US3875030A - Detection of grounded anodes - Google Patents

Detection of grounded anodes Download PDF

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Publication number
US3875030A
US3875030A US398286A US39828673A US3875030A US 3875030 A US3875030 A US 3875030A US 398286 A US398286 A US 398286A US 39828673 A US39828673 A US 39828673A US 3875030 A US3875030 A US 3875030A
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Prior art keywords
anode
voltage
current
pulses
fluctuations
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US398286A
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Inventor
Nolan Earle Richards
Jr James Simmons Berry
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Reynolds Metals Co
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Reynolds Metals Co
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Priority to US398286A priority Critical patent/US3875030A/en
Priority to JP10661774A priority patent/JPS572793B2/ja
Priority to PH16288A priority patent/PH11795A/en
Priority to SE7411651A priority patent/SE400095B/sv
Priority to CA209,316A priority patent/CA1033031A/en
Priority to NO743331A priority patent/NO140360C/no
Priority to DE2444393A priority patent/DE2444393C3/de
Priority to FR7431429A priority patent/FR2244018B1/fr
Priority to GB4047774A priority patent/GB1476695A/en
Priority to BR7744/74A priority patent/BR7407744D0/pt
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/20—Automatic control or regulation of cells

Definitions

  • Apparatus is provided to sense current in the anode block .and, from analysis of the variation in that current determines the presence of a ground or electronic path.
  • the measured current varies as a result of factors other than the gas bubbles so that the measurement signal is filtered to obtain a signal whose frequency of amplitude variation is in the range of interest.
  • a comparator compares the magnitude of the frequency signal with a reference to eliminate variations due to noise, and the comparator produces digital pulses that are fed to a first counter.
  • the measurement signal is also fed to a voltage-to-frequency converter and the output of the converter drives a second counter. The counts in the two counters are compared and the resulting signal indicates whether or not a grounded anode condition exists.
  • a data processor automatically controls plural pot lines each having plural cells so that the measurements are taken automatically.
  • An addressable multiplexer is provided for each cell so that only one ground detector is required for each pot line.
  • This invention relates to a method of, and apparatus for, detecting conditions of significant anode maladjustment of interelectrode distance in an alumina reduction cell. More particularly, the present invention provides a method of, and apparatus for, automatically detecting a grounded anode, or maladjustment of an anode in a multiple anode alumina reduction cell.
  • the alternating current signal When all of the anodes are in proper relationship to the molten aluminum layer, the alternating current signal is comparatively small and the reading on the meter is proportionately lower. This variation in amplitude of the alternating current signal may be used to accurately indicate when the anodes ofa cell should be adjusted. However, this method merely provides an indication that at least one of the individual anodes of a cell should be adjusted, but provides no indication as to which particular anode or anodes require the adjustment.
  • the carbon anodes of the reduction cell are consumed by a process that produces carbon dioxide gas. This gas is released as bubbles from the lower surfaces of the carbon anodes.
  • the present invention is based on the discovery that for a given electrolyte composition and hydrostatic pressure (anode emersion) the bubbles progress in size from the minimum for nucleation to a fairly narrow range of sizes (volume) at which time the bubbles overcome hydrostatic pressure and there is a rapid movement of the bubble from underneath the surface of the anode toward the atmosphere at the top of the cell. The number of bubbles is thus proportional to the rate of production of aluminum or the anode current density on the lower surface of the anode.
  • An object of the present invention is to provide z novel method and apparatus for detecting a grounder or maladjusted anode in a reduction cell.
  • An object of the present invention is to provide 2 method of detecting a grounded or maladjusted anode comprising the steps of: measuring the total curren' through the anode over an interval of time and generating a reference value corresponding to the number 0: current fluctuations that should result from the forma tion and release of gas bubbles at the anode during the interval the current is measured; deriving from the measured current a second value corresponding approximately to the number of current fluctuations tha actually occur during the measuring interval, and com paring the reference value to the second value.
  • An object of the present invention is to provide 2 method as set forth in the preceding paragrapl wherein a fluctuating voltage proportional to the tota current is produced, the voltage converted to a se quence of pulses, and the pulses counted to produce the reference value; and wherein the voltage is filterec to eliminate fluctuations at frequencies outside the range at which fluctuations occur as a result of the for mation and release of the gas bubbles to thereby pro prise a second sequence of pulses, and said second se .quence of pulses is counted over said time interval tr derive the second value, a grounded anode being pres ent if the comparison step indicates that the reference value is greater than the second value.
  • a further object of the invention is to provide appa ratus for automatically performing the steps of thl method set forth above.
  • appa ratus for detecting a grounded or maladjusted anodl comprises means for producing a fluctuating voltag corresponding to total current flow through the anode voltage to frequency converter means for convertin; the voltage to a first sequence of pulses having a fre quency proportional to the rate at which gas bubble should be formed and released at the anode when thanode is not grounded or maladjusted and the mea sured current flows therethrough, pulse shaper mean responsive to the voltage for producing a second se quence of pulses wherein each pulse corresponds to th formation and release of a gas bubble at the anode counter means for counting the sequences of pulses and comparison means for comparing the counts in th two counters and producing a signal indicating whethe the anode is grounded or not properly adjusted.
  • Yet another object of the invention is to provide a: apparatus as described above wherein the pulse shape includes filter means for filtering from said voltage fluctuations occurring at a rate outside the range of rates at which the gas bubbles might be produced, rectifier means responsive to the filtered voltage, and comparator means responsive to the filter means and the rectifier means for producing the pulses in the second sequence of pulses.
  • FIG. 1 is a side view, partly in section, showing a prior art multiple anode alumina reduction cell
  • FIG. 2 is a block diagram of a circuit for detecting a grounded or maladjusted anode
  • FIG. 3 is a schematic wiring diagram of a pulse shaper such as that used in FIG. 2;
  • FIG. 4 is a block diagram of a data processor and multiplexer system for controlling a plurality of pot lines
  • FIG. 5 is a logic diagram of the circuits employed in the section box associated with one pot line
  • FIGS. 6A-6C are logic diagrams showing the circuits of a multiplexer for controlling one reduction cell.
  • FIG. 7 is a graph showing the relationship between anode current and fluctuations in anode voltage for a typical adjusted cell.
  • FIG. 1 shows a prior art alumina reduction cell of a type known by various names such as prebake, Niagara, etc.
  • the present invention is not limited in use to cells of the type illustrated in FIG. 1.
  • the cell includes a plurality, i.e., N carbon block anodes 11 each connected to a copper anode rod or stem 12 by means of a metal stub 14 cast in the carbon anode block.
  • Each rod 12 is clamped to an anode bus 16 by means of a hand-operated clamp 18.
