US3817680A - Synthetic fiber spinning plate with colummar coating layer - Google Patents
Synthetic fiber spinning plate with colummar coating layer Download PDFInfo
- Publication number
- US3817680A US3817680A US00293994A US29399472A US3817680A US 3817680 A US3817680 A US 3817680A US 00293994 A US00293994 A US 00293994A US 29399472 A US29399472 A US 29399472A US 3817680 A US3817680 A US 3817680A
- Authority
- US
- United States
- Prior art keywords
- spinning
- plate
- layer
- spinning plate
- crystalline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009987 spinning Methods 0.000 title abstract description 57
- 229920002994 synthetic fiber Polymers 0.000 title description 7
- 239000012209 synthetic fiber Substances 0.000 title description 7
- 239000011247 coating layer Substances 0.000 title description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 150000002739 metals Chemical class 0.000 claims abstract description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 7
- 239000011651 chromium Substances 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- 239000010955 niobium Substances 0.000 claims abstract description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010936 titanium Substances 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- -1 platinum metals Chemical class 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229910017052 cobalt Inorganic materials 0.000 abstract description 3
- 239000010941 cobalt Substances 0.000 abstract description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 239000010949 copper Substances 0.000 abstract description 3
- 239000007792 gaseous phase Substances 0.000 abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052737 gold Inorganic materials 0.000 abstract description 3
- 239000010931 gold Substances 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 229910052759 nickel Inorganic materials 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 229910052715 tantalum Inorganic materials 0.000 abstract description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052721 tungsten Inorganic materials 0.000 abstract description 3
- 239000010937 tungsten Substances 0.000 abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 2
- 239000011733 molybdenum Substances 0.000 abstract description 2
- 238000002207 thermal evaporation Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 11
- 229920000620 organic polymer Polymers 0.000 description 8
- 239000013078 crystal Substances 0.000 description 6
- 238000013508 migration Methods 0.000 description 5
- 230000005012 migration Effects 0.000 description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D4/00—Spinnerette packs; Cleaning thereof
- D01D4/02—Spinnerettes
- D01D4/022—Processes or materials for the preparation of spinnerettes
Definitions
- liquid polymers are extruded in normal spinning direction from the spinning ducts of the spinning plate.
- the nozzle end of the spinning ducts is subject to disturbances, and the spinning process is subject to disturbances.
- the melted polymers deviate substantially from the directed flow, drips of liquid, melted polymers may form, resulting in an interruption of the spinning process. Deviation from the spinning path, and migration of the melted polymers can be observed particularly when the laminar flow at the terminal edge of a spinning duct is disturbed by irregularities in the geometry at the exit edges, or by wetting of the limit or terminal zone of the exit end of a spinning duct.
- Platinum-type metals are the metals platinum, palladium, rhodium, iridium, ruthenium and osmium.
- the thickness of the layer of crystal columns is about between 6 to 12 pm.
- the crystals of this layer have a preferred orientation perpendicular to the surface of the spinning plate.
- the end terminal of the spinning duct has a crystalline metallic structure which is columnar and oriented in the direction of flow of the organic polymers, which thus do not interfere with laminar flow of the liquid polymers eminating from the duct in the spinning plate.
- the crystalline layer In a plane parallel to the spinning plate, the crystalline layer has a fine crystalline surface structure, which, based on its fine crystalline structure effectively prevents wetting of the surface with the melted liquid polymers at the surface.
- the columnar crystalline structure, parallel to flow direction and at the exit ends of the ducts is coarsely crystalline, however.
- the crystalline layer can be so made that at least one metal of the group aforesaid is precipitated in a vacuum of less than 10 mm Hg, by condensation from the gaseous phase, on the surface of the spinning plate.
- the metal is vaporized on the spinning plate at the pressure of less than 10 mm Hg.
- the spinning plate is maintained at a temperature of at least C during the coating process.
- FIGURE is a schematic transverse sectional view through a spinning plate.
- the spinning plate 1 is made of steel and is formed with a plurality of spinning ducts 2, adapted to be connected to a source of melted polymer, not shown.
- the liquid melted organic polymer passes through the spinning duct in the direction of the arrows 3.
- the surface of the spinning plate from which the melted organic polymers exit, or emanate is coated with a crystalline layer 4 which consist essentially of adjacent crystal columns extending at right angles to the surface of the spinning plate 1.
- the crystal columns are so arranged that the crystalline layer 4, in a plane parallel to the surface of the spinning plate, exhibits a fine crystalline crystal structure.
- Synthetic fiber spinning plate comprising a structural plate formed with spinning ducts extending through the plate in a direction transverse to the plate surface, and a non isotropic coating layer of adjacent crystalline columns, of a thickness in the order of between 220 mm, said layer having a coarse columnar crystalline structure parallel to the direction of the spinning ducts at the exit ends columns are made of a material comprising at least one of the metals of the group of titanium, niobium, vanadium or chromium.
