US3852596A - Cold cathode gaseous discharge device for producing electrons in an x-ray fluorescence analysis apparatus - Google Patents
Cold cathode gaseous discharge device for producing electrons in an x-ray fluorescence analysis apparatus Download PDFInfo
- Publication number
- US3852596A US3852596A US00338869A US33886973A US3852596A US 3852596 A US3852596 A US 3852596A US 00338869 A US00338869 A US 00338869A US 33886973 A US33886973 A US 33886973A US 3852596 A US3852596 A US 3852596A
- Authority
- US
- United States
- Prior art keywords
- chamber
- channel
- gas
- enclosure
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004876 x-ray fluorescence Methods 0.000 title claims description 7
- 238000004458 analytical method Methods 0.000 title description 3
- 239000007789 gas Substances 0.000 claims description 35
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000161 steel melt Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/267—Heterocyclic compounds
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/223—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by irradiating the sample with X-rays or gamma-rays and by measuring X-ray fluorescence
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J35/00—X-ray tubes
- H01J35/02—Details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2223/00—Investigating materials by wave or particle radiation
- G01N2223/07—Investigating materials by wave or particle radiation secondary emission
- G01N2223/076—X-ray fluorescence
Definitions
- the invention has for its object to mitigate the disadvantages of the known arrangement.
- the ele'ctron beam emerging from the cathode is guided through a hollow cylinder, behind which the specimen is located in an equipotential space so that the electrons travel along substantially straight paths, while the gas pressure is of the order of to 10" Torr.
- the anode is formed by a hollow cylinder, the communication between the discharge space and the space accommodating the specimen is so large that the degree of vacuum in both spaces'is the same.
- the communication has such a flow resistance that impurities originating from the specimen can penetrate only with difficulty into the discharge space between the anode and the cathode. Also higher gas expulsions from the specimen can hardly affect the discharge.
- the specimen space may be traversed, if desired, by a flushing gas of the same pressure as required in the discharge space, if necessary with addition of'flushing gasthrough the discharge space.
- the arrangement embodying the invention it is possible, for example, to dispose in the specimen space a sample of a steel melt shortly after solidifience to the drawing, which shows schematically a device embodying the invention.
- the grid is connected via a capacitor 19 and a resistor 20 to the cathode.
- a direct voltage of 15 to 30 kV is applied to the terminals 21.
- the grid 5 takes a charge of 2 to 4,kV positive to the cathode.
- the discharge current is 1 to 2 mA and satisfactorily stable owing to the self-adjusting grid.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00338869A US3852596A (en) | 1970-03-20 | 1973-03-07 | Cold cathode gaseous discharge device for producing electrons in an x-ray fluorescence analysis apparatus |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7003972.A NL157144B (nl) | 1970-03-20 | 1970-03-20 | Inrichting voor materiaalonderzoek door middel van roentgenfluorescentie. |
| US12139271A | 1971-03-05 | 1971-03-05 | |
| US00338869A US3852596A (en) | 1970-03-20 | 1973-03-07 | Cold cathode gaseous discharge device for producing electrons in an x-ray fluorescence analysis apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3852596A true US3852596A (en) | 1974-12-03 |
Family
ID=19809628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00338869A Expired - Lifetime US3852596A (en) | 1970-03-20 | 1973-03-07 | Cold cathode gaseous discharge device for producing electrons in an x-ray fluorescence analysis apparatus |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3852596A (OSRAM) |
| JP (1) | JPS5213113B1 (OSRAM) |
| CA (1) | CA935568A (OSRAM) |
| DE (1) | DE2110323C3 (OSRAM) |
| FR (1) | FR2083464B1 (OSRAM) |
| GB (1) | GB1330948A (OSRAM) |