  • the clamps permit an operator, with the aid of a conventional hand jack generally used in the industry, to raise or lower one anode block 1 1 relative to the others.
  • a low voltage, high current source (not shown) has its positive side connected to the anode bus 16 and its negative side connected to a cathode bus 23.
  • the cathode bus is connected by means of current collectors 24 to a carbon cathode 26.
  • each carbon block 11 is maintained with its lower surface in contact with a layer of molten cryolite 28.
  • a layer of molten aluminum 30 forms adjacent the cathode 26 while oxygen combines with the carbon blocks 11 to form gas bubbles (oxides of carbon) at the lower faces of the carbon blocks.
  • FIG. 1 shows one gas bubble 32 as it is being formed at the lower face of the right-most carbon block 11 Depending upon the hydrostatic pressure at the lower face of each carbon block, the bubbles build up to a certain size (with limits) before they escape around the carbon blocks to the upper surface of the cell.
  • a gas bubble 33 is shown as it is released from the lower surface of a carbon block and begins movement into the atmosphere above the cell.
  • a carbon block 11 is referred to simply as an anode.
  • Each anode stem 12 has an anode current measuring means connected thereto for deriving a voltage proportional to the current flowing through the stem.
  • This current measuring means comprises two electrical leads 38 and 40 connected at separate points along the stem. Because of the electrical resistance of the anode stem to current flowing therethrough, a voltage differential, sometimes referred to as the stem voltage, exists between the two points on the stem and this voltage appears on the leads 38 and 40. This method of measuring anode current flow is well known in the art.
  • the presence of a grounded anode, an incipiently grounded anode, or an anode in need of vertical adjustment with respect to the liquid cathode may be detected by a method including the steps of determining the frequency of the voltage fluctuations appearing across leads 38 and 40 and comparing this frequency with what the normal frequency of the fluctuations should be for the amount of current flowing through the anode.
  • the frequency is significantly less for a given current flow than for normal or ungrounded anode operation with the same current flow.
  • FIG. 7 is a graph of total anode current versus the period between fluctuations due to gas bubble release for an anode of a typical cell.
  • the graph is obtained by applying anode stem voltages, one at a time to a conventional X-Y plotter and recording the fluctuations as a function of time.
  • visual analysis i.e., by counting the peaks of the generally sinusoidal trace over an interval of time, the period betweeen fluctuations for that particular anode current is determined. This fixes one point on the graph of FIG. 7.
  • the anode current is then changed and the process repeated to determine another point on the graph.
  • the anode current was varied in steps between about 13,750 amps and 5,500 amps and a point on the graph establishd for each step.
  • the data of the graph of FIG. 7 was obtained over a five day period with measurements being made each day on from two to 12 anodes in an 18 anode cell. However, the measurements need not be made over such a long interval of time.
  • the normal relationship between electrolytic current flowing through an anode, and the period between fluctions is represented by the equation where I is the electrolytic current flowing through the cell, Y is the intercept obtained by extrapolating the curve C of FIG. 7, dy/dx is the slope of the curve C, and T is the time in seconds between fluctuations. Having once established this normal relationship for a properly adjusted cell, measurements may later be made while the cell is in operation to determine which, if any, of its anodes are grounded or improperly adjusted.
  • Example I A manual analysis was made by recording anode stem voltages proportional to current for an interval of 30 to 40 seconds. From analysis of the recordings for all 18 anodes it was established, as explained above with respect to FIG. 7, that the period between successively released gas bubbles should be between 0.4 and 0.6 seconds for an anode carrying 12,000 amps. One anode carrying 12,000 amps showed a periodicity in the sinusoidal waveform of between 1.10 and 1.25 seconds. Partial electronic conduction was suspected. When the anode was removed for inspection it was found to have a projection.
  • the grounded anode was raised two inches. With the anode current at 7,300 amps the period of bubble release was redetermined and found to be 0.951015 sec.
  • the period should have been 0.86i12 sec. This indicated that the anode was no longer grounded. A physical check of the anode confirmed that the projection was no longer contacting the metal pad.
  • Example II In this example, the anode stem voltages were sensed for about 30 seconds each applied to the filter circuit of FIG. 3, described below, and the filtered signals applied to the X-Y plotter. Determination of the period between fluctuations was made manually by counting the number of fluctuations per unit of time on the recorded trace.
  • Example 111 In this example, the measurements were made as in Example 11, but with the differential amplifier 208 (FIG. 2) connected to the input of the filter circuit.
  • Example IV By the manual method of Example 1, two anodes were determined to be properly adjusted and carrying 1 1,300 and 8,400 amps. The fluctuations were determined to be occurring at intervals of 0.66 and 1.02 seconds, respectively.
  • GROUND DETECTOR CIRCUITS While referred to as ground detector circuits, it will be evident that the circuits subsequently described may be employed to detect a grounded anode, an incipientlygrounded anode, or, in general an electronic conductive path between an anode and the liquid cathode in a reduction cell.
  • the measured rate of stem voltage leads will vary 0.8 to 1.2 standard deviations from the normal relationship between anode current and voltage fluctuation.
  • FIG. 2 is a block diagram of a preferred embodiment of an apparatus for detecting grounded anodes in accordance with the method described above.
  • the stem voltage signals appearing across leads 38 and 40 are multiplexed so that they are applied one at a time to the input leads 201 and 202 of FIG. 2.
  • the leads 38 and 40, of FIG. 1 are directly connected to the leds 201 and 202 respectively.
  • the stem voltage representing current flow through the rightmost anode 11 (FIG. 1) is applied over leads 201 and 202 to a differential amplifier 208.
  • the output of amplifier 208 is connected to the inputs of a pulse shaper 203 and a voltage-to-frequency converter 205.
  • Pulse shaper 203 is subsequently described in detail but, generally speaking, it filters out noise from the incoming signal and produces an output lead 207 a sequence of pulses with each pulse corresponding to the formation and release of one gas bubble at the rightmost anode 11
  • the output pulses from pulse shaper 203 are applied over the lead 207 to a counter 213 which accumulates a count representing the actual number of bubbles released during a given interval.
  • the voltage-to-frequency converter 205 is designed such that over a given interval of time it produces on an output lead 209 a number of pulses corresponding to the number of gas bubbles which should be formed and released at an anode 11, if the anode is not grounded.
  • the conversion ratio may vary depending upon the type of cell being monitored, and should be adjusted accordingly when the ground detector apparatus is first set up.
  • the pulses on lead 209 are applied to a counter 211 to provide a digital standard of bubble count against which the actual bubble count may be compared.
  • the circuit of FIG. 2 operates as follows.
  • a reset pulse is applied over a lead 215 to reset both the counters 211 and 213.
