US3849078A - A sealing ring of stainless iron base alloy - Google Patents
A sealing ring of stainless iron base alloy Download PDFInfo
- Publication number
- US3849078A US3849078A US00299103A US29910372A US3849078A US 3849078 A US3849078 A US 3849078A US 00299103 A US00299103 A US 00299103A US 29910372 A US29910372 A US 29910372A US 3849078 A US3849078 A US 3849078A
- Authority
- US
- United States
- Prior art keywords
- alloy
- percent
- stainless
- base alloy
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 48
- 239000000956 alloy Substances 0.000 title claims abstract description 48
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 21
- 238000007789 sealing Methods 0.000 title claims description 5
- 238000005260 corrosion Methods 0.000 claims abstract description 16
- 230000007797 corrosion Effects 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 14
- 239000011651 chromium Substances 0.000 claims abstract description 14
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 238000005299 abrasion Methods 0.000 claims abstract description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 238000005266 casting Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001339 C alloy Inorganic materials 0.000 description 1
- 241000364057 Peoria Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000010112 shell-mould casting Methods 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/06—Cast-iron alloys containing chromium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12229—Intermediate article [e.g., blank, etc.]
- Y10T428/12264—Intermediate article [e.g., blank, etc.] having outward flange, gripping means or interlocking feature
Definitions
- This invention relates to a stainless alloy. More particularly, it relates to a particularly wear and corrosionresistant stainless alloy based upon iron and chromium and having a relatively high proportion of carbon.
- Stainless alloys have found extensive application throughout industry because of their outstanding corrosion resistance under severe conditions. This property, coupled with wear resistance and other favorable metallurgical properties, has accounted for their increasing utilization. However, where such alloys have been subjected to extremely severe service conditions, e.g., the presence of mud and dirt, and wherein such alloys are used to form seals to protect vital machinery parts, it has been found necessary to resort to stainless steels having even more pronounced wear and corrosion resistance.
- alloy stainless steels including costly alloying elements such as columbium, cobalt, molybdenum and vanadium.
- alloys have been found to be highly suitable for such severe service use.
- a stainless iron base alloy has now been developed which is totally free from such exotic” elements, but which exhibits comparable properties of wear and corrosion resistance. At the same time, the brittleness characteristics of the alloy are sufficiently low to obviate the necessity of careful handling during casting and subsequent operations.
- Such alloy comprises relatively high amounts of chromium and carbon which are alloyed in an iron base together with small percentages of manganese and silicon.
- Such stainless alloy differs from known stainless steel alloys possessing similar corrosion and wear resistant characteristics in that the more exotic materials such as molybdenum, cobalt, vanadium and columbium are eliminated, yet the alloy possesses conveniently low brittleness characteristics. This resultant alloy is an economical metallurgical composition which still exhibits the required characteristics for severe service use.
- the present invention is a stainless alloy, suitable for metal-to-metal face seals and like structures, wherein said alloy comprises a relatively large percentage of chromium, a lesser amount of carbon, and even smaller amounts of manganese and silicon, all alloyed with a major percentage of iron.
- It is still another object of the invention to provide a stainless alloy composition comprising iron, chromium, carbon, silicon and manganese having excellent wear and corrosion resistant characteristics, and comparatively low brittleness characteristics.
- the alloy of the present invention comprises a material exhibiting the properties of a wear-resistant, stainless steel wherein said properties are derived from a combination of the elements iron, chromium, carbon, manganese, and silicon.
- a stainless iron base alloy is provided having the following percentages (by weight) of these elements:
- chromium percentage in the alloy is about 25 percent to impart optimum abrasion and corrosion resistance.
- the carbon in the alloy forms intermetallic carbides which are dispersed throughout the solid solution of chromiumiron; these carbides impart excellent wear resistant properties to the alloy. It is preferable that carbon be present in the alloy in an amount of about 3.5 percent to obtain optimum wear resistance with minimal brittleness characteristics.
- This property of carbon which imparts brittleness to the stainless alloy of the invention requires that the percentage of carbon in the composition not exceed that indicated above, i.e., 3.65 percent, lest the alloy be too brittle for usefulness.