- platinum metals comprise at least one of the metals of the group of platinum, palladium, rhodium, iridium, ruthenium and osmium.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2148773A DE2148773B2 (de) | 1971-09-30 | 1971-09-30 | Spinndüsenplatte zum Verspinnen organischer Polymerer |
Publications (1)
Publication Number | Publication Date |
---|---|
US3817680A true US3817680A (en) | 1974-06-18 |
Family
ID=5821016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00293994A Expired - Lifetime US3817680A (en) | 1971-09-30 | 1972-10-02 | Synthetic fiber spinning plate with colummar coating layer |
Country Status (9)
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4137032A (en) * | 1976-09-07 | 1979-01-30 | E. I. Du Pont De Nemours And Company | Corrosion-resistant spinneret |
US4576811A (en) * | 1983-11-03 | 1986-03-18 | E. I. Du Pont De Nemours And Company | Process for adjusting the fiber structure of mesophase pitch fibers |
US6527532B1 (en) * | 1995-12-27 | 2003-03-04 | Trex Company, L.L.C. | Apparatus for making a wood-plastic profile |
US20040253027A1 (en) * | 2003-06-10 | 2004-12-16 | Canon Kabushiki Kaisha | Heating apparatus and image heating apparatus |
US20050218279A1 (en) * | 2004-04-01 | 2005-10-06 | Cicenas Chris W | Methods and apparatuses for assembling railings |
US20050266210A1 (en) * | 2004-06-01 | 2005-12-01 | Blair Dolinar | Imprinted wood-plastic composite, apparatus for manufacturing same, and related method of manufacture |
US20070134478A1 (en) * | 2003-12-20 | 2007-06-14 | Corovin Gmbh | Polyethylene-based, soft nonwoven fabric |
US7410687B2 (en) | 2004-06-08 | 2008-08-12 | Trex Co Inc | Variegated composites and related methods of manufacture |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3003136A1 (de) * | 1980-01-29 | 1981-07-30 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zum herstellen von thermisch stabilen, metallischen schichten |
JPS60139821A (ja) * | 1983-12-28 | 1985-07-24 | Katsutoshi Aoki | 炭素繊維紡出装置 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2848737A (en) * | 1952-07-18 | 1958-08-26 | Firestone Tire & Rubber Co | Extrusion die |
US3573092A (en) * | 1968-04-01 | 1971-03-30 | Fansteel Inc | Method for introducing carbon into chemical vapor deposited refractory metal,and resulting product |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595216A (en) * | 1948-06-05 | 1952-05-06 | Du Pont | Spinnerets coated by metal evaporation |
JPS5338326B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-08-26 | 1978-10-14 |
-
1971
- 1971-09-30 DE DE2148773A patent/DE2148773B2/de not_active Ceased
-
1972
- 1972-09-25 CH CH1396472A patent/CH542293A/de not_active IP Right Cessation
- 1972-09-28 IT IT53023/72A patent/IT966085B/it active
- 1972-09-28 FR FR7234418A patent/FR2154706B1/fr not_active Expired
- 1972-09-28 GB GB4485072A patent/GB1387348A/en not_active Expired
- 1972-09-28 NL NL7213169A patent/NL7213169A/xx not_active Application Discontinuation
- 1972-09-29 JP JP47097310A patent/JPS4842119A/ja active Pending
- 1972-09-29 AT AT838972A patent/AT326260B/de not_active IP Right Cessation
- 1972-10-02 US US00293994A patent/US3817680A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2848737A (en) * | 1952-07-18 | 1958-08-26 | Firestone Tire & Rubber Co | Extrusion die |
US3573092A (en) * | 1968-04-01 | 1971-03-30 | Fansteel Inc | Method for introducing carbon into chemical vapor deposited refractory metal,and resulting product |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4137032A (en) * | 1976-09-07 | 1979-01-30 | E. I. Du Pont De Nemours And Company | Corrosion-resistant spinneret |
US4576811A (en) * | 1983-11-03 | 1986-03-18 | E. I. Du Pont De Nemours And Company | Process for adjusting the fiber structure of mesophase pitch fibers |
US6527532B1 (en) * | 1995-12-27 | 2003-03-04 | Trex Company, L.L.C. | Apparatus for making a wood-plastic profile |
US20040253027A1 (en) * | 2003-06-10 | 2004-12-16 | Canon Kabushiki Kaisha | Heating apparatus and image heating apparatus |
US20090133813A1 (en) * | 2003-12-20 | 2009-05-28 | Fiberweb Corovin Gmbh | Method for the manufacture of polyethylene-based, soft nonwoven fabric |
US8420557B2 (en) | 2003-12-20 | 2013-04-16 | Fiberweb Corovin Gmbh | Polyethylene-based, soft nonwoven fabric |
US20070134478A1 (en) * | 2003-12-20 | 2007-06-14 | Corovin Gmbh | Polyethylene-based, soft nonwoven fabric |
US20090136606A1 (en) * | 2003-12-20 | 2009-05-28 | Fiberweb Corovin Gmbh | Device for the manufacture of polyethylene-based, soft nonwoven fabric |
US20050218279A1 (en) * | 2004-04-01 | 2005-10-06 | Cicenas Chris W | Methods and apparatuses for assembling railings |
US20060113441A2 (en) * | 2004-04-01 | 2006-06-01 | Trex Company, Inc. | Methods and Apparatuses for Assembling Railings |
US20060078713A1 (en) * | 2004-06-01 | 2006-04-13 | Trex Company, Inc. | Imprinted wood-plastic composite, apparatus for manufacturing same, and related method of manufacture |
US20050266210A1 (en) * | 2004-06-01 | 2005-12-01 | Blair Dolinar | Imprinted wood-plastic composite, apparatus for manufacturing same, and related method of manufacture |
US7410687B2 (en) | 2004-06-08 | 2008-08-12 | Trex Co Inc | Variegated composites and related methods of manufacture |
Also Published As
Publication number | Publication date |
---|---|
NL7213169A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-04-03 |
GB1387348A (en) | 1975-03-19 |
ATA838972A (de) | 1975-02-15 |
FR2154706B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-08-13 |
FR2154706A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-05-11 |
DE2148773A1 (de) | 1973-04-12 |
IT966085B (it) | 1974-02-11 |
CH542293A (de) | 1973-09-30 |
DE2148773B2 (de) | 1975-07-31 |
JPS4842119A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-06-19 |
AT326260B (de) | 1975-12-10 |
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