  • a gating pulse is applied to both of the counters over a lead 217.
  • This pulse may last for a considerable length of time, say 30 seconds, and during this 30 second interval conditions both counters 211 and 213 to receive the pulses applied to them over leads 209 and 207, respectively.
  • the gate pulse on lead 217 is terminated.
  • the counter 211 contains a count corresponding to the number of bubbles which should have been released from underneath the anode 11 during the 30 second interval, and the cpunter 213 contains a count of the number of bubbles actually released during that interval.
  • the outputs from counters 211 and 2.13 are applied to a digital comparator 219 which compares the two counts and determines whether they are equal or one is greater than the other. If the count in counter 213 is less than the count in counter 211, comparator 219 produces a signal on lead 221 to condition an output level selector 223. If the count in counter 211 is equal to or greater than that in counter 213 then the comparator 219 produces a signal on lead 225 or 227, respectively, to condition the output level selector.
  • the output level selector 223 comprises a conventional gating means for gatingonto an output lead 229 one of three voltage levels, 5V, V, or +V, depending upon whether the selector is conditioned by a signal on lead 221, 225 or 227, respectively.
  • the voltage on lead 229 might be used to visually or audibly signal to an operator the grounded condition of the anode.
  • the output voltage levels on lead 229 are fed to a data processor which controls a plurality of groups of cells each having a plurality of anodes 1 l, and the data processor uses the signals to monitor and control various operations associated below the frequency of interest may result from electri-,
  • the pulse shaper comprises integrated circuits 301 through 310.
  • Circuits 301 through 309 are microoperational amplifiers, for example Fairchild Type 741C, whereas circuit 310 may be a type 351K analog comparator such as that commercially available from Analog Devices, Inc.
  • the bias voltages and external connections for amplifiers 302 through 309 are not shown but it should be understood that they are the same as those shown for amplifier 301.
  • the voltage signal representing anode current is applied over lead 204 to amplifier 301 which functions merely as a scaling amplifier.
  • the output of amplifier 301 is applied to a notch filter means comprising amplifiers 302, 303, 304 and summing junction 312. More specifically, the output of amplifier 301 is applied to amplifier 302 through a filter circuit, generally indicated at 314, so that that the output of amplifier 302 includes signals of all frequencies less than the maximum frequency at which bubbles are produced and released;
  • the output of amplifier 302 is applied to the summing junction 312 through a resistor 316.
  • the output of amplifier 301 is also connected through a filter circuit, generally designated 318, to the input of amplifier 303.
  • the filter circuit 318 is such that the output of amplifier 303 is a signal containing only frequencies less than the minimum frequency at which bubbles are produced and released.
  • the output signal from amplifier 303 is inverted by amplifier 304 and applied to summing junction 312,v so that the input to scaling amplifier 305 is a signal comprising pulses or amplitude variations occurring at frequencies within the range of frequencies at which bubbles are produced and released.
  • These pulses are amplified by amplifier 309 and applied to one input of the comparator 310. In some cases it is possible to dispense with scaling amplifier 309 and apply the output of amplifier 305 directly to the comparator.
  • the pulses appearing at the output amplifier 305 are in the mature of half sine waves centered about a zero voltage level.
  • the pulses are also applied over a lead 322 to the amplifier 306 and the output of this amplifier is connected through a pair of diodes 324 and 326 to the amplifier 307.
  • Amplifiers 306 and 307 together with the diodes 324 and 326 provide full wave rectification and amplification of the output signal from amplifier 305.
  • the output of amplifier 307 is then applied to amplifier 308 which functions as a slow filter or integrator. As a result, the output of amplifier 308 is a DC signal equal to the average value of the peaks of the pulses produced at the output of amplifier 305.
  • the output of amplifier 308 is applied to the second input of comparator 310 so that the comparator produces a digital output pulse on lead 207 only for those intervals of time during which the output pulses from amplifier 305 exceed in magnitude the DC average of the pulses. This has the effect of eliminating noise pulses or pulses of small magnitude which might result from conditions other than the formation and release of gas bubbles at the anode.
  • the shaped pulses on lead 207 are then applied to counter 213 as previously described.
  • ground detector circuits such as those shown in FIGS. 2 and 3 might be provided for each anode in each cell in order to monitor operations of the cells and detect grounded anodes.
  • multiplexing means are provided for selectively connecting the voltages read at the anode stems 12 to a ground detector so that one ground detector may perform the detection function for all of the anodes in all of the cells of one pot line.
  • FIG. 4 is a block diagram of the multiplexer system.
  • a digital data processor 400 controls 3 pot lines (only two of which are shown) with each pot line including 30 potsor alumina reduction cells 402.
  • a cell multiplexer 404 is provided for each cell and a single section box 406 is provided for each pot line.
  • Each section box includes one ground detector 408, an isolator 410, and a calibrating power supply 412.
  • data read from a cell 402 is transferred over a bus 414 to its associated multiplexer 404 and control signals from the data processor are passed through the multiplexer and the bus 414 to perform various control functions in the cell.
  • All of the multiplexers for one pot line are connected in parallel to a data bus 416 and this data bus is connected to the section box 406.
  • the cell multiplexers for a given pot line are also connected in parallel to a ground detector bus 418 and this bus is connected to the ground detector 408 in the section box.
  • the output from the ground detector 408 is tied to the data bus 416 so that either the data on bus 416 or the output of the ground detector 408 may pass through the isolator 410 and over a connecting data bus 420 to the computer interface circuits 422.
  • Each of the cell multiplexers 404 is also connected in parallel to a control bus 424 which extends through the section box 406 to the computer interface circuits 422. As subsequently explained, certain leads within control bus 424 are also connected to circuits within the section box 406.
  • the control bus 424 contains 14 pairs of leads. One pair of leads is for transmitting one binary bit representing an interrupt signal from the cell multiplexers to the data processor. The remaining thirteen pairs of leads are for transmitting a thirteen bit command or control word containing address, function, and control signals from the data processor to the multiplexers and section box.
  • the bus 424 are five pairs of address lines which enable the data processor to address either the section box 406 for a pot line or any one of the cell multiplexers in the pot line. It should be noted that with only five pairs of address lines it is possible to address only 31 addresses. Thus, five pairs of address lines permits the addressing of 30 multiplexers and the section box for each pot line.
  • the selection of the pot line is determined by the program of the data processor which determines which of the interface circuits 422 will be enabled to pass the address signals. For example, if the data processor is working the portion' of the program dealing with pot line 1, and the binary address 00001 is generated, this address would pass through interface circuits 422 and select the multiplexer 404 for cell 1 in the first pot line. On the other hand, if the data processor is working that section on the program relating to the third pot line, and generates the address 00001, then this address would pass through interface circuit 422;, to select the multiplexer 404 for cell 61.
