US3847684A - Method of quenching zirconium and alloys thereof - Google Patents
Method of quenching zirconium and alloys thereof Download PDFInfo
- Publication number
- US3847684A US3847684A US00399130A US39913073A US3847684A US 3847684 A US3847684 A US 3847684A US 00399130 A US00399130 A US 00399130A US 39913073 A US39913073 A US 39913073A US 3847684 A US3847684 A US 3847684A
- Authority
- US
- United States
- Prior art keywords
- alloys
- zirconium
- quenching
- alpha
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract description 13
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 12
- 239000000956 alloy Substances 0.000 title claims abstract description 12
- 238000010791 quenching Methods 0.000 title claims description 14
- 230000000171 quenching effect Effects 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 239000002344 surface layer Substances 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/186—High-melting or refractory metals or alloys based thereon of zirconium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/002—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
Definitions
- This invention relates to the quenching of metals, and more particularly to a novel method of quenching zirconium and alloys thereof to inhibit the formation of blocky alpha structure during subsequent heating into the alpha temperature region.
- the blocky alpha structure has properties which are different from the interior of the material, and is therefore objectionable, requiring removal of the blocky alpha layer by machining, grinding, etc.
- the time involved in the machining and the magnitude of the loss of material resulting therefrom represent a significant cost factor in the production of usable metal.
- this invention involves the quenching of zirconium and its alloys in water having a temperature of at least about l40F., to inhibit the formation of an alpha structure layer.
- zirconium and its alloys are quenched in water having a temperature of at least about l40F.
- the preferred water temperature is in excess of l60F., and as close to the boiling point of water as is practicable.
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Forging (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Physical Vapour Deposition (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00399130A US3847684A (en) | 1973-09-20 | 1973-09-20 | Method of quenching zirconium and alloys thereof |
GB3848974A GB1438450A (en) | 1973-09-20 | 1974-09-03 | Method of quenching zirconium or an alloy thereof |
CA208,419A CA1042771A (en) | 1973-09-20 | 1974-09-04 | Method of quenching zirconium and alloys thereof |
JP49103989A JPS5057013A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-09-20 | 1974-09-11 | |
SE7411785A SE395915B (sv) | 1973-09-20 | 1974-09-19 | Forfarande for vermebehandling av zirkonium och legeringar derav genom sleckning fran temperaturer inom beta-fasomradet foljt av behandling vid en temperatur inom alfa-omradet |
DE19742444857 DE2444857A1 (de) | 1973-09-20 | 1974-09-19 | Verfahren zum abschrecken von zirkonium und zirkoniumlegierungen |
FR7431677A FR2244831B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-09-20 | 1974-09-19 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00399130A US3847684A (en) | 1973-09-20 | 1973-09-20 | Method of quenching zirconium and alloys thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US3847684A true US3847684A (en) | 1974-11-12 |
Family
ID=23578268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00399130A Expired - Lifetime US3847684A (en) | 1973-09-20 | 1973-09-20 | Method of quenching zirconium and alloys thereof |
Country Status (7)
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2302348A1 (fr) * | 1975-02-25 | 1976-09-24 | Gen Electric | Procede et appareil pour le traitement de zone de longues pieces en alliage de zirconium |
FR2302569A1 (fr) * | 1975-02-25 | 1976-09-24 | Gen Electric | Procede de traitement thermique d'alliages de zirconium et produits obtenus |
FR2303865A1 (fr) * | 1975-03-14 | 1976-10-08 | Asea Atom Ab | Procede de traitement d'alliages de zirconium contre la corrosion |
FR2538940A1 (fr) * | 1982-12-30 | 1984-07-06 | Kraftwerk Union Ag | Procede de realisation d'une gaine en alliage de zirconium pour le combustible d'un element combustible de reacteur nucleaire |
US4548657A (en) * | 1982-06-14 | 1985-10-22 | General Electric Company | Bow control for metallic structures |
US4584030A (en) * | 1982-01-29 | 1986-04-22 | Westinghouse Electric Corp. | Zirconium alloy products and fabrication processes |
