US3841898A - Process for imparting an anti-felting finish to animal fibres - Google Patents

Process for imparting an anti-felting finish to animal fibres Download PDF

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Publication number
US3841898A
US3841898A US00372115A US37211573A US3841898A US 3841898 A US3841898 A US 3841898A US 00372115 A US00372115 A US 00372115A US 37211573 A US37211573 A US 37211573A US 3841898 A US3841898 A US 3841898A
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US
United States
Prior art keywords
fibres
aqueous solution
group
fibre
synthetic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00372115A
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English (en)
Inventor
J Hefele
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUFNER TEXTILWERKE KG
KUFNER TEXTILWERKE KG DT
Original Assignee
KUFNER TEXTILWERKE KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE2023671A priority Critical patent/DE2023671C3/de
Priority to GB990171A priority patent/GB1288344A/en
Priority to FR7117464A priority patent/FR2092149B1/fr
Application filed by KUFNER TEXTILWERKE KG filed Critical KUFNER TEXTILWERKE KG
Priority to US00372115A priority patent/US3841898A/en
Application granted granted Critical
Publication of US3841898A publication Critical patent/US3841898A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2971—Impregnation

Definitions

  • An anti-felting finish is imparted to animal fibres by means of synthetic resins, by applying aliphatic and/or [30] Foreign Application Priority Data cycloaliphatic diamines and/or polyamines in aqueous May 14, 1970 Germany 2023671 Solution to the fibre and a Second aqufious solution is used to carry out an already known anti-felting 5 CL N 117/76 T, 117/1395 A, 117/141, treatment by impregnating the fibre with the solution 117/161 KP of a possibly bufiered salt of a polymer base which is [51] Int.
  • This invention relates to a process for imparting an anti-felting finish to animal fibres, which is suitable more particularly for finishing fabrics in web form.
  • the object of the invention therefore is to find a finishing process whereby webs of woven or knitted animal-fibre interlinings can be finished on conventional finishing plants and from an aqueous bath, with mini-. mum hardening of the touch or feel, so as reliably to prevent any felting or migration of the animal fibres during the wearing and conventional cleaning of the garments provided with the interlining fixed thereto.
  • aliphatic or cycloaliphatic diamines or polyamines in aqueous solution are applied to the fibres and then a second aqueous solution is used for an already known anti-felting treatment by impregnating the fibres with the solution of a possibly buffered salt of a polymer base which is deposited on the fibres during the subsequent action of heat.
  • All water-soluble diamines and polyamines are suitable, for example ethylene diamine, hexamethylene diamine, dicyclohexyl diamine, diethylene triamine, dipropylene triamine, triethylene tetramine.
  • ethylene diamine hexamethylene diamine, dicyclohexyl diamine, diethylene triamine, dipropylene triamine, triethylene tetramine.
  • amine calculated as NH and NH group
  • the quantity of amine can be increased to about 20 mg of amine per gram of animal fibre.
  • Treatment of the fibre may be carried out, for example, on the yarn in an aqueous bath of the amine heated to about C, a treatment time of about 10 to 30 minutes being sufficient.
  • the finishing process is carried out on the finished woven or knitted web material by means of a padding machine.
  • the material is dried and condensed.
  • the drying temperature should not exceed 160C. A temperature action of about 2 minutes is sufficient at C.
  • the impregnation with the solution of a salt of a polymer base which is deposited in the form of the free base on the fibre with the application of heat, possibly with the addition of a buffer substance, is carried out in another operation.
  • a salt of a polymer base which is deposited in the form of the free base on the fibre with the application of heat, possibly with the addition of a buffer substance.
  • anti-felting agents for example, are sulphonium halides which are linked to polyurethane radicals and which are particularly suitable for the proposed combined application with amines and which are therefore preferred.
  • Other usable salts of polymer bases are appropriately selected watersoluble salts of polyamidoamines, whose free amino groups can react with organic or inorganic acids to form salts.
  • methylol compounds, formaldehyde, formaldehyde liberating compounds such as urotropin, and other finishing agents based on aqueous solutions and dispersions for example reactive (meth)-acrylate dispersions, polyethylene dispersions, urea resins, melamine resins and so on, may be added to the solutions of salts of polymer bases.
  • EXAMPLE 1 3 piecesof a loose woven interlining consisting of a wool warp and a camel hair weft having a weight of 1 l0 gram per square metre were degreased on a conventional finishing machine, squeezed out and immediately finished, in the wet state, on a padding machine using an aqueous solution containing 0 gram, 20 gram and 40 g/l of hexamethylene diamine. The absorption of the The bath absorption was 100 gram per 100 gram of fabric. After drying, the material was condensed for 2 minutes at 140C. Ternary 6, 6/6, 12 copolyamide was then applied in spots, the application being 20 gram per square metre.
  • EXAMPLE 2 Degrcased sheeps wool and camel hair yarns wound on cheeses were rinsed for 25 minutes with an aqueous solution of dipropylene triamine which had been heated to 95C and which contained 0 gram, 0.5 gram and 1.5 gram of dipropylene triamine per 100 gram of animal fibre. After this treatment, the cheeses were washed with cold water, centrifuged and dried at 120C. The identically treated sheep's wool and camel hair yarns were woven into three interlining fabrics of a weight of about 1 10 gram per metre and then padded with the solution of polyurethane sulphonium halide from Example 1 and treated further.
  • the proposed combined treatment is not limited just to animal interlinings.
  • any animal fibre for any purpose necessitating anti-feltingtreatment can be treated by the process.
  • a process for imparting an antifelting finish to animal fibres which comprises a first step of applying to the fibers at least one compound selected from the group consisting of aliphatic and cycloaliphatic diamines and polyarnines from an aqueous solution thereof and a second step of applying an aqueous solution of a salt of a synthetic resin base to the resulting fibers and heating the fibers to condense the synthetic resin base from the applied solution onto the fibers said synthetic resin base salt being selected from the group consisting of polyurethane sulphonium halides and water-soluble polyamidoamine salts of organic or inorganic acids.
  • a process according to claim 1 wherein the compound selected from the group consisting of aliphatic and cycloaliphatic diamines and polyarnines is at least one compound selected from the group consisting of ethylene diamine, hexamethylene diamine, diethylene triamine, dipropylene triamine, dicyclohexyl diamine and triethylene tetramine.
  • a process according to claim l-for imparting an anti-felting finish to animal fibres selected from the group consisting of wool and camel hair which comprises a first step of applying to the fibres at least one compound selected from the group consisting of hexamethylenediamine and dipropylene triamine from an aqueous solution thereof, and a second step of applying an aqueous solution of polyurethane sulphonium halide to the resulting fibres and heating the fibres to condense the free base polymer from the applied solution onto the fibres.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US00372115A 1970-05-14 1973-06-21 Process for imparting an anti-felting finish to animal fibres Expired - Lifetime US3841898A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE2023671A DE2023671C3 (de) 1970-05-14 1970-05-14 Verfahren zur Antifilzausrüstung animalischer Fasern
GB990171A GB1288344A (en, 2012) 1970-05-14 1971-04-19
FR7117464A FR2092149B1 (en, 2012) 1970-05-14 1971-05-14
US00372115A US3841898A (en) 1970-05-14 1973-06-21 Process for imparting an anti-felting finish to animal fibres

