US3843354A - Pneumatic refining of pig iron - Google Patents
Pneumatic refining of pig iron Download PDFInfo
- Publication number
- US3843354A US3843354A US00225279A US22527972A US3843354A US 3843354 A US3843354 A US 3843354A US 00225279 A US00225279 A US 00225279A US 22527972 A US22527972 A US 22527972A US 3843354 A US3843354 A US 3843354A
- Authority
- US
- United States
- Prior art keywords
- converter
- blowing
- oxygen
- fluid
- outer tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007670 refining Methods 0.000 title claims abstract description 16
- 229910000805 Pig iron Inorganic materials 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000012530 fluid Substances 0.000 claims abstract description 20
- 238000007664 blowing Methods 0.000 claims abstract description 16
- 239000007789 gas Substances 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 239000000725 suspension Substances 0.000 claims abstract description 7
- 230000001681 protective effect Effects 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 11
- 235000011941 Tilia x europaea Nutrition 0.000 description 11
- 239000004571 lime Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000012159 carrier gas Substances 0.000 description 8
- 239000003345 natural gas Substances 0.000 description 7
- 230000002093 peripheral effect Effects 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/34—Blowing through the bath
Definitions
- the present invention relates to improvements in a process for the pneumatic refining of pig iron in which the refining gas constituted totally or to a large extent by commercially pure oxygen is blown into the refining bath through one or more tuyeres housed in the lower part (preferably in the bottom) of the converter.
- the object of the present invention is to provide a refining process in which desulphurizing of the bath takes place in the actual converter.
- This pig iron refining process in which use is made of a converter comprising at least one tuyere with two coaxial tubes housed in the converter bottom or in the lower part of the converter wall, includes two phases; during the first phase of the refining operation a fluid with a reducing character, such as a hydrocarbon, is blown into the molten metal via the peripheral conduit of the tuyere, and simultaneously a preferably non-oxidizing carrier gas which has lime in suspension (preferably in the form of a powder) is blown in via the central conduit of the tuyere; after removal of at least part of the slag formed in the course of the first phase there follows a second phase of blowing into the bath via the central conduit of the tuyere of a gas whose major component is oxygen, the oxygen preferably being commercially pure, while a protective fluid is blown in via the peripheral conduit, preferably of the same nature as the fluid with a reducing character injected via this same peripheral conduit in the course of the first phase.
- the carrier gas which has lime in suspension and is blown in via the central conduit in the course of the first phase of the operation can be an inert gas (i.e. a gas which is inert to the contents of the converter) such as nitrogen or aron; if necessary, however, the carrier gas can be of the same nature (i.e. composition) as the fluid with a reducing character blown in via the peripheral conduit.
- a preferential embodiment of the invention consists in the use of natural gas (a hydrocarbon gas obtained from the earths crust).
- the use as a gas for supporting the lime of a gaseous mixture comprising notably any two of the gases referred to above does not represent a departure from the scope of the invention.
- a mass of 17.6 tonnes of molten pig iron containing 0.068% sulphur was introduced into a converter having a perforated base fitted with tuyeres with two coaxial tubes whose internal and external diameters were respectively 12 and 15 mm., and 17 and 22 mm.
