-27 2007-04-19 Elena Brusilovsky Garment alteration
US8759681B2 (en) * 2008-11-19 2014-06-24 Sumitomo Wiring Systems, Ltd. Wire protective member
US20100122835A1 (en) * 2008-11-19 2010-05-20 Sumitomo Wiring Systems, Ltd. wire protective member
US20130212767A1 (en) * 2009-06-24 2013-08-22 Nike, Inc. Aerodynamic Garment With Applied Edge Treatments
US10918141B2 (en) 2009-06-24 2021-02-16 Nike, Inc. Drag-reducing exercise equipment
EP2483070A1 (en) * 2009-09-29 2012-08-08 Under Armour, Inc. Method for bonding supplemental material to textiles
EP2483070A4 (en) * 2009-09-29 2014-04-30 Under Armour Inc METHOD OF BINDING SUPPLEMENTAL MATERIALS ON TEXTILES
USD708666S1 (en) 2011-11-18 2014-07-08 Glue Dots International, Llc Dispenser
USD709129S1 (en) 2011-11-18 2014-07-15 Glue Dots International, Llc Dispenser
WO2020243923A1 (en) * 2019-06-05 2020-12-10 Regina Miracle International (Group) Limited Method of manufacturing an article of clothing
CN112334032A (zh) * 2019-06-05 2021-02-05 维珍妮国际(集团)有限公司 制造衣物的方法

Also Published As

Publication number Publication date
DE2237923A1 (de) 1974-02-21
CA991922A (en) 1976-06-29
CH583293A5 (xx) 1976-12-31
IT990090B (it) 1975-06-20
ZA735234B (en) 1975-03-26
AR208501A1 (es) 1977-02-15
FR2195282A5 (xx) 1974-03-01
NL7310442A (xx) 1974-02-05
AU467637B2 (en) 1975-12-04
BR7305904D0 (pt) 1974-05-16
GB1371019A (en) 1974-10-23
BE802921A (fr) 1974-01-28
AU5855373A (en) 1975-01-30

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