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE2023671A DE2023671C3 (de) 1970-05-14 1970-05-14 Verfahren zur Antifilzausrüstung animalischer Fasern
US13913271A 1971-04-30 1971-04-30
US00372115A US3841898A (en) 1970-05-14 1973-06-21 Process for imparting an anti-felting finish to animal fibres

Publications (1)

Publication Number Publication Date
US3841898A true US3841898A (en) 1974-10-15

Family

ID=27182591

Family Applications (1)

Application Number Title Priority Date Filing Date
US00372115A Expired - Lifetime US3841898A (en) 1970-05-14 1973-06-21 Process for imparting an anti-felting finish to animal fibres

Country Status (4)

Country Link
US (1) US3841898A (en, 2012)
DE (1) DE2023671C3 (en, 2012)
FR (1) FR2092149B1 (en, 2012)
GB (1) GB1288344A (en, 2012)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3357785A (en) * 1963-10-08 1967-12-12 Merck & Co Inc Shrinkproofing wool through serial impregnation with a diisocyanate having one or two terminal ester groups and a diamine

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2657151A (en) * 1949-09-23 1953-10-27 Bayer Ag Coating of fabrics
DE1066176B (en, 2012) * 1954-05-21 1959-10-01
NL291488A (en, 2012) * 1962-04-17
CH269069D (en, 2012) * 1968-02-23

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3357785A (en) * 1963-10-08 1967-12-12 Merck & Co Inc Shrinkproofing wool through serial impregnation with a diisocyanate having one or two terminal ester groups and a diamine

Also Published As

Publication number Publication date
FR2092149B1 (en, 2012) 1975-07-04
DE2023671A1 (de) 1971-11-25
DE2023671B2 (de) 1973-12-13
FR2092149A1 (en, 2012) 1972-01-21
DE2023671C3 (de) 1979-08-09
GB1288344A (en, 2012) 1972-09-06

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