| NL (1) | NL157144B (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4119855A (en) * | 1977-07-08 | 1978-10-10 | Massachusetts Institute Of Technology | Non vacuum soft x-ray lithographic source |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060061008A1 (en) | 2004-09-14 | 2006-03-23 | Lee Karner | Mounting assembly for vehicle interior mirror |
| US7881496B2 (en) | 2004-09-30 | 2011-02-01 | Donnelly Corporation | Vision system for vehicle |
| US7720580B2 (en) | 2004-12-23 | 2010-05-18 | Donnelly Corporation | Object detection system for vehicle |
| US7914187B2 (en) | 2007-07-12 | 2011-03-29 | Magna Electronics Inc. | Automatic lighting system with adaptive alignment function |
| US20100020170A1 (en) | 2008-07-24 | 2010-01-28 | Higgins-Luthman Michael J | Vehicle Imaging System |
| EP2401176B1 (en) | 2009-02-27 | 2019-05-08 | Magna Electronics | Alert system for vehicle |
| WO2011014497A1 (en) | 2009-07-27 | 2011-02-03 | Magna Electronics Inc. | Vehicular camera with on-board microcontroller |
| WO2011028686A1 (en) | 2009-09-01 | 2011-03-10 | Magna Mirrors Of America, Inc. | Imaging and display system for vehicle |
| US9264672B2 (en) | 2010-12-22 | 2016-02-16 | Magna Mirrors Of America, Inc. | Vision display system for vehicle |
| US10019841B2 (en) | 2011-05-18 | 2018-07-10 | Magna Electronics Inc. | Driver assistance systems for vehicle |
| US9146898B2 (en) | 2011-10-27 | 2015-09-29 | Magna Electronics Inc. | Driver assist system with algorithm switching |
| US10457209B2 (en) | 2012-02-22 | 2019-10-29 | Magna Electronics Inc. | Vehicle vision system with multi-paned view |
| US10328932B2 (en) | 2014-06-02 | 2019-06-25 | Magna Electronics Inc. | Parking assist system with annotated map generation |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2924715A (en) * | 1956-06-01 | 1960-02-09 | Philips Corp | X-ray analysis apparatus |
| US3155827A (en) * | 1960-04-07 | 1964-11-03 | Hilger & Watts Ltd | Electron microscope with a secondary electron source utilized for electron probe analysis |
| US3307066A (en) * | 1964-12-21 | 1967-02-28 | First Pennsylvania Banking And | Afocal-beam probe system and apparatus |
| US3346736A (en) * | 1964-09-22 | 1967-10-10 | Applied Res Lab Inc | Electron probe apparatus having an objective lens with an aperture for restricting fluid flow |
| US3374349A (en) * | 1966-11-14 | 1968-03-19 | Victor G. Macres | Electron probe having a specific shortfocal length magnetic lens and light microscope |
| US3435211A (en) * | 1966-01-04 | 1969-03-25 | Stanford Research Inst | Gaseous glow discharge tube with cathode means surrounding anode means |
-
0
- CA CA935568A patent/CA935568A/en not_active Expired
-
1970
- 1970-03-20 NL NL7003972.A patent/NL157144B/xx unknown
-
1971
- 1971-03-04 DE DE2110323A patent/DE2110323C3/de not_active Expired
- 1971-03-18 JP JP7115019A patent/JPS5213113B1/ja active Pending
- 1971-03-19 FR FR717109769A patent/FR2083464B1/fr not_active Expired
- 1971-04-19 GB GB2440271*A patent/GB1330948A/en not_active Expired
-
1973
- 1973-03-07 US US00338869A patent/US3852596A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2924715A (en) * | 1956-06-01 | 1960-02-09 | Philips Corp | X-ray analysis apparatus |
| US3155827A (en) * | 1960-04-07 | 1964-11-03 | Hilger & Watts Ltd | Electron microscope with a secondary electron source utilized for electron probe analysis |
| US3346736A (en) * | 1964-09-22 | 1967-10-10 | Applied Res Lab Inc | Electron probe apparatus having an objective lens with an aperture for restricting fluid flow |
| US3307066A (en) * | 1964-12-21 | 1967-02-28 | First Pennsylvania Banking And | Afocal-beam probe system and apparatus |
| US3435211A (en) * | 1966-01-04 | 1969-03-25 | Stanford Research Inst | Gaseous glow discharge tube with cathode means surrounding anode means |
| US3374349A (en) * | 1966-11-14 | 1968-03-19 | Victor G. Macres | Electron probe having a specific shortfocal length magnetic lens and light microscope |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4119855A (en) * | 1977-07-08 | 1978-10-10 | Massachusetts Institute Of Technology | Non vacuum soft x-ray lithographic source |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2110323C3 (de) | 1979-09-06 |
| GB1330948A (en) | 1973-09-19 |
| DE2110323A1 (de) | 1971-09-30 |
| JPS5213113B1 (OSRAM) | 1977-04-12 |
| FR2083464A1 (OSRAM) | 1971-12-17 |
| CA935568A (en) | 1973-10-16 |
| NL157144B (nl) | 1978-06-15 |
| FR2083464B1 (OSRAM) | 1973-06-08 |
| DE2110323B2 (de) | 1979-01-04 |
| NL7003972A (OSRAM) | 1971-09-22 |
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