- a second phase comprising blowing a fluid consisting of an oxygen-containing gas whose major component is oxygen through the inner tube, and simultaneously blowing a protective fluid through the outer tube.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE762837A BE762837A (fr) | 1971-02-11 | 1971-02-11 | Perfectionnements aux procedes d'affinage pneumatique de la fonte. |
Publications (1)
Publication Number | Publication Date |
---|---|
US3843354A true US3843354A (en) | 1974-10-22 |
Family
ID=3857716
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00225279A Expired - Lifetime US3843354A (en) | 1971-02-11 | 1972-02-10 | Pneumatic refining of pig iron |
Country Status (6)
Country | Link |
---|---|
US (1) | US3843354A (de) |
JP (1) | JPS587689B1 (de) |
BE (1) | BE762837A (de) |
DE (1) | DE2204789B2 (de) |
FR (1) | FR2125310B1 (de) |
LU (1) | LU64767A1 (de) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3972708A (en) * | 1973-09-13 | 1976-08-03 | Verfahrenstechnik Dr.-Ing. Kurt Baum | Process for avoiding formation of smoke and flames in bottom blown converters |
US4047937A (en) * | 1972-12-04 | 1977-09-13 | United States Steel Corporation | Method for controlling the operation of a steel refining converter |
US4295882A (en) * | 1978-10-24 | 1981-10-20 | Nippon Steel Corporation | Steel making process |
US4388112A (en) * | 1980-03-21 | 1983-06-14 | Nippon Steel Corporation | Steelmaking process with separate refining steps |
US6379425B1 (en) * | 1999-06-07 | 2002-04-30 | Kawasaki Steel Coporation | Method of desulfurizing molten iron |
WO2009003364A1 (fr) * | 2007-07-03 | 2009-01-08 | Northeastern University | Procédé de fabrication d'acier dans un convertisseur à lances supérieure, inférieures et latérale |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE773855A (fr) * | 1971-10-12 | 1972-01-31 | Centre Rech Metallurgique | Procede pour la desulfuration d'un metal. |
DE2822791C2 (de) * | 1977-05-26 | 1983-12-08 | Gruzinskij politechničeskij institut imeni V.I. Lenina, Tbilisi | Vorrichtung zum Einführen pulverförmiger Reagenzien mittels eines Trägergasstromes in eine Metallschmelze |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1166389A (fr) * | 1956-02-23 | 1958-11-05 | Procédé de désulfuration de la fonte et de l'acier et produits conformes à ceux obtenus par ledit procédé |
-
1971
- 1971-02-11 BE BE762837A patent/BE762837A/xx unknown
-
1972
- 1972-02-02 DE DE2204789A patent/DE2204789B2/de active Pending
- 1972-02-03 FR FR7203574A patent/FR2125310B1/fr not_active Expired
- 1972-02-10 LU LU64767D patent/LU64767A1/xx unknown
- 1972-02-10 US US00225279A patent/US3843354A/en not_active Expired - Lifetime
- 1972-02-12 JP JP47014375A patent/JPS587689B1/ja active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4047937A (en) * | 1972-12-04 | 1977-09-13 | United States Steel Corporation | Method for controlling the operation of a steel refining converter |
US3972708A (en) * | 1973-09-13 | 1976-08-03 | Verfahrenstechnik Dr.-Ing. Kurt Baum | Process for avoiding formation of smoke and flames in bottom blown converters |
US4295882A (en) * | 1978-10-24 | 1981-10-20 | Nippon Steel Corporation | Steel making process |
US4388112A (en) * | 1980-03-21 | 1983-06-14 | Nippon Steel Corporation | Steelmaking process with separate refining steps |
US4457778A (en) * | 1980-03-21 | 1984-07-03 | Nippon Steel Corporation | Steelmaking process with separate refining steps |
US6379425B1 (en) * | 1999-06-07 | 2002-04-30 | Kawasaki Steel Coporation | Method of desulfurizing molten iron |
WO2009003364A1 (fr) * | 2007-07-03 | 2009-01-08 | Northeastern University | Procédé de fabrication d'acier dans un convertisseur à lances supérieure, inférieures et latérale |
Also Published As
Publication number | Publication date |
---|---|
JPS587689B1 (de) | 1983-02-10 |
DE2204789B2 (de) | 1973-10-25 |
FR2125310B1 (de) | 1976-07-23 |
BE762837A (fr) | 1971-08-11 |
FR2125310A1 (de) | 1972-09-29 |
LU64767A1 (de) | 1972-07-04 |
DE2204789A1 (de) | 1972-09-28 |
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