JPS62226090A (ja) * | 1986-03-28 | 1987-10-05 | 原子燃料工業株式会社 | ライナ−付き核燃料被覆管の製造方法 |
US5876524A (en) * | 1994-06-22 | 1999-03-02 | Sandvik Ab | Method for the manufacture of tubes of a zirconium based alloy for nuclear reactors and their usage |
US20080230584A1 (en) * | 2007-03-19 | 2008-09-25 | The Boeing Company | Method for Manufacturing a Workpiece by Friction Welding to Reduce the Occurrence of Abnormal Grain Growth |
US20110076419A1 (en) * | 2009-09-28 | 2011-03-31 | Hitachi America, Ltd. | Method for developing fine grained, thermally stable metallic material |
US8555858B2 (en) | 2009-03-31 | 2013-10-15 | Hitachi, Ltd | High pressure fuel pipe construction for an internal combustion engine |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2651870C2 (de) * | 1975-11-17 | 1987-04-30 | General Electric Co., Schenectady, N.Y. | Verfahren zum Herstellen eines Bauteils aus einer Zirkoniumlegierung |
FR2368547A2 (fr) * | 1976-10-22 | 1978-05-19 | Gen Electric | Procede et appareil pour le traitement thermique de zone de longues pieces en alliage de zirconium |
JP3513587B2 (ja) * | 1999-07-26 | 2004-03-31 | 独立行政法人産業技術総合研究所 | チタン又はチタン合金製高生体親和性人工骨の作製方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2894866A (en) * | 1958-01-21 | 1959-07-14 | Marion L Picklesimer | Method for annealing and rolling zirconium-base alloys |
US3341373A (en) * | 1962-09-26 | 1967-09-12 | Imp Metal Ind Kynoch Ltd | Method of treating zirconium-base alloys |
US3689324A (en) * | 1968-09-27 | 1972-09-05 | George W Wiener | Process for obtaining preferred orientation in zirconium and its alloy |
-
1973
- 1973-09-20 US US00399130A patent/US3847684A/en not_active Expired - Lifetime
-
1974
- 1974-09-03 GB GB3848974A patent/GB1438450A/en not_active Expired
- 1974-09-04 CA CA208,419A patent/CA1042771A/en not_active Expired
- 1974-09-11 JP JP49103989A patent/JPS5057013A/ja active Pending
- 1974-09-19 DE DE19742444857 patent/DE2444857A1/de not_active Ceased
- 1974-09-19 SE SE7411785A patent/SE395915B/xx unknown
- 1974-09-19 FR FR7431677A patent/FR2244831B1/fr not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2894866A (en) * | 1958-01-21 | 1959-07-14 | Marion L Picklesimer | Method for annealing and rolling zirconium-base alloys |
US3341373A (en) * | 1962-09-26 | 1967-09-12 | Imp Metal Ind Kynoch Ltd | Method of treating zirconium-base alloys |
US3689324A (en) * | 1968-09-27 | 1972-09-05 | George W Wiener | Process for obtaining preferred orientation in zirconium and its alloy |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2302348A1 (fr) * | 1975-02-25 | 1976-09-24 | Gen Electric | Procede et appareil pour le traitement de zone de longues pieces en alliage de zirconium |
FR2302569A1 (fr) * | 1975-02-25 | 1976-09-24 | Gen Electric | Procede de traitement thermique d'alliages de zirconium et produits obtenus |
FR2303865A1 (fr) * | 1975-03-14 | 1976-10-08 | Asea Atom Ab | Procede de traitement d'alliages de zirconium contre la corrosion |
US4584030A (en) * | 1982-01-29 | 1986-04-22 | Westinghouse Electric Corp. | Zirconium alloy products and fabrication processes |
US4548657A (en) * | 1982-06-14 | 1985-10-22 | General Electric Company | Bow control for metallic structures |
FR2538940A1 (fr) * | 1982-12-30 | 1984-07-06 | Kraftwerk Union Ag | Procede de realisation d'une gaine en alliage de zirconium pour le combustible d'un element combustible de reacteur nucleaire |
JPS62226090A (ja) * | 1986-03-28 | 1987-10-05 | 原子燃料工業株式会社 | ライナ−付き核燃料被覆管の製造方法 |
US5876524A (en) * | 1994-06-22 | 1999-03-02 | Sandvik Ab | Method for the manufacture of tubes of a zirconium based alloy for nuclear reactors and their usage |
US20080230584A1 (en) * | 2007-03-19 | 2008-09-25 | The Boeing Company | Method for Manufacturing a Workpiece by Friction Welding to Reduce the Occurrence of Abnormal Grain Growth |
US8555858B2 (en) | 2009-03-31 | 2013-10-15 | Hitachi, Ltd | High pressure fuel pipe construction for an internal combustion engine |
US20110076419A1 (en) * | 2009-09-28 | 2011-03-31 | Hitachi America, Ltd. | Method for developing fine grained, thermally stable metallic material |
Also Published As
Publication number | Publication date |
---|---|
JPS5057013A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-05-19 |
CA1042771A (en) | 1978-11-21 |
SE395915B (sv) | 1977-08-29 |
SE7411785L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-03-21 |
DE2444857A1 (de) | 1975-04-03 |
GB1438450A (en) | 1976-06-09 |
FR2244831A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-04-18 |
FR2244831B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-06-09 |
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