- the high carbon alloy exhibits greatly superior wear characteristics over conventional stainless alloys, especially in high-speed applications. Further, such alloys have conveniently low brittleness characteristics which do not require special handling during casting or subsequent operations. These alloys are excellent for use in high-speed metalto-metal seal construction.
- Manganese and silicon are added to control depth of chill and hardness, inter alia.
- the ranges specified above contribute to an excellent wear and corrosion resistant alloy in conjunction with the specified amounts of carbon, chromium and iron.
- manganese is present in amounts of about 0.5 percent by weight in the alloy of the invention.
- Iron is of course the predominant element in the alloy, and in the presence of the amounts of chromium indicated above, forms a solid solution therewith having excellent corrosion and stain resistant properties.
- the alloys of the invention can be produced by metallurgical alloying techniques commonly practiced in the art.
- the alloy furnishes an excellent material for the production of cast products wherein extreme hardness and outstanding stain resistance are desirable, in particular cast seals such as those described in U.S. Pat. No. 3,180,648 to Kupfert, et al., filed Dec. 14, 1959, and having common assignee herewith.
- the abovedesignated patent includes a sealing ring having a generally axially extending portion and a generally radially extending flange.
- cast seals having an alloy composition of this invention were produced by conventional shell molding techniques. After the castings were cleaned, they were heated to 1,850 to 1,900 F for 1 hour, followed by air-quenching to room temperature, and then tempered by reheating to 375 F for 1 hour. The castings had a through hardness of Rockwell C63 and displayed an unexpectedly high transverse rupture strength.
- a sealing ring having a generally axially extending portion and a generally radially extending flange having high corrosion and abrasion resistance made of a stainless iron base alloy consisting essentially of 3.1 to 3.65 percent carbon, 24 to 27 percent chromium, up to 0.9 percent manganese, up to 1.50 percent silicon and the balance iron.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Sealing Devices (AREA)
- Powder Metallurgy (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Continuous Casting (AREA)
- Heat Treatment Of Articles (AREA)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00299103A US3849078A (en) | 1972-10-19 | 1972-10-19 | A sealing ring of stainless iron base alloy |
CA181,710A CA996783A (en) | 1972-10-19 | 1973-09-24 | Stainless iron base alloy metal to metal high speed seals |
BR8032/73A BR7308032D0 (pt) | 1972-10-19 | 1973-10-15 | Liga inoxidavel a base de ferro,para vedantes metal-a-metal de funcionamento a alta velocidade |
JP48116017A JPS4974112A (enrdf_load_stackoverflow) | 1972-10-19 | 1973-10-17 | |
DE2352546A DE2352546B2 (de) | 1972-10-19 | 1973-10-18 | Verwendung eines verschleiß- und korrosionsbeständigen ChromguBeisens |
GB4868773A GB1436156A (en) | 1972-10-19 | 1973-10-18 | Seal made from stainless iron base alloy |
FR7337214A FR2203886B1 (enrdf_load_stackoverflow) | 1972-10-19 | 1973-10-18 | |
IT53199/73A IT996315B (it) | 1972-10-19 | 1973-10-18 | Lega inossidabile a base di ferro per guarnizioni |
US00453846A US3849122A (en) | 1972-10-19 | 1974-03-22 | Stainless iron base alloy metal-to-metal high speed seals |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00299103A US3849078A (en) | 1972-10-19 | 1972-10-19 | A sealing ring of stainless iron base alloy |
Publications (1)
Publication Number | Publication Date |
---|---|
US3849078A true US3849078A (en) | 1974-11-19 |
Family
ID=23153320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00299103A Expired - Lifetime US3849078A (en) | 1972-10-19 | 1972-10-19 | A sealing ring of stainless iron base alloy |