  • the section boxes 496 are all identical and the details of a typical section box are shown in FIG. 5.
  • the control bus 424 is shown as several busses depending upon the functions performed by the signals appearing on the leads.
  • the bus 424a includes two leads for carrying a Function Reset signal
  • the bus 4242 includes ten leads for carrying the five digit binary code representing the function to be performed
  • the bus 424f includes two leads for carrying an Interrupt signal. These leads merely pass through the section box on their way between the multiplexers and the data processor and are not connected to any of the circuits in the section box.
  • the control bus also includes an address bus 424a having ten leads for carrying signals representing a 5bit binary address, a bus 424b having two leads for carrying an Enable signal, and a bus 4240 having two leads for carrying a Ground Detection Enable signal.
  • a pair of leads is required to transmit a signal representing a binary bit.
  • a binary 1 is represented by a high level voltage signal on one lead concurrently with a low level voltage on the second lead of the pair.
  • a binary 0 is represented by a low level signal on the first lead of a pair concurrently with a high level signal on the second lead.
  • Each section box is assigned the address 31.
  • Five differential receivers 502 are connected to the five pairs of address lines in the control bus 424a and when the address 31 appears on the control bus all five differential receivers produce a low level output signal.
  • the differential receivers are operational amplifiers connected in a comparator configuration.
  • the output of each differential receiver is connected through an inverter 504 to an input of a NAND gate 506.
  • a differential receiver 514 has its inputs connected to the pair of leads in the control bus 424b which carries the Enable signal.
  • a solid state relay may be a transistor or any combination of transistors for performing a specified switching function. For an easy understanding of the present description, a solid state relay is treated as though it were an electro-mechanical relay, and is illustrated as such in the drawings.
  • the relay 518 has a set of normally open relay contacts 518a connected in series with a solid state relay 520 across the power supply lines 522 and 524.
  • the opening of contacts 520a and 520b disconnects the data bus 416 and the output of ground detector 408 from the input to isolator 410 while the closing of contacts 5200 and 520d connects the output of calibrate power supply 412 to the input of the isolator.
  • the section box is provided with two power supplies.
  • the logic power supply 526 provides the power for operating the various logic circuits in the section box.
  • the calibrate power supply 412 is a highly regulated power supply which is used for checking the isolator 410. By applying a control word containing address 31 and an Enable bit to the section box in the manner just explained, the calibrate power supply may be connected to the isolator to apply a known voltage level to the input of the isolator. The output of the isolator is transmitted to the data processor over the bus 420 and from the value of the voltage received at the data processor it may determine if the isolator 410 is functioning properly. When the control word on control bus 424 is terminated the circuits for connecting the calibrate power supply to the isolator return to normal.
  • the section box is also addressed to read out to the data processor the output from the ground detector 408.
  • the command, Read Ground Detector includes the address 31 with no Enable bit.
  • the address 31 again causes the output of NAND 506 to condition one input of NAND gate 510 and 512.
  • the differential receiver 514 produces a high level output signal. This signal conditions the second input of NAND 512 at the same time that the signal is inverted at 516 to block NAND gate 510.
  • NAND 512 produces a low level output signal to energize a solid state relay 528.
  • Relay 528 has a set of normally open contacts 528a connected in series with a further solid state relay 530 across the power supply lines 522 and 524.
  • relay 530 When relay 530 is energized it opens normally closed contacts 530a and 530b and closes contacts 530C and 530d. This disconnects the data bus 416 from isolator 410 and connects the output of the ground detector 408 to the isolator so that the output from the ground detector may pass through the isolator and over bus 420 to the data processor.
  • the counters in the ground detector must be reset at the beginning of the measuring interval and then the inputs of the counters must be enabled over a period of time to enable the counters to accumulate a count.
  • the circuits for generating the counter reset pulse and the counter gating pulse are shown in FIG. 5.
  • the command Determine Status enables the stem voltage drop at one anode of one cell on the pot line to be applied over bus 418 to the ground detector 408 for that pot line.
  • the command Determine Status comprises the Ground Detector Enable bit with an address specifying the multiplexer controlling the cell anode whose status is to be determined. Two leads in the control bus 424e carry the voltage levels representing the Ground Detection Enable bit.
  • This bit is applied to a differential receiver 532 and the output of the receiver 532 drops to a low level at the time a measuring interval is to begin.
  • the output of differential receiver 532 triggers a 15 millisecond single shot multivibrator 534 and a 30 second timer 536.
  • the multivibrator 534 applies a signal over the lead 215 to the ground detector to reset the counters in the ground detector.
  • the output of multivibrator 524 is inverted by an inverter 538 to block one input of a NAND gate 540.
  • the NAND gate 540 has a second input that is conditioned by the output of the 30 second timer 536 as soon as the timer is triggered. At the end of the 15 millisecond reset interval the output of amplifier 538 goes to a high level to condition NAND 540. The output of NAND 540 is applied over lead 217 to the gating inputs of the counters in the ground detector 408. At the end of the 30 second interval the output of the timer 536 drops to a low level thus blocking NAND 540 and terminating the gating pulse.
  • FIGS. 6a-6c All of the multiplexers are identical and the circuits for a typical multiplexer are shown in FIGS. 6a-6c.
  • the leads of the function bus 4242 are connected to five differential receivers 601 which respond to the combination of voltage levels on the leads to produce the five binary function signals F 1-F 5.
  • the signal F5 is inverted by an inverter 602 to produce the function signal F5.
  • the function signals Fl-F4 are applied to a first function decoder 603 (FIG. 6b) and to a second function decoder 604, a portion of which is shown in FIG. 6b and a portion of which is shown in FIG. 60.
  • the decoders are both 4-to-l6 bit decoders and the function signals-F 1-F4 serve to energize the decoders to select one of the 16 possible outputs from each of the decoders.
  • the function signal F5 is applied to the decoder 604 whereas the function signal F5 is applied to the function decoder 603.
  • the signals F1 -F4 may energize decoder 604whereas if the signal F5 is present the signals may energize the decoder 603.
  • the function signals appearing on the function bus 424e are applied simultaneously to all of the multiplexers on the pot line it is necessary to limit the function decoding operation to only those functions intended for the particular multiplexer addressed. This is accomplished as follows.
  • the signals on the address bus 424a are applied to five differential receivers 605' which have their outputs connected to input terminals of a manual plug board 606.
  • Two NAND gates 607 and 608s have multiple inputs that are also connected to output terminals of the plug board 606.
  • the output of NAND 608 is connected by way of a lead 609 to one input of NAND 607 so as to form an extended NAND gate, as is well known in the art.
  • Manually inserted plug wires 610 are used to selectively connect the outputs of the differential receivers 605 to the inputs of NAND 607 and NAND 608.
  • Each multiplexer on the pot line is assigned a different address and the plug wiring 610 is such that when the combination of address signals on address bus 424a corresponds to the address of the multiplexer a low level output signal is produced at the output of NAND 607.
  • the output of NAND 607 is connected through an inverter 611 and over leads 612 and 613 to the gates 614 and 615 (FIG. 6b).
  • the multiplexer when the multiplexer is addressed one of the function decoders 603 or 604 may be energized to produce an output signal on one of its 16 output leads.
  • the decoder 604 will produce an output signal on one of its 16 output leads, the particular output lead energized being determined by.,the combigation of signals Fl-F4.
  • the signal F5 is present then the decoder 603 will produce an output signal on one of its 16 output leads, the particular output lead energized being determined by the combination of signals F1-F4.
  • Each output from the decoders 603 and 604 controls one of a series of flip-flops (FF) 616-624 and each flipflop controls a function.
  • FF flip-flops
  • a further function flip-flop 625 is provided to control the connection of the various anode stem voltages to the data bus 416 or the ground detector bus 418.
  • All of the flip-flops are reset at the time certain commands are to be performed by the multiplexer.
  • the commands will contain an Enable bit which appears on bus 424b. This bit conditions a differential receiver 626 (FIG. 6a) which produces a low level output signal. This signal is inverted by an inverter 627 and applied to one input of a NAND gate 628.
  • the address applied to differential receivers 605 causes the output of NAND 607 to go to a low level.
  • the output of NAND 607 is inverted at 611 to condition the second input of NAND gate 628.
  • the gate produces a low level output signal that is inverted by inverter 629 before being applied to a NOR circuit 630.
  • the NOR circuit produces a low level output signal when any input is at a high level.
  • the low level output of NOR 630 is applied over a lead 631 to the reset inputs of the function control flip-flops 616 625 (FIGS. 6b and 6c).
  • one of the decoders produces an output signal, as previously described, to set one of the flip-flops 616-624.
  • Read Stem Voltage This command causes the multiplexer to connect the voltage sensing leads 38 and 40 (FIG. 1) for one anode stem to the data bus 416 so that the voltage may be sensed by the data processor.
  • the command includes the address of the multiplexer, the function code, and the Enable bit is a binary l.
  • the function code identifies the particular anode of the addressed cell that is to have its anode stern voltage drop read onto the data bus. Thus, the function code may represent any number between one and eighteen, assuming the cell has 18 anodes 11.
  • the address and Enable bits reset the function fiip-flops 616-625 and energize the decoder 603 or 604 as previously described. Assume that the function is 00001 so that decoder 603 produces an output signal on lead 632. This signal sets the function flip-flop 616.
  • Two solid state relays 634 and 636 having normally open contacts 634a and 636a, respectively, are connected to the output of FF616. The output of the flip-flop energizes the relays 634 and 636 to close the contacts 634a and 636a.
  • the contacts 634a and 636a have one side connected to the leads 38, and 40, respectively, which are attached to the anode stem of the anode block 11 shown in FIG. 1. Thus, when the flip-flop 616 is energized the voltage at this anode stem is applied through the contacts 634a and 636a to a pair of leads 638 and 640.
  • the measured stem voltage is applied to' the data bus 416 through a pair of contacts 650a and 650b. These contacts are closed at this time because FF625 is reset.
  • the high level output signal on output lead 641 from the flip-flop is applied to one input of a NAND gate 642 (FIG. 6a).
  • NAND gate 642 FIG. 6a
  • the gate 642 produces a low level output signal that is inverted by an inverter 644 and applied over a leads 646 to FIG. 6b where it energizes a solid state relay 648.
  • the relay has a single set of normally open contacts 648a connected in series across the power supply with a mercury relay 650.
  • the mercury relay 650 has two sets of normally open contacts 650a and 65% which connect the leads 638 and 640 to the data bus 416.
  • the stem voltage drop at the anode stem 11 is thus applied to the data bus from whence it may pass through the section box to the data processor.
  • the output of NAND 642 goes to the high level.
  • This releases relay 648 (FIG. 6B) which in turn releases relay 650 and its associated contacts 650a and 65012.
  • the function flip-flop 616 remains energized and will be reset only when the multiplexer is again addressed with a command that includes the enable bit.
  • the commands for reading the stem voltage drops at stems 2 through 18 differ from the command for reading the stem voltge drop at stem 1 only in the function code.
  • the function code were 00010 the voltage drop at stem 2 would be connected to the data bus, etc. and if the function code were 18 then the voltage drop at stem 18 would be connected to the data bus.
  • this requires 18 function flipflops like FF616, each flip-flop controlling twosolid state relays corresponding to 634 and 636, the relays having contacts corresponding to contacts 634a and 636a. Sixteen of the flip-flops are controlled by decoder 603 but only the one flip-flop 616 is shown in the drawing.
  • FF617 Two of the flip-flops are controlled by decoder 604 and only one of these, i.e., FF617 is shown.
  • Determine Status This command comprises an address and a binary one bit on the ground detection enable bus 424c. No function code, or enable bit is required. However, the command must be preceded by a command Read Steam Voltage which reads the stem voltage drop at the anode whose grounded/ungrounded status is to be determined.
  • the Read Stem Voltage command leaves the function flip-flop, such as FF616 for stem 1, set so that the stem voltage drop appears across leads 638 and 640.
  • the Determine Status command energizes the differential receiver 652 (FIG. 6b) and the output of the receiver is applied over a lead 654 to set FF625. At this time the low level output signal from the flip-flop energizes solid state relay 655 and the relay closes its contacts 655a.
  • the contacts 655a are connected in series with a mercury relay 656 having two sets of normally open contacts 656a and 656b. When contacts 6550 are closed relay 656 is energized to thus close contacts 656a and 656b. This connects the stem voltage for the selected anode, now appearing on leads 638 and 640, to the leads 201 and 202 of the ground detector bus 418. The voltage is applied to the ground detector 408 in the section box serving the multiplexer. As previously explained, the ground detector is enabled by the ground detector enable bit on bus 4246 so that its counters are reset and their input gates opened to receive the two sequences of pulses that are derived from the stem voltage.
  • the Determine Status command includes an address only to reset a flip-flop 750 (FIG. 6a) for reasons that will later be explained.
  • a command Read Stem Voltage sets a function relay to connect the stem voltage for the selected anode to leads 638 and 640.
  • a command Determine Status conditions the ground detector 408 to conduct a 30 second measurement, and connects the stem voltage on leads 638 and 640 to the ground detector bus.