Country Status (8)
Country | Link |
---|---|
US (1) | US3849078A (enrdf_load_stackoverflow) |
JP (1) | JPS4974112A (enrdf_load_stackoverflow) |
BR (1) | BR7308032D0 (enrdf_load_stackoverflow) |
CA (1) | CA996783A (enrdf_load_stackoverflow) |
DE (1) | DE2352546B2 (enrdf_load_stackoverflow) |
FR (1) | FR2203886B1 (enrdf_load_stackoverflow) |
GB (1) | GB1436156A (enrdf_load_stackoverflow) |
IT (1) | IT996315B (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4132419A (en) * | 1976-05-31 | 1979-01-02 | Toyo Kogyo Co., Ltd. | Oil seal ring for rotary piston engines |
US4318738A (en) * | 1978-02-03 | 1982-03-09 | Shin-Gijutsu Kaihatsu Jigyodan | Amorphous carbon alloys and articles manufactured from said alloys |
US20140319780A1 (en) * | 2013-04-24 | 2014-10-30 | Caterpillar Inc. | Use of dissimilar metals in floating style seals |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0278208A1 (en) * | 1987-02-06 | 1988-08-17 | Weartech Limited | Wear resistant sleeve for use in a die casting machine |
FR3146063A1 (fr) | 2023-02-23 | 2024-08-30 | Capsum | Produit comprenant une composition liquide et une composition solide comprenant au moins une cavité |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1245552A (en) * | 1916-04-10 | 1917-11-06 | Electro Metallurg Co | Alloy. |
US2038639A (en) * | 1933-07-26 | 1936-04-28 | Union Carbide & Carbon Corp | Method of producing castings |
US2268426A (en) * | 1941-11-10 | 1941-12-30 | Hughes Tool Co | Wear resisting alloy |
US2355726A (en) * | 1942-06-12 | 1944-08-15 | Pangborn Corp | Abrasion resistant articles and alloys |
-
1972
- 1972-10-19 US US00299103A patent/US3849078A/en not_active Expired - Lifetime
-
1973
- 1973-09-24 CA CA181,710A patent/CA996783A/en not_active Expired
- 1973-10-15 BR BR8032/73A patent/BR7308032D0/pt unknown
- 1973-10-17 JP JP48116017A patent/JPS4974112A/ja active Pending
- 1973-10-18 IT IT53199/73A patent/IT996315B/it active
- 1973-10-18 DE DE2352546A patent/DE2352546B2/de active Pending
- 1973-10-18 GB GB4868773A patent/GB1436156A/en not_active Expired
- 1973-10-18 FR FR7337214A patent/FR2203886B1/fr not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1245552A (en) * | 1916-04-10 | 1917-11-06 | Electro Metallurg Co | Alloy. |
US2038639A (en) * | 1933-07-26 | 1936-04-28 | Union Carbide & Carbon Corp | Method of producing castings |
US2268426A (en) * | 1941-11-10 | 1941-12-30 | Hughes Tool Co | Wear resisting alloy |
US2355726A (en) * | 1942-06-12 | 1944-08-15 | Pangborn Corp | Abrasion resistant articles and alloys |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4132419A (en) * | 1976-05-31 | 1979-01-02 | Toyo Kogyo Co., Ltd. | Oil seal ring for rotary piston engines |
US4318738A (en) * | 1978-02-03 | 1982-03-09 | Shin-Gijutsu Kaihatsu Jigyodan | Amorphous carbon alloys and articles manufactured from said alloys |
US20140319780A1 (en) * | 2013-04-24 | 2014-10-30 | Caterpillar Inc. | Use of dissimilar metals in floating style seals |
Also Published As
Publication number | Publication date |
---|---|
FR2203886A1 (enrdf_load_stackoverflow) | 1974-05-17 |
JPS4974112A (enrdf_load_stackoverflow) | 1974-07-17 |
DE2352546A1 (de) | 1974-05-02 |
IT996315B (it) | 1975-12-10 |
DE2352546B2 (de) | 1975-11-20 |
BR7308032D0 (pt) | 1974-06-27 |
GB1436156A (en) | 1976-05-19 |
FR2203886B1 (enrdf_load_stackoverflow) | 1979-01-26 |
CA996783A (en) | 1976-09-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: CATERPILLAR INC., 100 N.E. ADAMS STREET, PEORIA, I Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:CATERPILLAR TRACTOR CO., A CORP. OF CALIF.;REEL/FRAME:004669/0905 Effective date: 19860515 Owner name: CATERPILLAR INC., A CORP. OF DE.,ILLINOIS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CATERPILLAR TRACTOR CO., A CORP. OF CALIF.;REEL/FRAME:004669/0905 Effective date: 19860515 |