  • a command Read Ground Detector reads out onto the data bus 416 from the ground detector 408 a binary bit indicating whether the anode is grounded or ungrounded.
  • Read Cell Voltage The purpose of this command is to read the voltage drop between the anode bus 12 and the cathode bus 23 (FIG. 1), and apply the voltage over data bus 416 and bus 420 to the data processor.
  • the command contains the address of the multiplexer associated with the cell whose voltage is to be determined, a function code identifying the operation to be performed, and an enable bit.
  • the enable bit and the address reset the. function flipflops 616-625, and the function code with the address energizes the decoder 604 in the manner previously described.
  • the decoder produces an output signal to set FF620.
  • the output of FF620 energizes two solid state relays 658 and 659 having contacts 658a and 659a associated therewith. When FF620 is set the contacts 658a and 659a close.
  • the contacts 658a and 659a are connected on one side to the leads 638 and 640. On the other side, the contacts are connected by leads 42 and 44 to the anode bus 12 and the cathode bus 23. When the contacts 658a and 659a close, the voltage drop across the cell appears on leads 638 and 640. Ground detector bus FF625 is reset so the contacts 650a and 650b are closed, as described above. Thus, the voltage drop across the cell is applied to the data bus 416 from whence it passes through the section box to the data processor. Break Crust: During the reduction process it is necessary to break the crust which forms on the surface of a cell so that more alumina may be added to the cell.
  • motor driven means may be provided to break the crust at one, the other, or both ends of the cell.
  • Each command includes the address, the function code, and an enable bit, which operate as described above to reset all of the function flipflops 616-625, energize the decoder, and set one of the function flip-flops. Specifically, if the command is Break Crust End 1 FF623 (FIG. 6C) is set. If the command is Break Crust End 2 FF622 is set, and if the command is Break Crust Both Ends FF621 is set.
  • FIG. 60 there is shown the logic power supply 670 for the multiplexer, and an auxiliary power supply 672. Both power supplies are connected to a source of power through a transformer 674.
  • the transformer output leads 676 and 678 are connected through a pair of normally closed contacts 774e and 774f to a pair of leads 682 and 684.
  • a plurality of Triacs 686, 688 and 690 are connected tothe lead 682.
  • each of the relays has a pair of normally open contacts which may be connected in-parallel with manual switches.
  • the relay contacts or the manual switches may energize motors to perform such functions as moving the anode bridge up or down, dumping of at one end or the other of a cell, or breaking the crust near one, the other, or both ends of the cell.
  • the Triacs are controlled by the output of the function decoder 604. If the command to be performed by the multiplexer is Break Crust End 1, the function signals will cause the decoder 604 to produce an output signal on lead 698 to set FF623.
  • the output of FF623 energizes a solid state relay 702.
  • the relay 702 has a set of normally open contacts 702a connected'between the gate electrode of Triac 688 and the lead 704.
  • the lead 704 is connected to one side of a set of contacts 706a on an auto-manual control switch 706 which is located remote from the multiplexer. The other side of switch contacts 706a is connected to the lead 684.
  • switch 706 If the switch 706 is in the auto position, indicating that operations are under data processor control, the closing of switch contacts 702a causes Triac 688 to conduct thereby energizing relay 694.
  • the relay contacts 694a close to energize a motor (not. shown) to break the crust at the designated end of the cell.
  • the function decoder 604 produces an output signal on a lead 707 to set FF 622 if the command to be performed is Break Crust End 2.
  • FF622 controls a solid state relay 704 having contacts 604a which in turn control Triac 690 to energize electro-mechanical relay 696 and close its contacts 696a.
  • the function decoder 604 produces an output signal on lead 710 to set FF621.
  • This flip-flop has two solid state relays 714 and 716 connected to its output.
  • Relay 714 has a set of contacts 714a connected in parallel with the contact 704a and the relay 716 has a set of normally open contacts 716a connected in parallel with the contacts 702a.
  • each of these circuits is energized by an output lead from the decoder 604 and includes a flipflop like 624, a solid state relay like 722, a Triac like 686, and an electro-mechanical relay like 692.
  • Switch Status This command is provided to enable the data processor to determine whether the switch 706 is in the auto or the manual position.
  • Output leads 730 and 732 of the auxiliary power supply 672' are connected through switch contacts 706b and 7060 to a pair of leads 734 and 736. These leads extend into FIG.
  • switch 706 When the data processor wishes to determine the status of switch 706 associated with the multiplexer, it applies the Switch Status command including an address, a function code, and an enable bit, to the multiplexer.
  • the function flip-flops are reset as for commands previously described, and then the decoder 706 produces an output signal on leads 738 to set FF618.
  • the output of this flip-flop energizes two solid state relays 742 and 744 for closing the contacts 742a and 744a.
  • switch contacts 706b and 706c are closed and the output voltage of the auxiliary power supply 672 is applied to the leads 638 and 640 through contacts 742a and 744a, from whence it passes through contacts 650a and 650b (closed because FF625 is reset) to the data bus 416 and eventually to the data processor.
  • switch 706 is in the manual position contacts 706b and 706c are open and no voltage is applied across the leads 638 and 640 from the power supply. This condition is transmitted to the data processor over the data bus to signify that the switch is in the manual position.
  • Each multiplexer is provided with circuits for detecting various abnormal conditions resulting from cell upset, circuit failures, or programming errors. Upon detecting any of these conditions the multiplexer generates an interrupt signal that is transmitted to the data processor. Upon receipt of the interrupt signal the data processor may enter a diagnostic routine to discover what the abnormal condition is and, depending upon the condition, possibly emit commands to the multiplexer to correct the condition.
  • the circuits for producing the interrupt signal are shown in FIG. 6a and include a flip-flop 750.
  • This flipflop is connected to the output of NAND gate 607 by a lead 751 so that FF750 changes state each time the multiplexer is addressed. That is, one addressing of the multiplexer sets FF750 and the next addressing resets FF750.
  • One output of FF750 is connected to a NAND 752 and the other output is connected to a timer circuit 753 which has its output connected as a second input to NAND 752.
  • FF750 is in a state such that one output blocks NAND 752.
  • the address causes the output of NAND 607 to go to a low level thus changing the state of FF750.
  • the signal on lead 754 conditions one input of NAND 752 and the signal on lead 755 triggers the timer 753.
  • the output of timer 753 conditions the second input of NAND 752 if FF750 has not changed state as a result of a second address causing the output of NAND 607 to go low a second time.
  • the programming of the data processor should be such that the multiplexer is addressed a second time within 45 seconds after it is addressed afirst time.
  • the reason for this is that the first address may be associated with a command such as Move Bridge Up.
  • this causes circuits to energize a motor to move the anode bridge upwardly. If this command is not cancelled then the anode bridge might be moved upwardly to such an extent that one or more anodes might be withdrawn from the electrolyte. Since the anodes carry currents in the range of several tens of thousands of amperes, the open-circuiting of the cell in this manner would obviously be undesirable.
  • multivibrator 758 When multivibrator 758 receives a signal at its input, it triggers a timer 759 and applies a signal to a tri-state logic circuit which includes NOR circuits 760 and 761, inverter 762, and an AND gate763.
  • the tri-state logic circuit may be of a type such as the model DM8831 which is commercially available from the National Semiconductor Co.
  • the tri-state logic circuit produces across the two leads in interrupt control bus 424f a voltage differential representing an interrupt signal. This signal exists until the timer 759 times out, and is applied over bus 424f, through the section box, to the data processor.
  • timer 759 The purpose of timer 759 is to prevent the tri-state logic circuit from emitting several interrupt signals in a short interval of time as a result of a single abnormal condition triggering multivibrator 758 several times. This might occur as a result of pot voltae fluctuations which might trigger the multivibrator several times when an upset condition occurs in the cell, as described later.
  • the multivibrator 758 When the multivibrator 758 is triggered it turns on timer 759.
  • the output of timer 759, acting through NOR 760 maintains a high impedance at the output of the tri-state logic circuit'for a fixed interval of time after the multivibrator is first triggered.
  • the multivibrator may be triggered by an output signal from NOR 756, then time out and return to its initial condition, and then in a very short interval be triggered again, the tri-state circuit will produce only one interrupt signal.
  • the tri-state logic circuit is being inhibited by the timer circuit 759 so a second interrupt signal is not produced.
  • 19 output signal from NAND 752 is inverted at 756 and applied over lead 770 to NOR 630.
  • the resulting output signal from NOR 630 is applied over lead 631 to FIGS. 6b and 60 where it resets the function flip-flops 616-625.
  • inverter 756 is also applied over a lead 771 to FIG. 60 where it energizes a solid state relay 772.
  • Relay 772 has a set of normally open contacts 772a connected in series with a set of normally closed contacts 773aand a solid state relay 774. The series circuit is directly connected across the output of transformer 674 so when contacts 772a close, relay 774 is energized.
  • Relay 774 has a set of normally open contacts 774a connected in parallel with contacts 7 72a. Contacts 774a close to provide a holding circuit for holding relay 774a energized after relay 772 returns to the deenergized state.
  • An indicator lamp 775 is connected in parallel with relay 774, and as long as the relay is energized the lamp is on to visually indicate to an operator that an interrupt condition exists as a result of failure to cancel a commanded function, or, stated differently, failure to reset F F750 within the required time.
  • Relay 774 controls normally closed contacts 774e and 774f so that when the relay is energized the contacts open. This removes power from the triacs so that any function being controlled by the Triacs is immediately terminated.
  • Relay 774 has a set of normally open contacs 7741; connected in series with manual switch contacts 706d and a speaker, bell, or other audible alarm 776.
  • the series circuit is connected across the output of transformer 674 so when relay 774 is energized the alarm 776 is sounded if the switch 706 is in the auto position.
  • Relay 774 has two further sets of normally open contacts 774a and 774d connected between the output leads 730 and 732 of the auxiliary power supply 672 and two further leads 777 and 778.
  • a multiplexer may send an interrupt signal to the data processor as a result of failure to reset FF750 within the required time, as described above, or as a result of an over-voltage across the cell, as subsequently described.
  • Failure to reset FF750 causes relay 774 to be energized as just described whereas the over-voltage condition causes an interrupt signal without energizing relay 774.
  • the course of action to be taken by the data processor is determined by what caused the interrupt, so means must be provided to enable the data processor to determine the cause. This is done by the data processor by issuing a command called Determined Failure which checks the status of relay 774.
  • the Determine Failure command includes an address, a function code, and an enable bit. These signals function to reset function control flip-flops 616-625 as previously described, and then enable decoder 604 (FIG. 6b) to set FF619.
  • This flip-flop controls two solid state relays 779 and 780 having normally open contacts 779a and 780a. When FF619 is set, the contacts close thus connecting leads 777 and 778 to leads 638 and 640. Since F F625 is reset, contacts 650a and 65012 are closed so that the Determine Failure command places on data bus 416 the voltage appearing across leads 777 and 778.
  • relay 774 if relay 774 is energized the contacts 7740 and 774d apply the output of the auxiliary power supply 672 to the leads 777 and 778. On the other hand, if the interrupt is the result of an overvoltage condition relay 774 will not be energized so there will be no voltage across leads 777 and 778. Thus, the data processor will receive over the data bus either a voltage differential indicating the interrupt was caused by failure to reset FF750, or no voltage differential indicating the interrupt was caused by an overvoltage across the cell.
  • the data processor receives an interrupt signal it cannot, from that signal alone, determine which of the cells on the pot line generated the interrupt. Thus, when an interrupt signal is received by the data processor it must generate one Determine Failure command for each cell on the pot line. These commands will differ from each other only in the address portion so that the multiplexers on the pot line are addressed in turn. By the response signal it receives.
  • the data processor is able to identify which, if any, of the multiplexers generated an interrupt signal as a result of failure to reset a FF750. If, after addressing each multiplexer, the data processor received no signal on data bus 416 as a result of a relay 774 being energized, this is an indication that the interrupt was a result of an over-voltage across a cell. The data processor may then be programmed to execute a sequence of Read Cell Voltage commands to locate the cell which caused the interrupt.
  • the data processor determines that the interrupt signal is a result of the failure to reset a FF 750, it generates the command Failure Reset.
  • This command comprises a single binary bit on the bus 424d and is applied to all the multiplexers for the pot line.
  • the Failure Reset command is applied to a differential receiver 781.
  • the output of the differential receiver is applied over a lead 782 to reset FF750.
  • the output of the differential receiver is inverted by an inverter 783 and applied over a lead 784 to NOR 630.
  • the output of NOR 630 is applied to FIGS. 61b and 60 when it resets the function flip-flops 616-625.
  • inverter 783 The output of inverter 783 is inverted by an inverter 785 and applied over a lead 786 to FIG. 60 where it energizes a solid state relay 773.
  • This relay controls normally closed contacts 773a so when the relay is energized the contacts 773a open. This opens the circuit to relay 774 and lamp 775.
  • Relay 774 drops out so its contacts transfer. This shuts off the audible alarm 766, disconnects the auxiliary power supply 672 from the leads 777 and 778 and reapplies power to the Triacs. As soon as the Failure Reset command is terminated, relay 773 returns to normal. The circuit is now cleared of its error-indicating condition.
  • the voltage drop across the cell is continuously monitoredand an interrupt signal produced if the voltage drop becomes excessive.
  • An abnormally high voltage drop generally indicates an upset condition in the cell that requires correction.
  • the voltage drop across the cell is available on leads 42 and 44 connected to the anode bus 12 and the cathode bus 23.
  • the lead 42 (FIG. 6B) is connected to the parallel combination of a Zener diode 765 and a solid state relay 766.
  • Lead 44 is connected through a resistor 767 and a Zener diode 768 to the other side of diode 765 and relay 7 66. As long as the voltage drop across the cell is within normal limits, say 4.5V, diode 768 does not conduct and relay 766 is not energized.
  • said total current is measured by producing a voltage which varies as said total current varies;
  • said voltage is converted to a sequence of pulses having a frequency proportional to the rate of said current fluctuations
  • said pulses are counted over said interval of time to produce said reference value.
  • comparison step comprises comparing said reference value with said second value to produce a first output signal when said reference value is greater than said second value or a second output signal when said reference value is less than said second value.
  • Apparatus for determining the position of an anode in an alumina reduction cell comprising:
  • digital counter means for counting said digital pulses to develop a reference value
  • pulse shaper means responsive to said voltage representing current flow for producing a second se- 5O quence of pulses wherein each pulse represents an actual fluctuation in anode current;
  • comparison means responsive to said counter means and said pulse shaper means over a given interval of time for indicating maladjustment of the anode when said first sequence contains more pulses than said second sequence during said interval.
  • said comparison means comprises a second counter means responsive to said second sequence of pulses and a digital comparator for comparing the counts in said counters.
  • said pulse shaper means comprises filter means responsive to said voltage for passing only the fluctuations in said voltage that corresponding to a range of frequencies selected for determining the rate at which gas bubbles are formed and released at said anode.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Fuel Cell (AREA)
  • Secondary Cells (AREA)
  • Primary Cells (AREA)
US398286A 1973-09-17 1973-09-17 Detection of grounded anodes Expired - Lifetime US3875030A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US398286A US3875030A (en) 1973-09-17 1973-09-17 Detection of grounded anodes
JP10661774A JPS572793B2 (sv) 1973-09-17 1974-09-13
SE7411651A SE400095B (sv) 1973-09-17 1974-09-16 Sett och anordning for detektering av leget av anoden i en aluminiumreduktionscell
CA209,316A CA1033031A (en) 1973-09-17 1974-09-16 Detection of anode position in an alumina reduction cell
PH16288A PH11795A (en) 1973-09-17 1974-09-16 Detection of anode position in an alumina reduction cell
NO743331A NO140360C (no) 1973-09-17 1974-09-16 Fremgangsmaate og apparat til aa detektere feilinnstilling av en anode i en redusjonscelle for aluminiumoksyd
DE2444393A DE2444393C3 (de) 1973-09-17 1974-09-17 Verfahren und Vorrichtung zum Feststellen der Fehleinstellung einer Anode in einem Reduktionstiegel
FR7431429A FR2244018B1 (sv) 1973-09-17 1974-09-17
GB4047774A GB1476695A (en) 1973-09-17 1974-09-17 Detection of anode maladjustment in an alumina reduction cell
BR7744/74A BR7407744D0 (pt) 1973-09-17 1974-09-17 Processo e aparelho para detectar o desajuste de um anodo numa celula de alumina

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US398286A US3875030A (en) 1973-09-17 1973-09-17 Detection of grounded anodes

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US3875030A true US3875030A (en) 1975-04-01

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JP (1) JPS572793B2 (sv)
BR (1) BR7407744D0 (sv)
CA (1) CA1033031A (sv)
DE (1) DE2444393C3 (sv)
FR (1) FR2244018B1 (sv)
GB (1) GB1476695A (sv)
NO (1) NO140360C (sv)
PH (1) PH11795A (sv)
SE (1) SE400095B (sv)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4752362A (en) * 1987-01-27 1988-06-21 Aluminum Company Of America Detecting and estimating shorting phenomena in hall cells and control of cell anodes in response thereto
WO1991000380A1 (en) * 1989-07-05 1991-01-10 Hull Harry F Electrolytic processing apparatus and method with time multiplexed power supply
CN104746101A (zh) * 2013-12-26 2015-07-01 贵阳铝镁设计研究院有限公司 一种铝电解槽阳极行程测量装置及其测量方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3345273A (en) * 1964-02-04 1967-10-03 Reynolds Metals Co Method of and apparatus for indicating anode positions
US3674674A (en) * 1968-12-27 1972-07-04 Delfzijl Aluminium Apparatus for controlling electrode adjustment during aluminum oxide reduction
US3761379A (en) * 1971-07-20 1973-09-25 C Elliott Aluminum production apparatus

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3345273A (en) * 1964-02-04 1967-10-03 Reynolds Metals Co Method of and apparatus for indicating anode positions
US3674674A (en) * 1968-12-27 1972-07-04 Delfzijl Aluminium Apparatus for controlling electrode adjustment during aluminum oxide reduction
US3761379A (en) * 1971-07-20 1973-09-25 C Elliott Aluminum production apparatus

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4752362A (en) * 1987-01-27 1988-06-21 Aluminum Company Of America Detecting and estimating shorting phenomena in hall cells and control of cell anodes in response thereto
US5007993A (en) * 1989-06-20 1991-04-16 Hull Harry F Electrolytic processing apparatus and method with time multiplexed power supply
WO1991000380A1 (en) * 1989-07-05 1991-01-10 Hull Harry F Electrolytic processing apparatus and method with time multiplexed power supply
CN104746101A (zh) * 2013-12-26 2015-07-01 贵阳铝镁设计研究院有限公司 一种铝电解槽阳极行程测量装置及其测量方法
CN104746101B (zh) * 2013-12-26 2017-07-11 贵阳铝镁设计研究院有限公司 一种铝电解槽阳极行程测量装置及其测量方法

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FR2244018B1 (sv) 1981-04-10
CA1033031A (en) 1978-06-13
NO140360C (no) 1979-08-15
SE7411651L (sv) 1975-03-18
BR7407744D0 (pt) 1975-07-29
PH11795A (en) 1978-07-05
DE2444393B2 (de) 1977-12-01
DE2444393C3 (de) 1978-07-27
GB1476695A (en) 1977-06-16
NO743331L (sv) 1975-04-14
NO140360B (no) 1979-05-07
SE400095B (sv) 1978-03-13
JPS5077204A (sv) 1975-06-24
JPS572793B2 (sv) 1982-01-18
DE2444393A1 (de) 1975-03-27
FR2244018A1 (sv) 1975-04-11

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